Escolar Documentos
Profissional Documentos
Cultura Documentos
Prepared By:
SYED HAIDER ABBAS
DEPARTMENT OF CHEMICAL ENGINEERING
COMSATS INSTITUTE OF INFORMATION TECHNOLOGY
Email: haidy_42@hotmail.com
ACKNOWLEDGMENT
TABLE OF CONTENTS
Page
Introduction to OMV
Scope of Plant
Process description
10
12
Chemical Injection
13
Water Conning
14
15
17
Compressors
18
19
Centrifugal Compressors
23
Separators
24
Membranes
29
31
36
Sorption
39
Absorption
39
Adsorption
40
Pre-treatment
41
Memguard
42
H2S Polisher
46
Recycle Compressor
48
49
Cooling Towers
50
53
Produced Water
54
Incinerator
54
Control System
55
Safety System
55
Page |1
Introduction to OMV:
OMV is Austrias largest listed industrial company. As the leading oil and gas
group in Central Europe, OMV is active in Refining and Marketing (R&M) in 13
countries and in Exploration and Production (E&P) OMV is active in 18 countries
on five continents. In Pakistan, OMV has been active as an operator and partner
since 1990. In the years to date OMV (Pakistan) has established itself as the
largest international gas producer in Pakistan with an operated volume of more
than 110,000 barrels of oil equivalent per day from Kadanwari-Miano and Sawan
fields. This represents about 16% of the total gas produced in Pakistan. The first
significant achievement was the discovery of the Miano gas reservoir in the Thar
Desert of Sindh province. It came about by the end of 1993; just three years after
OMV came to Pakistan. The second major breakthrough came five years later i.e.
in 1998, from the field named Sawan, again in the same area of Sindh. Sawan
was and still is one of the largest discoveries of gas reserves in Pakistan. In a
record nineteen months from the ground-breaking ceremony in January 2002 of
the Sawan Gas Plant, OMV was able to sell its raw gas by July 2003. Parallel to
the Sawan development OMV also took over the operator-ship of the Kadanwari
Gas Processing Plant on 1st January 2003 from Lasmo, currently ENI. OMV
remained quite aggressive on new developments and Kadanwari plant gas
processing capacity was enhanced to 232 MMscfd while Sawan plant capacity
has been enhanced to 400 MMscfd. To further meet raw gas requirements
development drilling was continued successfully for both fields. Besides these
activities carried out in OMV Pakistans core area, OMV is pursuing new projects
in other parts of Pakistan. Health, Safety and Environmental standards are
parallel to the highest international level and second to none in the local
perspective. OMV has strong commitment to reduce emissions to the
environment. To achieve the same an Emission Reduction project has been
initiated for Kadanwari Plant.
Page |2
Scope of Plant:
Carbon dioxide and hydrogen sulfide, which fall into the category of acid gases,
are commonly found in natural gas streams at levels as high as 80%. In
combination with water, they are highly corrosive and can rapidly destroy
pipelines and equipment unless they are partially removed or exotic and
expensive materials of construction are used. Hydrogen sulfide is toxic and at
relatively modest levels can be life threatening. Carbon dioxide also reduces the
heating value of a natural gas stream and wastes pipeline capacity. In LNG
plants, CO2 must be removed to prevent freezing in the low-temperature chillers.
Therefore, the composition of gas is adjusted as per limits prescribed by SNGPL
(Sui Southern Gas Pakistan Limited) and is sold to the government. The gas is
injected to the SNGPL main facility at a pressure of 1100 psi.
The sales gas specifications are as follows:
CO2 Maximum = 3%
H2S Maximum =
3.8 ppm
CV Minimum =
920 Btu/scf
Water =
7lb/MMscf
OMV Kadanwai facility sale gas composition:
Page |3
Process Description:
Gas from Kadanwari High pressure wells is routed to Kadanwari High Pressure
slug catcher. Gas from Kadanwari low pressure wells is routed to Kadanwari low
pressure slug catcher and is fed to 2 stage Front End Compressor (FEC) to
increase the pressure up to production pressure. Gas from FEC is fed to high
pressure stream flowing into Kadanwari High Pressure slug catcher. The gas
from Miano wells is fed to Miano Slug Catcher.
Kadanwari and Miano gas streams after separately metered are fed to a common
header which splits into two identical skids A and B. Here we will discuss one
skid in common. Each skid is routed to fin fan coolers where it is cooled and fed
to Inlet separator where water and heavy hydrocarbons are removed from feed
gas. The condensate from all units is sent to produce water system.
Page |4
The gas then passes through pretreatment skid which consists of following units:
Feed Cooler
Filter Coalescer
Particle Filter
Its main function is to remove contaminants from gas such as dust, lube oils,
heavy hydrocarbons etc. which may poison or reduce efficiency of membrane
unit.
After pretreatment gas is fed to Molecular Sieve Absorbers (Memguard Units)
which ensures gas supplied to membranes is up to membrane standards of UOP
(vendor of membrane system). It removes all moisture and heavy hydrocarbons
from gas stream.
Pretreated gas is now fed to the primary membranes. The permeate stream (rich
in CO2) is sent to recycle membranes after passing through recycle compressor
and recycle pretreatment. The permeate stream of recycle membranes is used as
regenerative medium for Memguard units and rest is sent to incinerator and
burnt. The residual gas (rich in CH4) from primary membrane and recycle
membranes (all skids) is sent to H2S polishers via a common header.
H2S polisher unit reduce the hydrogen sulfide level to the sales limit. The gas is
now metered after compressing in sales gas compressor and is sent to SNGPL
trunk line after metering.
Water is remove from condensate at produced water system by a three phase
separator. The condensate is sold to refinery. Major quantity is exported to
various industries.
Page |5
Page |6
Wellhead
A wellhead is the component at the surface of an oil or gas well that provides the
structural and pressure-containing interface for the drilling and production
equipment. Its function is to maintain surface control of the well. It forms a seal to
prevent well fluids from leaking or blowing at the surface. They are rated for
working pressure of 2000 psi to 15000 psi (or greater).
When the well has been drilled and it is ready to provide an interface with the
reservoir rock and a tubular channel for the well fluids. The surface pressure
control is provided by a Christmas tree, which is installed on top of the wellhead,
with valves and choke equipment to control the flow of well fluids during
production.
Christmas tree
A Christmas tree is an assembly of valves, spools, and fittings used for an oil
well, gas well, water injection well, gas injection well, condensate well and other
types of wells.
The primary function of a tree is to control the flow, usually oil or gas, out of the
well. When the well and facilities are ready to produce and receive oil or gas, tree
valves are opened and the formation fluids are allowed to go through a flow line.
This leads to a processing facility. A tree often provides numerous additional
functions including chemical injection points, well intervention means, pressure
relief means, monitoring points (such as pressure, temperature, corrosion,
erosion, sand detection, flow rate, flow composition, valve and choke position
feedback), and connection points for devices such as down hole pressure and
temperature transducers (DHPT). On producing wells, chemicals or alcohols or
oil distillates may be injected to preclude production problems (such as
blockages).
The control system attached to the tree controls the down-hole safety valve
(SCSSV) while the tree acts as an attachment and means of the control system
to the down-hole safety valve.
Page |7
Figure 1
Well Head and Christmas Tree
Page |8
Master Valves:
The two lower valves are called the master valves. Master valves are normally in
the fully open position and are never opened or closed when the well is flowing
(except in an emergency) to prevent erosion of the valve sealing surfaces. They
are gate type valves.
1. Lower Master Valve (LMV)
2. Upper Master Valve (UMV)
The lower master valve will normally be manually operated, while the upper
master valve is often hydraulically actuated, allowing it to be used as a means of
remotely shutting in the well in the event of emergency.
Wing Valve:
A wing valve is normally used to shut in the well when flowing, thus preserving
the master valves for positive shut off for maintenance purposes. The wing
valve can be a gate valve or ball valve. Hydraulic operated wing valves are
usually built to be fail safe closed, meaning they require active hydraulic pressure
to stay open. This feature means that if control fluid fails the well will
automatically shut itself in without operator action.
In Kadanwari well sites there is only one manually operated wing valve. On the
other hand, at Miano well sites there are two wing valves one being operated
manually and other hydraulically.
Production Wing Valve
The right hand valve is often called the flow wing valve or the production wing
valve, because it provides flow path for hydrocarbons to production facility.
Kill wing valve
The left hand valve is often called the kill wing valve. It is primarily used for
injection of fluids such as corrosion inhibitors or methanol to prevent hydrate
formation. It is typically manually operated. It can kill the well temporarily be
injection brine solution which provides a pressure head to well and temporarily
Page |9
suspends it for maintenance of well head. Also it is used to permanently kill the
well. A chemical is injected down the well that seals the piping down the well and
kills the well permanently.
Swab valve
The swab valve is used to gain access to the well for wire line operations,
intervention and other work over procedure. On top of it is a tree adapter
and cap that will mate with various equipment. For such operations, a
lubricator is assembled up onto the top of the tree and the wire or coil is lowered
through the lubricator through swab valve and into the well. This valve is typically
manually operated.
Choke
A choke holds back pressure by restricting the flow opening at the well head. This
is done to make better use of the gas for natural gas lift and to control the bottomhole pressure for recovery reasons.
CHECK VALVE
The check is introduced in production flow line to prevent any reverse flow from
the line into the well. It has a hinged flap which lifts to permit normal flow, but
closes to prevent reverse flow.
TOP ADAPTOR
The top adaptor is a fitting on top of the swab valve with a threaded connection.
During normal well operations, a pressure gauge is fitted to monitor flowing and
shut in wellhead pressures. However, during well service operations the cap can
be removed to allow installation of lubricators for wire-line operations.
SCSSSV (Surface Control Sub Surface Safety Valve)
A subsurface safety valve is essentially a shutdown valve installed at the upper
wellbore for emergency shutdown to protect the production tubing and wellhead
in case of overpressure. Subsurface safety valves can offer a barrier against flow
in the event of a wellhead collapse or other disastrous event. Purpose of a
subsurface safety valve (SSSV) is to avoid the ultimate disaster which can result
P a g e | 10
in release of reservoir fluids to the surroundings. This makes SSSV a very
important component of a well completion.
A subsurface safety valve is typically a uni-directional flapper valve, directed in
such a way that the flappers open downwards when pressure is applied from an
upward direction. The flapper can only open in the downward direction. So even if
high pressure is applied by the well fluids from a
downward direction, a safety valve can remain
closed. This makes a subsurface safety valve failsafe. To open the valve, hydraulic signal is sent from
the surface well control panel. This hydraulic
pressure is responsible for keeping the flappers of
SSSV open and loss of hydraulic pressure result in
closing of the valve. Thus wellbore can be isolated in
case of system failure or damage to the surface
facilities.
P a g e | 11
Figure 2
Figure 3
P a g e | 12
Wellhead Control Panel:
Wellhead control panel is key equipment in oil & gas industry to protect oilfield
facilities and environment from emergency incidents such as wellhead fire, which
is one of main control systems to ensure oilfield oil production and transportation
to be safely operation according to international standards and national
regulation. Wellhead control panel is composed of hydraulic power unit, tubing &
fitting and instrument valve and electrical control devices. Hydraulic power unit
supply hydraulic resource to open and close safety valves including master
valves, wing valves and SCSSSV.
Its performs
P a g e | 13
Chemical Injection:
Chemical injection systems are commonly used in production facilities to prevent
or eliminate a wide range of problems that might negatively affect the production
flow. It is done for flow assurance, protection of process equipment such as
pipelines or to optimize processes in production facilities.
Typical flow assurance chemicals are:
Wax inhibitors
Asphaltene inhibitors
Corrosion inhibitors.
P a g e | 14
which prevents access of the corrosive substance to the metal. The corrosive
agents are generally oxygen, hydrogen sulfide, and carbon dioxide.
At our production site the major risk is corrosion of piping and equipment. The
maximum allowable corrosion rate is approximately 0.2 mm per year, and
corrosion rate without inhibitor could be approximately 11 mm per year, so the
corrosion protection program is designed to achieve a target corrosion rate of
less than 0.1 mm per year which is achieved by an inhibitor system efficiency of
99%. Inhibitor is injected into the well stream flow through an atomizing nozzle
located downstream of the respective wellhead coolers at the duplex/carbon steel
interface. In normal operation as per NALCO standards chemical (brand name
EC1144B) at rate of Liter per MMSCFD of gas is being injected into the flow
line of miano#15 flow lines made of carbon steel . Moreover, the composition can
vary depending upon the composition of well fluids and material of pipeline. This
method of injection ensures even distribution of the chemical on the interior
surface of the pipeline. The individual well sites are equipped with Chemical
Injection Packages comprising of a stainless steel storage tank and two
pneumatic motor driven pumps in parallel. Instrument gas is used to drive the
pumps. Normally one pump is running with the other standby.
Water Conning
Water coning is a term used to describe the mechanism underlying the upward
movement of water into the perforations of a producing well. Coning can seriously
impact the well productivity and influence the degree of depletion and the overall
recovery efficiency of the reservoir. The specific problems of water coning are
listed below.
Costly added water handling
Gas production from the original or secondary gas cap reduces pressure
Reduced efficiency of the depletion mechanism
The water is often corrosive and its disposal costly
The affected well may be abandoned early
Loss of the total field overall recovery
P a g e | 15
Therefore, conning has an important influence on operations, recovery, and
economics. The phenomena is shown in picture below.
Corrosion
Corrosion is referred as chemical deterioration of a metal. Commonly this
means loss of electrons of metals reacting with water and oxygen.
Weakening of iron due to oxidation of the iron atoms is a well-known
example of electrochemical corrosion. This is commonly known as
rust. Most structural alloys corrode merely from exposure to moisture
in the air, but the process can be strongly affected by exposure to
certain substances Corrosion can be concentrated locally to form a pit
or crack, or it can extend across a wide area to produce general
deterioration (uniform corrosion).
The following reaction takes place at the active sites:
2Fe => 2Fe++ + 4eThe free electrons travel through the metal path to the less active sites, where
the following reaction takes place:
O2 + 4e- + 2H20 => 4 OH-
P a g e | 16
Recombination of these ions at the active surface produce the following
reaction, which yields the iron-corrosion product ferrous hydroxide:
2Fe + O2 + 2H2O => 2Fe (OH) 2
Corrosion Inhibitors
Corrosion inhibitor is injected into the flow lines as mentioned in
detail on page 8.
Cathodic Protection
Cathodic Protection (CP) is a technique used to control the corrosion of a
metal surface by making it the cathode of an electrochemical cell. It
converts all of the anodic (active) sites on the metal surface to cathodic
(passive) sites by supplying electrical current (or free electrons) from an
alternate source. It is accomplished in two ways:
P a g e | 17
structure to be protected by the cathodic protection system. The rectifier
output DC positive cable is connected to the anodes.
How to account for corrosion:
Corrosion Coupons
Erosion Probes
Corrosion probes
P a g e | 18
frequently to limit liquid holdup and minimize the slug volumes of liquid which can
be generated by the system.
Coating
Pigs may be used to apply internal pipe coatings, such as epoxy coating
materials, in operating pipelines. Pigs may also be used with corrosion inhibitors
to distribute and coat the entire internal wetted perimeter.
Inspection
Pigs are being used more frequently as inspection tools. Gauging or sizing pigs
are typically run following the completion of new construction or line repair to
determine if there are any internal obstacles, bends, or buckles in the pipe. Pigs
can also be equipped with cameras to allow viewing of the pipe internals.
Electronic intelligent, or smart, pigs that use magnetic and ultrasonic systems
have been developed and refined that locate and measure internal and external
corrosion pitting, dents, buckles, and any other anomalies in the pipe wall.
Intelligent pigs
The accuracy of location and measurement of anomalies by the intelligent pigs
has continued to improve. Initially, the electronics and power systems were so
large that intelligent pigs could be used only in lines 30 in. and greater in size.
The continued sophistication and miniaturization of the electronic systems used
in the intelligent pigs has allowed the development of smaller pigs that can be
used in small-diameter pipelines. Newly enacted DOT pipeline-integrity
regulations and rules acknowledge the effectiveness of the intelligent pigs and
incorporate their use in the pipeline-integrity testing process.
Compressors:
A gas compressor is a mechanical device that increases the pressure of a gas by
reducing its volume. Gas pressure is increased by forcing gas molecules together
to reduce gas volume. When volume is reduced, gas pressure increases.
All gases have large spaces among their molecules. These spaces could be
enhanced further and decreased by doing some work. Work done which is used
P a g e | 19
for the enhancement of these spaces is called expansion, and work done to
minimize these spaces is called compression. All gases while expansion
produces cooling effect and while compression of gases raises there
temperature. Compression is a term used to force gases to occupy smaller
volumes by increasing their pressure. Volume of gases is interlinked with
temperature and pressure of the gas, which is cleared by 2 laws, govern gas
compressions.
Boyles Law
Charles Law
P a g e | 20
also equipped with a variable, volume head end pocket.
In case of compressor emergency shutdown the production chokes and the
Upper Master Valves on the on line wells will close and operator will be notified in
central control room. Sweet gas from gas distribution network is used to operate the
gas engine driver of the compressor package. The detailed scheme of working is
shown in figure (page 22 )
PT Reciprocating Compressor
The mechanical cycle of piston tube reciprocating compressor comprises four
strokes: the expansion stroke, the intake stroke, the compression stroke and the
discharge stroke.
Expansion Stroke
As the piston moves back on the expansion stroke, the chamber volume
increases and the pressure drop. As the pressure drops the discharge valve
closes, since there is greater pressure in the discharge line than in the chamber.
Intake Stroke
As the piston moves back during the intake stroke the pressure decreases until it
is less than the pressure in the inlet line. This higher intake pressure opens the
inlet valve, and gas rushes into the cylinder, equalizing the pressure there with
the intake pressure. The compression chamber is now at or near the intake
pressure.
Compression Stroke
The piston now starts the compression stroke by moving forward, decreasing the
chamber volume and increasing the pressure. The increased pressure is now
higher than the intake pressure, causing the intake valve to close.
Discharge Stroke
The piston continues to move to the left during the discharge stroke. This creates
an increase in chamber pressure until it is greater than the discharge pressure.
When this happens the. Discharge valve opens and the compressed air from the
P a g e | 21
cylinder goes into the discharge line. The compression cycle is then repeated
from the stage.
Compressor Capacity
The capacity of the compressor depends upon cylinder displacement.
That
displacement is simply the volume that the piston displaces (moves) as it travels
from one end of the cylinder to the other. Capacity and displacement is equal to
the cross-sectional area of the cylinder times the length of the stroke.
Lubrication and Cooling
Lubricating oil is circulated through the system by a gear pump which is chain
driven from the engine crank shaft. The oil pump is mounted on the engine front
housing.
The pump operates between 30 - 40 psig.
P a g e | 22
A circulating pump deliver cooling water to the water jackets in the cylinder block,
flowing around the cylinder liners, and is directed into the cylinder heads. Each
cylinder head has water cooled exhaust elbows which outlet the water into the
water cooled exhausts. From the end of engine the water flows to compressor
1st and 2nd stage cylinders and compressor lube oil cooler (L.O./water heat
exchanger). The water from the compressor cylinder and lube oil cooler returns
to engine water cooled exhaust.
P a g e | 23
Centrifugal Compressor
Centrifugal compressors are machines in which velocity and pressure given to air
or gas in a radial direction by one or more impellers diffuser combination. In a
centrifugal compressor the mechanical energy is increased by centrifugal action.
The gas enters the suction eye of a high speed rotary element called the impeller
which carries radial vanes integrally cast in it. As the impeller rotates, the blades
of the impeller force the gas outward from the center the impeller to the outer rim
of impeller, the increase in velocity of the gas creates a flow pressure area at the
eye of the impeller. The gas at the outer rim of the impeller is forced in to a
passage way called a diffuser where the velocity decreases in the pressure of the
gas.
Inlet
The inlet to a centrifugal compressor is typically a simple pipe. It may include
features such as a valve and both pressure and temperature instrumentation.
Centrifugal impeller
The key component that makes a compressor centrifugal is the centrifugal
impeller shown above. It is the impeller's rotating set of vanes (or blades) that
gradually raises the energy of the working gas. This is identical to an axial
compressor with the exception that the gases can reach higher velocities and
energy levels through the impeller's increasing radius.
P a g e | 24
Diffuser
The next key component to the simple centrifugal compressor is the diffuser.
Downstream of the impeller in the flow path, it is the diffuser's responsibility to
convert the kinetic energy (high velocity) of the gas into pressure by gradually
slowing (diffusing) the gas velocity.
SEPERATORS
A well-stream is a mixture of gases, hydrocarbon liquids, water, solids and
contaminants. Due to variations in pressure and temperature, gases evolve from
the liquids, water vapor condenses and some of the well-stream changes to liquid
and free gas. The separation of well-stream fluids takes place in a separator. This
pressure vessel is manufactured in three forms:
1. horizontal
2. vertical
3. spherical
To help separation, the vessel is normally designed with a series of internal
fittings. These fittings are built into the separator to ensure total phase separation
of the well-stream.
In gas plants, separators are given alternative names due to the function they
perform in the process system. A scrubber does a similar job to a knockout drum.
However, the scrubber usually separates a stream containing high gas-to-liquid
ratios. The knockout drum is used where a high degree of liquids are entrained in
the gas.
Fluid flow from a well can include gas, condensable liquid vapors, water, water
vapor, crude oil and solids. As well-stream fluids reach ground level, where
pressure is lower than in the reservoir, the capacity of the liquid to hold gas in
solution decreases and gas separates out of the oil.
Separation depends upon the effect of gravity to separate liquids. For adequate
separation one fluid must be lighter than the other fluid. For example, distillates
P a g e | 25
(gasoline, kerosene, etc.) and crude oil will not separate in a vessel because they
tend to dissolve in each other. Because a separator basically depends upon
gravity to separate the fluids, the ease with which separation takes place
depends upon the difference in density of the fluids.
Droplets of liquid will separate from gas provided:
a) The gas remains in the separator long enough,
b) The gas flow remains constant to provoke separation.
The difference in density between a gas and liquid will, therefore, determine the
maximum flow rate of liquid in the vessel
Gas bubbles in the liquid will break out in some oil field applications in 30 to 60
seconds. Consequently, the separator is designed so that the liquid remains in
the vessel for 30 to 60 seconds. The length of time that a liquid remains in the
vessel is called its residence time. Residence time differs widely from field to field
depending upon viscosity and API Gravity.
Another important factor which must be considered is temperature. Generally, a
decrease in operating temperature will increase the liquid recovery in a separator
P a g e | 26
as the gas condenses. By reducing the pressure on the fluid, flash separation
occurs, resulting in a flow through the separator which is controlled by external
instrumentation.
COALESCENCE
Another important principle in fluid separation is that of coalescence. This means
the coming together of liquid droplets created by the force of gravity.
A common example of coalescing occurs when drops of water form on the
windshield of a car as it is driven in fog. As the tiny drops or water which make up
the fog strike the windshield, they combine and eventually form a drop large
enough to run down the glass.
Several of the internal devices of a separator, such as deflector plates,
straightening vanes and even the vessel walls are forms of coalescers. In each
vessel drops of liquid adhere to the surface of the device and combine with other
P a g e | 27
drops until the drop is large enough to fall out. The effectiveness of separation
will also depend upon the total amount of coalescing surface area that is present.
There are many different types of separators used in the Oil & Gas industry.
Consequently, separators are manufactured with one, two or several internal
fittings, depending on their use and quick removal of these fluids from the vessel.
DEFLECTOR PLATES
These are fitted in front of the inlet to the separator and can be net or
dish-shaped. Their purpose is to absorb the impact of the incoming fluids and to
encourage the separation of gas and liquids. They also slow the flow rate of the
liquids through the vessel.
WEIRS
A weir is a metal wall which is fitted across the inside of the vessel, normally to a
height of 50% of the overall height of the separator. Its purpose is to assist the
process of three phase separation. The inlet fluids (oil plus water) are given time
to separate in the liquid accumulation section. The water level (interface) is
normally controlled at 50% of the height of the weir. Oil floating on the water
overflows the weir and accumulates in the small oil compartment where it is
drawn off under level control.
CENTRIFUGAL DEVICES
These are used in both vertical and horizontal separators for gas-liquid
separation. The device imparts a swirling motion to the fluids entering the vessel.
Centrifugal force causes the heavier liquids to travel outwards towards the walls
of the vessel and the lighter gases to flow up the centre. Centrifugal devices are
also known as cyclones.
VORTEX BREAKERS
When liquid flows through a drain outlet, a vortex (whirlpool) will form. This can
be seen when we pull the plug from a sink or bath tub. The same would happen
as water and oil flow from the separator. This condition, a vortex, could allow gas
to flow down the centre of the whirlpool and enter the liquid phase, causing
P a g e | 28
pressurizing of tanks etc. To stop this happening, vortex breakers are fitted to all
liquid outlets. Although they come in a number of different designs, vortex
breakers all serve the same purpose - to prevent a whirlpool from forming.
MIST OR DEMISTER PADS
The gas which is released from the fluids in the separator still contains droplets of
oil and water which coalesce and fall when the drops get large enough. The
demister pad assists in this process. Made from knitted wire and contained within
a sturdy frame, it causes the gas to continually change its direction of flow.
Because gas changes direction far easier than liquid, the gas will flow around
each strand of wire, whilst the liquid entrained in the gas stream will continue and
stick to the wire.
COALESCING PLATES
There are several different forms of coalescing devices, the most common of
which are coalescing plates. These plates are mounted in the flow stream of the
fluids and assist in breaking down oil-water emulsions. The fluid is forced to
follow a path that constantly changes direction. This causes the water droplets to
gather together or coalesce and fall to the bottom of the separator. The same
principle is used to separate gas and oil mixtures when the oil droplets are
induced to coalesce. Simply stated, every surface within the separator, including
the separator walls, assists with the coalescing process.
STRAIGHTENlNG VANES
These are often fitted to horizontal separators to remove turbulence in the gas
stream after initial separation at the inlet deflector.
FLOAT SHEILD
Internal floats are used as level controllers. Any agitation of the liquid surface or
the effect of coalesced liquids falling on the float may cause control problems.
Therefore a float shield is fitted to enclose the float, creating an area of still liquid.
P a g e | 29
MEMBRANES
The gas contains 12% carbon dioxide and 22 ppm of hydrogen sulphide at 115oF
and 1100 psig. This needs to be removed before the gas can be exported. The
majority of carbon dioxide, hydrogen sulphide and water is removed by means of
membranes.
Membranes are thin semipermeable barriers that selectively separate some
compounds from others. Currently, the only commercially workable membranes
used for CO2 removal are polymer based, for example cellulose acetate,
polyimides, polyamides, polysulfone, polycarbonates, and polyetherimide. The
membrane does not operate as a filter, where small molecules are separated
from larger ones through a medium with pores, rather, it separates based on how
well different compounds dissolve into the membrane and diffuse through it. The
membranes are manufactured in flat sheets consisting of an extremely thin
nonporous layer mounted on a much-thicker and highly porous layer of the same
material, providing mechanical strength. The flat sheets are combined into a
spiral-wound element (Figure below). Feed gas enters along the side of the
membrane and passes through the feed spacers. As the gas travels between
membrane sheets, CO2, H2S, and H2O permeate through the membrane and are
collected in the permeate tube. The driving force for transport is the high-feed
pressure and low-permeate pressures. The gas on the feed side that does not
permeate leaves through the side of the element opposite the feed position. Once
the membranes have been manufactured into elements, six to 12 elements are
joined together and inserted into a tube. Multiple tubes are mounted on skids in a
horizontal orientation.
P a g e | 30
In high H2S applications, most polymers have been shown to have very little
resistance to H2S plasticization (softening of the membrane) and as a
consequence can only be used at very low H2S partial pressure limits. Cellulose
acetate membranes in contrast, have been shown to be applicable at extreme
H2S partial pressure conditions. It is these membranes that have been utilized in
the testing to determine the limits of membrane performance in high H 2S
applications.
The primary membranes used in Kadanwari facility are Cellulose acetate.
Cellulose, acetic acid, and acetic anhydride are mixed together and reacted to
form cellulose acetate polymers. This process is aided by the addition of a small
amount of sulfuric acid which is subsequently neutralized during processing.
However, the membranes are bought from UOP (vendor) and installed for use.
P a g e | 31
How membrane work?
The basic principle of separation is selectivity of certain components of a mixture
for the membrane. For example the cellulose acetate membrane has very high
selectivity for CO2 and H2S as compared to CH4. Therefore such type of
membrane can be used in gas sweetening process.
The selectivity is directly related to the Permeability of gas which accounts that
which gas can pass across the membrane more easily. In simple words,
membranes being polymer materials are made of long chains of molecules. The
different structure of polymer materials only allow selective molecules to pass
through them depending upon chemical and physical compatibility. Thus,
permeability depends upon choice of polymer.
The permeability is determined by permeability coefficient (P) and is product of
solubility (S) and diffusivity (D).
P=S*D
Solubility
The solubility is mainly determined by ease of condensation. Heavy molecules
are more readily condensed. Therefore, higher molecular weighted molecules will
more easily condensed and therefore have greater solubility.
Molecule
Molecular weight
CH4
16
H2S
34
CO2
44
P a g e | 32
Diffusivity
Diffusivity is ease of molecule to penetrate into some material. It depends on size
of gas molecule. Here size of molecule is not to be confused by molecular weight,
it is the size of the structure. E.g. the size of O2 molecule is smaller than N2.
Molecule
CO2
3.3
H2S
3.6
Ch4
4.0
S CO2/S CH4
P CO2/P CH4
4.5
7.3
30.8
Chemical degradation
Cellulose acetate polymer is chemically degraded by a process called hydrolysis,
which means breaking apart by the addition of water. This is a chemical reaction
in which water is added to the cellulose acetate polymer causing the release of
acetic acid molecules. This process proceeds stepwise until all the acetate
groups are released resulting in the reformation of cellulose. Moreover alcohols,
aromatic hydrocarbons or solvents with chlorine, nitro benzene, or similar
aromatic solvents will harm the membrane. It will expand and lose plastification in
contact with them.
Effect of Temperature
The permeation rates of all gases increases with increasing temperature,
however, membrane selectivity for CO2 over hydrocarbon decreases at higher
P a g e | 33
temperature. Consequently, CO2 removal will improve as operating temperature
increases but hydro carbon recovery will decrease.
Primary Membrane
The primary membranes comprise of two trains. Each train consists of two
sections A/B and C/D, each section consists of a 30 tube membrane skid (A and
C), followed by a 25 tube skid (B and D). The conditioned gas (after pretreatment) enters the primary membrane via the particulate filter adjacent to the
skid. The gas is fed to the membranes through a common inlet manifold, which
supplies primary membranes skids A and C. A pressure control loop located
upstream of the manual inlet isolation valve is provided to maintain a constant
supply pressure to the membrane skid and to allow for preheating at the inlet
prior to skid start-up. This pressure control loop can also be used during start-up
to control the pressurization of the pretreatment skid and associated pipes to the
primary membranes.
The gas passes through membrane skid A, the residual gas exiting the membrane
skid is sent to skid B, and the permeate to common permeate discharge header. An
identical arrangement is provide on the inlet to skid C as provided on skid A. The
residual gas from skid B combines with the residual gas from skid D in a common
discharge header and is then sent to the H2S polishing towers via the feed coolers
on the pre-treatment skid. The permeate from skid B is sent to the common
permeate discharge header. The permeate discharge header sends the gas to
either the recycle compressor or the vent header via a pressure control loop.
Overpressure protection for the membranes is provided by a pressure safety valve
on the supply header to the membrane banks.
P a g e | 34
P a g e | 35
P a g e | 36
ADVANTAGES OF MEMBRANE SYSTEMS
Membrane systems have major advantages over more-traditional methods of
acid gas removal:
Lower capital cost: Membrane systems are skid mounted and so the
scope, cost, and time taken for site preparation are minimal. Installation
costs are significantly lower than alternative technologies, especially for
remote areas. Furthermore, no additional facilities for solvent storage and
water treatment, needed by other processes, are required.
Lower operating costs: The only major operating cost for single-stage
membrane systems is membrane replacement. This cost is significantly
lower than the solvent replacement and energy costs associated with
traditional
technologies.
The
improvements
in
membrane
and
P a g e | 37
unscheduled downtime and are extremely simple to operate. They can
operate unattended for long periods of time. The addition of a recycle
compressor adds some complexity to the system but still much less than
with a solvent- or adsorbent-based technology. Multistage systems can be
operated at full capacity as single-stage systems when the recycle
compressor is down.
P a g e | 38
Ideal for debottlenecking: Because expanding solvent- or adsorbentbased acid gas removal plants without adding additional trains is difficult,
an ideal solution is to use membranes for bulk acid gas removal and leave
the existing plant for final cleanup. An additional advantage is that the
permeate gas from the membrane system can often be used as fuel for
the existing plant, thus avoiding significant increase in hydrocarbon
losses.
Ideal for remote locations: Many of the factors mentioned above make
membrane systems a highly desirable technology for remote locations,
where spare parts are rare and labor unskilled. Furthermore, solvents
storage and trucking, water supply, power generation, or extensive
infrastructure, are not required.
P a g e | 39
Sorption
Sorption is a physical and chemical process by which one substance becomes
attached to another.
It is of two main types:
1. Absorption
2. Adsorption
Absorption
Absorption is a physical or chemical phenomenon or process in which atoms,
molecules, or ions enter some bulk phase gas, liquid, or solid material. This is a
different process from adsorption, since molecules undergoing absorption are
taken up by the volume, not by the surface (as in the case for adsorption).
Absorption process may be chemical (reactive) or physical (non-reactive).
Physical absorption
Physical absorption or non-reactive absorption is made between two phases of
matter: a liquid absorbs a gas, or a solid absorbs a liquid.
When a liquid solvent absorbs a gas mixture or part of it, a mass of gas moves
into the liquid. For example, water may absorb oxygen from the air. This mass
transfer takes place at the interface between the liquid and the gas, at a rate
depending on both the gas and the liquid. This type of absorption depends on the
solubility of gases, the pressure and the temperature. The rate and amount of
absorption also depend on the surface area of the interface and its duration in
time.
When a solid absorbs a liquid mixture or part of it, a mass of liquid moves into the
solid. For example, a clay pot used to store water may absorb some of the water.
This mass transfer takes place at the interface between the solid and the liquid,
at a rate depending on both the solid and the liquid.
P a g e | 40
Chemical absorption
Chemical absorption or reactive absorption is a chemical reaction between the
absorbed and the absorbing substances. Sometimes it combines with physical
absorption. This type of absorption depends upon the stoichiometry of the
reaction and the concentration of its reactants.
Adsorption
Adsorption is the adhesion of atoms, ions, or molecules from a gas, liquid, or
dissolved solid to a surface. This process creates a film of the adsorbate on the
surface of the adsorbent. The binding to the surface is usually weak and
reversible. Compounds with color and those that have taste or odor tend to bind
strongly. Compounds that vibrate at frequencies in the visible spectrum are very
often are strongly adsorbed on activated carbon.
The most common industrial adsorbents are activated carbon, silica gel, and
alumina, because they present enormous surface areas per unit weight.
Depending on the nature of attractive forces existing between the adsorbate and
adsorbent, adsorption can be classified as:
i) Physical adsorption
P a g e | 41
ii) Chemical adsorption (Chemisorption)
In chemisorption, the forces of attraction between the adsorbate and the
adsorbent are very strong; the molecules of adsorbate form chemical bonds with
the molecules of the adsorbent present in the surface.
Adsorption is generally accompanied by release of energy, that is, most
adsorption processes are exothermic in nature. Adsorption is a spontaneous
process; therefore its free energy change is negative (G<0). However, the
entropy change associated with adsorption is generally negative because the
adsorbate molecules lose their translation freedom when they get attached to the
surface of the adsorbent. Therefore, in order for G to be negative, the enthalpy
change (H) must be sufficiently negative, such that, (G=H-TS) < 0. This
explanation accounts for exothermic adsorption processes. In cases, where
endothermic adsorption occurs, the entropy change S is sufficiently positive
such that G remains negative.
Pre treatment
The main function of pretreatment skid is to provide membrane inlet specification
gas as mentioned by the vendor UOP. It removes the contaminants that would
poison the membranes like dust, solids (adsorbent particles), lube oil, heavy
hydrocarbons etc. It consists of
Feed Cooler
Filter Coalescer
Particle Filter
P a g e | 42
Mineral oil
Poly aromatic hydrocarbons (PACs)
Phenol
Adsorption of halogenated substance: I, Br, Cl, H en F
Non-polar substances (Substances which are non-soluble in water)
MemGuard
The main function of MemGuard unit is to remove moisture and heavy
hydrocarbons (branched and cyclic) that may reduce membrane life and
efficiency. There are four identical Memguard adsorber vessels, two used for
each train of gas. The Memguard technology incorporates two main cycles,
adsorption and regeneration and two vessels will alternate between the cycles so
that while one vessel is adsorbing the other on regeneration and vice versa. Each
vessel
contains
two
Memguard
media
MG-3
and
MG-5
(Class
of
Aluminosilicates). Feed gas enters the bottom of the vessel and flows upward
through the media which selectively remove water and trace heavy hydrocarbon
containments contained in the feed gas and exist the vessel from the top the
vessel. The primary source of regeneration gas is the permeate from the recycle
membranes.
Adsorption Step
4 hours
Regeneration Step
2 hours
P a g e | 43
The regeneration is carried out by heated permeate gas from the recycle
membranes at 450oF. The vessel is depressurized to 20 psi and heated gas is
introduced from top. The gas carries out the adsorbed contaminants and leaves
the vessel from bottom cleaning the adsorbent. This contaminated gas is burnt in
the flare.
UOP, the vendor of Memguard unit has never disclosed that what substance
MG3 and MG5 exactly are. But as mentioned by vendor that both care class of
aluminosilicates. Therefore, MG3 can be potassium aluminosilicate and MG5 can
be Calcium aluminosilicate. These are molecular sieves adsorbents. Molecular
sieves are a microporous material which can selectively adsorb gases and
liquids. They are synthetic zeolites (crystalline metal aluminosilicates) which
upon dehydration can efficiently and selectively remove water or other
solvents. The selectivity of a molecular sieve is determined by its pore size,
molecules with a critical diameter which is less than the pore size will be
efficiently adsorbed while larger molecules will be excluded.
P a g e | 44
3A Molecular Sieve Adsorbent
The 3A molecular sieve adsorbent has a 3 angstrom (3A) pore size which means
that any molecule that is larger than the 3 angstrom pores will not be adsorbed.
The 3A molecular sieve is the potassium type of A crystalline structure and is a
form of alkali Aluminosilicate. For a 3A molecular sieve, the sequence rate that
adsorption occurs is He, Ne, N, and H2O.
Due to the crystalline structure, molecular sieves that have a 3 angstrom pore
size have a very high rate of adsorption and properties that promote a longer life
for products treated by the sieve. The most common use for the 3A molecular
sieve is to remove water and moisture from materials that are in gas and liquid
form.
Adsorption of nC4H10
Adsorption of nC4H10
Separation of aromatic
P a g e | 45
MOLE%
10.96
85.93
1.73
0.23
0.08
0.04
0.04
0.00
0.76
0.07
MOLE%
10.98
86.08
1.73
0.23
0.08
0.04
0.04
0.00
076
0.00
H2S polisher
The H2S polishing unit has been designed to treat 187 MMscf/day of natural gas
containing up to 11% CO2 and 21 ppm H2S, where the level of the CO2 and H2S
is reduced using a MemGuard / Membrane separation unit. The unit is situated
down-stream of the membrane unit and will further reduce the level of H2S in the
processed gas to a sales gas specification of 3.8 ppm.
P a g e | 46
This process uses three non-regenerable fixed bed absorber vessels using a low
temperature, high activity absorbent. The absorbent is a mixture of activated
metal oxides (mainly zinc oxide). The three towers can are generally operated in
parallel arrangement but on demand can be used in series (any of alternate
arrangements of A, B, C vessels) as shown in figure.
The higher sales gas flow rate increased the catalyst consumption and
replacement frequency.
109oF
1215 psig
P a g e | 47
Inlet pipe
4 Drums of 19mm
ceramic Balls
112 drums of
Catalist (ZnO)
6 Micron mesh
01 Drums of
6mm ceramic
5 Drums of 50mm
ceramic
1 Drums of
19mm ceramic
Figure
H2S Tower
P a g e | 48
Recycle Compressor:
The permeate gas of the primary membrane unit carries recoverable amount of
CH4. It is fed to recycle membrane unit for further CH4 recovery. But the
permeate pressure from primary membranes which has been reduced to 12 psi
must be regenerated to 1200 psi for the gas to be fed again to the system. For
this purpose we have employed recycle compressor. The compressor is a four
stage centrifugal compressor. It is driven by gas turbine of 31200 HP. It has 25
MW producing capacity.
P a g e | 49
P a g e | 50
Cooling Towers:
A cooling tower is a heat rejection device which extracts waste heat to the
atmosphere through the cooling of a water stream to a lower temperature. Hot
water from the system enters the cooling tower and is distributed over the fill
(heat transfer surface). Air is induced or forced through the fill, causing a small
portion of the water to evaporate. This evaporation removes heat from the
remaining water, which is collected in the cold water basin and returned to the
system to absorb more heat. Each cooling tower line, although operating under
the same basic principle of operation, is arranged a little differently.
Types:
Natural draft Utilizes buoyancy via a tall chimney. Warm, moist air naturally
rises due to the density differential compared to the dry, cooler outside air. Warm
moist air is less dense than drier air at the same pressure. This moist air
buoyancy produces an upwards current of air through the tower.
P a g e | 51
Forced Draft Cooling Tower Vs. Induced Draft Cooling Tower:
Induced Draft Cooling Tower have the ability to handle large water flow
rate than Forced Draft Cooling Tower
Induced Draft Cooling Tower is suitable for large cell sizes and fan sizes
as compared with Forced Draft. Larger fan size may result in greater
efficiency and consequently lower power and sound level.
Induced Draft Cooling Tower uses more compact ground area than Forced
Draft Cooling Tower equivalent capacity due to absence of fan on one
side.
Configuration
There are two main configurations of factory assembled cooling towers: crossflow
and counterflow. In crossflow cooling towers, the water flows vertically down the
fill as air flows horizontally across. In counterflow cooling towers, the water flows
vertically down the fill as air flows vertically up.
Crossflow Configuration
Counterflow Configuration
P a g e | 52
Drift Water droplets that are carried out of the cooling tower with the exhaust
air. Drift droplets have the same concentration of impurities as the water entering
the tower. The drift rate is typically reduced by employing baffle-like devices,
called drift eliminators through which the air must travel after leaving the fill and
spray zones of the tower.
Blow-out Water droplets blown out of the cooling tower by wind, generally at
the air inlet openings. Water may also be lost in the absence of wind through
splashing or misting. Devices such as wind screens, louvers, splash deflectors
and water diverters are used to limit these losses.
Blow-down The portion of the circulating water flow that is removed (usually
discharged to a drain) in order to maintain the amount of Total Dissolved Solids
(TDS) and other impurities at an acceptably low level. Higher TDS concentration
in solution may result from greater cooling tower efficiency. However the higher
the TDS concentration, the greater the risk of scale, biological growth and
corrosion.
Make-up The water that must be added to the circulating water system in
order to compensate for water losses such as evaporation, drift loss, blow-out,
blow-down, etc.
Approach The approach is the difference in temperature between the cooledwater temperature and the entering-air wet bulb temperature.
Range The range is the temperature difference between the warm water inlet
and cooled water exit.
Fill Inside the tower, fills are added to increase contact surface as well as
contact time between air and water, to provide better heat transfer. The efficiency
of the tower depends on the selection and amount of fill.
P a g e | 53
There are two types of fills that may be used:
o
Splash type fill (breaks up falling stream of water and interrupts its
vertical progress)
Important:
Scale build up is controlled by adding chemicals to the cooling loop and diluting
the concentration by blow down and make-up. Following chemicals are added to
the Cooling to control Corrosion/Sale and microbial growth.
They are a "green" solution as compared to cooling towers and shell and
tube heat exchangers because they do not require an auxiliary water
P a g e | 54
supply (water lost due to drift and evaporation, plus no water treatment
chemicals are required).
Produced Water
The produced water system receives liquid from the equipment Miano slug
catcher, train 1 and 2 inlet separators and is fed to three phase separator where
water, oil and gas is separated. The gases produced are burnt in incinerator
whereas hydrocarbon liquid is stored to be sold. Liquid from compressors,
recycle inlet separator, recycle feed scrubber, high and low pressure slug
catchers is passed to degasser. Separated water is injected down the earth.
Incinerator
The term incinerate means to burn something until nothing is left but ashes. An
incinerator is a unit or facility used to burn trash and other types of waste until it is
reduced to ash. An incinerator is constructed of heavy, well-insulated materials,
so that it does not give off extreme amounts of external heat. The high levels of
heat are kept inside the furnace or unit so that the waste is burned quickly and
efficiently. If the heat were allowed to escape, the waste would not burn as
completely or as rapidly.
P a g e | 55
Control System:
The plant is controlled at CCR (Central Control Room) by PLCs (Programmable
Logic Controllers) through fiber optic control line. All control parameters are
received at LER (Local Equipment Room) via two optic fiber control lines. One
being primary and other secondary operating in redundancy i.e. if primary fails
control shifts to secondary. These control parameters are sent to CCR via single
optic fiber cable.
Safety System:
Wellheads and Gas Processing Plant have their own Fire & Gas detection
systems, emergency shutdown (ESD). Plant has a fault tolerant controller. It is
based on Triple Modular Redundant (TMR) architecture manufactured by
Triconex. The TMR system is based on three isolated, parallel control systems
integrated into one system. The system operates on a two out of three voting
principle, which provides high integrity, error free, uninterrupted operation with no
single point of failure. The TMR receives inputs from Process Sensors, Manual
Switches, Fire & Gas Detectors, Packaged Equipment Control Systems and
Product Exporting Facilities. The TMR carries out cause and effect processing on
the data received and, where necessary, produces output signals. Outputs from
the TMR are hard wired directly to ESD shutdown and blow down valve
solenoids, motor control instrument/electrical interfaces to control electrical
drives, package equipment logic control systems, manifold area as well as
telecoms.
The operator in central control room is able to accept alarms and once the fault
has been cleared, reset the input. All the control systems are centralized to a
single interface All the PLCs (Programmable Logic Controllers) communicate with
the servers and servers communicate with the clients through Ethernet connectivity.
Centralization eases the navigation of different systems at a common interface.
Emergency Shutdown
The ESD system receives inputs from field mounted instrumentation on the process
P a g e | 56
and utility equipment and initiates executive actions appropriate to the level of ESD.
The system is an Active system which is in standby and will activate when in an
alarm or fault condition. The Kadanwari Gas Process Facility ESD system is
comprised of five (5) levels. The emergency severity decreases with increasing ESD
level number.
ESD 1
This shutdown level is automatically initiated by fire, major gas leak or a detected
toxic atmosphere in the process area of the plant or manually from CCR. A level 1
shutdown will cause all production to cease, close all emergency shutdown
valves, stop the process and shutdown of the main power generation. The
emergency vent valves to the stack will open and in addition all equipment of zone 1
certified will be isolated. This is the highest level of ESD and will cause the following
to occur:
Wellhead Choke Valves Close, Wing Valves Close Upper Master Valve
(UMV) Close.
ESD 2
This shutdown level is activated automatically if a major process or utility failure
occurs or manually from CCR. All production to the plant from the wellhead is
stopped. All emergency shutdown valves trip to their fail safe position.
Venting shall be as specified. This level of ESD will cause the following to occur:
P a g e | 57
Wellhead Choke Valve Close, Wing Valves Close and Upper Master Valve
(UMV) Close.
ESD 3
The level 3 shutdown isolates and stops a single process train only. Production
continues via the other train. This ESD level is initiated by process conditions or
operator at local panel. This level of ESD will cause the following to occur:
ESD 4
A level 4 shutdown shall cease all production from an entire field, either
Kadanwari or Miano, upstream of the associated slug catchers. ESD 4K for
Kadanwari & ESD 4M for Miano. This ESD level is initiated automatically by slug
catcher abnormal process conditions. This level of ESD will cause the following
to occur:
All SDVs close isolating the relevant slug catcher and its upstream gas
production facility from the Kadanwari Gas Processing Plant.
All Wellhead Choke Valves Close, Wing Valves Close and Upper Master
Valves (UMV) of the relevant gas production facility Close.
ESD 5
A level 5 shutdown represents equipment shutdown for the protection of the
individual equipment without any change in the process. This level of ESD is for the
protection of various pieces of equipment and is initiated by its own inputs e.g.
P a g e | 58
Rotary equipment have trip logic with vibration high high etc. This level may cause a
process
plant
shutdown
of
higher
level
if
the
cause
of
the
Smoke Detectors.
Heat Detector.