Escolar Documentos
Profissional Documentos
Cultura Documentos
Emissions Control
Options For In-Use
Diesel Vehicles
Shenzhen, China
February, 2005
NOx emissions
PM emissions
Ultra-fine particles
Personal breathing space
Local & regional impacts
Global warming impacts
Toxic HC emissions
Sulfate Emissions
Smoke
Range of applications
Michael P. Walsh
International Consultant
Michael P. Walsh
PM Health Effects
Europe Studies
8%
7%
6%
5%
4%
3%
All Causes
Pulmonary
Lung Cancer
2%
1%
0%
Journal of American Medical Association, March 2002
Michael P. Walsh
1,3
-B
u
Be tad
i en
nz
e
Ch en e
ro
Ca me
r b VI
Fo o n
Te
r
pa mal tra
d
c
ra
- D ehy hlor
ich de
id
Ac
e
eta loro
be
Pe
ld
n
e
rc
hl hyd z en
or
e
e
Al oe
l O th
th e ylen
rs
e
2,100
2,040
FEV1
1,980
1,920
1,860
7500
12500
17500
22500
PM10
(10 m)
Human Hair
(60 m diameter)
Michael P. Walsh
Ultrafine Particles
Dp < 100 nm
0.16
Fine
Particles
Nanoparticles
Dp < 50 nm
0.18
0.9
0.8
PM10
Dp < 10 m
0.14
0.7
0.12
0.6
0.1
0.5
0.08
0.4
0.06
0.3
0.04
Nuclei
Mode
0.02
Accumulation
Mode
0.2
Coarse
Mode
0.1
0.001
PM2.5
(2.5 m)
Ultrafine PM
(0.1 m)
PM10
(10 m)
PM2.5
(2.5 m)
0.010
0.100
1.000
10.000
Diameter (m)
Mass Weighting
Number Weighting
10000
8000
6000
4000
2000
0
Inside Vehicle 1
Ozone
Ozone and
Respiratory
Hospital
Admissions
Michael P. Walsh
Sulfur Dioxide
Sulfur Dioxide
SO2 and All
Cause
Mortality
40
O3
-1.6%
-1.8%
-2.4%
-2.8%
-4.2%
-4.8%
-6
No change in
other pollutants
NO2
SO2
-5
60
PM10
20
80
1988
1989
1990
1991
1992
Year
Michael P. Walsh
1993
1994
1995
15-64
65+
All causes
15-64
65+
Cardiovascular
15-64
65+
Respiratory
Initial Results:
Asian Risk Estimates Similar to West
Particulates
PM10 and
All Cause
Mortality
0.62
0.46
0.49
Conclusions
Michael P. Walsh
Improved Maintenance
Improved
Maintenance
Improved Maintenance
Maintenance Enforcement
Improved Maintenance
Effect of Maintenance on 26
smoking HDVs
independent inspection.
Most inspection regimes only look at smoke emissions (opacity)
Michael P. Walsh
Refuelling
Definition
Refueling
Classification/Evaluation criteria
Engine/vehicle modifications
Blending
AQ improvement
WTW GHG
Experience in use
Costs
Availability / Infrastructure
Feedstock
Emulsions 1 (2)
Refueling
Michael P. Walsh
Emulsions - 2
Issues:
Suitable for old high PM engines
Compatibility / effects on new engines (EGR
optimised)
Increased noise
Increased fuel consumption / lower range
Water separation, freezing
WTW GHG: More energy demanding than diesel, hence higher GHG
emissions
Experience: Limited
Costs: Much higher than conventional diesel (energy intensive)
Availability: Better than crude oil
Issues:
Biofuels: Biodiesel
WTW GHG: Decreasing with its increasing blend in the fuel (is N2O
from agriculture an issue?)
Experience: Widely available in several countries (Germany, France,
Austria, ) as a 5% blend. Pure biodiesel in pilot programs (Austria)
Costs: Higher than conventional diesel
Availability: Depending on the cost of the procedure
Issues:
Michael P. Walsh
No major AQ benefits
Cost and GHG benefits depend on the procedure
PM Filter
0.05
PM Emissions
grams/kilometer
0.02
0.04
0.015
0.03
0.01
0.02
0.005
0.01
Oxidation Catalyst
0.04
Other PM
Sulfur
0.03
0.02
0.01
0
0
500
1000
1500
2000
2500
3000
3500
Fuel Sulfur
PPM
0
0
Euro 2-2005
Euro 3-2010
Euro 5-2010
Euro 3-2005
Euro 4-2010
Alternative Fuels
(Alternative Engines)
U
S U
EU 20 S
0
E U 20 6
E
0
Sw U 2 20 00
ed D e 0 0 5 5
G e n er n m 9
m C ar
an l a k
y ss
J a 20 1
J a p J a 03
a
So pan n pan
2
T a ut H o 20 00
ip h K ng 0 5 4
ei o K 7
, r
A u C h ea o n
Sa
i 2 g
n t Thstrana 00
ia a li 20 6
g o i la a 0
, C nd 20 7
hi 2 06
le 01
20 0
04
500
450
400
350
300
PPM 250
200
150
100
50
0
Gasoline
Diesel
Michael P. Walsh
10
Comparison of CNG
technologies over a
Euro 2 diesel bus
(VITO Data)
CONCLUSIONS
On average, CNG delivers
better emission
performance than CRT
equipped diesel
Retrofitting / Refuelling
Michael P. Walsh
11
Biofuels: Biogas
LPG
Feedstock: Crude Oil
Engine: Dedicated LPG with spark ignition (or bi-fuel).
AQ potential:
NG (Methanol)
Retrofitting
procedure
Issues:
Michael P. Walsh
12
Retrofitting
Costs:
Experience:
Issues
CO
Aldehydes
HC
PAH
SO2
NOx
C2H2n+2
CO2
H2O
SO2 /SO3
NOx
PAH
Soot
Metals
SO2+H2O
CO + 1/2 O2
HC + O2
PAH + O2
Aldehydes + O2
CO2
CO2 + H2O
CO2 + H2O
CO2 + H2O
SO2+H2O
Soot
Metals
No reduction of soot
NO2 production by Pt-based catalysts
Retrofitting
Description: Wall flow devices installed in the exhaust line combined with a DOC
to enable NO2-based regeneration
AQ Effect:
Costs:
Experience:
Issues
Michael P. Walsh
Filter System
Not available for PCs (low NO2/PM ratios, low exhaust temperature)
Busses: 4.5-9.5 k (+0.02-0.05 /bus km maintenance cost)
Retrofitting activities throughout the world
Appears as a candidate technology for (future) heavy duty vehicles
Applicability for different vehicle technologies and duty cycles
NO2 production by Pt-based catalysts
Reliability, maintenance
13
their use
Variety of technologies for a
variety of applications
Not universally applicable,
Baseline (ave.)
0.98
Conventional Diesels
1.00E+12
0.430
0.321
0.30
0.34
0.17
0.018
1.00E+13
ULSD + DPF
Emissions, g/mi
1.00E+11
Conventional Diesel
Direct
Injection
Gasoline
1.00E+10
G-DI
1.00E+09
Gasoline and LPG
MPI and
LPG
Gasoline
1.00E+08
0.005
1.00E+07
HC
CO/10
PM
NOx/100
1.00E+06
1
10
100
1000
Michael P. Walsh
14
0.01
Experience:
Costs:
Issues
Michael P. Walsh
0.06
0.03
0.07
0.08
0.05
Retrofitting
PM Emissions, g/kW-hr
Resistant to plugging
Engine-out
Tailpipe
0.04
Euro 4/5 Limit
Euro 4/5 Limit
0.02
0
ETC
ESC
Source: MAN
Retrofitting
AQ Effect:
Costs:
Experience:
Issues
15
Reduction
Combined DPF/Lean NOx Catalyst System Verified in CA
Michael P. Walsh
16
Retrofitting
Description: Open channel devices with urea injection for the reduction
of NOx to nitrogen and water
AQ Effect:
Costs:
Experience:
Issues
SCR Applications
Retrofitting
Demonstrations / Approaches:
USEPA/CARB
Voluntary Diesel Retrofit Program (EPA)
SCR
Michael P. Walsh
17
Retrofitting
Retrofitting
Examples of Practices in
Europe 1(2)
21 Projects running
5000 busses in 30 states (DOCs and CRDPFs)
Retrofitting
Examples of Practices in
Europe 2
Michael P. Walsh
A new cab
Retrofit SCRT system (?)
Convert to LPG
Retrofitting
Hong-Kong Activities
18
Weather influence
With
Automobile tunnel
Roadside
Existing
Carbon
(EC)
- 49%
Osakabashi
Air Monitoring Station
Cancercausing
agents
Up to - 58%
Cancerausing
agents
- 36%
Carbon
(EC)
- 30%
Planned
Existing CA regulations
Michael P. Walsh
NYC
19
Replacing Engine
(Repowering)
Repowering
EU HD Emission Regulation
20
Diesel Euro 2
Brand A
Diesel Euro 3
Pre*
Particulates (g/kWh)
Euro 0*
Brands A&B
CNG Euro2
Brand B
15
CNG Euro3
CNG EEV
NOx g/km
Brand A
Brand C
Brand C
10
Brand A
Brand A
Brand B
Brand C
Euro 4
Brands D&E
Euro 5 / EEV
Euro 3
Euro 1
Euro 2
0
0.0
NOx (g/kWh)
14,4
18
0.1
0.2
0.3
0.4
0.5
0.6
0.7
PM g/km
Michael P. Walsh
20
NYCT Project
Clean Diesel Costs
Additional Costs Compared to
Diesel Buses
Annual Maintenance
Fuel
DPF Purchase
Fuel Station
Depot Modifications
Michael P. Walsh
__________________
$150 to clean filter + 3 hrs R&R, 5%
plugging rate
+$0.030.10/gallon for ULSD
+$4000--$7000 per bus
Nothing additional required
Nothing additional required
21
Michael P. Walsh
22