Cement - Notes for AL Tech by Hafeel Sir
AL-Mubarak Malwna Engineering for Technology Unit 1 - Introduction notes By :- Eng. A.A.HAFEEL AHAMED BSc(Hons)(Eng)(AMIESL)(1st Class Honor)
Cement - Notes for AL Tech by Hafeel Sir
AL-Mubarak Malwna Engineering for Technology Unit 1 - Introduction notes By :- Eng. A.A.HAFEEL AHAMED BSc(Hons)(Eng)(AMIESL)(1st Class Honor)
Cement - Notes for AL Tech by Hafeel Sir
AL-Mubarak Malwna Engineering for Technology Unit 1 - Introduction notes By :- Eng. A.A.HAFEEL AHAMED BSc(Hons)(Eng)(AMIESL)(1st Class Honor)
BSc(Hons)(Eng)(AMIESL)(1st Class Honor) Portland Cement By definition a hydraulic cement produced by pulverizing clinker consisting essentially of hydraulic calcium silicates, usually containing one or more of the forms of calcium sulfate as an interground addition Source: PCA, 2003 Raw Materials Necessary for Portland Cement Manufacture Must Provide the Following Calcium Silica Alumina Iron Calcium Iron Silica Alumina Sulfate Alkali waste Aragonite Calcite Cement-kiln dust Cement rock Chalk Clay Fullers earth Limestone Marble Marl Seashells Shale Slag Blast-furnace flue dust Clay Iron ore Mill scale Ore washings Pyrite cinders Shale Calcium silicate Cement rock Clay Fly ash Fullers earth Limestone Loess Marl Ore washings Quartzite Rice-hull ash Sand Sandstone Shale Slag Traprock Aluminum-ore refuse Bauxite Cement rock Clay Copper slag Fly ash Fullers earth Granodiorite Limestone Loess Ore washings Shale Slag Staurolite Anhydrite Calcium sulfate Gypsum Source: PCA, 2003 Traditional Manufacture of Portland Cement 1. Stone is first reduced to 125 mm (5 in.) size, then to 20 mm (3/4 in.), and stored. Source: PCA, 2003 2. Raw materials are ground to powder and blended. or 2. Raw materials are ground, mixed with water to form slurry, and blended. Source: PCA, 2003 3. Burning changes raw mix chemically into cement clinker. Source: PCA, 2003 Source: Mindess, Young, and Darwin, 2004 Source: Mindess, Young, & Darwin, 2004 3. Burning changes raw mix chemically into clinker. Note four stage preheater, flash furnaces, and shorter kiln. Source: PCA, 2003 Pyro- Processing Source: PCA, 2003 4. Clinker is ground with gypsum into portland cement and shipped. Source: PCA, 2003 Clinker Gypsum Source: PCA, 2003 Grinding Clinker is ground with gypsum (calcium sulfate) to produce portland cement Fine grinding is necessary for high early strength 85-95% -325 mesh (45 microns) ~ 7 trillion particles per pound Gypsum absorbs water and prevents setting of C 3 A during shipment Source: van Oss and Padovani, 2002 Process of Clinker Production Source: PCA, 2003 Source: PCA, 2003 Source: PCA, 2003 Source: Taylor, 1997 Source: MacLaren and White, 2003 Source: MacLaren and White, 2003 Clinker Phases Alite or 3CaOSiO 2 or C 3 S Hydrates & hardens quickly High early strength Higher heat of hydration (setting) Belite or 2CaO SiO 2 or C 2 S Hydrates & hardens slower than alite Gives off less heat High late strength (> 7 days) Modern cements are manufactured to be higher in alite for early strength Clinker Phases Aluminate or 3CaO Al 2 O 3 or C 3 A Very high heat of hydration Some contribution to early strength Low C 3 A for sulfate resistance Ferrite or 4CaO Al 2 O 3
Fe 2 O 3 or C 4 AF Little contribution to strength Lowers clinkering temperature Controls the color of cement Microscopic Images of Clinker Microscopic Images of Clinker Alite Microscopic Images of Clinker Belite Microscopic Images of Clinker Aluminate Microscopic Images of Clinker Ferrite Types of Portland Cement I Normal II Moderate sulfate resistance III High early strength IV Low heat of hydration V High sulfate resistance ASTM C 150 (AASHTO M 85) Source: Mindess, Young, and Darwin, 2004 Source: Mindess, Young, and Darwin, 2004 Source: Mindess, Young, and Darwin, 2004 Source: Mindess, Young, and Darwin, 2004