Collin Jeremiah R.

Balayan 2013 - 14713

Answers to Questions
Experiment 1

1. For solutes that are dissolved because of intermolecular attractions with the solvent, state the
intermolecular forces of attraction involved.
Acetone + water - LDF, H-bond Acetone +Diethyl ether - LDF, dipole-dipole
Ethanol + water - LDF, H-bond Ethanol + Diethyl ether - LDF, dipole - dipole
Sucrose + water - LDF, H-bond

2. For solutes that are dissolved because of reaction with the solvent, write the balanced equation
involved.
A. C6H5COOH + NaOH ----> NaC6H5COO + H2O
B. none
C. none
D.
E.
F. none
G. C6H5OH + NaOH ----> NaC6H5O + H2O
H.C6H5NH2 + HCl ----> C6H5NH3(+) + Cl(-)
I. none
J. none
K. none
L. none
3.. On the basis of solubility behavior, determine the best solvent to differentiate the following
pairs of compounds
a. CH3COOH and CH3(CH2)5COOH - Diethyl ether
b. CH3CH2OCH2CH3 and CH3CH2OH - NaOH
c. toluene and benzaldehyde - concentrated H2SO4
d. tert-butyl chloride and tert-butanol - H2O
Compound Structure
Functional Groups
Benzoic acid
Arene, Carboxylic acid, alkane
Tert-butyl chloride
Halide, alkane
toluene
Arene, alkane
Benzaldehyde
Arene, alkane, aldehyde
Benzyl alcohol
Alcohol, alkane, arene
Acetone
Alkane, ketone
Phenol
Arene, alcohol
Aniline
Arene, amine
Hexane
Alkane
Benzamide
Amide, arene, alkane
Ethanol
Alcohol, alkane
sucrose

http://www.uobabylon.edu.iq/eprints/publication_10_5343_904.pdf