,

CHEMISTY
FORM 5
RATE OF REACTION 18 Januari 2011
Exercise 1 :
1. The table shows the total volume of gas collected at regular time intervals in a reaction.
Time (s) 0 30 60 90 120 150 180
Volume of gas
(cm
3
) 0.00 12.50 19.70 24.60 28.70 31.50 31.50
What is the average rate of reaction in the second minute ?
2. The diagram shows the graph of total volume of hydrogen released against time for a reaction
between hydrochloric acid and excess zinc.
olume of gas !cm
"
#

v$2
2% &% '% (% time !s#
Which of the following statements can be deduced from the graph ?
) There is no more hydrochloric acid left at the (% th second.
* The volume of gas produced at the &%
th
second is v$2.
+ The rate of reaction is highest at the 2%
th
second.
, The average rate of reaction is v$&% cm
"
s
-1
.
". 2 .2/2 !a0# ------- 2 .2/ !l# 1 /2 !g#
Which of the hydrogen peroxide solutions will liberate oxygen gas at the highest rate ?
Concentration of 2!2 (mol "m#
3
) $ass of manganese (%V) o&i"e a""e" (g)
' 0.2 0.2
( 0.4 0.2
C 0.6 0.4
) 0.8 0.4
&. The rate of reaction between calcium carbonate and sulphuric acid decreases with time because
) 2roduct of reaction increases
* 2ressure of the reaction decreases
+ temperature of sulphuric acid decreases
, concentration of sulphuric acid increases
Exercise 2 :
a!er "
1. )n experiment was carried out to investigate the rate of reaction between 3.% g of zinc granules
and 3% cm" of %.2 mol dm-" of hydrochloric acid. The volume of hydrogen produced was
measured by displacement of water in a burette as shown in ,iagram 1.
,iagram 1
!a# ,iagram 2 shows the burette readings at "% second intervals. 4ecord the burette
readings in the spaces provided.
,iagram 2
5' mar6s7
!b# .ow can the total volume of gas collected for each "% second interval be calculated ?
5" mar6s7
!c# +alculate the total volume of gas collected for each "% second interval. +onstruct a
table to record all the burette readings and the volumes of gas collected in the
experiment.
5" mar6s7
!d# 8tate the operational definition of the rate of reaction based on this experiment.
5" mar6s7
!e# 8tate three factors that can affect the rate of this experiment.
5" mar6s7
!f# 2lot a graph of volume of gas in cm" produced against time in seconds on the graph
paper.
5" mar6s7
!g# 9se the graph in !f# to calculate the rate of reaction at :% seconds. 8how on the graph
how you determine this rate of reaction.
5" mar6s7
!h# .ow does the rate of reaction change with time in this experiment ? ;xplain this
change of rate.
5" mar6s7
!i# 86etch the curve you would expect to obtain on the graph in !f# if the experiment is
repeated using 3.% g of zinc powder and 3% cm " and %.2 mol dm-" of hydrochloric
acid.
5" mar6s7
!<# 8uggest another method to measure the volume of hydrogen gas produced in this
experiment other than by using displacement of water in a burette.
5" mar6s7
TOTA# MAR$S : "" %ar&s
!6# 2lot a graph of volume of gas in cm" produced against time in seconds on the graph
paper.
5" mar6s7
!l# 9se the graph in !f# to calculate the rate of reaction at :% seconds. 8how on the graph
how you determine this rate of reaction.
5" mar6s7
!m# .ow does the rate of reaction change with time in this experiment ? ;xplain this
change of rate.
5" mar6s7
!n# 86etch the curve you would expect to obtain on the graph in !f# if the experiment is
repeated using 3.% g of zinc powder and 3% cm " and %.2 mol dm-" of hydrochloric
acid.
5" mar6s7
!o# 8uggest another method to measure the volume of hydrogen gas produced in this
experiment other than by using displacement of water in a burette.
5" mar6s7
TOTA# MAR$S : "" %ar&s
)nswer
1. )
2. )
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