Escolar Documentos
Profissional Documentos
Cultura Documentos
www.elsevier.com/locate/fuel
Department of Power Engineering, Harbin Institute of Technology, Harbin 150001, Peoples Republic of China
Department of Chemical & Environmental Engineering, Illinois Institute of Technology, Chicago, IL 60616, USA
Received 9 September 1998; received in revised form 15 February 1999; accepted 28 June 1999
Abstract
A steady state model of a coal-fired circulating fluidized-bed boiler, based on hydrodynamics, heat transfer and combustion, is presented.
This model predicts the flue gas temperature, the chemical gas species (O2, H2O, CO, CO2 and SO2) and char concentration distributions in
both the axial and radial locations along the furnace including the bottom and upper portion. The model was validated against experimental
data generated in a 35 t/h commercial boiler with low circulation ratio. q 1999 Elsevier Science Ltd. All rights reserved.
Keywords: Circulating fluidized-bed boiler; Modelling; Coal combustion
1. Introduction
Circulating fluidized bed combustors (CFBCs) are
considered in some respects to be an improvement over
the traditional methods of coal combustion. Operation of
industrial CFBCs has confirmed many advantages including
fuel flexibility, broad turn-down ratio, high combustion
efficiency, low NOx emissions and high sulphur capture
efficiency. These characteristics assure increasing commercialization of CFBC in power generation applications.
Although CFBC technology is becoming more common,
there are some significant uncertainties in predicting performance in large-scale systems.
Technical knowledge about design and operation of CFBC
is widely available, but little has been done in the field of
mathematical modelling and simulation of combustion in
CFBCs. This might be attributed to the fact that the combustion process occurring in a CFBC involves complex phenomena including chemical reaction, heat and mass transfer,
particle size reduction due to combustion, fragmentation
and other mechanisms, and gas and solid flow structure.
Using a lumped-modelling approach, Weiss et al. [1] and
Arena et al. [2] introduced a CFBC model by dividing it
into several blocks, each corresponding to continuous stirred
tank reactors for both gas and solid phase. Lee and Hyppaueu
[3] presented a CFBC model that considered the riser as a
plug flow reactor for the gas phase and a continuous stirred
tank reactor for the solid phase. The model also considers the
feed particle size distribution and the attrition phenomena.
* Corresponding author.
Weib et al. [4] and Maggio et al. [5] developed a model for
circulating bed reactors including the riser, cyclone, loop seal
and external fluidized heat exchanger. Kudo et al. [6]
proposed a computer program to simulate flow and heat
transfer in a circulating fluidized bed boiler. Radiative heat
transfer is modelled by using a Monte Carlo method.
Sotudeh-Gharebaagh et al. [7] developed a CFBC model
based on ASPEN, and predicted the performances of a
CFBC in terms of combustion efficiency, emission levels.
Park and Basu [8] and Wang et al. [9] introduced a combustion model for CFBCs to characterize the effect of the operating conditions on CFB behaviour. Adanez et al. [10]
proposed a mathematical model for a circulating fluidized
bed coal combustion process. The model considered the
bed to have two regions: a dense zone of constant voidage
and a dilute zone of core-annulus structure. However, most of
the models do not completely take account of the performance of the dense zone. Generally speaking, the particle
size distribution of bed material in a CFB boiler is in a
very wide range. A calculated average particle diameter is
not suitable to represent the behaviour of the total bed particles. The particles will be segregated by their different
diameters and densities. Only the fine particles can be
entrained with flue gas passing through the furnace. Most
of large particles remain in the bottom of furnace. The particle concentrations are much higher in the bottom than in the
upper portion in the furnace. The fluidization regime in the
bottom may be bubbling or turbulent fluidized bed. Leckner
et al. [11] examined this zone and found that it could be
explained by the presence of bubble-like voids. They reported
the height of the dense zone was about 1.0 m from the
0016-2361/00/$ - see front matter q 1999 Elsevier Science Ltd. All rights reserved.
PII: S0016-236 1(99)00139-8
166
2. Modelling approaches
Nomenclature
A
surface area (m)
a
decay coefficient (m 21)
b
dimensionless coefficient
gas concentration (mol)
Cb
concentration in particulate (mol)
Cp
bubble diameter (m)
Db
diffusion coefficient (m 2 s 21)
Dg
d
particle diameter (m)
solid flux (kg m 22 s 21)
Gr
net solid flux (kg m 22 s 21)
Gs
H
heating value (J kg 21);
h
heat transfer coefficient (W m 22 K 21)
mass transfer coefficient (s 21)
kbe
c
kinetic rate (s 21)
k
m
diffusion rate (s 21)
k
ke
coefficient (s 21)
total reaction rate (g mol m 22 s 21)
kr
m
particle mass (m 3)
r
radial coordinate
R
reaction rate (g mol m 22 s 21)
universal gas constant (J mol K 21)
Rg
temperature (K)
Tg
residence time (s)
tr
devolatilization time (s)
tv
ub
bubble velocity (m s 21)
superficial gas velocity (m s 21)
ug
minimum fluidization velocity
umf
vb
bubble volume
z
height (m)
Greek letters
e
voidage
eb
voidage of bubble phase
e mf
voidage at minimum fluidizatiion
f
constant
r
density (kg m 23)
b
fraction of flux
s
StefanBoltzman constant (W m 22 K 24)
distributor in a 12 MW thermal CFB boiler. Montat et al. [12]
also found that the dense zone was characterized by a
bubbling bed, and the bulk density was in the range of 700
1000 kg/m 3 in a 125 MWe CFB boiler. These results imply
that the combustion of coal, particles mixing and heat transfer
in the dense zone dominate the performances of CFB boilers.
In the present work, a steady state mathematical model of
a coal fired CFB boiler has been developed, integrating the
hydrodynamics, heat transfer and combustion which include
the dense zone and dilute region in the furnace. The model
predicts the distributions of the gas concentration, chemical
species, temperature and heat flux along the furnace in both
the axial and radial locations. The model was validated
against experimental data generated in a 35 t/h CFB boiler
of low circulation ratio with wide size distributions.
b12
umf ke
1 2 1b
uo
167
Table 1
Expressions of the overall reaction rate
#
( "
)
X
dCOE 2
1
1 2 1b
dVb 2 ub 1b
1 kbe COB2 2 COE 2 1b 2 COE 2
2
R1;i j 1 R2 1mf 2 2fO2
uo 2 ub 1b
2
dz
dz
i
dCOB2
1
1
dV
2 R2 1b 2 kbe COB2 2 COE 2 1b 1 COE 2 2 COB2 b
Vb
2
dz
dz
E
dCCO
1
uo 2 ub 1b
dz
"
R1;i j 2 R2 1mf 1 2
!
B
E
E
R3;i j 2 fCO 1 2 1b 1 kbe CCO
2 CCO
1b 2 CCO
dVb 2 ub 1b
dz
B
dCCO
1
dV
B
E
E
B
uo 2 ub 1b
dz
("
R2 1mf 2
#
B
E
E
R3;i j 1 2 1b 1 kbe CCO
2 CCO
1b 2 CCO
2
2
2
dVb 2 ub 1b
dz
B
dCCO
1
dV
B
E
E
B
2
R2 1b 2 kbe CCO
2 CCO
1b 1 CCO
2 CCO
b
2
2
2
2
Vb
dz
dz
C1
1
2
CO 1
O2 ! CO :
1
2
O2 ! CO2 :
R1;
1
C R T ;
1=K1c 1 1=K1m O2 g g
K1c 0:667exp216000=Rg Tg ;
R2; K2c CH2 O 1=2 CCO CO2 1=2 ; K2c 1:3 1014 exp230000=Rg Tg ;
1 i 1p 2 1p 2 11 exp20:5aZi21 1 Zi
K1m 4D=dp Rg Tg
K3c 4:1 1010 Rg Tg 21 exp259200=Rg Tg
168
where kr and tr are the total reaction rate of char particles and
the residence time, respectively.
The concentrations of chemical species can be expressed
as a function of the mass combustion rate. Table 1 shows the
reaction model of the dense zone required for simulations
[20].
Dilute region: The particles in the dilute region include
particles coming from the dense zone and recirculated particles from the separator. Only char combustion was considered in the model. It is assumed that particles are sufficiently
separated from each other that the single-particle combustion analysis is valid for each, the temperature of the particle
is uniform, and the particle density remains constant. The
concentrations of the chemical species are given as follows
[14,20]:
"
#
dCO2
1X
1
tg
R j 2 R2 1 2 1s
9a
2 i 1;i
2
dz
"
#
X
X
dCCO
tg
R1;i j 1 2 R3 j 2 R2 1 2 1s
dz
i
i
9b
"
#
X
dCCO2
tg
R3;i j 1 R2 1 2 1s
dz
i
9c
1
2
O2 ! CaSO4
11
where Sg is the specific surface area correlated with calcination temperature given by [21]:
Sg 2384Tg 1 5:6 104
Tg $ 1253 K
12a
Tg , 1253 K
12b
dTf
Af mv;c Hv;c 2 Qv 1 Af hTg 2 Tf
dt
Af s1f Tg4
Tf4
dmH2 O
1 HH2 O
dt
13
dTs
As hTg 2 Ts 1 As s1s Tg4 2 Ts4
dt
14
4h
T 2 Tg
D w
15
where superscripts, z and r, represents axial and radial directions, respectively. Qre and Qrad are energy released from
combustion and radiative heat fluxes to the walls, and D is
the equivalent diameter of the furnace. The convection coefficient, h, is predicted according to the model of Mahalimgam and Kolar [22] for circulating fluidized beds.
The most extensively used model to predict the radiative
properties of spherical particles is the Mie theory. The particles in a CFB combustor that may be assumed as spheres
present typical size parameters x (x pd=l, where d and l
are the particle diameter and wavelength) that do not fall
into the Mie theory [23]. For the cases where particles have
a size parameter x much larger than unity the scattering is
mainly a reflection process and hence can be calculated
from relatively simple geometric reflection relations. The
overall emissivity was computed considering the gases
and particles as a mixture of gray media. The radiative
heat flux to the walls is evaluated by the zone method.
The gas and wall cells are assigned, and the temperature
is assumed to be constant within each cell. The energy
equation for gas cell j is:
X
X
4
4
4
Si Gj sTw;i
1
Gi Gj sTg;i
4KDV sTg;j
2 qh;g;j
16
i
17
C
43.7
41.9
43.0
H
1.8
1.8
1.9
O
3.9
3.9
3.4
N
0.9
1.3
1.5
S
0.6
0.7
0.7
Moisture
8.9
8.6
8.3
Ash
40.0
41.9
41.3
Qnet J/kg
16024
15681
15773
3. Numerical procedure
Coal particles are considered as a discrete number of
sizes. Each particle size is partially burned out in each
passage in the furnace, and its diameter is thus reduced.
The recirculating char particles are considered in the size
classes closer to the diameter at the end of previous passage.
The overall strategy applied to the model can be outlined
in four steps. (1) The solution of the hydrodynamic equations of mass was first obtained by means of the hydrodynamic model. To calculate the size distribution of ash and
limestone in the dense region, it was initially assumed that
the limestone in the dense region had the same distribution
as that of the feed. The mean particle size present in the
dense region was calculated and the hydrodynamic model
was solved. Then, taking into account the distribution of
solids in the recirculation stream, a new particle diameter
in the dense region was determined and the hydrodynamic
model was again solved. This process was iterated until
convergence to the given condition. In the dilute region,
plug flow of gas was assumed, and the particle concentration, size and flow-rate of solids were obtained by means of
the hydrodynamic model. (2) With the size distribution and
concentration values obtained in step 1, the devolatalization
of a coal particle and combustion of the char particle were
computed by making use of the combustion model. The set
of non-linear differential equations governing the combustion model are solved using the RungeKutta method [25].
In the dense region, the oxygen concentration of the input
169
170
transferred by convection. In this case, the gassolid is relatively dense and the convective heat transfer still plays an
important role in the transfer process. For low loadings,
however, computed data showed that radiation transfer
dominates the whole heat transfer process, and the convection component is negligible.
Fig. 6 shows the variations of heat flux with boiler loads.
It can be seen that the heat flux decreases with decreasing
boiler loads. The measured and computed boiler performances are shown in Table 3. The computed circulating
ratio is 4.75, while the design value of the boiler was 3.32
for 100% maximum continuous rating.
Fig. 7 shows the SO2 concentration profiles as a function
of the limestone mean particle size with furnace height. The
smaller particles have higher reactivity than the larger particles, this means a larger capability to absorb SO2 for large
particles in the combustion gas, but their residence time is
low. Considering recirculation, however, the residence time
171
5. Conclusions
A numerical model to simulate two regions with combustion in the furnace of a circulating fluidized bed boiler of
low circulating ratio with wide size distribution was implemented. This model was coupled a model for the dense
region derived from turbulent bubbling bed theory with a
model for dilute region which was a core-annular flow structure. Radiative heat transfer in the dilute region was
modeled by using zone method.
The model allows for the calculation of gas concentration, chemical species, temperature and heat flux along the
furnace. A model for SO2 retention was also included. The
model can now be used to represent a CFBC unit in various
applications but more experimental data are still required to
confirm the proposed CFBC model in order to make it more
comprehensive and reliable.
Table 3
Test performance of the 35 t/h CFB boiler with low circulating ratio
110% MCR
100% MCR
75% MCR
a
b
Heat loss
due to
unburned
carbon (%)
Heat loss
due to
unburned
gases (%)
Boiler
combustion
efficiency (%)
38.2
35.0
24.5
0.37
0.32
0.93
10.16 a/4.28 b
9.90 a/5.61 b
11.09 a/5.74 b
5.74 a/2.07 b
5.36 a/2.13 b
7.70 a/2.63 b
84.1 a/93.65 b
84.74 a/92.26 b
81.21 a/91.63 b
Experimental values.
Computed data.
172
Acknowledgements
This work is currently supported by The State Key
Laboratory of Clean Combustion of Coal in Tsinghua
University.
[12]
[13]
References
[14]
[1] Weiss V, Fett FN, Heimerich H, Janssen K. Mathematical modelling
of circulating fluidized bed reactors by reference to solid decomposition and coal combustion. Chem Engng Prog 1987;22:79.
[2] Arena U, Malandrion A, Massimilla L. Modelling of circulating fluidized bed combustion of a char. Can J Chem Engng 1991;69:860.
[3] Lee YY, Hyppaueu T. A coal combustion model for circulating
fluidized boilers. In: International Conference on FBC, 1989. p.
75364.
[4] Weiss V, Scholer J, Fett FN. Mathematical modelling of coal combustion in a circulating fluidized bed reactor. In: Circulating Fluidized
bed Technology, 1988. p. 28998.
[5] Maggio D, Bursi JM, Lafanechere L, Roulet V, Jestin J. Circulating
fluidized bed boilers numerical modelling, Fifth International Conference on CFB, Beijing, MSR7, 1996.
[6] Kudo K, Taniguchi H, Kaneda H, Yang WJ, Zhang YZ, Guo KH,
Matsumura M. Flow and heat transfer simulation in circulating fluidized beds. In: Basu P, Horio M, Hasami M, editors. Circulating
Fluidized Bed Technology III, 1991. p. 26974.
[7] Sotudeh-Gharebaagh R, Legros R, Chaouki J, Paris L. Simulation of
circulating fluidized bed reactors using ASPEN PLUS. Fuel
1998;77:327.
[8] Park CK, Basu P. A model for prediction of transient response to the
change of fuel rate to a circulating fluidized bed boiler furnace. Chem
Eng Sci 1997;52:3499.
[9] Wang XS, Gibbs BM, Rhodes MJ. Modelling of circulating fluidized
bed combustion of coal. Fuel 1994;73:1120.
[10] Adanez J, Diego LF, Gayan P, Armesto L, Cabanillas A. A model for
prediction of carbon combustion efficiency in circulating fluidized
bed combustor. Fuel 1995;74:1049.
[11] Leckner B, Golriz MR, Zhang W, Andersson BA, Johnsson F.
[15]
[16]
[17]
[18]
[19]
[20]
[21]
[22]
[23]
[24]
[25]
[26]