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(A) Find the slope and the intercept for this data
(B) Make a plot of the data and fit a trendline to it
( C) Calculate the [Lead] for a signal of 234 and 584 mamps
(D) Find the 95% CL error associated with the predictions of concentration of one measurement of signal 1200
(E) Find the 95% CL error associated with the predictions of concentration of five measurements of signal with average 1200
(F) Find the r-squared for the linear regression of the data with and without the internal standard
(G) Using the internal standard data shown below, calculate the [Lead] for 1200 mamps, and internal standard 2945
(H) Find the 95% CL error associated with the predictions of concentration of five measurements of signal with average 1200
Given signal
1200.00
Error 1 replicate
Error 5 replicates
RSQ
ppm
ppm
0.999007215
ppm
AVG
STDEV
New "X"
Known [Lead] ppm
AES Signal (mamps)
IS (70 ppm)
Ratio Conc.
0.00
0.00
2925.00
1.00
40.00
2000.00
5.00
200.00
2700.00
25.00
1100.00
2888.00
50.00
2213.43
3080.00
100.00
4199.25
2920.00
150.00
6100.00
2900.00
47
1979
58
2366
Unknown
Given signal
IS (70 ppm)
Unknown
1200.00
2945
Error 1 replicate
Error 5 replicates
ppm
ppm
New "Y"
Ratio Signals
Sxx
#3) Third term in the Sxo formula
#4) Put all together to get Sxo
ratio
ppm error
7000.00
6000.00
AES Signal
Slope
40.96
Intercept
42.31
Known [Lead] ppm AES Signal (mamps)
0.00
0.00
1.00
40.00
5.00
200.00
25.00
1100.00
50.00
2213.43
100.00
4199.25
150.00
6100.00
Unknown
AES signal
4.68
234
5000.00
4000.00
3000.00
2000.00
1000.00
0.00
0.00
20.00
40.00
60.00
60.00
ppm Lead
AVG
STDEV
RSD
Slope
Intercept
Known [Lead] ppm AES Signal
0.00
1.00
5.00
25.00
50.00
100.00
150.00
47.29
57.73
Unknown
AES signal
28.267
7.6%
40.96
42.31 Step 1: Find the Sy/x statistic -- use STEYX function
Sy/x
81.66
Step 2: Calculate the Sxx statistic
Sxx
19999.43
Step 3: Find the overall Sxo - term 3
Sxo, term 3
0.018087
Step 4: Calculate Sxo
Sxo all
2.15
0.00
40.00
200.00
1100.00
2213.43
4199.25
6100.00 95% CL
1978.95
2365.75
1200
7000.00
6000.00
AES Signal
5000.00
4000.00
3000.00
2000.00
1000.00
0.00
0.00
20.00
40.00
60.00
80.00
ppm Lead
5.25662141
95% CL
Note: I used a t-value of 2.571, DF=
wn concentrations
se STEYX function
ppm
ep 4: Calculate Sxo
Sxo all
1.20 ppm
1.377223
ote: I used a t-value of 2.571, DF=5
Example 3
No Internal Standard
With Internal Standard (70 ppm Ag)
Slope
40.95
Slope
Intercept
42.56
Intercept
Known [Lead] ppm AES Signal
IS (70 ppm)
0.00
1.00
2909.34
1.00
40.00
1200.00
5.00
200.00
2700.00
25.00
1100.00
2888.00
50.00
2213.43
3080.00
100.00
4199.25
2920.00
150.00
6100.00
2900.00
AVG
47.29
1979.10
STDEV
57.73
2365.62
Unknown
AES signal
Unknown
28.26
1200
27.98
Sxo, one replicate
2.17
1.22
CL 95%, DF =5
5.31
2.97
RSD
18.8%
10.6%
Sxo, five replicates
1.237
0.68
CL 95%, DF =5
1.42 t=2.571
0.78
RSD
5.0%
2.8%
Note: I used a t-value of 2.571, DF=5
AND NOTE: The reason this is divided by sqrt 5 is because there are FIVE replicate measurements (not because of DF)
t=2.571
2945
0.68 ppm