Tutorial CHM 138 Chapter 3 :

Concepts of acid-base neutralization

CHAPTER 3 : Concepts of acid-base neutralization
1. Select the a) best and b) poorest electrical conductors from the following solutions. Explain
the reasons for your choices.
0.10 M H2S! 0.10 M "H#
0.10 M $H#$H %ethanoic acid) 0.10 M $&H12& %glucose)
2. How many grams of potassium hydroxide' (H' are re)uired to prepare 2.00 * of
0.2+0 M solution,
#. a) 1+ ml of (H are re)uired to neutrali-e 2+ ml of a 0.2&. M monoprotic acid solution'
i) /i0e an example of an acid that is in0ol0ed in this reaction'
ii) 1rite a balanced e)uation for this reaction'
iii) 1hat is the concentration of the (H solution,
i0) *abel the titration cur0e for the abo0e neutrali-ation reaction.

0.0
b) $alculate the )uantity indicated by the letters a2d.
3H
4
5 %moles6*) 3H
2
5 %moles6*) pH pH
2.+ x10
2#
a
1 x1 0
2!
b
c 7..
d 12.+
!. /i0en &.2# 8 10
22
molecules of $&H12&' determine
a) the number of H atoms in the compound.
b) molarity of $&H12& if dissol0ed in 1+0 m* of distilled water.
1
a
e
f
d
c
b
Tutorial CHM 138 Chapter 3 :
Concepts of acid-base neutralization
+. $alculate the pH of
i) 0.#2 M "aH
ii) 0.2+0 MH2S0!
!. 9raw the titration cur0e for the reaction between 2+.00 m* of 0.#+ M "aH and 0.2+ M
hydrochloric acid solution. *abel all important information.
&. :)ueous solutions of calcium hydroxide' $a%H)2' and phosphoric acid' H#;!' react to gi0e
calcium phosphate' $a#%;0!)2' and water. <he calcium phosphate precipitates from solution.
1rite a balanced o0erall chemical e)uation for this reaction.
.. a) State the =ronsted2*owry definition for acid and base.
b) >dentify the acid2con?ugate base pairs in the e)uation below.
H2$# 4 "H# H$#
2
4 "H!
4
@. a) 2+.0 cm
#
0.1 mol dm
2#
' H2S! is titrated with 0.1 mol dm
2#
(H.
i) 1rite a balanced e)uation for the abo0e acid2base reaction.
ii) 1hat is the pH of the solution before (H was added.
iii) $alculate number of moles of base used in the abo0e titration.
i0) SAetch a titration cur0e for the abo0e reaction and label any significant points.
b) 9efine the following and gi0e one example for eachB
i) Electrolyte'
ii) "onelectrolyte.
7. $alculate the pH of the following solutionsB
a) 0.0+1 M =a%H)2
b) 0.22 M H"#
10. <o determine the molar mass of a strong acid' H:' 1.0+& g of H: was dissol0ed in
2+.00 m* of distilled water and was titrated with "aH.
i) $alculate the molar mass of H: if the acid' H:' reacts with ##..@ m* of 0.2+&M "aH.
ii) $alculate the molarity of the strong acid' H:.
iii) 9raw the titration cur0e for the abo0e reaction.
11. 1hat is the molarity of 1.++ g (Mn! dissol0ed in a +00 m* flasA,
12. : solution is prepared by dissol0ing 2!.+ g of H2S! in enough water to maAe @00.0 m* of
solution.
i) $alculate the molarity of H2S! in the solution.
ii) >f 20.0 m* of the acid solution was transferred in a conical flasA and was titrated with
(H' calculate the molarity of the (H solution if #0.1+ m* of the (H%a)) was needed
to reach the e)ui0alence point.
iii) SAetch the titration cur0e for the reaction in )uestion %ii).
i0) >f +0.0 m* of the H2S! solution is mixed with 100 m* of H2' what would be the
molarity and the pH of H2S! in the diluted solution,
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Tutorial CHM 138 Chapter 3 :
Concepts of acid-base neutralization
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