Ductile Iron is 4-12 times tougher than gray cast iron and so ductile that it can be bent and twisted without breaking. The material is produced by treating molten iron with a "small but adequate" amount of magnesium. Today, 16 million tons are produced each year worldwide, representing nearly onethird of all u.s. Casting shipments.
Ductile Iron is 4-12 times tougher than gray cast iron and so ductile that it can be bent and twisted without breaking. The material is produced by treating molten iron with a "small but adequate" amount of magnesium. Today, 16 million tons are produced each year worldwide, representing nearly onethird of all u.s. Casting shipments.
Ductile Iron is 4-12 times tougher than gray cast iron and so ductile that it can be bent and twisted without breaking. The material is produced by treating molten iron with a "small but adequate" amount of magnesium. Today, 16 million tons are produced each year worldwide, representing nearly onethird of all u.s. Casting shipments.
The inherently strong structure of this relatively new and versatile metal makes it an ideal choice for automotive and other high-performance castings. excerpted from material provided by the Ductile Iron Marketing Group I n 1948, ductile iron was first unveiled to the engineering world. Treatment of molten iron with a small but adequate amount of magnesium causes the graphite to precipitate as spheroids, rather than flakes as in gray cast iron, giving the material an inherently stronger structure. The material is 4-12 times tougher than gray cast iron and so ductile that it can be bent and twisted without breaking. The new ductile iron family bridged the gap between gray iron and steel, of- fering the processing advantages of gray ironlow melting point, good fluidity and castability, and ready machinability combined with many of the engineering advantages of steelhigh strength, duc- tility and wear resistance. Strength at Less Expense Whether in an automobile component or a water pipe, ductile iron has made major inroads in every industrially devel- oped country. Today, 16 million tons of ductile iron castings are produced each year worldwide, representing nearly one- third of all U.S. casting shipments. The motivating factor for using this metal is the opportunity for greater strength at less expense. Other reasons to select duc- tile iron include its reliability in service, vi- bration damping and surface hardenability. In addition, since the modulus of elas- ticity of ductile iron is somewhat lower than that of steel, the stresses due to unavoidable misalignment in parts such as gears will re- sult in lower bending fatigue strength. While not all foundries produce all ductile iron grades, virtually all castings or cast shapes can be made from an appro- priate grade of ductile iron. The Ductile Iron Family The majority of ductile iron castings are produced in one of the following three types, which do not require heat treat- ment. The parenthetical information rep- resents the common notation for grades, and the three numbers express tensile strength in pounds per square inch, yield strength and percent elongation (mini- mum 2 in.), respectively: ferritic ductile iron (60-40-18) Composed of graphite spheroids in a ferrite matrix (basically pure iron), this grade exhibits high impact resis- tance, relatively good thermal conduc- tivity, high magnetic permeability, low hysteresis loss, and good machinabil- ity and corrosion resistance; pearlitic-ferritic ductile iron (80-55- 06)Composed of graphite sphe- roids in a mixed matrix of ferrite and pearlite, this grade is probably the most common and least expensive grade of ductile iron, exhibiting properties between those with fully ferritic or fully pearlitic structures, including good machinability; pearlitic ductile iron (100-70-03) Composed of graphite spheroids in a matrix of pearlite (a fine aggregate of ferrite and cementite), this grade is relatively hard, displaying moderate ductility, high strength, good wear Metals Focus Because the graphite in ductile iron pre- cipitates as spheroids rather than flakes, as in gray iron, they act as crack arrest- ers, allowing the metal to bend without breaking. Shown above is a ductile bar machined flat from a casting and a simi- lar bar that has been twisted, illustrating the irons exceptional ductility. Ductile iron is versatile enough to be used in a variety of applications from this 52-ton turbine casting used in hydro power generation (l) to this assortment of fairly intricate truck parts. 167 This graph shows the tensile and hardness properties of ductile iron con- forming to different grades of ASTM Specification A536. resistance, moderate impact resistance, somewhat reduced thermal conductiv- ity, low magnetic permeability, high hysteresis loss and good machinability. The designer also may encounter special situations that call for the special grades of ductile iron alloys: austempered ductile iron (ADI)This re- cent addition to the ductile iron family of- fers a remarkable combination of strength, toughness and wear resistance. ADI is almost twice as strong as the regular ASTM grades of duc- tile iron while still re- taining high elonga- tion and toughness characteristics. In addition, ADI of- fers exceptional fatigue strength, enabling designers to reduce com- ponent weight and costs. A closely controlled heat treatment operation (austempering) develops a unique matrix structure of bainitic ferrite (60%) and retained (high carbon) austenite. The retained austenite is thermally stable to extremely low tem- peratures but is work hardenable and will locally transform to martensite under suitable conditions of stress; martensitic ductile iron (quenched and tempered)In the as-cast con- dition the alloy is hard and brittle and seldom used, however, tempered mar- tensite has very high strength and wear resistance. A 930F (500C) tempering results in 300 Bhn and 1110F (600C) tempering results in 250 Bhn; austenitic ductile iron (also known as ductile Ni-Resist)The outstanding features of this grade are good cor- rosion and oxidation resistance, magnetic properties, strength and di- mensional stability at el- evated temperatures. Production Familiarizing oneself with ductile iron design advantages helps not only to achieve engineering elegance (uniform stress- flow and optimum economy) but also helps the designer to decide when the use of ductile iron is preferable to an alterna- tive material. The volume changes that occur during the cooling and solidifica- tion of ductile iron are un- like those in any other al- loy. The volume of the liq- uid decreases with decreas- ing temperature until slightly above the solidifica- tion temperature. Upon further cooling, the con- traction stops and a definite volumetric expansion starts. Unfortunately, the expansion phase prevails through only part of the solidification process. The ex- pansion gives way to another contraction phase, secondary shrinkage, which contin- ues until all of the liquid metal solidifies. The liquid iron temperature should be high enough to provide for complete fusion of the separate streams and to avoid the en- trapment of small gas bubbles. Each section thickness has its optimum pouring tem- perature range. Ductile iron castings with 3 mm-thick walls may need to be poured as Table 1. Short Summary of Ductile Iron Specifications Specifying Spec. Class or Min. Min. % Heat Other Uses Typical Body No. Grade Tensile psi Yield psi Elongation Treatment Requirements Applications ASTM A536-80 60-40-18 60,000 40,000 18 May be For maximum Pressure- Annealed shock resistant containing parts to be used castings such at sub-zero as valve & temperatures. pump bodies. ASTM A536-80 65-45-12 65,000 45,000 12 - Most widely used Machinery grade for normal castings service. subject to shock and fatigue loading. ASTM A536-80 80-50-06 80,000 55,000 6 - Suitable for flame Crankshafts, and induction gears and hardening. rollers. ASTM A536-80 100-70-03 100,000 70,000 3 Usually Best combination High strength Normalized of strength, wear gears, resistance and automotive response to surface and machine hardening. components. ASTM A536-80 120-90-02 120,000 90,000 2 Quenched Maximum strength Pinions, gears, and and wear rollers and Tempered resistance. slides. In all grades in this specification, chemical composition is subordinate to mechanical properties. However, the content of any element may be specified by mutual agreement. 1200 1000 800 600 400 200 30 20 10 0 180 200 220 240 260 280 300 160 Tensile strength Yield strength S t r e n g t h ,
M P a E l o n g a t i o n ,
% Hardness, HB 160 120 80 40 100-70-03, air quenched Grace 120-90-02, oil quenched 80-55-06, as-cast 65-45-12, annealed 60-40-18, annealed Grade 60-40-18, annealed 65-45-12, annealed 80-55-06, as-cast 100-70-03, air quenched 120-90-02, oil quenched 168 hot as 2640F (1450C), while 100 mm thick castings can be poured at between 2300- 2400F (1260-1320C). Production complex- ity may increase when large differences in section thickness exist in one casting. There- fore, it is best to design with as little differ- ence in wall thicknesses as possible. Strength Required The grade of ductile iron selected will have a considerable effect on cost. Grade 65-45-12 is one of the least expensive, es- pecially when considering machining costs. Pearlitic-ferritic costs approximately the same to cast but is somewhat less ma- chinable. Pearlitic is still relatively inexpen- sive and should be selected where its high strength and good wear resistance are needed. Ferritic and martensitic grades can be the most expensive to cast, but they may be the most economical choice if the par- ticular material characteristics are impor- tant. The evaluation of the higher cost aus- tenitic grades must be considered indi- vidually on the basis of their excellent cor- rosion, erosion and oxidation resistance, performance at elevated temperatures, magnetic properties, low thermal expansivity and other unique features. Machining Cost Strength, weight, service life and other considerations may be overruled on occasion to minimize machining cost. The grades easiest to machine are pearlitic and martensitic, followed by austenitic and pearlitic-ferritic. The ma- chinability of ferritic is superior to steel with the same hardness, and the machin- ability of austenitic ductile iron is generally superior to that of stainless steels. Wall Thickness In terms of wall thickness, 6 mm-or-heavier sections are relatively easy to produce. Thinner walls are increasingly difficult to produce without de- terioration in the as-cast con- dition. Brittleness and high hardness can be eliminated through heat treatment, but this is expensive and results in distortion to various degrees. Whenever practical, cast wall thickness should be at least 6 mm to facilitate as-cast deliv- ery. Otherwise, heat treatment may be required, increasing casting cost by 10-30%. This graph shows the relationships between endurance ratio, tensile strength and matrix microstructure for ductile iron. The fatigue strength of a material is related to its tensile strength by an endur- ance ratio, or the ratio of a fatigue limit to tensile strength. Casting Soundness Unlike most other alloys, the designer should aim at simultaneous solidification of the whole casting. This minimizes and sometimes eliminates the need for risers while improving casting yield. Conversely, parts of a ductile iron casting that cool much slower may require additional feeding. Some examples of such isolated hot spots are: cast-on heavy bosses; cast-on heavy test coupons; sharp internal corners; joints between equally thick walls; multiple joints (2 is better than 3, 3 is better than 4, etc.); joints at acute angles (90 is best); isolated heavy sections. Dimensional Accuracy With the exception of dimensional prob- lems caused by patterns and coreboxes, gen- erally the larger the casting the wider the tol- erances that can be expected. To minimize costs, designers should strive to specify no more dimensional accuracy than what is absolutely needed. Dimensional inaccuracies from mold deformation during pattern withdrawal are minimized through proper tapering (draft) of the pattern. A minimum draft of 1:100 suffices only for very shallow patterns. Deep patterns may require as much as 5:100 for maximum accuracy. Mechanical Qualities The effect of section size on proper- ties is the result of changes in micro- scopic structure, which is influenced by cooling rate. Three prominent effects of cooling rate are: very high cooling rates may not per- mit all the insoluble carbon to pre- cipitate in the form of spheroidal graphite. Instead, various amounts of a hard and brittle component, iron carbide (Fe 3 C), may form; very slow cooling can result in large-diameter, irregularly shaped spheroids of graphite up to 1.5 mm in diameter; varying the cooling rate in the 1560-480F (850-250C) tempera- ture range from very fast to very slow produces different structures from martensite (very fast cooling) through pearlite, pearlite-ferrite to all ferrite (slow cooling). For design calculations, the engi- neer must request test castings that will cool at approximately the same rate as the final product. Mechanical tests on these castings will yi el d t he most accurat e prediction of properties. The presence or absence of carbides and the type of matrix obtained in any given section can be controlled by alloying or heat treatment. The size of the spheroidal graphite, on the other hand, can be influenced by, among other things, the cooling rate of the casting, which in turn can be deter- mined by the shape or design of the casting. Safety-Critical Applications Both automobile steering knuckles and plow-shares are often made in ductile iron, even though these castings 0.5 0.4 0.3 E n d u r a n c e
r a t i o 60 100 140 160 Tensile strength, 1000 psi Pearlitic Ferritic 300 500 700 900 1100 1300 Tensile strength, MPa Tempered Martensite This ductile iron roller bracket, used on a large cement truck, replaced a nine-piece steel weldment. The 12 x 12 x 8-in., 27- lb casting was made by The Dotson Co. Mankato, Minnesota, in grade 80-55-06 ductile iron using the green sand pro- cess. Per part savings were approxi- mately $15, and with an annual usage of 8000 components, the customer achieved an annual savings of $120,000. 169 Ductile Iron Data for Design Engineers, Rio Tinto Iron & Titanium, Chicago, IL (1990). Design of Ferrous Castings, American Foundrymens Society, Des Plaines, IL (1984). A Design Engineers Digest of Ductile Iron, 7th Edition, Rio Tinto Iron & Titanium, Montreal, Quebec, Canada (1990). A Tribute to Keith Millis and the Unveiling of Ductile Iron 50 Years Ago, p. 33-66, modern casting, Des Plaines, IL (Oct. 1998). have different safety requirements. An en- gineer must design with a degree of re- quired safety in mind, and a foundry must cast a quality component to meet those re- quirements. Safety requirements, however, must be applied judiciously, because in- creasing part safety invariably increases cost. The available controls include: approximating the ultimate load car- rying capacity of the material to vari- ous predetermined degreesUnder static loads, the maximum permissible stress equals the yield strength. Usual design stresses vary from 50-75% of the yield strength (0.2% offset proof stress). Parts exposed to frequently varying loads should be designed so as not to exceed the maximum endur- ance limit for a particular stress level. Design stresses of 50-100% of the en- durance limit are customary, corre- sponding to a very high and low mar- gin of safety, respectively; estimating the effect of potential emer- gency overloads involves the determi- nation of the most likely failure mechanismExcessive static or dy- namic loads may cause failure either through deformation of the part or by fracture. Depending on the use, one failure mechanism will prove to be safer than the other. For example, in a pressure-tight container a major in- crease in the internal pressure may burst or deform the casting. A perma- nent deformation will probably be the safer failure mechanism. Dont indis- criminately use the high-ductility grade (ferritic). Pearlitic-ferritic can withstand 70-80% higher loads; Grade 120-90-02 can withstand 2.5 times more load, either static or dy- namic, than ferritic. Beyond these lim- its, grades 120-90-02, 100-70-03 and 80-55-06 will fail through fracture while grade 65-45-12 and ferritic will fail through permanent deformation under much lighter loads. Trust the Foundry Foundries producing ductile iron are well aware of choices in manufacturing pro- cesses, the effects of chemical composition and heat treatment, and the in-plant con- trols necessary to produce a casting. Deci- sions regarding fine details affecting economy and performance require a better understanding of the casting process and the foundry involved. Its best to meet with the foundryman during the design of the raw or ideal part. Engineers may even be able to see some good examples of castings simi- lar to what they require. For a free copy of this article circle No. 339 on the Reader Action Card. For More Information 170
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