Escolar Documentos
Profissional Documentos
Cultura Documentos
TAYLOR
NAVAL SHIP RESEARCH AND DEVELOPMENT CENTER
Md. 20084
4Bethesda,
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VV
MATERIALS DEPARTMENT
PAnnapolis
0
U
'-4
April 1.976
'
Report 76-0034
The Naval Ship Research anid Development Center io a U. S. Navy center for laboratory
effort directed at achlevinj imoroved sea and air vehicles. It was formed in March 1967 by
merging the David Taylor Modal Basin at Carderock, Maryland with the Marine Enginoiring
Laboratory at Annapolis, Mryland.
Novel Ship Research and Deveiop-ent Center
Bethesa, Md. 20034
0t
TECHNICAL DIRECTOR
61
REPORT ORIGINATOR-OFFICER-IN.CHAAGE
CARDEROCK 05ANNAPOLIS
SYSTCMS
DEVELOPMENT
DEPARTMENT
OF FICER-IN.CHARGIF
0
STRUCTURES
DEPARTMENT
17
COMPUTATION
AND MATHEMAATICS
DEPARTMENT
SHIPACOUTICSPROPULSION AND
AUXILIARY SYSTEMS
SHIPACOTICST
19
MATERIALS
DEPARTMEN~T
DEPARTMENT
27
*CENTRAL
INSTRUMENTATION
28
DEPARTMENT
UNCLASSIFIED
SECURITY CLASSIFICATION OF THIS PAGE (When Date, Entered)
SEAWATER CORSO
_VAR:IOUS
READ INSTRUCTIONS
STRUCTURAL
3. RECIPIENT'r*
Research 10evelopment~ti
FFSEESIN
MATERIALS,
_____________
AUTHOR(*)
Harvey P. Hack
9
4,1714-WokUit1-1_-352
CONTROLLING OFFICE
11
Apri 10767
1S
ot
Unclassified
IS&.
'6
it
DECL.\SSIFICATION/0OWNGRADING
SCHEDULE
17
DISTRIBUTION
STATEMENT (of the ahstract entered In Block 20, itdifferent from Report)
18
SUPPLEMENTARY NOTES
19
Seawater corrosion
Structural materials
Constant-immersion exposures
Panel materials
O
0
Bolt materials
Sealant material
UNCLASSIFIED
UNCLASSIFIED
-1
20.
--
Abstract
(Cont)
Results of the
ealant material was Coast Pro-Seal 800/B-2.
For fiber glass structures in constant
study are presented.
saltwater immersion,\"titanium, MP35N, A286, and 316 stainless
steel fasteners with se lant performed well in these tests.
For 5456 aluminum structures in similar environments, use of
a sealant and additional corrosion protection would have been
necessary to minimize corrosion regardless of the bolt material.
IY-130 steel structures in constant immersion performed
adequately with properly sealed titanium, MP35N, A286, 304, or
Only titanium and MP35N
316 stainless steel fasteners.
Use of
fasteners performed well in titanium structures.
MP35N, A286, and 304 stainless steel fasteners for constantly
immersed 17-4PH stainless steel structures would have been
satisfactory only if sealant was not used and if protection had
been provided to the 17-4PH to minimize crevice corrosion.
Additional tests should be performed if different materials are
to be joined or if the service environment is different from
that of these exposures.
(Author)
UNCLASSIFIED
SECURITY CLASSIFICATION OF THIS PAGE(Viben Data Entered)
ADMINISTRATIVE INFORMATION
This work was performed
Work Unit 1153-524, covering
manager for this work is Mr.
and the project managers are
Morton, DTNSRDC (Code 2803).
LIST OF ABBREVIATIONS
corr
crev -- corrosion
crevice
galvanic
intense
micrometers
meters
millimeters
probable
galv
int
)AM
.m
nunm
prob
SS
- stainless steel
0W IUTO AALGLT
ACCESSION
_for
Do
OE
an-o SE A
DollSevtW
3 1T
704
~76-0034i
TABLE OF CONTENTS
Page
ADMINISTRATIVE INFORMATION
LIST OF ABBREVIATIONS
INTRODUCTION
Fasteners
Panels
Sealant
EXPERIMENTAL PROCEDURE
RESULTS AND DISCUSSION
Fiber Glass Titanium and HY-130 Steel Panels
Aluminum Panels
17-4PH Stainless Steel Panels
Bolts in Fiber Glass Panels
Bolts in Aluminum Panels
Bolts in HY-130 Panels
Bolts in Titanium Panels
Bolts in 17-4PH Panels
Small 304 Sample Fasteners from PHM
Joints with Mixed Materials
CONCLUSIONS AND RECOMMENDATIONS
Fiber Glass
5456 Aluminum
HY-130 Steel
i
1
1
2
3
3
3
6
6
6
7
7
8
8
8
9
9
10
10
10
10
Titanium
11
17-4PH Stainless Steel
11
Mixed Materials
11
TECHNICAL REFERENCES
11
LIST OF FIGURES
Figure
1 - Photograph; Bolt Assembly with Sealant,
Before Exposure
Figure
2Photographs; Corrosion Attack on HY-130
Steel Panels
Figure
3 - Photographs; Localized Corrosion Attack on
Aluminum Panels (Bolt Materials as Indicated)
Figure
4 - Photograph; Corrosion Attack on 17-4PH Panels
with Aluminum Bolts
Figure
5 - Photograph; Corrosion Attack on 17-4PH Panels
with Steel Bolts
Figure
6 - Photograph; Corrosion Attack on 17-4PH ?anels
with 304 Stainless Bolts
Figure 7 - Photograph; Corrosion Attack on 17-4PH Panels
with 316 Stainless Bolts
Figure
8 - Photograph; Corrosion Attack on 17-4PH Panels
with A286 Bolts
Figure
9 - Photograph; Corrosion Attack on 17-4PH Panels
with MP35N Bolts
Figure 10 - Photograph; Corrosion Attack on 17-4PH Panels
with Titanium Bolts
Figure 11 - Photograph; Corrosion Attack on 17-4PH Panel
with Small 304 Stainless Bolts
76-0034
ii2
TABLE OF CONTENTS
(Cont)
Titanium Panels
Figure 16 - Photograph; Corrosion Attack on Bolts in
17-4PH Panels
Figure 17 - Photograph; Corrosion Attack on Small 304
Stainless Bolts in 17-4PH Panel
INITIAL DISTRIBUTION
S76-0034
iv
INTRODUCTION
Due to the weight-critical nature of hydrofoil. craft, the
hulls are generally constructed of aluminum. Several materials
have been used or are being considered for strut-foil systems.
These include 17-4PH scainless steel, HY-130 steel, aluminum,
In addition, fiber glass is
mild steel, and titanium alloys.
frequently used for nonstructural fairings.
This unique combination of materials leads to complex problems of fastener selection. Two somewhat interrelated factors
affecting the selection of fastener materials from a corrosion
standpoint are galvanic
compatibility and susceptibility to
uji-ject o
Most papers written on the
crevixe corrosion. 1 2
fastener corrosion emphasize corrosion in marine or industrial
These environments are quite different from
atmospheies. ,'
constant seawater immersion environments. The intensities of
galvanic and crevice corrosion are greater in constant-immersion
Sacrificial
environments than in atmospheric environments.
coatings which can be of great value in limiting corrosion
attack in atmospheric exposures'," are depleted too rapidly to
Thus, evaluation
be of value in constant-immersion exposures.
of the interrelationship between galvanic and crevice corrosion
in fastened assemblies and of the overall compatibility between
various base materials and various fastener materials in macine
environments is best accomplished by means of constant-immersion
This report presents the results
seawater corrosion exposures.
of such a set of exposures and makes recommendations regarding
the selection of fastener materials from a corrosion standpoint
for specific structure/material combinations.
MATERIALS
FASTENERS
Aluminum alloy 2024-T4 hex head fasteners, 1/4 - 20 x
1 1/2 inches (40 mm),* were supplied by ITT Harper Company, Inc.
These were subsequently cut to 1-inch (25-mm) length and threaded
up to the head to obtain the standard size 1/4 - 20 x 1 inch
(25 mm) used for the test.
Anodized ASTM grade 5 steel hex head fasteners, 1/4 - 20 x
1 inch (25 mm), were obtained from GSA (stock No. 5305-225-3840)
Passivated stainless steel. hex head bolts of types 304 and 316
in this size were also furnished by ITT Harper Company, Inc.,
and A286 stainless steel fasteners in this size were obtained
from Standard Pressed Steel Company.
'Superscripts reter to similarly numbered entries in the Technical References at the end of the text.
*Definitions of abbreviations used are given in page i.
76-0034
Nominal Compositions
Fasteners
Aluminum
A12024
Stainless steels
Type 304
Type 316
A286
Titanium
Ti6-4
Multiphase
MP35N
Steel
Aluminum
A15456
Low alloy steel
IIY-130
Stainless steel
17-4PH
Titanium
Ti6-4
PANELS
The test panels weie made from 1/4-inch (6-mm) thick
fiber glass type G-10, aluminum alloy 5456-11117, HY-130 steel,
titanium-6Ai-4V, and 17-4PH-H950 stainless steel. The 17-4PH
76-0034
part, room-temperture-curing, flexible, synthetic rubber sealant (polysulfide base) without corrosion inhibitors, which has
the panel, a 450 taper was added to the hole on the side of the
This was necessary to
panel which would contain the bolt head.
provide clearance for the short section of shank under the bolt
ji,
panels except those made of HY-130 and all bolts except those
The
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76-0034
each panel had only one major area of attack, although in several
cases areas of minor crevice attack or pitting were present on
the same plate.
The relative position of the bolt material in the electromotive series did not appear to have any significant effect on
the intensity, location, or probability of attack. In one
instance the corrosion appeared to initiate at the crevice
formed by an aluminum bolt. The use of the sealant seemed to
have the effect of establishing a better crevice, thereby
increasing the extent of the attack under the sealant.
Photographs of the side of the panels which contained the
bolt head are presented as figures 4 through 10. The upper photographs are the panels where no sealant was used, and the lower
photographs are the panels where sealant was used. In several
instances the attack at the bolt hole clearly delineates the
areas where the sealant was in contact with the plate. Also
present in some panels were areas of localized attack which
were not associated with the fasteners.
Figure 11 is a photograph of the 17-4PH panel with the
small 304 stainless steel sample fasteners from PHM. The attack
on this panel was confined to only two bolt holes (marked with
arrows) arid a small area near the edge, in spite of the number
of crevices present. In addition, the intensity of attack did
not appear as great as the panels with the large 304 stainless
steel bolts (figure 6).
BOLTS IN FIBER GLASS PANELS
Figure 12 shows the corrosion attack on the bolts from the
fiber glass panels. The aluminum bolts experienced pitting in
the threads, especially at the cut end of the bolt,and intense
pitting of the head of the bolt applied with sealant. Both
steel bolt3 experienced a mild general attack, with some protection afforded under the sealant. The 304 stainless steel bolts
suffered mild crevice attack which was somewhat reduced near the
bolt head where sealant had been used. The 316 and A286 bolts
suffered a mild crevice attack which amounted to only a slight
etching. Use of the sealant completely eliminated this attack,
however MP35N and titanium bolts were unaffected by the
exposure.
BOLTS IN ALUMINUM PANELS
Bolts in the aluminum panels, illustrated in figure 13, all
received adequate galvanic protection to eliminate all corrosion
attack with one exception. The aluminum bolt applied with sealant experienced intense pitting on the exposed threads. This
was not expected, as 2024 aluminum is slightly cathodic to 5456
aluminum in seawater.
76-0034
76-0034
76-0034
76-0034
10
TITANIUM
Bolt sealant is not necessary to mitigate corrosion in
bolted titanium structures. Its use appears to have no significant effect on the corrosion behavior of the fasteners. Titanium
and MP35N are the only fasteners tested that are recommended
for this application. The A286 and stainless steel fasteners
would suffer serious pitting and crevice corrosion in this
application, whereas the steel and aluminum fasteners would
suffer serious galvanic attack.
17-4PH STAINLESS STEEL
Use of a sealant material on 17-4PH stainless steel structure's is definitely contraindicated. The sealant tends to
establish a tighter crevice, increasing the likelihood of
crevice corrosion on the structure. Unless the entire structure is well painted, use of aluminum or steel bolts is not
recommended due to their high rate of galvanic attack, and use
of 304 stainless steel is undesirable due to extensive crevice
corrosion of the fasteners. Use of A286, 316 stainless steel,
MP35N, and titanium is favored from the viewpoint of fastener
corrosion; however, some means of corrosion protection is
necessary to prevent crevice attack of the structure.
MIXED MATERIALS
MP35N and titanium bolts did not experience any corrosion
attack in any material tested and should therefore not corrode
in a structure having a mixture of the panel materials tested.
The effects of these bolt materials on the structural materials
in a mixed joint are not known.
Listings of fastener material recommendations for mixed
material joints are available.' These listings should be used
only with caution, however, since many factors can exert significant influence on the corrosion behavior of fastened assemblies.
TECHNICAL REFERENCES
1 -"ITT Harper Fastener Guide for the Marine Industry," Technical Bulletin 109, ITT Harper, Inc., Morton Grove, Ill.
(1973)
2 - "ITT Corrosion Resistant Fasteners from Harper," Technical
Bulletin 114, ITT Harper, Inc., Morton Grove, Ill. (1973)
3 - Taylor, Edward, "Combating Fastener Corrosion in Mechanical
Assemblies," Materials Engineering, p. 30 (Mar 1975)
4 - Taylor, Edward, "Corrosion Compatibility of Fasteners and
Structures," Paper 72, presented at Corrosion/72 (1972)
76-0034
11
Figure 1
Bolt Assembly with Sealant
Before Exposure
-W
General Attack
I i:em (a)
Bolt S;hank Side
Galvanic Attack
Item (b)
Bolt Head Side
Ie
'~'4SELANT
.<
Mt,
Figure 2
Corrosion Attack on HY-1'7O Steel Panels
2024-T4 Al
ANODIZED STEEL
304 STAINLESS
HEAD$V
SIDE
THREAD
SIDEIN4
IT
WI
2024-T4 Al
ANODIZED STEEL
304 STAINLESS
HEAD
SIDE
Z7,
rHREAD
SIDE
76-0034
Figure 3
-Localized
corrosion Attack
WITHOUT 'SEALANT
NLESS
316 STAINLESS
A286 IRON-BASE
TITANIUM
A286 IRON-BASE
MP35N MULTIPHASE
TITANIUM
WITH SEALANT
INES316 STAINLESS
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Figure 12
Corrosion Attack on Bolts in Fiber Glass Panels
(Arrow Indicaties Mechanical Damage)
Ti
With Sealant
Al
Steel
3LA~Ss
-4J6ss
A286
MP35N
Fiqurc -13
Co~rrosion Attack on Bolts in Aluminum Pan(-ls
Ti
Wi thou t Sealaunt
With
A]
S t c("
3JASS
Sj(-,lant
31 6SS
IF'i(JUrCC
A2 6
mP35N
Ti
Wi thOLt. Seal1ant
Missing
with scalant
missing
S t-!(.
Corro):iion
3otss
316SS
Ficjure 15
Attack on I3olts in
APc36
MP35N
Titanium Panels
Ti
WILlhout
Sealant
w It f
Iant
missing
sea
isn
M~issing
'.1
t'e
3's
Corros~ion Attack
6ss
on Boltii
mP35N
in
1(-IPII Tancl~s
Ti
Withou. Sealant
With Sealant
Figurc J.'
Corrosion Attack on Small 3U4 Stainless
Bolts in 1'(-4PH Panel
(Arrow Indicates Mechanical Damage)
INITIAL DISTRIBUTION
Copies
9
2
12
CENTER DISTRIBUTION
NAVSEA
1 (SEA
2 (SEA
1 (SEA
1 (SEA
2 (SEA
1 (PMS
1 (PMS
Copies
03C)
0322)*
035)
03523)
09632)
303)
304-31C)
Mr. K. Kulju
Standard Pressed Steel Co.
Jenkintown, Pa. 19046
Mr. I. Palmer
Grumman Aerospace Corp.
Marine Dept. 943
Plant 36
Bethpage, N.Y. 11714
Mr. Boczon
Bell Aerospace Co.
P. 0. Box 29307
New Orleans, La. 70129
Addressee.
76-0034, April 1976
1
1
1
1
1
1
3
5
3
2
12
3
1
1
1
30
2
2
2
Code
(115)
(1153)
(1154)
(1158)
(1182)
(1732, Beach)
(173.3)
(2803)
(281)
(2813)
(2813, Hack)
(2814, Czyryca)
(282)
(2841)
(2841, Bohlander)
(5211.4)
(5221)
(5222)
(5231)