ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT JEE - 2014

TIME: 1 HR

TW TEST
TOPICS:ATOMIC STRUCTURE

MARKS: 65
DATE: 26/08/12

SECTION-I
This section contains 10multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out which ONLY ONE is correct.
(+3, - 1)

1.

Which of the following sets of quantum number is allowable:

(a) n 2, l = 1, m = 0,s = +1 2
(b) n 2, l 2, m 1,s 1 2
(c) n 2, l 2, m 1, s 1 2
(d) n 2, l 1, m 0,s 0

2.

Which shape is associated with the orbital designated by n 2; l 1 ?

(a) Spherical
(b) Tetrahedral
(c) Dumb-bell
(d) Pyramidal

3.

Which out of the following configurations is incorrect?

(a) 1s 2 2s 2 2p 2x 2p 2y 2p 0z (b) 1s 2 2s 2 2p1x 2p1y
(c) 1s 2 2s 2 2p1x 2p1y 2p1z (d) 1s 2 2s 2 2p6 3s 2 3p6 3d5 4s1

4.

For which of the following electron distributions in ground state, the Paulis exclusion principle is
violated?

5.

In the Schrodingers wave equation represents

(a) Orbit
(b) Wave function
(c) Wave

6.

(d) Radial probability

Ground state electronic configuration of nitrogen atom can be represented by

(a)
(b)
(c)
(d)

7.

The ionisation potential of hydrogen atom is 13.6 eV. The energy required to remove an electron in
the n 2 state of the hydrogen atom is
(a) 3.4 eV
(b) 6.8eV
(c) 13.6 eV
(d) 27.2 eV

8.

The orbital diagram in which the Aufbau principle is violated is

9.

The total spin and magnetic moment for the atom with atomic number 24 are:
3
3
(a) 3, 48 BM
(b) 3, 35 BM
(c) , 48 BM
(d) , 35 BM
2
2

10.

The important principles that do not help in assigning electronic configuration to atoms are
(a) Aufbau rule
(b) Hunds rule
(c) Heisenberg uncertainty principle
(d) Paulis exclusion principle

SECTION-II
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out which ONE OR MORE is/are correct.
(+3, 0)
11.

The isotone(s) of
(a)

12.

77
32

Ge

76
32

Ge is/are

(b)

77
33

As

The atomic nucleus contains

(a) Protons
(b) Neutrons

(c)

77
34

As

(c) Electrons

(d)

78
34

Se

(d) Photons

13.

Which of the following sets of quantum number is/are not permitted?

1
1
(a) n 3, l = 3, m = +1,s = +
(b) n 3, l = 2, m = +2,s = 2
2
1
1
(c) n 3, l = 1, m = +2,s = (d) n 3, l = 0, m = 0,s = +
2
2

14.

The energy of an electron in the first energy level of H atom is 13.6eV . The possible energy value
(s) of the excited state (s) for the electron in He is (are).
(a) 54.4 eV
(b) 13.6 eV
(c) 3.4eV

(d) 6.4eV

15.

A hydrogen-like species in ground state absorbs n photons having the same energy and its emits
exactly n photons when electrons transition take placed. Then, the energy of the absorbed photon
may be
(a) 91.8eV
(b) 40.8eV
(c) 48.4 eV
(d) 54.4 eV

16.

An electron has spin quantum number (s) 1 2 and magnetic quantum number is 1 . It can be
present in
(a) s orbital

(b) d orbital

(c) p orbital

(d) f orbital

17.

Which is correct statement in case of Hunds rule?

(a) It states that if more than one atomic orbital of the same energy is available, electrons will occupy
different atomic orbitals with parallel spins, as far as possible, in the configuration of lowest energy
(b) Total energy of many electron atom with more than one electron occupying a set of degenerated
orbitals is lowest, is far as possible, electrons occupy different atomic orbitals and have parallel
spins.
(c) Hunds rule forbid any configuration that does not violate the Paulis exclusion principle
(d) Hunds rule simple tells us which of the possible configurations is lowest in energy and other
configurations are those of excited states, higher in energy than the ground state.

SECTION-III

(Paragraph Type)

This section contains 2 groups of questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
(+3, -1)
o

The characteristic X-ray wavelength for the lines of K series in elements X and Y are 9.87 A and
o

14.6 A , respectively. IfMoseleys equation,

frequency z atomic no,

18.

19.

4.9 107 Z 0.75 is followed:

c = speed of light = 3 108 m / s

The atomic number of X is

(a) 8
(b) 10

(c) 12

(d) 16

The atomic number of Y is

(a) 10
(b) 6

(c) 8

(d) 12

SECTION-IV

(Integer Answer Type)

This section contains 2 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9. The correct digit below the question number in the ORS is be bubbled. (+4, 0)

20.

The sum of all the quantum numbers of helium atom is.

21.

The magnitude of an orbital angular momentum vector of an electron is

h
. Into how many
2

components will the vector split if an external field is applied to it?

Head Office: Andheri: 26245223

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ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

TOPICS:Atomic Structure (Answer Key)

DATE: 26/08/12

1. a

2. c

3. a

4. c

5. b

6. a

7. a

8. b

9. a

10. c

11. b,d

12. a,b

13. a,c

14. b,c

15. a,b

16. b,c,d

17. a,b,c,d

18. c

19. a

20. 1

21. 5

Atomic Structure Solution

2.

(c)
l = 1 , therefore p orbitals

3.

(a)

1s2 , 2s2 , 2p1x 2p1y 2p1z (Paulis exclusion principle)

5.

(b)
wave function

9.

(a)
Atomic number 24
Configuration is [Ar] 3d 5 , 4s1 , n = 6

1
Total spin 6 3
2
Magnetic moment n n 2 6 6 2
48 BM

11.

(b, d)
Species having the same number of neutrons are called isotones.
76
32

Neutrons

Ge
34

77
33

As
34

12.

(a, b)
The atomic nucleus contains protons and neutrons.

14.

(b, c)

78
34

Se
34

13.6 4
n2
n 2, 3, 4... for excited state
E He

15.

(a, b)

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Exp: Number of dark lines (in absorption), i.e.,

excitation Number of bright lines (in emission), i.e., de-excitation
It is possible only when the e is excited to n 2 from ground state.
Clearly, E 91.8eV and 40.8eV are possible:

Li He
2

19.

(a)
v
0.75
4.9 10 7
[You will get to know about this]
v 4.9 107 Z 0.75 Z

For 9.87 A v

Zx

0.3 1018
0.75 12
4.9 107
o

For 14.6 A v
Zy

20.

c
3 108

0.3 1018
10
9.87 10

3 108
0.2 1018
10
14.6 10

0.2 108
0.75 10
4.9 107

1
He 1s 2 ; n 1; l = 0; m = 0;s = 1 2, 1 2

1 1
Sum 1 1
2 2

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