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12
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2 Hazards identification
Classification of the substance or mixture:
GHS02 Flame
Flam. Aerosol 1 H222 Extremely flammable aerosol.
GHS08 Health hazard
Muta. 1B
Carc. 1B
Eye Irrit. 2A
H319 Causes serious eye irritation.
STOT SE 3
H336 May cause drowsiness or dizziness.
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Warning! Pressurized container.
(Contd. on page 2)
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Classification system:
The classification was made according to the latest editions of international substances lists, and expanded upon
from company and literature data.
Risk phrases:
May cause cancer.
May cause heritable genetic damage.
Extremely flammable.
Irritating to eyes.
Vapours may cause drowsiness and dizziness.
Safety phrases:
Keep locked up and out of the reach of children.
Keep container in a well-ventilated place.
Keep away from food, drink and animal feedingstuffs.
Keep away from sources of ignition - No smoking.
When using do not eat or drink.
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
Avoid contact with eyes.
Take precautionary measures against static discharges.
Wear suitable protective clothing.
In case of insufficient ventilation, wear suitable respiratory equipment.
Special labelling of certain preparations:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50C, i.e. electric lights.
Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material.
Classification in accordance with Directive 75/324/EEC: Extremely flammable
Hazard description:
WHMIS-symbols:
A - Compressed gas
B5 - Flammable aerosol
D2A - Very toxic material causing other toxic effects
Health = 2
Fire = 4
Reactivity = 0
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
67-64-1 acetone
Flam. Liq. 2, H225;
Eye Irrit. 2, H319; STOT SE 3, H336
68476-85-7 Petroleum gases, liquefied
Flam. Gas 1, H220; Flam. Liq. 1, H224;
Muta. 1B, H340; Carc. 1B, H350; Press.
Gas, H280
30-60%
25-40%
(Contd. on page 3)
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5 Firefighting measures
Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
For safety reasons unsuitable extinguishing agents: Water with full jet
Special hazards arising from the substance or mixture: No further relevant information available.
Protective equipment: No special measures required.
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Storage
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Observe official regulations on storing packagings with pressurized containers.
Information about storage in one common storage facility: Not required.
Further information about storage conditions:
Keep receptacle tightly sealed.
Do not gas tight seal receptacle.
Store in cool, dry conditions in well sealed receptacles.
Protect from heat and direct sunlight.
Specific end use(s): No further relevant information available.
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Eye protection:
Tightly sealed goggles
pH-value:
Not determined.
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
-95.3 C
> 56 C
Flash point:
Ignition temperature:
465 C
Decomposition temperature:
Not determined.
Auto igniting:
Danger of explosion:
Explosion limits
Lower:
Upper:
2.6 Vol %
13.0 Vol %
Vapor pressure at 20 C:
219 mm Hg
Density at 20 C:
Relative density:
Vapour density at 20 C:
Evaporation rate at 20 C:
0.715 g/cm
Not determined.
2.0 (AIR=1)
>5.7 (BA=1)
Emulsifiable.
Not determined.
Not determined.
Solvent content:
Organic solvents:
54.5 %
(Contd. on page 6)
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Solids content:
Other information
9.1 %
VOC Content:
VOC %:
HAP Content:
MIR Value:
Heat of Combustion:
259.994 g/l
37%
None
0.588 g O/g
31.592 MJ/kg
11 Toxicological information
Information on toxicological effects:
Acute toxicity
LD/LC50 values that are relevant for classification:
67-64-1 acetone
Oral
LD50 5800 mg/kg (rat)
Dermal LD50 20000 mg/kg (rabbit)
Primary irritant effect
on the skin: No irritant effect.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic.
The product can cause inheritable damage.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
7631-86-9 silicon dioxide, chemically prepared
12 Ecological information
Aquatic toxicity: No further relevant information available.
Persistence and degradability: No further relevant information available.
Behavior in environmental systems
Bioaccumulative potential: No further relevant information available.
Mobility in soil: No further relevant information available.
(Contd. on page 7)
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13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings
Recommendation:
Place in a sealed container and label as waste. Place in a safe area, and comply with all federal, state, provincial
and local regulations for disposal.
14 Transport information
UN-Number
DOT, TDG, IMDG, IATA
UN1950
AEROSOLS, flammable
1950 AEROSOLS
AEROSOLS
Class
Label
TDG (Transport dangerous goods):
2.1
2.1
TDG class:
Label
2 5F Gases
2.1
IMDG, IATA
Class
2.1
(Contd. on page 8)
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Label
2.1
Packing group
DOT, TDG, IMDG, IATA
Not Available
Environmental hazards:
Marine pollutant:
No
Warning: Gases
F-D,S-U
TDG
IMDG
Remarks:
IATA
Remarks:
UN "Model Regulation":
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
67-64-1 acetone
68476-85-7 Petroleum gases, liquefied
7631-86-9 silicon dioxide, chemically prepared
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
(Contd. on page 9)
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A4
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16 Other information
This MSDS format meets ANSI Z400.1-1998, OSHA 1910.1200 and WHMIS requirements. Kemper System
America, Inc. provides the information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary
handling of the material by a properly trained person using this product. Product use and conditions of use are
beyond the control of Kemper System America, Inc. Warranty of materials is limited to test results of product
performance as detailed in certificates of compliance. Interpretation of test results is the responsibility of end-user.
No other warranties, expressed or implied, are made. Kemper System America, Inc is an ISO 9001:2008
registered company.
Department issuing MSDS: Product safety department
Contact: Stephen Nowicki
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
NFPA: National Fire Protection Association (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
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