Croda Europe Ltd 2009.

All Rights Reserved

Speciality Rolling Oil
Components
Croda Europe Ltd 2009. All Rights Reserved
Steel Rolling - Aims
Cooling
Control and filterability of iron fines
Tramp oil rejection
Emulsion stability/particle size control
Clean burn annealing characteristics
Corrosion inhibition
Controlled lubrication
Minimise roll wear protect surface roughness
Reduce wear of metal surface reduce iron fines generation
Reduce mill loads and power consumption
Control mill chatter and vibration
Croda Europe Ltd 2009. All Rights Reserved
Basic Chemistry Types
Brand Chemistry Formulation Effect Extra Features
Priolube Ester Lubricity Clean Burn
Pripol Dimer Acids Lubricity Lubricity Boost
Crodasinic Sarcosine Corrosion Prevention Temporary protection
Hypermer Polymeric
Surfactant
Emulsion Stabilisers Droplet Size Control/Stability
Tramp oil Rejection
Synperonic
Atlas
Surfactant Emulsion Formers
Wetting Agents
Broad Range of HLB
Crodafos
Monalube
Phosphate
Esters
AW Additives Extra Lubrication
Reduces Wear
Croda Europe Ltd 2009. All Rights Reserved
Base Oils Data
Based on a variety of chemistries and can be used for both Tinplate and Sheet rolling.
The esters are manufactured to give controlled and consistent lubrication performance
and to give excellent post-anneal cleanliness.
Product Description
SAP Value
(mgKOH/g)
Acid Value
(mgKOH/g)
Viscosity @
40C (cSt)
Pour Point
(C)
TGA
Inflection
Point (C)*
TGA
Midpoint
(C)**
TGA
Deposits
Falex
Coefficient
of Friction
Falex Load
to Fail
Priolube 1407 Glycerol mono-oleate 170 0.5 84 0 413 388 Trace 0.048 1825
Priolube 1427 TMP tri-oleate 182 1.0 48 -51 441 431 Slight Trace 0.057 1200
Priolube 1451 n-Butyl stearate 172 0.1 6.4 21 280 263 None 0.044 1320
Priolube 1808 TMP coco 242 1.0 35 -1 413 393 None 0.050 1230
Priolube 1921 NPG coco 232 3.0 17 0 347 330 None 0.068 1140
Priolube 2044 TMP monomerate 180 9.0 85 -3 447 429 Slight Trace 0.052 1050
Priolube 3970 TMP C8/C10 310 0.1 20 -51 364 346 None 0.059 1240
Priolube 3971 PE C8/C10 330 0.1 32 -10 399 382 None 0.046 1330
Estol 1540 2EH cocoate 174 0.1 5.4 -24 267 254 None
* Inflection Point is the temperature where the rate of weight loss is at its maximum
** Midpoint is the temperature where the weight loss of the product is 50%
Croda Europe Ltd 2009. All Rights Reserved
Lubricity Booster Data
Dimer acids and complex esters providing excellent lubricity boosting properties.
Complex esters also have the advantage of being cleaner post-anneal.
Product
SAP Value
(mgKOH/g)
Acid Value
(mgKOH/g)
Viscosity @
40C (cSt)
Pour Point
(C)
TGA
Inflection
Point (C)
TGA
Midpoint
(C)
TGA
Deposits
Falex
Coefficient
of Fricti on
Falex Load
to Fail
Priolube 1929 160 0.1 1700 -21 450 435 Trace 0.060 1270
Priolube 1968 180 2 100 5 443 433 Trace 0.065 1210
Priolube 2087 260 0.5 320 -40 436 417 Slight Trace 0.032 1400
Priolube 3986 0.1 47000 446 445 Trace 0.062 1130
Pripol 1017 198 193 2400 -12 455 411 Trace 0.060 1480
Pripol 1022 199 193 1834 -18 452 407 Trace 0.600 1300
Croda Europe Ltd 2009. All Rights Reserved
Emulsifiers
Product Description HLB
Hypermer A70 Polymeric 6
Hypermer B261 Polymeric 8
Atlas G1086 Ethoxylated Sorbitol Ester 10.2
Atlas G1096 Ethoxylated Sorbitol Ester 11.4
Synperonic A Series Ethoxylated Alcohols 5.9 18.3
Synperonic LF/RA Series Alkoxylated Alcohols -
Synperonic PE Series EO/PO Block Copolymers -
Broad range of emulsifiers to optimise particle size and stability
Two or more emulsifiers are used in combination to get the perfect balance
between emulsion spontaneity and stability
Croda Europe Ltd 2009. All Rights Reserved
Emulsifiers Hypermers
Particle Distribution
0.6 1.0 1.5 2.3 3.4 5.2 7.9
1 3 5 10 21 42
Particle size distribution using Hypermer A70
Particle size distribution using Hypermer B261
Unique polymeric emulsifiers that control the particle size and therefore
controls the amount of oil that plates-out on the surface of the strip and the
amount of lubrication.
They are shear stable and resist the formation of multi-modal particle
distributions which lead to irregular lubrication in the roll bite.
Croda Europe Ltd 2009. All Rights Reserved
Emulsifiers Hypermers
Tramp Oil Rejection
0
10
20
30
40
50
60
70
80
0 10 20 30 40 50 60
Ti me (mi ns)
m
l
s
Rol l i ng emul si on Mi xed emul si on Rej ected tramp oi l
Without Hypermer
0
10
20
30
40
50
60
70
80
0 10 20 30 40 50 60
Ti me (mi ns)
m
l
s
Rol l i ng emul si on Mi xed emul si on Rej ected tramp oi l
With Hypermer
Test : Modification of ASTM D1401 Test
These graphs demonstrate that the Hypermer completely rejects the tramp oil.
The unique chemistry of the Hypermers prevents any emulsification of the
tramp oil.
Croda Europe Ltd 2009. All Rights Reserved
Phosphate Esters
Product
4 Ball Mean Wear Scar
(mm)
Falex Load to Fail
Falex Coefficient of
Friction
Monalube 215
0.536 1970 0.054
Crodafos T5A
0.562 1825 0.075
Crodafos N3A 0.464 1770 0.059
Crodafos 2EHAP
0.422 1880 0.065
Crodafos N10A
0.452 2100 0.048
Broad range of products.
Variety of basic chemistries.
Croda Europe Ltd 2009. All Rights Reserved
Wetting Agent/Film Former
Unique and highly effective film former offering significant
benefits to the formulator:
Superior wetting performance
Film consistency between stands
Excellent emulsion distribution in roll bite
Improved mill performance
Standard rolling emulsion
Standard rolling emulsion plus
Synperonic LR/RA30
Croda Europe Ltd 2009. All Rights Reserved
Corrosion Inhibitors
Product Appearance Acid Value
Crodasinic L White waxy solid 202-214
Crodasinic O Clear yellow liquid 154-163
Crodazoline O Liquid n/a
Effective coil protection.
Can be employed in standard form or neutralised form.
Temporary corrosion protection prior to downstream processes.
Easily removed.
Croda Europe Ltd 2009. All Rights Reserved
The information in this publication is believed to be accurate and is
given in good faith but no representation or warranty as to its
completeness or accuracy is made.
Suggestions for uses or applications are only opinions. Users are
responsible for determining the suitability of these products for their
own particular purpose.
No representation or warranty, express or implied, is made with
respect to information or products including without limitation
warranties of merchantability or fitness for a particular purpose or
non-infringement of any third party patent or other intellectual
property rights including without limit copyright, trademark and
designs.
Any trademarks identified herein are trademarks of the Croda group
of companies.
Disclaimer