Anexo IV Hojas de Seguridad

Monday, April 23, 2012
To:
GAS NATURAL SDG S.A

Avenida SAN LUIS 77 pl. EN
28033 Madrid (Espaa)
Re: Compliance with EU Regulation on Registration, Evaluation, Authorization and Restriction of

Chemicals (EC 1907/2006) (REACH)
Dear Customer,
We are writing in relation to the above mentioned regulation which came into force in June 2007 and in response
to your recent inquiry.
REACH is an on-going compliance process which will have a significant impact to the business of all
manufacturers, importers and downstream chemical users. All have specific obligations under the new
legislation, and at M-I SWACO we are committed to ensuring full continuity of business relationships, throughout
the implementation of REACH.
We wish to assure you that M-I SWACO (or our upstream supplier) has pre-registered all non exempt substances
we manufacture and/or import into the EU.
REACH requires, amongst other obligations:
pre-registration with the European Chemicals Agency of certain substances (as such, or contained in
preparations/mixtures to the extent where they are not covered by other more specific legislation, or, in
articles if substance is intended to be released during conditions of use) manufactured/used in, or
imported into, the European Economic Area (EEA) by December 1 2008; and
Subsequent registration of certain substances by specified deadlines, depending on the hazard profile
and/or annual manufacture, use or import volumes of the substance by the registrant in question.
Further information and guidance on the REACH Regulation can be found on the European Chemicals Agency
(ECHA) website (http://echa.europa.eu/home_en.asp).
Compliance with REACH is essential for the future marketing in the EEA of both M-I SWACO products and any of
your products which incorporate M-I SWACOs product(s). M-I SWACO is therefore dedicated to ensuring
effective REACH compliance for all M-I SWACO products placed on the EEA market whilst maintaining our
relationships with our customers and avoiding business interruption.
All of M-I SWACO chemicals used are either compliant with REACH requirements or are exempt from REACH
registration requirements either because they are listed in the relevant annex or covered under other legislation.
1|P a g e
Regarding your specific inquiry on the products, please see below answers:
Please note that the following products are considered exempt under REACH.
Product name
BARITE
Calcium Carbonate
MICA FINE
MICA MEDIUM
NUT PLUG FINE
KWIK-SEAL
MIKHART 0.35 0.7
MIKHART 130
MIKHART 10
MIKHART 10
MIKHART 65
NUT PLUG FINE
SUGAR
For the products below; please be assured that all the non exempt substances present in the product are REACH
compliant; non exempt substances will be registered by M-I SWACO or our upstream supplier.
Product name
KCL
KOH
XCD Polymer
Polypac UL
POLYPAC REGULAR
SODA ASH
BICARBONATE
DEFOAM X-EH
SOLTEX
LUBE 167
POTASSIUM CARBONATE
GLYDRIL MC
POLYPLUS LIQUID
SAFE SCAV NA
SAFE CIDE
SAFE COR
2|P a g e
We trust this satisfies your initial inquiry and we will keep you updated on any developments affecting supply to
your company.
For further questions regarding REACH, you can contact any member of our REACH Implementation Team at
REACH@miswaco.slb.com or send an email to csmith03@slb.com. You can also find more about our
commitment to REACH in the QHSE portion of the M-I SWACO website at
http://www.slb.com/services/miswaco/qhse/reach.aspx
Kind regards,
Chioma Smith
Chemical Regulatory Specialist
on behalf of the M-I SWACO REACH Compliance Team
3|P a g e
Revision Date 15-FEB-2012
SDS No.
10201
Revision 5
Supersedes date 15-NOV-2011
SAFETY DATA SHEET

DEFOAM-X* EH
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name
DEFOAM-X* EH
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Defoamer.
1.3. Details of the supplier of the safety data sheet

Supplier
M-I SWACO
A Schlumberger Company
Endeavour Drive
Arnhall Business Park, Westhill
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288
E-mail = MBXMSDS-EH@miswaco.slb.com
1.4. Emergency telephone number

(24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East
and Africa +44 (0) 1235 239 671, USA 001 281 561 1600.
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (1999/45/EEC)
Not classified.
2.2. Label elements

Risk Phrases
NC
Not classified.
NC
Not classified.
Safety Phrases
2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
WATER
Classification (EC 1272/2008)

Not classified.
60-100%
Not classified.
1/ 6
SDS No.
10201
DEFOAM-X* EH
POLY(DIMETHYLSILOXANE)
5-10%

Not classified.
Not classified.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Do not induce vomiting. Get medical attention
if any discomfort continues.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation.
This is unlikely to occur but symptoms similar to those of ingestion may develop.
Ingestion
May cause discomfort if swallowed.
Skin contact
Prolonged skin contact may cause redness and irritation.
Eye contact
May cause temporary eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Get medical attention if any discomfort continues.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Water spray, foam, dry powder or carbon dioxide.
Unsuitable extinguishing media
Not known.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
When heated, vapours/gases hazardous to health may be formed.
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
2/ 6
SDS No.
DEFOAM-X* EH
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Stop leak if possible without risk. Dike far ahead of larger spills for later disposal. Absorb spillage with suitable absorbent material. Shovel
into dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact. Do not eat, drink or smoke when using the product.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place. Protect from freezing and direct sunlight.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Ingredient Comments
No exposure limits noted for ingredient(s).
8.2. Exposure controls
Protective equipment
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists.
Hand protection
Use protective gloves made of: Rubber, neoprene or PVC.
Eye protection
Wear tight-fitting goggles or face shield.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance
Liquid
Colour
Off-white
Odour
Slight odour.
Solubility
Miscible with water
Initial boiling point and boiling range
~ 100C
Relative density
0.98 - 1.02 s.g @ 20C
pH-Value, Conc. Solution
6-8
Flash point
> 100C
9.2. Other information

Not relevant
SECTION 10: STABILITY AND REACTIVITY
3/ 6
10201
SDS No.
DEFOAM-X* EH
10.1. Reactivity
There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Not known.
10.4. Conditions to avoid
Not known.
10.5. Incompatible materials
Materials To Avoid
Not known.
10.6. Hazardous decomposition products
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Acute toxicity:
Acute Toxicity (Oral LD50)
> 2000 mg/kg
*Based on components
Aspiration hazard:
Not anticipated to present an aspiration hazard based on chemical structure.
Inhalation
Gas or vapour in high concentrations may irritate respiratory system.
Ingestion
Skin contact
Prolonged and frequent contact may cause redness and irritation.
Eye contact
Spray and vapour in the eyes may cause irritation and smarting.
Route of entry
No route of entry noted.
Target Organs
No specific target organs noted
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at env@miswaco.slb.com.
12.1. Toxicity
Acute Fish Toxicity
Not considered toxic to fish.
Acute Toxicity - Fish
LC50 > 100 mg/l
12.2. Persistence and degradability
Degradability
The product is not readily biodegradable.
4/ 6
10201
SDS No.
DEFOAM-X* EH
12.3. Bioaccumulative potential
Bioaccumulative potential
Bioaccumulation is negligible. LogPow < 3
12.4. Mobility in soil
Mobility:
Not determined.
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
SECTION 14: TRANSPORT INFORMATION
General
The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
Water hazard classification
WGK 1
5/ 6
10201
SDS No.
10201
DEFOAM-X* EH
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact REACH@miswaco.slb.com for REACH information. Complies with the following national/regional chemical inventory requirements:
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New
Zealand (NZIoC), Phillipines (PICCS), United States (TSCA).
SECTION 16: OTHER INFORMATION
Abbreviations and acronyms used in the safety data sheet
*a mark of M-I L.L.C.
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
General revision. Compiled or Revised by Ewan MacLeod
Issued By
Bill Cameron
Revision Date
15-FEB-2012
Revision
Supersedes date
15-NOV-2011
SDS No.
10201
Risk Phrases In Full

NC
Not classified.
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk.
We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or
situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any
nature with respect to this product or to the data herein is made or incurred hereunder.
6/ 6
Revision Date 06-09-11
SDS No.
10759
Revision 6
Supersedes date 15-11-10
SAFETY DATA SHEET

GLYDRIL* MC
Product name
GLYDRIL* MC
Identified uses
Shale control agent.

Supplier
M-I SWACO
Endeavour Drive
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288

and Africa +44 (0) 1235 239 671, USA 001 281 561 1600.
Physical and Chemical Hazards Not classified.

Human health
Eye Dam. 1 - H318
Environment
Not classified.
Xi;R41.
2.2. Label elements

Label In Accordance With (EC) No. 1272/2008
Signal Word
Danger
Hazard Statements
H318
Causes serious eye damage.
P280
P305+351+338
Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary Statements
Supplementary Precautionary Statements

P310
IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor/physician.
2.3. Other hazards

1/ 6
SDS No.
10759
GLYDRIL* MC
3.1. Substances
GLYCOL ETHER MIXTURE
CAS-No.: 9004-77-7
60-100%
EC No.: 500-012-0

Eye Dam. 1 - H318
Xi;R41.
Inhalation
continues.
Ingestion
Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn't enter the lungs. Risk of chemical
pneumonia after aspiration. Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical
attention.
Skin contact
washing.
Eye contact
Continue to rinse for at least 15 minutes and get medical attention.
Inhalation.
This is unlikely to occur but symptoms similar to those of ingestion may develop. Gas or vapour in high concentrations may irritate
respiratory system.
Ingestion
Nausea, vomiting. Risk of chemical pneumonia after aspiration. If swallowed, especially in large quantities: Central nervous system
depression.
Skin contact
Eye contact
Irritation of eyes and mucous membranes. Splashes may cause serious eye damage.
Extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.
Fire or high temperatures create: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).
Containers close to fire should be removed immediately or cooled with water. Do not use water jet as an extinguisher, as this will spread
the fire.
2/ 6
SDS No.
GLYDRIL* MC
Protective equipment for fire-figthers
Avoid spilling, skin and eye contact. Keep away from heat, sparks and open flame.
Store in tightly closed original container in a dry, cool and well-ventilated place.
Ingredient Comments
contamination exists. Chemical respirator with organic vapour cartridge.
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Butyl rubber. or Neoprene gloves are recommended.
Eye protection
Wear approved chemical safety goggles where eye exposure is reasonably probable.
Other Protection
Appearance
Liquid
Colour
Colourless. to Straw. Yellow. / Brown.
Odour
Mild.
Solubility
Miscible with water
> 200C
Relative density
1012 kg/m3 (1.012 g/cm3) @ 15 C
Vapour pressure
<0.931 kPa (<7mm Hg)

3/ 6
10759
SDS No.
GLYDRIL* MC
Viscosity
7.3 mm2/S (7.3 cSt) @ 40 C
Flash point (C)
> 140C PM Closed cup.

Not relevant
Pour Point (C)
<-12C

10.1. Reactivity
Hazardous Polymerisation
Will not polymerise.
Avoid heat, flames and other sources of ignition.
Materials To Avoid
Avoid contact with acids and oxidising substances.
> 2000 mg/kg Rat
Acute Toxicity (Dermal LD50)
> 2000 mg/kg Rat
Inhalation
Gas or vapour may irritate respiratory system.
Ingestion
Gastrointestinal symptoms, including upset stomach. Nausea, vomiting. Central nervous system depression.
Skin contact
Prolonged contact may cause redness and irritation.
Eye contact
Irritating to eyes. Risk of serious damage to eyes.
Route of entry
Ingestion. Skin and/or eye contact.
Target Organs
Central nervous system Eyes
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at env@miswaco.com.
12.1. Toxicity
Acute Fish Toxicity
Degradability
The product is expected to be biodegradable.
The product does not contain any substances expected to be bioaccumulating.
4/ 6
10759
SDS No.
GLYDRIL* MC
Mobility:
Semi-mobile.
None known.
General
ADR/RID).
14.1. UN number
Not applicable.
Not applicable.
Not applicable.
14.4. Packing group
Not applicable.
No.
Not applicable.
The product has been assessed and contained in Chapters 17 and 18 of the IBC Code and the latest MEPC.2/Circular and is permitted to
be carried under Annex II of MARPOL and resolution A.673 (16) Offshore Supply Vessel Code. Ship Type:- 3. Pollution Category:- Z.
EU Legislation
Contact REACH@miswaco.com for REACH information. Complies with the following national/regional chemical inventory requirements:
AICS, DSL / NDSL, IECSC, EINECS / ELINCS, METI ENCS, TCCL ECL, NZIoC, PICCS, TSCA,
General information
HMIS Health - 2 HMIS Flammability - 1 HMIS Physical Hazard - 0 J - Splash Goggles, Gloves, Synthetic Apron, Dust and Vapour
Respirator.
5/ 6
10759
SDS No.
10759
GLYDRIL* MC
Information Sources
Bureau - ESIS (European Chemical Substances Information). MARPOL 73/78. Marine Environment Protection Committee (MEPC)
Circulars. MEPC.2 MEPC 54/10/4. IBC Code. IMO Resolution A.673 (16), Guidelines for the Transport and Handling of Limited Amounts of
Hazardous and Noxious Liquid Substances in Bulk Offshore Support Vessels.
Revision Comments
Issued By
Bill Cameron
Revision Date
06-09-11
Revision
Supersedes date
15-11-10
SDS No.
10759

R41
Risk of serious damage to eyes.
Hazard Statements In Full

H318
Causes serious eye damage.
Disclaimer
6/ 6
Revision Date: 19-05-11
SDS No.
10895
Revision: 3
Supersedes Date: 01-04-08
SAFETY DATA SHEET

LUBE-167*
Product Name
LUBE-167*
Identified uses
Oil well drilling fluid additive. Lubricant

Supplier:
M-I SWACO
Endeavour Drive
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288

and Africa +44 (0) 1235 239 671, USA 001 281 561 1600.
Not classified.
2.2. Label elements

Risk Phrases
NC
Not classified.
NC
Not classified.
Safety Phrases
2.3. Other hazards
3.2. Mixtures
GLYCOL BLEND

Not classified.
30-60%
Not classified.
POLYPROPYLENE GLYCOL, MONOBUTYL ETHER

Not classified.
30-60%
Not classified.
1/ 6
SDS No.
10895
LUBE-167*
VEGETABLE OIL
10-30%
Not classified.

Not classified.
The Full Text for all R-Phrases and Hazard Statements is Displayed in Section 16
Inhalation.
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Do not induce vomiting. Get medical attention
if any discomfort continues.
Skin Contact
washing.
Eye Contact
Inhalation.
Ingestion
Skin Contact
Eye Contact
Extinguishing Media
Hazardous Combustion Products
Specific Hazards
Fire or high temperatures create: Vapours/gases/fumes of: Carbon dioxide (CO2). and Carbon monoxide (CO).
Protective Measures In Fire
2/ 6
SDS No.
LUBE-167*
Avoid spilling, skin and eye contact. Avoid inhalation of vapours and spray mists.
Store in tightly closed original container in a dry, cool and well-ventilated place. Do not store near heat sources or expose to high
temperatures.
Ingredient Comments
Protective Equipment
Engineering Measures
Respiratory Equipment
Hand Protection
For prolonged or repeated skin contact use suitable protective gloves. Use protective gloves made of: Butyl rubber. or Neoprene.
Eye Protection
Other Protection
Appearance
Liquid
Colour
Light brown
Odour
Slight odour
Solubility
Disperses.
Relative Density
0.96 - 1.01 @ 25C
Vapour Density (Air=1)
>10
pH-Value, Diluted Solution
8-10 @ 1%
Flash Point (C)
>110 P/M Pensky-Martens.

Not relevant.
3/ 6
10895
SDS No.
LUBE-167*
10.1. Reactivity
Not known.
Not known.
Materials To Avoid
Strong oxidising substances.
Fire or high temperatures create: Vapours/gases/fumes of: Carbon dioxide (CO2). and Carbon monoxide (CO).
Inhalation
Ingestion.
Skin Contact
Eye Contact
Route of entry
Target Organs
No specific target organs noted.
Ecotoxicity:
12.1. Toxicity
Acute Fish Toxicity
Degradability:
There are no data on the degradability of this product.
Bioaccumulative Potential:
No data available on bioaccumulation.
Mobility:
Not known.
None known.
4/ 6
10895
SDS No.
LUBE-167*
General
ADR/RID).
14.1. UN number
Not applicable.
14.2 UN Proper shipping name
Not applicable.
14.3 Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
No.
Not applicable.
Not applicable.
EU Legislation
Water Hazard Classification
WGK 1
AICS, DSL / NDSL, IECSC, EINECS / ELINCS, TCCL ECL, NZIoC, PICCS, TSCA,
Abbreviations And Acronyms Used In The Safety Data Sheet
General Information
Respirator.
Information Sources
Revision Comments
Issued By
Bill Cameron
Revision Date
19-05-11
Revision
Supersedes Date
01-04-08
SDS No.
10895
5/ 6
10895
SDS No.
10895
LUBE-167*
NC
Not classified.
Disclaimer
6/ 6
REVISION DATE: 24-08-10
SDS NO.:
SAFETY DATA SHEET

POLY-PLUS
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
PRODUCT NAME
POLY-PLUS
APPLICATION
Flocculant
SUPPLIER
M-I SWACO.
Endeavour Drive
Arnhall Business Park
Westhill
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288
E-mail =
MBXMSDS-EH@miswaco.com
EMERGENCY TELEPHONE
(24 Hour) Europe +44 (0) 1235 239 670, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Middle
East and Africa +44 (0) 1235 239 671, Australia +61 2801 44558.
2 HAZARDS IDENTIFICATION
Not regarded as a health or environmental hazard under current legislation.
3 COMPOSITION/INFORMATION ON INGREDIENTS
Name
EC No.
CAS-No.
Content
Classification (67/548)
WATER
231-791-2
7732-18-5
30-60%
30-60%
10-30%
Xn;R65.
1-5%
Xn;R22. Xi;R41.
SYNTHETIC COPOLYMER
DISTILLATES (PETROLEUM), HYDROTREATED
LIGHT; KEROSINE - UNSPECIFIED
ETHOXYLATED FATTY ALCOHOL
265-149-8
64742-47-8
The Full Text for all R-Phrases are Displayed in Section 16

COMPOSITION COMMENTS
The data shown is in accordance with the latest EC Directives. The viscosity of this product is high enough that it is not an aspiration risk
and the R65 phrase does not apply.
4 FIRST-AID MEASURES
INHALATION
continues.
INGESTION
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if any discomfort
continues.
SKIN CONTACT
washing.
EYE CONTACT
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
SPECIAL FIRE FIGHTING PROCEDURES
1/ 4
10086
SDS NO.:
POLY-PLUS
SPECIFIC HAZARDS
Fire or high temperatures create: Vapours/gases/fumes of: Oxides of: Carbon. and Nitrogen.
PROTECTIVE MEASURES IN FIRE
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
ENVIRONMENTAL PRECAUTIONS
SPILL CLEAN UP METHODS
into dry containers. Cover and move the containers. Flush the area with water. In case of spills, beware of slippery floors and surfaces.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
STORAGE PRECAUTIONS
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
INGREDIENT COMMENTS
Oil mist (mineral) workplace exposure limits are currently under review by legislative authorities. This workplace exposure limit (WEL)
standard is applicable to highly refined mineral oils and is provided as a guidance limit only LT. EXP = 5mg/m3 and ST. EXP = 10mg/m3.
PROTECTIVE EQUIPMENT
ENGINEERING MEASURES
RESPIRATORY EQUIPMENT
HAND PROTECTION
For prolonged or repeated skin contact use suitable protective gloves. Rubber gloves are recommended.
EYE PROTECTION
OTHER PROTECTION
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Viscous liquid
COLOUR
Milky.
ODOUR
Hydrocarbon
RELATIVE DENSITY
pH-VALUE, DILUTED SOLUTION
FLASH POINT (C)
1.07 - 1.10 s.g

6 - 8 @ 5g/l
>93.3C (200F) P/M
Pensky-Martens.
VAPOUR PRESSURE
VISCOSITY
POUR POINT (C)
10 STABILITY AND REACTIVITY

STABILITY
CONDITIONS TO AVOID
Avoid frost. Avoid heat, flames and other sources of ignition.
2/ 4
0.002 mm Hg @ 20C (68F)

>7cSt @ 20C
-28.9C (-20F)
10086
SDS NO.:
POLY-PLUS
MATERIALS TO AVOID
Avoid contact with oxidising agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Fire or high temperatures create: Vapours/gases/fumes of: Oxides of: Carbon. and Nitrogen.
11 TOXICOLOGICAL INFORMATION
INHALATION
INGESTION
SKIN CONTACT
EYE CONTACT
12 ECOLOGICAL INFORMATION
ECOTOXICITY
13 DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
14 TRANSPORT INFORMATION
GENERAL
ADR/RID).
15 REGULATORY INFORMATION
RISK PHRASES
NC
Not classified.
NC
Not classified.
SAFETY PHRASES
UK REGULATORY REFERENCES
EU DIRECTIVES
INTERNATIONAL CHEMICAL INVENTORIES
AICS, DSL / NDSL, IECSC, EINECS / ELINCS, METI ENCS, TCCL ECL, NZIoC, PICCS, TSCA
16 OTHER INFORMATION
GENERAL INFORMATION
HMIS Health -1 HMIS Flammability - 1 HMIS Physical Hazard - 0 J - Splash Goggles, Gloves, Synthetic Apron, Dust and Vapour
Respirator.
INFORMATION SOURCES
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. Micromedex. European
Chemicals Bureau - ESIS (European Chemical Substances Information).
REVISION COMMENTS
General revision. Compiled or revised by Sandra McWilliam
ISSUED BY
Bill Cameron
REVISION DATE
24-08-10
3/ 4
10086
SDS NO.:
10086
POLY-PLUS
REV. NO./REPL. SDS GENERATED 8
SDS NO.
10086
RISK PHRASES IN FULL

R22
Harmful if swallowed.
R65
Harmful: may cause lung damage if swallowed.
R41
Risk of serious damage to eyes.
DISCLAIMER
4/ 4
SDS No.
10844
Revision 6
SAFETY DATA SHEET

POLYPAC* (All Grades)
Product name
Synonyms, Trade Names
POLYPAC ELV, R, UL & POLYPAC SUPREME R, UL .
Identified uses
Fluid loss control

Supplier
M-I SWACO
Endeavour Drive
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288

and Africa +44 (0) 1235 239 671, USA 001 281 561 1600.
Not classified.
2.2. Label elements

Risk Phrases
NC
Not classified.
NC
Not classified.
Safety Phrases
2.3. Other hazards
3.1. Substances
POLYANIONIC CELLULOSE

Not classified.
60-100%
Not classified.
1/ 6
SDS No.

Inhalation
continues.
Ingestion
continues.
Skin contact
washing.
Eye contact
Inhalation.
Irritation of nose, throat and airway.
Ingestion
Skin contact
Eye contact
Extinguishing media
None known.
Unusual Fire & Explosion Hazards
High concentrations of dust may form explosive mixture with air.
Specific hazards
Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water. In case of
spills, beware of slippery floors and surfaces.
2/ 6
10844
SDS No.

Avoid inhalation of dust and contact with skin and eyes. Avoid handling which leads to dust formation. Keep away from heat, sparks and
open flame.
Store in tightly closed original container in a dry, cool and well-ventilated place. Take precautionary measures against static discharges.
Ingredient Comments
NUI = Nuisance dust, WEL TWA 4mg/m3 Respirable Dust, 10 mg/m3 Total Dust.
contamination exists. Dust filter P2 (for fine dust).
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Use protective gloves made of: Nitrile. or Neoprene.
Eye protection
Other Protection
Appearance
Granular Powder, dust
Colour
White / off-white.
Odour
Odourless.
Solubility
Soluble in water.
Relative density
1.5 - 1.6 @ 25 C
Bulk Density
400 - 880 kg/m3
6.5 - 9.5 @ 1 %
Decomposition temperature (C)
> 230C

Not relevant
10.1. Reactivity
Stable under normal temperature conditions and recommended use. The substance is hygroscopic and will absorb water by contact with
the moisture in the air.
Hazardous Polymerisation
Will not polymerise.
3/ 6
10844
SDS No.

The substance is hygroscopic and will absorb water by contact with the moisture in the air.
Materials To Avoid
Strong oxidising substances.
When heated, vapours/gases hazardous to health may be formed. Fire or high temperatures create: Vapours/gases/fumes of: Carbon
monoxide (CO). Carbon dioxide (CO2). Na2O Na2CO3
27000 mg/kg Rat
2000 mg/kg Rabbit
Acute Toxicity (Inhalation LC50)
5800 mg/l (dust/mist) Rat 4 hours
Inhalation
Dust may irritate respiratory system or lungs.
Ingestion
Skin contact
Prolonged contact may cause redness, irritation and dry skin.
Eye contact
Particles in the eyes may cause irritation and smarting.
Route of entry
Target Organs
Ecotoxicity
12.1. Toxicity
Acute Fish Toxicity
Degradability
The product is slowly degradable.
The product is not bioaccumulating.
Mobility:
The product is soluble in water.
None known.
Waste Class
EWC-Code: 16 03 06
4/ 6
10844
SDS No.

General
ADR/RID).
14.1. UN number
Not applicable.
Not applicable.
Not applicable.
14.4. Packing group
Not applicable.
No.
Not applicable.
Not applicable.
EU Legislation
WGK 1
General information
HMIS Health -1 HMIS Flammability - 1 HMIS Physical Hazard - 0
Information Sources
Revision Comments
General revision. Updated according to CLP. Compiled or Revised by Ewan MacLeod
Issued By
Bill Cameron
Revision Date
21-06-11
Revision
Supersedes date
03-07-09
SDS No.
10844

NC
Not classified.
5/ 6
10844
SDS No.
10844
Disclaimer
6/ 6
SAFETY DATA SHEET

(According to Regulation (EC) No. 1907/2006 of 18.december 2006, article 31)
Date of issue:
14.1.2011
Date of revision:
5.10.2011(CLP)
Page: 1 / 9
Product name:
POTASSIUM CARBONATE
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
1.1
Product identifier:
Name:
Potassium carbonate
Further names of the product:
1.2
1.3
1.4
Annex I index:
Substance is not listed in Annex XIV or XVII of REACH Regulation
Registration number:
01-2119532646-36-0010111nvcncn1111
Appopriate specified applications of

the substance /mixture and non
recommended applications:
Specified applications:
Industrial and professional uses:In the ceramics, glass,

detergents and leather industries, alkalizing of the cocoa
industry, fertilizer industry, in preparations for constructions,
water treatment agents, antifreeze or de-icing products. In the
etching process and absorption of acid gases (CO2 and
H2S).Consumption uses De-icing or antifreeze products,
disinfectants, paints, fertilizers, inks, detergents, plastic
products, stone, concrete, glass, ceramic, metal, paper, rubber,
wood.
Non recommended applications:
No significant not recommended use is reported.
Detailed particulars about the provider

of the safety data sheet:
Importer:
AG CHEMI GROUP s.r.o.
Place of business or domicile:
Rybnin 18/1 162 00 Praha 6
Identification number:
61508195
Telefon:
+420 233 371 850
Fax:
+420 233 371 860
E-mail:
director@agchemiegroup.eu (ing.Igor evenko)
Web:
http://www. agchemigroup.eu
Skilled advisor:
Ing. Ladislav Folberger
Emergency phone:
In the Czech republic:

Toxikologick informan stedisko, Na Bojiti 1, 128 08, Praha 2
Telefon (24 hours/day):
+420 2 2491 9293
+420 2 2491 5402

Rybnin 18/1
162 00 Prague 6
Czech Republic / Europe
Tel.: +420 233 371 850

Fax: +420 233 371 860
E-mail: info@agchemigroup.eu
www.agchemigroup.eu
SAFETY DATA SHEET

Date of issue:
14.1.2011
Date of revision:
5.10.2011(CLP)
Page: 2 / 9
Product name:
POTASSIUM CARBONATE
+420 2 2491 4575
Information concerning health risks acute poisoning of people
and animals only

2.1
Classification of the substance/

mixture:
Codes of class and category of danger
According to Regulation 1272/2008
EC:
Codes of standard hazard phrases
Skin irritation cat.2

Eye irritation cat.2
STOT Single Exp.3
H 315; H 319; H 335
According to European Directive

67/548/EEC:
Classification:
R - phrases
2.2
R 36/37/38 Irritant to eyes, respiratory system and skin.
Label elements:
Signal word
Standard hazard phrases
Precautionary statements
2.3
Xi - Irritant
Xi - Irritant
Further hazards:
Warning
H 315 Causes skin irritation
H 319 Causes serious eye irritation
H 335 May cause respiratory irritation
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash with soap and water thoroughly after handling.
P280: Wear protective gloves/protective clothing/
eye protection/face protection.
P305+P351+P338: IF IN EYES: Rinse cautiously with water
for several minutes. Re-move contact lenses, if present and
easy to do. Continue rinsing.
P362: Take off contaminated clothing and wash before reuse.
P403+P233: Store in a well-ventilated place. Keep container
tightly closed.
Not applicable

Identifier of main substance:
Chemical name:
Synonyms:
Rybnin 18/1
162 00 Prague 6
Potassium carbonate
Tel.: +420 233 371 850

Fax: +420 233 371 860
www.agchemigroup.eu
SAFETY DATA SHEET

Date of issue:
14.1.2011
Date of revision:
5.10.2011(CLP)
Product name:
POTASSIUM CARBONATE
Content (%):
CAS number:
EC (EINECS) number:
Index number:
Hazard:
Remark:
Page: 3 / 9
92,5 98,0 %
584-08-7
209-529-3
Not listed
Skin Irrit.2 H 315; Eye Irrit. 2 H 319; STOT Single Exp.3 H 335;
Xi R 36/37/38
-
For the full text of the H and R - Statements mentioned in this Section, see Section 16.
4.1
Description of first aid measures:
Immediately transport the victim from the contaminated area,

tak deep breaths of fresh air
In case of aspiration:
Move to fresj air. Rinse immediately with plenty of water: mouth,

face, eyes. Obtain medical treatment if necessary.
In case of skin contact:
Wash off with plenty of water. Take off contaminated clothing.
In case of eye contact:
Rinse out with plenty of water with the eyelid held wide open. If
pain persists, call in ophthalmologist.
If swallowed:
Make victim drink plenty of water. Induce vomiting. Summon

doctor.
4.2
Most important acute and delayed

symptoms and effects:
May cause slight irritation to the respiratory tract, mucous

membranes of nose and throat. Irritating to eyes. Can
cause redness, tearing, pain and weakness of vision. May cause
irritation, dryness and redness of the skin. After consuming large
amounts casualty may experience vomiting, stomach pain,
diarrhea.
4.3
Indication of any immediate medical

attention and special treatment
needed:
Notes to physician: treat symptomatically. If large quantities

swallowed, immediately contact a doctor specialized in poisoning.
SECTION 5: FIRE-FIGHTING MEASURES

Suitable extinguishing media:
Depending on materials stored in the nearest neighborhood All

extinguishing products are allowed: water, water/foam, carbon
dioxide CO2, extinguishing powder.
Unappropriate extinguishing media:
Do not use dense streams of water.
5.2
Particular hazards resulting from the

substance/mixture
When heated to decomposition toxic gas and fumes of carbon

dioxide CO2 are emitted.
5.3
Guidelines for fire-brigade
Isolate the area by removing all persons from the surrounding of

the accident, when a fire broke out. Do not tak any action
involving any personal risk. Fire fighters should wear appropriate

Rybnin 18/1
162 00 Prague 6
Tel.: +420 233 371 850

Fax: +420 233 371 860
www.agchemigroup.eu
SAFETY DATA SHEET

Date of issue:
14.1.2011
Date of revision:
5.10.2011(CLP)
Page: 4 / 9
Product name:
POTASSIUM CARBONATE
protecitive equipment and breathing apparatus.
The product is not flammable.

6.1
Personal precautions:
6.2
Environmental precautions:
6.3
Methods and materials for containment

and cleaning up:
6.4
References to others sections:
For non-emergency personnel:

Do not take any action that could cause personal risk unless you
are properly trained. Do not touch or walk through spillage of
material. Wear appropriate personal protective equipment.
For emergency responders:
Workwear, respiratory protection (fabric or protective masks with
particle filter P2), tight-fitting goggles, gloves.
Should not be released into the environment. When such
situation occurs, call the relevant health and environmental
protection authorities.
Sweep up or vacuum up spillage and collect in suitable container
for disposal. Avoid dust formation. Residues rinse with water.
Information on appropriate personal protective equipment is
specified in section 8. Information regarding waste treatment is
given in section 13.

7.1
Precautions for safe handling:
7.2
Conditions for safe storage including

non compatible matters and mixtures
7.3
Specific final application/applications:
Wear personal protective equipment. Use of the basic principles

of Industrial Hygiene. Ensure adequate ventilation. Do not get in
eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid
dust formation.
Eating, drinking and smoking in areas where the material is
handled, stored and processed should be forbidden. Workers
should wash hands and face before eating, drinking and smoking.
Store in a tightly closed container. Keep containers in a cool, wellventilated place. Do not use light-weight-metal containers. Do not
store together with alkalies. Warehouse personnel must be
equipped with the necessary protec-tive equipment.
No specific end uses

8.1
Controlling parametres:
There is no specific emission limit set especially for this
Limits of exposition set by
substance
Govermental decree No.361/2007 Sb.:

Rybnin 18/1
162 00 Prague 6
Tel.: +420 233 371 850

Fax: +420 233 371 860
www.agchemigroup.eu
SAFETY DATA SHEET

Date of issue:
14.1.2011
Date of revision:
5.10.2011(CLP)
Product name:
POTASSIUM CARBONATE
Substance name
(Component):
Carbonates of
alcaline metals
Page: 5 / 9
PEL = 5 mg/m3
CAS:
NPK-P = 10 mg/m3 Remark:
Producer announces treshold limit value for dust and power: 10 mg/m3
Recommended monitoring procedures: atmosphere or biological monitoring may be required to determine
the effec-tiveness of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to European Standard EN 689 for methods for the
assessment of exposure by inhala-tion to chemical agents and national guidance documents for methods
for the determination of hazardous substances.
8.2
DNEL
No data available
PNEC
No data available
Exposition minimising:
Exposition minimising of workers:
After work wash the skin and take off contaminated clothes. Do
not eat, drink, smoke or take drugs during the work.
Respiratory protection:
Fabric or protective masks with particle filter P2.
Eye protection:
Tight-fitting goggles.
Hand protection:
Protective gloves resistant to chemicals, made of nitrile rubber or

other approved by the manufacturer to contact with the product.
Skin and body protection:
Protective clothing of a compact fabric. Working boots.
Additional information:
Prior to handling with this product, please select the appropriate

footwear and addition-al skin protection measures, based on the
tasks performed and the associated risks. They are subject to
approval by the Health and Safety Specialist
Environment protection:
Emissions from ventilation or work process equipment should be

checked to ensure they comply with the requirements of
environmental protection legislation.

9.1
Information on basic physical and chemical properties

Appearance:
Solid fine white crystals
Odour or smell:
Odourless
Treshold value of odour:
pH (at 20 C):
11,5 12,5 (50 g/L)
Melting point / Freezing point:
891 C
Not applicable
Flash point (C):

Initial boilling point and distillation
range (C):
No data available
Solubility in water:
110 g/L 20 C

Rybnin 18/1
162 00 Prague 6
Tel.: +420 233 371 850

Fax: +420 233 371 860
www.agchemigroup.eu
SAFETY DATA SHEET

Date of issue:
14.1.2011
Date of revision:
5.10.2011(CLP)
Product name:
POTASSIUM CARBONATE
Flammability:
9.2
Page: 6 / 9
Not flammable
Relative density:
2270 2430 kg/m3
Bulk density:
750 kg/m3
Additional information:
No data

10.1
Reactivity:
No
10.2
Chemical stability:
Stable
10.3
Possibility of hazardous reactions:
No possible reactions
10.4
Conditions to avoid:
Humidity
10.5
Incompatible materials:
Acids
10.6
Hazardous decomposition products:
Under normal conditions of storage and use the product does not
decompose.

11.1
Information on toxicological effects

Acute toxicity:
DL50 Rat, oral > 2000 mg/kg
Skin corrosion/irritation:
Causes skin irritation
Serious eye damage/eye irritation:
Causes serious eye irritation
Respiratory or skin sensitization:
May cause respiratory irritation
Germ cell mutagenicity:
No data available
Carcinogenicity:
No data available
Reproductive toxicity:
No data available
Specific target organ toxicity - single

exposure:
May cause respiratory irritation
Specific target organ toxicity repeated exposure:
No data available
Aspiration hazard
No data available
Information on likely routes of

exposure:
Inhalation, skin/eyes,ingestion
Symptoms related to physical,chemical Contact with skin:

Irritation with redness. Defatting of the skin.
and toxilogical characteristics:
Contact with eyes:
Irritation with redness and tearing. Eyesight damage may occur.
Inhalation of dust:
Coughing,sore throat, respiratory tract irritation.
Ingestion:
Nausea, sore throat, esophagus, stomach pain. Swallowing large
quantities can cause intestinaL perforation.
Rybnin 18/1
162 00 Prague 6
Tel.: +420 233 371 850

Fax: +420 233 371 860
www.agchemigroup.eu
SAFETY DATA SHEET

Date of issue:
14.1.2011
Date of revision:
5.10.2011(CLP)
Page: 7 / 9
Product name:
POTASSIUM CARBONATE
Delayed and immediate effects as well No data available

as chronic effects from short and longterm exposure:
No data available
Interactive effects:
Other information:
No other information.

12.1
Toxicity:
Fish:
LC50 stickleback: 70 mg/L 48 hours
Algae:
No data
Invertebrates:
EC50 daphnia: 160 mg/L 6 hours
Bacteries:
No data
Soluble in water, increases pH
12.3
Persistence and degradability:

Bioaccumulative potential:
12.4
Soil mobility:
No data
12.5
PBT and vPvB assessment:

Other adverse effects
This substance is neither PBT nor vPvB
12.2
12.6
Not applicable
Hard depands on the pH. In small quantities is not hazardous to

the environment.
SECTION 13: DISPOSAL CONSIDERATIONS:

13.1
Methods for waste disposal:
The generation of waste should be avoided or minimized

wherever possible. Significant quantities of waste product
residues should not be disposed of via the foul sewer but
processed in a suitable effluent treatment plant. Dispose of
surplus and non-recyclable products via a licensed waste
disposal contractor. Disposal of this product, solutions and
any by-products should at all times comply with the
requirements of environmental protection and waste
disposal legislation and any regional local authority
requirements.

14.1
UN number: Not applicable
14.5
Kemler code: Not applicable
14.2
Proper shipping name UN for consignment: Not applicable
14.3
Surface transportation ADR:
Not applicable
Railway transportation RID:
Not applicable
Sea transportation IMDG:
Not applicable
Air transportation ICAO/IATA:
Not applicable
Class / Classes of danger for transportation : Not applicable

Rybnin 18/1
162 00 Prague 6
Tel.: +420 233 371 850

Fax: +420 233 371 860
www.agchemigroup.eu
SAFETY DATA SHEET

Date of issue:
14.1.2011
Date of revision:
5.10.2011(CLP)
Page: 8 / 9
Product name:
POTASSIUM CARBONATE
14.4
Packing group: Not applicable
14.6
Danger for environment: Not applicable
14.7
Special safety measures for the user: Not applicable

Addition information: Durin transport avoid the influence of humidity!
14.8
Bulk transportation according to appendix II MARPOL 73/78 and decree IBC: No data

15.1
Regulation concerning safety, health and environement / specific legal regulations concerning the product
or mixture:
In the Czech republic:
Law 356/2003 Sb., and respective implementing regulations
Law 102/2001 Sb., in valid version
Law 185/2001 Sb., in valid version
see 44a of the Law 258/2000 Sb., Part 8 section (6); (8); (9) and (10)
Regulation EU 1907/2006 (REACH)
Regulation EU 1272/2008 (CLP)
15.2
Chemical safety assessment:
Not applicable
15.5
Further regulations:
This substance is not SVHC and is not listed in the Annex XIV or
XVII of REACH Regulation

Changes of MSDS made within framework of revision:
This MSDS was worked out in compliance with CLP demands. Compared to the previous version of
14.01.2011 was further clarified industrial, professional and consumer use.
Explications or legend to the used abbreviations:
Skin Irrit. 2 Skin corrosion/irritation, Category 2
Eye Irrit. 2 Serious eye damage/eye irritation Category 2
STOT Single Exp.3 Specific target organ toxicity Single exposure Category 3
Important references to literature and sources of information:
MSDS of the producer
List of relevant standard phrases (H phrases) / ( P phrases):
H 315 Causes skin irritation
H 319 Causes serious eye irritation
H 335 May cause respiratory irritation
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash with soap and water thoroughly after handling.
P280: Wear protective gloves/protective clothing/
eye protection/face protection.
P305+P351+P338: IF IN EYES: Rinse cautiously with water
Rybnin 18/1
162 00 Prague 6
Tel.: +420 233 371 850

Fax: +420 233 371 860
www.agchemigroup.eu
SAFETY DATA SHEET

Date of issue:
14.1.2011
Date of revision:
5.10.2011(CLP)
Product name:
POTASSIUM CARBONATE
Page: 9 / 9
for several minutes. Re-move contact lenses, if present and

easy to do. Continue rinsing.
P362: Take off contaminated clothing and wash before reuse.
P403+P233: Store in a well-ventilated place. Keep container
tightly closed.
R 36/37/38 Irritant to eyes, respiratory system and skin
Instructions for staff training:
Regular training on handling with chemicals
The above information is believed to be correct but does not purport to be all inclusive and shall be used
only as a guide. The information is based on the preset knowledge and is applicable to the product with
regard to appropriate safety precaution. It does not represent any guarantee of the properties of the
product
This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Rybnin 18/1
162 00 Prague 6
Tel.: +420 233 371 850

Fax: +420 233 371 860
www.agchemigroup.eu
Version:2
Potassium chloride
Date: 20-06-2011
Supersedes: 04-07-2008
Safety Data Sheet
OA00130
according to Regulation (EC) No. 1907/2006
1.
Identification of the substance/mixture and of the company/undertaking
1.1.
Product identifier
Product name - Trade name
: Potassium chloride
1.2.
Relevant identified uses of the substance or mixture and uses advised against
1.2.1.
Relevant identified uses
No additional information available

1.2.2.
Uses advised against

1.3.
Details of the supplier of the safety data sheet
Univar Zwijndrecht N.V.

Noordweg 3
3336 LH Zwijndrecht - Nederland
T +31 (0)78 6250 000 - F +31 (0)78 6250 050
sds@univareurope.com - www.univareurope.com
1.4.
Emergency telephone number
Country
NETHERLANDS
Official advisory body

National Poisons Information Centre
Address
National Institute for Public Health and the Environment, NB this

service is only available to health professionals
2.
Hazards identification
2.1.
Classification of the substance or mixture
2.1.1.
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Emergency number
+31 30 274 88 88
P.O. Box 1
3720 BABilthoven
Not classified
2.1.2.
Classification according to Directive 67/548/EEC or 1999/45/EC
Not classified
2.1.3.
Adverse physicochemical, human health and environmental effects

2.2.
Label elements
2.2.1.
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
No labelling applicable
2.2.2.
Labelling according to Directive 67/548/EEC or 1999/45/EC
No labelling applicable
2.3.
Other hazards
3.
Composition/information on ingredients
3.1.
Substances
Name
Product identifier
Classification according to
Directive 67/548/EEC
Potassium chloride
(CAS No.)7447-40-7
~ 98
Not classified
(EC no)231-211-8
Name
Product identifier
Classification according to
Regulation (EC) No.
1272/2008 [CLP]
Potassium chloride
(CAS No.)7447-40-7
~ 98
Not classified
(EC no)231-211-8
Full text of R-, H- and EUH-phrases: see section 16.

3.2.
Mixtures
Not applicable
20-06-2011
EN (English)
1/4
Potassium chloride
Safety Data Sheet
4.
First aid measures
4.1.
Description of first aid measures
After inhalation
: Dust of the product, if present, may cause respiratory irritation after an excessive inhalation
exposure. Seek medical attention if ill effect or irritation develops. Remove the victim into fresh
air.
After skin contact
: Wash skin thoroughly with mild soap and water.
After eye contact
: Flush with lukewarm water for 15 minutes.
After swallowing
: Rinse mouth.
4.2.
Most important symptoms and effects, both acute and delayed
Inhalation
: Not expected to be an irritant.
Skin contact
Eye contact
4.3.
Indication of any immediate medical attention and special treatment needed
5.
Firefighting measures
5.1.
Extinguishing media
Suitable extinguishing media

5.2.
: Use extinguishing media appropriate for surrounding fire.
Special hazards arising from the substance or mixture

5.3.
Advice for firefighters
6.
Accidental release measures
6.1.
Personal precautions, protective equipment and emergency procedures
6.1.1.
For non-emergency personnel
6.1.2.
: Avoid making dust.
For emergency responders

6.2.
Environmental precautions
Avoid release to the environment.

6.3.
Methods and material for containment and cleaning up
Methods for cleaning up

6.4.
: Contain and collect as any solid. Prevent entry to sewers, ground and public waters.
Reference to other sections
7.
Handling and storage
7.1.
Precautions for safe handling

7.2.
Conditions for safe storage, including any incompatibilities
Technical measures
: No special requirements.
Storage
: Store in dry, well-ventilated area.
7.3.
Specific end use(s)
8.
Exposure controls/personal protection
8.1.
Control parameters
20-06-2011
EN (English)
2/4
Potassium chloride
Safety Data Sheet
8.2.
Exposure controls
- Hand protection
: Wear gloves.
- Eye protection
: Safety glasses with side guards should be worn to prevent injury from airborne particles and/or
other eye contact with this product.
- Skin protection
: If skin contact or contamination of clothing is likely, protective clothing should be worn.
- Respiratory protection
: Approved dust or mist respirator should be used if airborne particles are generated when
handling this material.
9.
Physical and chemical properties
9.1.
Information on basic physical and chemical properties
Appearance
: Solid.
Physical state
: Solid
Colour
: White.
Odour
: Odourless.
pH value
: 5,4-8,6 (5%)
Melting point
: 770 C
Boiling point
: 1420 C
Density
: 1987 kg/l
Water solubility
: 340 g/kg
9.2.
Other information
10.
Stability and reactivity
10.1.
Reactivity

10.2.
Chemical stability
Stable under normal conditions.

10.3.
Possibility of hazardous reactions

10.4.
Conditions to avoid
Moisture.
10.5.
Incompatible materials

10.6.
Hazardous decomposition products
11.
Toxicological information
11.1.
Information on toxicological effects
12.
Ecological information
12.1.
Toxicity

12.2.
Persistence and degradability

12.3.

12.4.
Mobility in soil

12.5.
Results of PBT and vPvB assessment

12.6.
Other adverse effects

20-06-2011
EN (English)
3/4
Potassium chloride
Safety Data Sheet
13.
Disposal considerations
13.1.
Waste treatment methods
Waste treatment methods
: Dispose in a safe manner in accordance with local/national regulations.
Additional information
: After last use, the packing should be totally empty and closed.
14.
Transport information
No dangerous good in sense of transport regulations.
15.
Regulatory information
15.1.
Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1.
EU-Regulations

15.1.2.
National regulations
Water hazard class
: 11 - Low toxicity to aquatic organisms
Remediation Efforts
: B - Minimize discharge; apply best available techniques
15.2.
Chemical safety assessment
16.
Other information
Further information
: The contents and format of this MSDS are in accordance with regulation (EC) no. 1907/2006 of
the European Parliament and Council of 18 December 2006 concerning the registration,
evaluation, authorisation and restriction of Chemicals (REACH). Appendix Of the raw materials
in chapter 3 at moment of reporting of this material safety data sheet, chemical safety reports
have not been registered in the scope of regulation (EC) no. 1907/2006.
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product.
20-06-2011
EN (English)
4/4
Page : 1
MATERIAL SAFETY DATA SHEET
Revision nr : 3
Date : 23 / 3 / 2009
Supersedes : 30 / 5 / 2006
Potassium hydroxide flakes
CA25041
Label 8 : Corrosive
substance.
C : Corrosive
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

: Potassium hydroxide flakes
: Industrial.
: Univar Zwijndrecht N.V.
Noordweg 3
3336 LH Zwijndrecht
Tel.: +31 786250000
Fax: +31 786250050
E-mail: sds@univareurope.com
Web: www.univareurope.com
: Contact your National Anti Poison Centre. (Only to be contacted by a physician)
Trade name
Use
Company identification
Emergency phone nr
2. HAZARDS IDENTIFICATION
: Corrosive.
Hazards identification
3. COMPOSITION / INFORMATION ON INGREDIENTS

This product is considered to be hazardous and contains hazardous components.
Substance name
Potassium hydroxide
Other information
Value(s)
50 to 100 %
CAS
1310-58-3
EG
215-181-3
EC index
019-002-00-8
Classification
Xn; R22
C; R35
: Full text of R-Phrases : see under section 16.
4. FIRST AID MEASURES

First aid measures
- Prevention
- Inhalation
- Skin contact
- Eye contact
- Ingestion
: Immediately remove contaminated clothing.

: Dust from this product, if present, may cause respiratory irritation following an
excessive inhalation exposure.
Seek medical attention if ill effect or irritation develops.
Remove victim to fresh air.
: Wash skin thoroughly with mild soap and water.
: Flush with lukewarm water for 15 minutes.
: Seek medical attention immediately.
Rinse mouth.
5. FIRE-FIGHTING MEASURES
Flammable class
Extinguishing media
- Suitable extinguishing media
: Not combustible.
: Use extinguishing media appropriate for surrounding fire.
Page : 2
Revision nr : 3
Date : 23 / 3 / 2009
Supersedes : 30 / 5 / 2006
CA25041
5. FIRE-FIGHTING MEASURES (continued)

- Unsuitable extinguishing media
Special procedures
Special protection measures
: Water
: Evacuate unnecessary personnel.
Stop release.
: S36 : Wear suitable protective clothing.
Use self-contained breathing apparatus
6. ACCIDENTAL RELEASE MEASURES

Personal precautions
Environmental precautions
Clean up methods
Contaminated product, soil, water
: Avoid making dust.

: Avoid release to the environment.
: Contain and collect as any solid.
Prevent entry to sewers, ground and public waters.
7. HANDLING AND STORAGE

General
Precautions in handling and storage
Storage
Storage - away from
: Use good housekeeping practices to avoid rendering dust airborne.

Handle in accordance with good industrial hygiene and safety procedures.
: Store in dry, well-ventilated area.
: Acids
8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Occupational Exposure Limits
Personal protection
- Respiratory protection
- Hand protection
- Eye protection
- Skin protection
- Ingestion
Industrial hygiene
: Potassium hydroxide : MAC Value - France : 2 mg/m3

: Approved dust or mist respirator should be used if airborne particles are generated
when handling this material.
: Wear gloves.
: Safety glasses with side guards should be worn to prevent injury from airborne
particles and/or other eye contact with this product.
: If skin contact or contamination of clothing is likely, protective clothing should be
worn.
: When using, do not eat, drink or smoke.
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state
Colour
Odour
pH value
Density
Melting point [C]
:
:
:
:
:
:
Flakes.
White.
Odourless.
14 (56g/l)
2.04
360
Page : 3
Revision nr : 3
Date : 23 / 3 / 2009
Supersedes : 30 / 5 / 2006
CA25041
9. PHYSICAL AND CHEMICAL PROPERTIES (continued)

Bulk density [kg/m3]
Solubility in water [g/100ml]
: 1200
: 112
10. STABILITY AND REACTIVITY

Stability
Conditions to avoid
Materials to avoid
: Stable under normal conditions.

: Moisture.
: Acids
Metals.
11. TOXICOLOGICAL INFORMATION

Toxicity information
Acute toxicity
Effects by ingestion
Effects on skin contact
Effects on inhalation
Effects on eye contact
On ingredients
Potassium hydroxide
:
:
:
:
Severe skin irritant.
Severe irritation
Severe eye irritant.
: Rat oral LD50 [mg/kg] : 365
12. ECOLOGICAL INFORMATION

Ecological effects information
On ingredients
Potassium hydroxide
Other information
National prescriptions
WGK class (Germany)
General evaluation method (NL)
: LC50-96 Hour - fish [mg/l] : 80
: Water hazard class 1 : slightly hazardous for water

: Water hazard class 11
Sanitizing effort B
13. DISPOSAL CONSIDERATIONS

Disposal method
Treatment of dirty packing

: After last use, the packing should be totally empty and closed.
14. TRANSPORT INFORMATION

UN No.
- Class
- Packing group
Labelling ADR
: 1813
: 8
: II
Page : 4
Revision nr : 3
Date : 23 / 3 / 2009
Supersedes : 30 / 5 / 2006
CA25041
14. TRANSPORT INFORMATION (continued)

- Warning panel
Proper shipping name
Sea transport
- IMDG-Marine pollution
- EMS-Nr
: 80
: UN1813 POTASSIUM HYDROXIDE, SOLID, 8, II
: No.
: F-A, S-B
15. REGULATORY INFORMATION

EC Labelling
: Classification and labelling following EC directives 67/548/EEC and 1999/45/EC and

their adaptions to technical progres
Symbol(s)
Contains
: Corrosive.
: EG : 215-181-3
Potassium hydroxide
: R22 : Harmful if swallowed.
R35 : Causes severe burns.
: S1/2 : Keep locked up and out of reach of children.
S26 : In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36/37/39 : Wear suitable protective clothing, gloves and eye/face protection.
S45 : In case of accident or if you feel unwell, seek medical advice immediately (
show the label when possible).
R Phrase(s)
S Phrase(s)
16. OTHER INFORMATION

: R22 : Harmful if swallowed.
R35 : Causes severe burns.
The contents and format of this MSDS are in accordance with regulation (EC) no. 1907/2006 of the European Parliament and
Council of 18 December 2006 concerning the registration, evaluation, authorisation and restriction of Chemicals (REACH).
Appendix Of the raw materials in chapter 3 at moment of reporting of this material safety data sheet, chemical safety reports
have not been registered in the scope of regulation (EC) no. 1907/2006.
List of relevant R phrases
DISCLAIMER OF LIABILITY The information in this MSDS was obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling,
storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we
do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with
the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the
product is used as a component in another product, this MSDS information may not be applicable.
End of document
SDS No.
11326
Revision 7
SAFETY DATA SHEET

SAFE-SCAV* NA
Product name
SAFE-SCAV* NA
Identified uses
Oxygen Scavenger

Supplier
M-I SWACO
Endeavour Drive
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288

and Africa +44 (0) 1235 239 671, USA 001 281 561 1600.
Xi;R36. R31.
2.2. Label elements

Labelling
Irritant
Risk Phrases
R31
R36
Contact with acids liberates toxic gas.

Irritating to eyes.
S25
S26
Avoid contact with eyes.
Safety Phrases
In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
2.3. Other hazards

3.1. Substances
1/ 6
SDS No.
11326
SAFE-SCAV* NA
AMMONIUM BISULPHITE
CAS-No.: 10192-30-0
40-70%
EC No.: 233-469-7

EUH031
Eye Irrit. 2 - H319
Xi;R36.
R31.
WATER
CAS-No.: 7732-18-5
30-60%
EC No.: 231-791-2

Not classified.
Not classified.
Inhalation
continues.
Ingestion
continues.
Skin contact
washing.
Eye contact
Inhalation.
Ingestion
Skin contact
Eye contact
Extinguishing media
Specific hazards
Fire or high temperatures create: Oxides of: Sulphur. Ammonia or amines. and Nitrous gases (NOx).
2/ 6
SDS No.
SAFE-SCAV* NA
This product slowly releases sulphur dioxide in contact with air. Ventilate well, avoid breathing vapours. Use approved respirator if air
contamination is above accepted level. Avoid spilling, skin and eye contact.
Store in a cool and well-ventilated place. Store in closed original container at temperatures between 5C and 30C.
Name
STD
SULPHUR DIOXIDE
WEL
TWA - 8 Hrs
1 ppm
2.6 mg/m3
STEL - 15 Min
1 ppm
Notes
2.6 mg/m3
WEL = Workplace Exposure Limit.

Ingredient Comments
Exposure Limit noted above is for decomposition product Sulphur Dioxide.
Respiratory protection must be used if air contamination exceeds acceptable level. Use respiratory equipment with gas filter, type K.
Hand protection
Use protective gloves made of: Butyl rubber. Neoprene. or Nitrile.
Eye protection
Other Protection
3/ 6
11326
SDS No.
SAFE-SCAV* NA
Appearance
Liquid
Colour
Colourless to pale yellow.
Odour
Pungent. Sulphur.
Solubility
Miscible with water
105C
Relative density
1.27 - 1.39 @ 20C
Vapour density (air=1)
<1
Vapour pressure
18 mmHg 20C
4.5 - 5.5 @ 20C
Flash point (C)
N/A

Not relevant
10.1. Reactivity
Reacts violently with strong oxidising substances. Reaction with: Acids.
Generates toxic gas in contact with acid.
Avoid exposing to heat and contact with strong oxidising substances. Avoid contact with acids.
Materials To Avoid
Strong oxidising substances. Strong acids. Strong alkalis.
Sulphurous gases (SOx). Nitrous gases (NOx).
Other Health Effects
Bisulfites may cause skin sensitization in sulfite sensitive persons. Bisulfites may also cause respiratory sensitization in asthmatics and
sulfite sensitive persons.
> 2000 mg/kg Rat
Inhalation
Ingestion
May irritate and cause stomach pain, vomiting and diarrhoea.
Skin contact
Irritating and may cause redness and pain.
Eye contact
Irritating to eyes. Spray and vapour in the eyes may cause irritation and smarting.
Route of entry
Target Organs
Ecotoxicity
12.1. Toxicity
Acute Fish Toxicity
Do not empty into river: may cause impoverishment of oxygen and ammonia increase.
4/ 6
11326
SDS No.
SAFE-SCAV* NA
Degradability
The product is biodegradable.
The product does not contain any substances expected to be bioaccumulating.
Mobility:
Mobile.
None known.
General
ADR/RID).
14.1. UN number
Not applicable.
Not applicable.
Not applicable.
14.4. Packing group
Not applicable.
No.
Not applicable.
Not applicable.
EU Legislation
WGK 3
5/ 6
11326
SDS No.
11326
SAFE-SCAV* NA
General information
HMIS Health - 3 HMIS Flammability - 0 HMIS Physical Hazard - 1
Information Sources
Revision Comments
Classification updated. Compiled or Revised by Ewan MacLeod
Issued By
Bill Cameron
Revision Date
23-06-11
Revision
Supersedes date
16-05-11
SDS No.
11326

R31
R36
Irritating to eyes.

EUH031
H319
Causes serious eye irritation.
Disclaimer
6/ 6
SDS No.
10707
Revision 8
SAFETY DATA SHEET

SAFE-CIDE*
Product name
SAFE-CIDE*
Identified uses
Biocide

Supplier
M-I SWACO
Endeavour Drive
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288

and Africa +44 (0) 1235 239 671, USA 001 281 561 1600.
Physical and Chemical Hazards Not classified.

Human health
Acute Tox. 4 - H302;Acute Tox. 2 - H330;Skin Sens. 1 - H317
Environment
Not classified.
T;R23. Xn;R22. R43.
2.2. Label elements
Contains
2,2',2''-(HEXAHYDRO-1,3,5-TRIAZINE-1,3,5-TRIYL)TRIETHANOL
Label In Accordance With (EC) No. 1272/2008
Signal Word
Danger
Hazard Statements
H302
H317
H330
May cause an allergic skin reaction.
Fatal if inhaled.
P280
P310
P501A
Wear protective gloves/protective clothing/eye protection/face protection.

Immediately call a POISON CENTER or doctor/physician.
Precautionary Statements
Dispose of waste and residues in accordance with local authority

requirements. This material and its container must be disposed of as a
hazardous waste.
1/ 7
SDS No.
10707
SAFE-CIDE*
Supplementary Precautionary Statements
P261
P363
P405
Avoid breathing vapour/spray.

Wash contaminated clothing before reuse.
Store locked up.
2.3. Other hazards

3.2. Mixtures
2,2',2''-(HEXAHYDRO-1,3,5-TRIAZINE-1,3,5-TRIYL)TRIETHANOL
CAS-No.: 4719-04-4
60-100%
EC No.: 225-208-0

Acute Tox. 4 - H302
Acute Tox. 2 - H330
Skin Sens. 1 - H317
T;R23.
Xn;R22.
R43.
2-AMINOETHANOL
CAS-No.: 141-43-5
1-5%
EC No.: 205-483-3
C;R34
Xn;R20/21/22

Acute Tox. 4 - H302
Acute Tox. 4 - H312
Acute Tox. 4 - H332
Skin Corr. 1B - H314
STOT SE 3 - H335
ETHYLENDIAMINOTETRAACETIC ACID, TETRASODIUM SALT
CAS-No.: 64-02-8
1-5%
EC No.: 200-573-9

Acute Tox. 4 - H302
Eye Irrit. 2 - H319
Xn;R22.
Xi;R36.
Inhalation
continues.
Ingestion
Do not induce vomiting. Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical
attention.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention.
Eye contact
Continue to rinse for at least 15 minutes. Get medical attention.
2/ 7
SDS No.
SAFE-CIDE*
Inhalation.
Toxic by inhalation.
Ingestion
Skin contact
May cause sensitisation by skin contact.
Eye contact
Extinguishing media
Specific hazards
Fire or high temperatures create: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Nitrous gases (NOx).
Sulphurous gases (SOx).
Name
STD
2-AMINOETHANOL
WEL
TWA - 8 Hrs
1 ppm
WEL = Workplace Exposure Limit.

Sk = Can be absorbed through skin.
3/ 7
2,5 mg/m3
STEL - 15 Min
3 ppm
7,6 mg/m3
Notes
Sk
10707
SDS No.
SAFE-CIDE*
Wear suitable respiratory protection. A minimum of a chemical respirator with organic vapour cartridge should be worn. If there are
conditions in which this triazine containing product produces a vapor, a chemical respirator with A1 +Formaldehyde and P2 particulate
pre-filter combination would be required.
Hand protection
Chemical resistant gloves required for prolonged or repeated contact. Use protective gloves made of: Nitrile. or Neoprene.
Eye protection
Other Protection
Appearance
Liquid
Colour
Colourless to pale yellow.
Odour
Characteristic.
Solubility
Miscible with water
>100C
Relative density
1.14 - 1.18g/cm3 @ 20C
Vapour pressure
14.8 hPa @ 20C
9.5-11.5 @ 1%
Viscosity
1850mPas @ 20C
Flash point
68C
Auto Ignition Temperature (C)
>200C

Not relevant
10.1. Reactivity
Not known.
Not known.
Materials To Avoid
Avoid contact with acids. Avoid contact with strong oxidisers. Avoid contact with strong reducing agents.
Fire or high temperatures create: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Nitrous gases (NOx).
Sulphurous gases (SOx).
4/ 7
10707
SDS No.
SAFE-CIDE*
Toxicological information
This product may contain or release trace amounts of formaldehyde. The International Agency for Research on Cancer (IARC) has
classified formaldehyde as a Group 1carcinogen(limited evidence in humans, sufficient evidence in animals). exposure to formaldehyde
has been linked to adverse reproductive effects in some human and animal studies. In other reproductive studies, however, no adverse
effects were noted. (Meditext). Formaldehyde may also cause skin and respiratory sensitisation (allergic reaction).
Acute toxicity:
1400 mg/kg Rat
Acute Toxicity (Inhalation LC50)
0.371
mg/l 4h. Method - Aerosol.
Aspiration hazard:
Inhalation
Ingestion
Skin contact
Eye contact
Irritating to eyes.
Route of entry
Target Organs
Ecotoxicity
12.1. Toxicity
Acute Fish Toxicity
LC50 96 hours > 100 mg/l Brachydanio rerio (Zebra Fish)
> 100 mg/l
EC 50, 48 Hrs, Daphnia, mg/l
IC 50, 72 Hrs, Algae, mg/l
10-100 mg/l

Degradability
The product is biodegradable.
Mobility:
No data available.
None known.
5/ 7
10707
SDS No.
SAFE-CIDE*
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements. This material
and its container must be disposed of as hazardous waste.
14.1. UN number
UN No. (ADR/RID/ADN)
2810
UN No. (IMDG)
2810
UN No. (ICAO)
2810

Proper Shipping Name
TOXIC LIQUID, ORGANIC, N.O.S. (2, 2', 2"-(hexahydro -1, 3, 5-triazine -1, 3, 5-triyl) triethanol)

ADR/RID/ADN Class
6.1
ADR/RID/ADN Class
Class 6.1:Toxic substances.
IMDG Class
6.1
ICAO Class/Division
6.1
Transport Labels
TOXIC
6
14.4. Packing group
ADR/RID/ADN Packing group
II
IMDG Packing group
II
ICAO Packing group
II

No.

EMS
F-A, S-A
Emergency Action Code
2X
Hazard No. (ADR)
60
Tunnel Restriction Code
(D/E)
Not applicable.
6/ 7
10707
SDS No.
10707
SAFE-CIDE*
EU Legislation
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New
Zealand (NZIoC), Phillipines (PICCS), United States (TSCA).
General information
Respirator.
Information Sources
Revision Comments
Classification updated. The following sections have been revised: 11, Compiled or revised by Sandra McWilliam
Issued By
Bill Cameron
Revision Date
01-11-11
Revision
Supersedes date
13-07-11
SDS No.
10707

R34
Causes burns.
R20/21/22
Harmful by inhalation, in contact with skin and if swallowed.
R22
R36
Irritating to eyes.
R37
Irritating to respiratory system.
R43
R23

H302
H312
Harmful in contact with skin.
H314
Causes severe skin burns and eye damage.
H317
May cause an allergic skin reaction.
H319
H330
Fatal if inhaled.
H332
Harmful if inhaled.
H335
May cause respiratory irritation.
Disclaimer
7/ 7
Revision Date 31-Jan-2012
SDS No.
11302
Revision 7
Supersedes date 10-Feb-2011
SAFETY DATA SHEET

SAFE-COR*
Product name
SAFE-COR*
Identified uses
Corrosion inhibitor.

Supplier
M-I SWACO
Endeavour Drive
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288

and Africa +44 (0) 1235 239 671, USA 001 281 561 1600.
Xi;R36. R52/53.
2.2. Label elements

Labelling
Irritant
Risk Phrases
R36
R52/53
Irritating to eyes.
S25
S26
Avoid contact with eyes.
Safety Phrases
S60
Harmful to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.
In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
This material and its container must be disposed of as hazardous waste.
2.3. Other hazards

3.2. Mixtures
1/ 6
SDS No.
11302
SAFE-COR*
WATER
60-100%

Not classified.
Not classified.
ETHANOL, 2,2'-OXYBIS-, REACTION PRODUCTS WITH AMMONIA, MORPHOLINE DERIVATIVES RESIDUES

CAS-No.: 68909-77-3
EC No.: 272-712-1

Eye Irrit. 2 - H319
Aquatic Chronic 3 - H412
Xi;R36.
R52/53.
Inhalation
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. DO NOT induce vomiting. Get medical
attention immediately.
Skin contact
washing.
Eye contact
Continue to rinse for at least 15 minutes and get medical attention.
Inhalation.
Ingestion
Skin contact
Eye contact
May cause severe irritation to eyes.
Extinguishing media
Water. Carbon dioxide (CO2).
Not known.
2/ 6
30-60%
SDS No.
SAFE-COR*
Store in tightly closed original container in a dry, cool and well-ventilated place. Suitable containers: Mild steel.
Ingredient Comments
Hand protection
Use protective gloves made of: Rubber, neoprene or PVC.
Eye protection
Wear splash-proof eye goggles to prevent any possibility of eye contact.
Other Protection
Appearance
Liquid
Colour
Dark. Amber.
Odour
Slight odour.
Solubility
Soluble in water.
3/ 6
11302
SDS No.
SAFE-COR*
>100C
Relative density
1.03-1.05 @ 20 C
>10.2
Flash point
>100C CC (Closed cup).

Not relevant
10.1. Reactivity
Not known.
Not known.
Materials To Avoid
Strong acids. Nitriles.
Acute toxicity:
> 5000 mg/kg Rat
> 2000 mg/kg
*Based on components
Aspiration hazard:
Not anticipated to present an aspiration hazard based on chemical structure.
Inhalation
Ingestion
May irritate and cause stomach pain, vomiting and diarrhoea.
Skin contact
Irritating and may cause redness and pain.
Eye contact
May cause severe irritation to eyes.
Route of entry
Target Organs
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at env@miswaco.slb.com.
12.1. Toxicity
Acute Fish Toxicity
4/ 6
11302
SDS No.
SAFE-COR*
LC50 96 hours > 45 mg/l
*Aquatic species (calculated data following Dir. 1999/45/CE)
Acute Toxicity - Aquatic Invertebrates
EC50 48 hours > 100 mg/l Daphnia magna
Degradability
The product is not readily biodegradable.
Mobility:
The product is soluble in water.
None known.
General
ADR/RID).
14.1. UN number
Not applicable.
Not applicable.
Not applicable.
14.4. Packing group
Not applicable.
No.

Not applicable.
Not applicable.
5/ 6
11302
SDS No.
11302
SAFE-COR*
EU Legislation
Contact REACH@miswaco.slb.com for REACH information. Complies with the following national/regional chemical inventory requirements:
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), New Zealand (NZIoC), United States (TSCA).
General information
Respirator.
Information Sources
Revision Comments
Compiled or Revised by Ewan MacLeod Classification updated.
Issued By
Bill Cameron
Revision Date
31-Jan-2012
Revision
Supersedes date
10-Feb-2011
SDS No.
10031

R52/53
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R36
Irritating to eyes.

H319
H412
Harmful to aquatic life with long lasting effects.
Disclaimer
6/ 6
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page1 of27
1.IDENTIFICATIONOFTHESUBSTANCE/MIXTUREANDOFTHECOMPANY/UNDERTAKING
1.1ProductIdentifier
ProductName
ChemicalName
AlternativeName
ChemicalFormula
CASNumber
ECNumber
IndexNumber
1.2Relevantidentifieduses
:SODIUMCARBONATE
:Sodiumcarbonate
: Disodiumcarbonate,sodaash
:Na2CO3
:497198
:2078388
: 011005002
: glassproduction; intermediatein chemicalsproduction;water
treatmentchemicals;washingandcleaningproducts;other
industrial,professionalandconsumeruses.Exposurescenarios
coveringusescanbefoundintheAnnex
1.2.1Usesadvisedagainst
1.3CompanyDetails
CompanyName
Address
Telephone
1.4EmergencyTelephoneNumber
EmergencyNumber(24hours)
: noneidentified
:TataChemicalsEurope
:WinningtonLane
:MondHouse
:Northwich
:Cheshire
:CW84DT
:+44(0)1606724000
:+44(0)1606781353
:www.tatachemicals.com/europe
:msdstce@tatachemicals.com
:+44(0)1606781000
2. HAZARDS IDENTIFICATION
2.1Classificationofthesubstance
2.1.1ClassificationaccordingtoRegulation(EC)1272/2008[CLP/GHS]
Classification:EyeIrritant2
2.1.2ClassificationaccordingtoDirective67/548/EEC
Classification:Irritatingtoeyes
2.2Labelling
2.2.1LabellingaccordingtoRegulation(EC)1272/2008[CLP/GHS]
HazardPictograms:
SignalWord
HazardStatements
H319
:Warning
:Causesseriouseyeirritation
Winnington Lane, Northwich, Cheshire, CW8 4DT, United Kingdom

Tel +44 (0) 1606 72400 Fax +44(0) 1606 781353 www.tatachemicals.com
Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page2 of27
Precautionary
Statements:
P264
P280
P305+P351+P338
P337+P313
:Washhandsandfacethoroughlyafterhandling
:Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection
:IFINEYES,rinsecautiouslywithwaterforseveralminutes,removecontact
lenses,ifpresentandeasytodo.Continuerinsing
:Ifeyeirritationpersists:Getmedicaladvice/attention
2.2.2LabellingaccordingtoDirective67/548/EEC
Symbol
RiskPhrases:
R36
SafetyPhrases:
S2
S22
S24
:Xiirritant
:Irritatingtoeyes
:Keepoutofthereachofchildren
:Donotbreathedust
:Avoidcontactwithskin
2.3Otherhazards
ThesubstancedoesnotmeetthecriteriaforPBTorvPvBaccordingtoAnnexXIIIoftheREACHRegulation
EC1907/2006(aninorganicsubstance)
Nootherhazardsidentified
3.COMPOSITION/INFORMATIONONINGREDIENTS
3.1Substance
Mainconstituent
Formula
Purity%w/w(typical)
>99.0
Sodiumcarbonate
Na2CO3
IMPURITIES
Noimpuritiesrelevantforclassificationandlabelling
CASNumber
497198
ECNumber
2078388
4.FIRSTAIDMEASURES
4.1Descriptionoffirstaidmeasures
Generaladvice
Noknowndelayedeffects
Followinginhalation
Removetofreshair,keepwarmandatrest
Ifsymptomspersist,seekmedicalattention
Followingskincontact
Removecontaminatedclothingandwashbeforereuse
Washoffwithsoapandwater
Ifsymptomspersist,seekmedicalattention
Followingeyecontact
Removecontactlensesifpresent
Irrigateeyethoroughlywitheyewashsolutionorcleanwaterforatleast15minutes

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page3 of27
Eyelidsshouldbeheldawayfromtheeyeballtoensurethoroughrinsing
Ifeyeirritationpersistsseekmedicalattention
Afteringestion
DONOTinducevomiting
Washoutmouthwithwaterandgiveplentyofwatertodrink(atleast300ml.)
Obtainmedicaladviceifnecessary.
5.FIREFIGHTINGMEASURES
5.1ExtinguishingMedia
5.1.1Suitableextinguishingmedia
Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurroundingenvironment
5.1.2Unsuitableextinguishingmedia
None
5.2Specialhazardsarisingfromthesubstanceormixture
None
5.3Adviceforfirefighters
Nospecialprecautionsrequired
6. ACCIDENTAL RELEASE MEASURES
6.1PersonalPrecautions
6.1.1Fornonemergencypersonnel
Keepdustlevelstoaminimum
Wearsuitableprotectiveequipment(seeSection8)
6.2EnvironmentalPrecautions
Preventuncontrolleddischargesintotheenvironment(rivers,watercourses,sewersetc.)
Avoidanymixturewithanacidintosewer/drains(CO2gasformation)
6.3Methodsforcontainmentandcleanup
Inallcasesavoiddustformation
Usevacuumsuction,orshovelintobags
Collectasmuchaspossibleinasuitablecleancontainer,preferablyforreuse,otherwisefordisposal(See
Section13)
6.4Referencetoothersections
Formoreinformationonexposurecontrols/personalprotectionordisposalconsiderations,pleasesee
section8and13
7. HANDLING AND STORAGE
7.1PrecautionsforSafeHandling
7.1.1Protectivemeasures
Keepdustlevelstoaminimum
Ensureadequateventilation
Wearprotectiveequipment(seeSection8.2)
Keepawayincompatiblematerials
7.1.2Adviceongeneraloccupationalhygiene
Goodpersonalandhousekeepingpracticestobeused
Nodrinking,eatingorsmokingattheworkplace
7.2Conditionsforsafestorage,includinganyincompatibilities
Storeinadryplace

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page4 of27
Storeinoriginal,closedandcorrectlylabelledcontainer
Storeawayfromincompatiblematerials
8.EXPOSURECONTROLS/PERSONALPROTECTION
8.1ControlParameters
8.1.1OccupationalExposureStandards
NotlistedbyH&SE(GuidanceNoteEH40)orACGIH
RecommendedLimits:WEL10mg/m3(totaldust)(8hrTWA)
4mg/m3(respirabledust)(8hrTWA)
8.1.2DNELs/PNEC
Exposureroute
ofrelevance
Inhalation
DNELs(localeffects)
Workers
Longterm
Acute
Generalpopulation
Longterm
10mg/m3
Acute
PNEC:
ThelowestL(E)C50valueis>100mg/l(48hEC50is200mg/lindaphnids(Ceriodaphniasp)).Thereforesodiumcarbonate
neednotbeclassifiedaccordingtoDirective67/548/EECandEUClassification,LabellingandPackagingofSubstances
andMixtures(CLP)Regulation(EC)No.1272/2008
EnvironmentalClassificationisnotwarranted
8.2ExposureControls
8.2.1Appropriateengineeringcontrols
provideappropriateexhaustventilationatplaceswheredustisformed
applytechnicalmeasurestocomplywiththeoccupationalexposurelimits
8.2.2Personalprotection
8.2.2.1Eye/faceprotection
weareye/faceprotectionratedtoprotecteyesagainstdust(EN166)eg.safetyeyeshieldswithdust
protection,gogglesorfacevisor
8.2.2.2Handprotection
wearsuitablechemicalresistantprotectivegloves,thatcomplywiththespecificationofECDirective
89/686/EECandtherelatedstandardEN374.Suitablematerials,Neopreneornaturalrubber
8.2.2.3Skin/bodyprotection
dustimperviousprotectivesuit
rubberorplasticsafetyboots
8.2.2.4Respiratoryprotection
inthecaseofhighdustlevelswearsuitablerespiratoryprotectiveequipmenteg.dustmaskor
respirator,that
conformtonational/internationalstandard,EN143.RecommendedfiltertpeP2
8.3EnvironmentalExposureControls
containanyspillage
avoiddischargestotheenvironment
disposeofanyrinsewaterinaccordancewithlocalandnationalregulations
9.PHYSICALANDCHEMICALPROPERTIES
9.1InformationonBasicPhysicalandChemicalProperties

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page5 of27
Appearance
Odour
Odourthreshold
pH
Melting/freezingpoint
Boilingpoint
Flashpoint
Evaporationrate
Flammability
Upperflammabilitylimit
Lowerflammabilitylimit
Vapourpressure
VapourDensity
Relativedensity
Watersolubility
Partitioncoefficient
Autoignitiontemperature
Decompositiontemperature
Viscosity
Explosiveproperties
Oxidisingproperties
:whitepowder
:odourless
:noinformationavailable
:>11(saturatedsolution,studyresult,OECDGuideline105)
:851oc(publisheddata)
:notapplicable(meltingpoint>300oc)
:notapplicable(inorganicsubstance)
:notapplicable(meltingpoint>300oc)
:nonflammable(studyresult,EUMethodA.10))
:nonflammable
:nonflammable
:notapplicable (inorganicsubstance,vapourpressurenegligible)
:notapplicable
:2.52@20oc(studyresult,EUMethodA.3)
:212.5g/l@20oc(studyresult,OECDGuideline105)
:notapplicable(inorganicsubstance)
:nonflammable
:notinformationavailable
:notapplicable (solid)
:nonexplosive(voidofchemicalgroupsassociatedwithexplosive
properties)
:nonoxidising (basedonthechemicalstructureofthesubstanceand
theoxidationstateoftheconstituentelement)
10.STABILITYANDREACTIVITY
10.1Reactivity
Decomposesbyreactionwithstrongacidstoevolvecarbondioxide
10.2ChemicalStability
Stableunderrecommendedstorageconditions(seeSection7)
10.3Possibilityofhazardousreactions
None
10.4ConditionstoAvoid
Contactwithacidsunlessundercontrolledconditions
Exposuretomoisture
10.5Incompatiblematerials
Finelydividedaluminium
10.6Hazardousdecompositionproducts
None
11.TOXICOLOGICALINFORMATION
11.1InformationonToxicologicalEffects

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page6 of27
Toxicityendpoints
Acutetoxicity
Irritation/
corrosion
Sensitisation
Repeateddose
toxicity
Detailsoftheeffectsassessment
Oral
: LD50 ,rat2800 mg/kgbw
Dermal
:LD50 ,rabbit >2000 mg/kgbw
Method:EPA16CFR1500.40
Inhalation
:LC50 ,rat 2300mg/m3 air
Method:basedonOECD Guideline
403
Valuesexceedthecutofflimitof2000mg/kgestablishedbyEUDirective67/548/EECandEU
Classification,LabellingandPackagingofSubstancesandMixtures(CLP)Regulation(EC)No.
1272/2008
Classificationforacutetoxicity: isnotwarranted
Eyeirritation
Skinirritation
Respiratoryirritation
:irritatingMethod:OECDGuideline405
:notirritatingMethod:OECDGuideline404
:notirritating Basedonavailabledata
ClassificationforEyeirritancy:Xi,R36(irritatingtoeyes)accordingtoDirective
67/548/EEC
:Category2,H319(causesseriouseyeirritation)
accordingtoCLPRegulation(EC)1272/2008
ClassificationforSkinirritancy:isnotwarranted
ClassificationforRespiratoryirritancy :isnotwarranted
Nodataavailableonthesensitisation ofsodiumcarbonate.
Sodiumcarbonateisconsiderednottohaveanysensitisingproperties,basedonthephysiological
roleofbothitsconstituentionsanditslongtermhistoricalandwidedispersiveuseinindustrial
processesandconsumerproducts.
Classificationforsensitisation:isnotwarranted
Oral: Sodium carbonatedissociates intoionsthatarepresentphysiologicallyin

relativelyhighlevelsinvertebrates.Therefore,repeateddosetoxicity
studiesareconsidered(scientifically)unnecessary,inaccordancewith
column2ofREACHAnnexVIIIandIX.Furthermore,sodiumcarbonateis
usedasafoodadditive,whichconfirmsthatthesubstancehasalow
Repeateddosetoxicity.
Dermal: Sodiumcarbonatedissociatesintoionsthatarepresentphysiologicallyin
studiesareconsidered(scientifically)unnecessary,inaccordancewith
Column2ofREACHAnnexVIIIandIX
Inhalation: Sodiumcarbonatedissociatesintoionsthatarepresentphysiologicallyin
studiesareconsidered(scientifically)notnecessary,Inaccordancewith
column2ofREACHAnnexVIIIandIX.
Mutagenicity
Invitro Theavailableinvitrotests(SOSchromotestwithsodiumcarbonateandAmestestwith
sodiumbicarbonate)werenegative.Furthermoresodiumbicarbonateisnaturallypresentincells
andboththestructureofsodiumbicarbonateandsodiumcarbonatedonotindicateagenotoxic
potential.Therefore,thereisnoreasontoevaluatethepotentialgenotoxicityofsodiumcarbonate
furtherandnogenotoxiceffectsareexpected.
Classificationformutagenicityisnotwarranted
Classificationforrepeateddosetoxicity: isnotwarranted

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page7 of27
Toxicityendpoints Detailsoftheeffectsassessment
Carcinogenicty
Nodataavailableforcarcinogenicityofsodiumcarbonate.Althoughthesubstancehasawideand
varieduse,therearenoindicationsthatitcaninducehyperplasia,preneoplasticlesionsoris
mutagenic.Therefore,acarcinogenicitystudyisconsideredunnecessary
Classificationforcarcinogenicityisnotwarranted
Reproductive
toxicity
Fertlity :
Nodataavailable
Developmentaltoxicity:
InaccordancewithSection1ofREACHAnnexXI,testingdoes
notappearscientificallynecessary,asthesubstancewill
usuallynotreachthefoetusorthemaleandfemale
reproductiveorganswhenexposedorally,dermallyorby
inhalation,asitdoesnotbecomeavailablesystemically.As
such,itisconsiderednotusefultoperformareproduction
study
ClassificationforreproductivetoxicityaccordingtoRegulation(EC)1272/2008isnotrequired
12.ECOLOGICALINFORMATION
12.1Toxicity
12.1.1Acute/shorttermtoxicitytofish
LC50(96h)forfreshwaterfish:300mg/l
12.1.2Chronic/longtermtoxicitytofish
Studyscientificallyunjustified,sodiumcarbonatedissociatesreadilyintosodiumandcarbonateionsinan
aquaticenvironment.Bothionsoriginallyexistinnature,andtheirconcentrationsinsurfacewaterare
dependentonvariousfactors,suchasgeologicalparameters,weatheringandhumanactivities.Therefore,
thereisacontinuoussourceofbothionsintotheenvironmentandhavebeenmeasuredextensivelyin
aquaticecosystems
12.1.3Acute/shorttermtoxicitytoaquaticinvertebrates
EC50(48h)forfreshwaterinvertebrates:200227mg/l
12.1.4Chronic/longtermtoxicitytoaquaticinvertebrates
aquaticecosystems
12.1.5Acutetoxicitytoalgaeandaquaticplants
aquaticecosystems
12.1.6Toxicitytosoilmacroorganisms
InaccordancewithREACHAnnexXIastudyisnotrequiredasinwatersodiumcarbonateisdissociatedinto
sodiumandcarbonateions,bothofwhichwillnotadsorbonparticulatematter.Furthermore,exposureof
thesoilcompartmentisunlikely
12.1.7Toxicitytoterrestrialplants
InaccordancewithREACHAnnexXIastudyisnotrequiredasinwatersodiumcarbonateisdissociatedinto
sodiumandcarbonateions,bothofwhichwillnotadsorbonparticulatematter.Furthermore,exposureof
thesoilcompartmentisunlikely

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page8 of27
12.2Persistenceanddegradeability
Inwater
Insoil
Insediment
:Notapplicable(quicklydissociates)
:Notapplicable(inorganicsubstance)
:Notapplicable(inorganicsubstance)
12.3BioaccumulativePotential
Notbioaccumulative(inorganicsubstancethatinwaterdissociatesintosodiumandcarbonateions,which
donotaccumulateinlivingtissues)
12.4MobilityinSoil
Ifsodiumcarbonateisemittedtosoilitcanescapetoatmosphereascarbondioxide,precipitateasametal
carbonate,formcomplexesorstayinsolution
12.5ResultsofPBTandvPvBAssessment
AccordingtoAnnexXIIIofREACHRegulationinorganicsubstancesdonotrequireassessment
12.6OtherAdverseEffects
Nootheradverseeffectsareidentified
13.DISPOSALCONSIDERATIONS
13.1WasteTreatmentMethods
Ifrecyclingorreuseisnotpracticable,disposeofincompliancewithlocalornationalregulations
Neutralisewithacidundercontrolledconditions
Dilutewithplentyofwater
Packaging:
Wherepossible,recyclingispreferredtodisposalorincineration
Cleancontainerwithwater,disposeofrinsewaterinaccordancewithlocalornationalregulations
Mustbeincineratedinaregisteredincinerationplantwithpermitfromthelocalauthorities
14.TRANSPORTINFORMATION
Sodiumcarbonateisnotclassifiedashazardousfortransport
14.1UNNumber
Notregulated
14.2UNpropershippingname
Notregulated
14.3Transporthazardclass
LandTransport
InlandWaterwayTransport
SeaTransport
AirTransport
:ADR/RID
:ADN
:IMO/IMDG
:ICAOTI/IATADGR
Notrestricted
Notregulated
Notregulated
Notregulated
15.REGULATORYINFORMATION
15.1Safety,healthandenvironmentalregulations
Waterhazardclass:WGK1,VwVwS(Germany)
TSCAInventory:Listed
15.2Chemicalsafetyassessment
AChemicalSafetyAssessment/Report(CSA/CSR)hasbeenundertakenonsodiumcarbonate
16.OTHERINFORMATION
16.1Indicationofchanges
Section1changeofcompanyname,logoandcontactdetails

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page9 of27
IssueNo.:02Revision01DateofIssue:10012011supercedesIssueNo.2DateofIssue:10012011
16.2Abbreviationsandacronyms
WEL
ACGIH
TWA
DNEL
NOEC
PBT
vPvB
PNEC
ADR
RID
ADN
:Workplaceexposurelimit
:AmericanConferenceofIndustrialHygiene
:TimeWeightedAverage
:Derivednoeffectlevel
:NoObservedEffectConcentration
:Persistent,Bioaccumulative,Toxic
:veryPersistent,veryBioaccumulative
:PredictedNoEffectConcentration
:EuropeanAgreementConcerningtheInternationalCarriageofDangerousGoodsbyRoad
:InternationalRuleforTransportofDangerousSubstancesbyRail
:EuropeanAgreementconcerningtheInternationalCarriageofDangerousGoodsbyInland
Waterway
IMO/IMDG :InternationalMaritimeOrganization/InternationalMaritimeDangerousGoodsCode
ICAO/IATA :InternationalCivilAviationOrganization/InternationalAirTransportAssociation
OECD
:OrganisationofEconomicCooperationandDevelopment
SIDS
:ScreeningInformationDataSet
16.3Keyliteraturereferencesandsourcesofdata
DataistakenfromtheChemicalsafetyreport(CSR)and/orOECDSIDSreportforsodiumcarbonate
16.4FurtherInformation
16.4.1Theaboveinformationdescribesexclusivelythesafetyrequirementsoftheproductandisbasedonourpresent
dayknowledge.Theinformationisintendedtogiveyouadviceaboutthesafehandlingoftheproductnamed
inthissafetydatasheet,forstorage,processing,transportanddisposal.Theinformationcannotbetransferred
tootherproductsorinthecaseofprocessing,theinformationonthissafetydatasheetisnotnecessarily
valid.
Toourbestpresentknowledgetheinformationgiveniscorrectandcompleteasofthedateofthisdocument
andisgiveningoodfaithbutwithoutwarranty,eitherexpressedorimplied,nordoweacceptanyliabilityin
relationtothisinformationoritsuse.ThisversionoftheSDSsupercedesallpreviousversions.
16.4.2AnytradenamesreferencedinthisdocumentareregisteredtrademarksofTataChemicalsEuropeLimited
ANNEXTOEXTENDEDSAFETYDATASHEET(eSDS):
Page1113ExposureScenario1(ES.1)SodaashManufacturingofsodiumcarbonate
Page1416ExposureScenario2(ES.2)SodaashGlassproduction
Page1719ExposureScenario3(ES.3)SodaashFormulation
Page2025ExposureScenario4(ES.4)SodaashOtherindustrialandprofessionaluse
Page2628ExposureScenario5(ES.5)SodaashConsumeruse

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page10 of27
ExposureScenarioforcommunication:
ES1:Manufacturingofsodiumcarbonate
0.Generalinformation
ESidentifier
Versionno
Revisiondate
EC#
CAS#
ES1
01
28.10.2010
2078388
497198
1. Use descriptors
Manufacturingofsodiumcarbonate
Marketsector:SU3(Industrialuses)
Sectorofuse:SU8(Manufactureofbulk,largescalechemicals)
Environment:(EnvironmentalReleaseCategory)Manufactureofsubstances
ERC1
Worker(ProcessCategoryPhrase)
Useinclosedprocess,nolikelihoodofexposure
PROC1
Useinclosed,continuousprocesswithoccasionalcontrolledexposure
PROC2
Useinclosedbatchprocess(synthesisorformulation)
PROC3
Useinbatchandotherprocess(synthesis)whereopportunityforexposurearises
PROC4
Transferofsubstanceorpreparation(charging/discharging)from/tovessels/largecontainersatnondedicated
facilities
PROC8a
Transferofsubstanceorpreparation(charging/discharging)from/tovessels/largecontainersatdedicated
facilities
PROC8b
Transferofsubstanceorpreparationintosmallcontainers(dedicatedfillingline,includingweighing)
PROC9
Potentiallyclosedprocessingoperationswithminerals/metalsatelevatedtemperature
PROC22
Processes,tasks,activitiescovered
Manufacturing,maintenance,loading,packaging,samplingandmonitoring.
2.Conditionsofuseaffectingexposure
2.0DefaultProductCharacteristics
Physicalformofproduct/article
Solid
Volatility
Notrelevant
Dustiness
Medium(PROCs1,2,3,4,8a,8b,9)
Low(PROC22)
2.1.Controlofenvironmentalexposure:
ManufactureofsubstancesERC1

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page11 of27
Amountsused
Annualsitetonnage(tonnes/year):upto1500000.
Frequencyanddurationofuse
Continuous
Othergivenoperationalconditionsaffectingenvironmentalexposure
Notapplicable.
Technicalandorganizationalconditionsandmeasures
Seesection8ofSafetydatasheet.
Conditionsandmeasuresrelatedtomunicipalsewagetreatmentplant
Wastewaterstreamsfromsodiumcarbonateproductionsitescontaininorganicsubstancesandarethereforenottreatedin
sewagetreatmentplants.
Conditionsandmeasuresrelatedtoexternaltreatmentofwaste
In Chapter 2.3.5 of the Reference Document on Best Available Techniques for the Manufacture of Large Volume Inorganic
Chemicals Solids and Others Industry(EC, 2007) two types of solid waste, generated during themanufacturing of sodium
carbonate,arediscussed.Bothtypesofsolidwasteoriginatefromrawmaterialsandtheconcentrationofsodiumcarbonate
inthesolidwasteisnegligible.Forthisreasonspecificwasterelatedmeasuresarenotneeded.
AdditionalgoodpracticeadvicebeyondtheREACHCSR(ChemicalSafetyReport)
Seesections6and13ofSafetyDataSheet
2.2.Controlofworkersexposure
ValidforPROCs1,2,3,4,8a,8b,9,22.
Amountsused,frequencyanddurationofuse
Amountsused
NotRelevant
ParameterdoesnotinfluenceexposureestimationsforthisES
Daily8h/day
Seesection8ofSafetyDataSheet.
Ensureworkersaretrainedtominimizeexposures.
3.Exposureestimationandreferencetoitssource
3.1Environmentexposureestimationandreferencetoitssource
ThetablebelowgivesthesummaryoftheenvironmentexposureestimationmadeintheChemicalSafetyReport,referringto
DocumentonBestAvailableTechniquesfortheManufactureofLargeVolumeInorganicChemicalsSolidsandOthers
Industry.
Compartments
Measuredrelease(kg/d)
Explanation/sourceofmeasureddata
Aquatic
Negligible
ReferenceDocumentonBestAvailableTechniques(EC,2007)
Air(direct)
2.2118
Soil(directonly)
Negligible

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page12 of27
3.2Workersexposureestimationandreferencetoitssource
TheECETOCTRAtoolhasbeenusedtoestimateworkplaceexposuresunlessotherwiseindicated.
Productionofsodiumcarbonate:longtermexposureconcentrationstoworkers
Exposure
Routesofexposure concentrations
(Characteristics,Duration,Frequency,OCandRMMdescribedabove)
3
(mg/m )
Modeledexposuredata
Dermalexposure
Notrelevant
Noassessmentfordermalexposurebecauseofnolocalskineffectsandno
systemicavailabilityafterdermalcontact.
Inhalationexposure
0.01
ECETOCTRAV2.PROC1
0.5
ECETOCTRAV2.PROC2
ECETOCTRAV2.PROC3
ECETOCTRAV2.PROC4
ECETOCTRAV2.PROC8a
ECETOCTRAV2.PROC8b
ECETOCTRAV2.PROC9
ECETOCTRAV2.PROC22
Measuredexposuredata
Inhalationexposure
7.9
Anextensiveset(intotal:698observations)ofworkerexposuredatafrom4
sitesthatmanufacturesodiumcarbonate.Measurementsarerepresentative
foraworkdayof8hours.
4.GuidancetoDUtoevaluatewhetherheworksinsidetheboundariessetbytheES
4.1Environment.
NotApplicable:thisscenariodoesnotconcernDU.
4.2Health.
NotApplicable:thisscenariodoesnotconcernDU.

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page13 of27
Substance:SodiumCarbonate;EC:2078388;CAS:497198
ES2:Glassproduction
ESidentifier
Versionno
Revisiondate
EC#
CAS#
ES2
01
28.10.2010
2078388
497198
1.Usedescriptors
GlassProduction
Sectorofuse:SU3(Industrialuses)
Environment:(EnvironmentalReleaseCategory)Industrialuseresultinginmanufactureof
anothersubstance(useofintermediates)
ERC6a
PROC1
PROC2
PROC3
PROC4
Transferofsubstanceorpreparation(charging/discharging)from/tovessels/largecontainersat
nondedicatedfacilities
PROC8a
dedicatedfacilities
PROC8b
Potentiallyclosedprocessingoperationswithminerals/metalsatelevatedtemperature
PROC22
Openprocessingandtransferoperationswithminerals/metalsatelevatedtemperature
PROC23
Handlingofsolidinorganicsubstancesatambienttemperature.
PROC26
Manufacturing,maintenance,loading,packaging,samplingandmonitoring.
Solid
Volatility
Notrelevant

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page14 of27
Dustiness
Medium(PROCs1,2,3,4,8a,8b,26)
High(PROCs22and23)
MixtureArticleConcentration
ForPROCs1,2,3,4,8a,8band26theneatsubstanceistakenintoaccount,becausetheneatsubstanceistransferred
totheprocess.
Percentageof525%sodiumcarbonateinthemixtureduringthemeltingprocessisassumed.
Useasintermediate:industrialuseresultinginmanufactureofanothersubstance.
Amountsused
Upto200000tonnes/year.
Continuous.
TheimpactofglassmanufacturingontheenvironmenthasbeendescribedextensivelyintheReferenceDocumenton
Best Available Techniques in the Glass Manufacturing Industry (EC, 2001). The document was established in the
contextoftheEUDirectiveonIntegratedPollutionPreventionandControl(Directive96/61/EC).
Incaseofdustformation,usefiltertoreduceatmosphericemissions.
Wastewaterstreamsoftheglassindustrydonotcontainsodiumcarbonateasitisstoredincoveredsilosandnot
linkedtointernalsewagesystems.Forthisreasonanemissionassessmentforthesewagetreatmentplantisnot
neededfortheindustrialenduseofsodiumcarbonateintheglassindustry.
Nospecificwasterelatedmeasuresaretobedefined.
AdditionalgoodpracticeadvicebeyondtheREACHCSA
ValidforPROCs1,2,3,4,8a,8b,9,22,26.
Amountsused
NotRelevant
Parameterdoesnotinfluenceexposureestimationsfor
thisES
Daily8h/day
Technicalandorganisationalconditionsandmeasures
Seesection8ofSafetyDataSheet

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page15 of27
ThetablebelowgivesthesummaryoftheenvironmentexposureestimationmadeintheChemicalSafetyReport,
referringtoDocumentonBestAvailableTechniquesintheGlassManufacturingIndustry(EC,2001).
Compartments
Measuredrelease
(kg/d)
Aquatic
Negligible
Air(direct)
Negligible
Soil(directonly)
Negligible
Glassproduction:longtermexposureconcentrationstoworkers
Routesofexposure
Estimated
exposure
concentrations
(mg/m3)
Dermalexposure
Notrelevant
0.01
0.5
1
5
5
5
1
1
ECETOCTRAV2.PROC1
ECETOCTRAV2.PROC2
ECETOCTRAV2.PROC3
ECETOCTRAV2.PROC4
ECETOCTRAV2.PROC8a
ECETOCTRAV2.PROC8b
ECETOCTRAV2.PROC22a
ECETOCTRAV2.PROC23a
Inhalationexposure
PROC26isnotforeseeninECETOCTRAbutitinvolvesactivitieswhicharedescribedbyPROC8aand8b.Thereforethe
calculationwithPROC8aand8bcoversPROC26.
4.1Environment.
PredictedexposuresarenotexpectedtoexceedtheDNELwhentheRiskManagementMeasures/Operational
ConditionsoutlinedinSection2areimplemented.
4.2Health.

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page16 of27
ES3:Formulation
ESidentifier
Versionno
Revisiondate
EC#
CAS#
ES3
01
28.10.2010
2078388
497198
1.Usedescriptors
Formulation
Sectorofuse:SU10(Formulation[mixing]ofpreparationsand/orrepackaging(excludingalloys))
Environment:(EnvironmentalReleaseCategory)Formulationofpreparations
ERC2
PROC1
PROC2
PROC3
Mixingorblendinginbatchprocessesforformulationofpreparationsandarticles(multistage
and/orsignificantcontact)
PROC5
PROC8a
dedicatedfacilities
PROC8b
Transferofsubstanceorpreparationintosmallcontainers(dedicatedfillingline,including
weighing)
PROC9
Productionofpreparationsorarticlesbytabletting,compression,extrusion,pelletisation
PROC14
Useaslaboratoryreagent
PROC15
storage,materialstransfers,mixing,maintenance,samplingandassociatedlaboratoryactivities.
Volatility
Solid
Notrelevant
Dustiness
Medium
Notrelevant:forexposureestimationtheneatsubstanceistakenintoaccount,becausetheneatsubstanceisaddedto
theformulationprocess.

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page17 of27
Formulationofpreparations ERC2
SPERC(AISE,2010E)arealsoused(http://www.aise.eu/reach/exposureass_sub4.htm).
Amountsused
Upto5000tonnes/year
Continuous
ControlthepHoftheliquideffluentiftheeffluentissenttoSTP.
AdditionalgoodpracticeadvicebeyondtheREACHCSA
ValidforPROCs1,2,3,5,4,8a,8b,9,14,15.
Amountsused
NotRelevant
Parameterdoesnotinfluenceexposureestimationsforthis
ES
Daily8h/day
ThetablebelowgivesthesummaryoftheenvironmentexposureestimationmadeintheChemicalSafetyReportandin
SpecificEnvironmentalReleaseCategories(SPERC)(AISE,2010):
Compartments
Measuredrelease
(kg/d)
Explanation/sourceofdata
Aquatic
Negligible
Air(direct)
2.7
SpecificEnvironmentalReleaseCategories(SPERC)(AISE,2010)
Soil(directonly)
Negligible

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page18 of27
3.2 Workers exposure estimation and reference to its source

Formulation:longtermexposureconcentrationstoworker
Routesofexposure
Dermalexposure
Inhalationexposure
Estimated
exposure
concentrations
(mg/m3)
Notrelevant
0.01
ECETOCTRAV2.PROC1
0.5
ECETOCTRAV2.PROC2
ECETOCTRAV2.PROC3
ECETOCTRAV2.PROC4
ECETOCTRAV2.PROC5
ECETOCTRAV2.PROC8a
ECETOCTRAV2.PROC8b
ECETOCTRAV2.PROC9
ECETOCTRAV2.PROC14
0.5
ECETOCTRAV2.PROC15
4.1Environment.
4.2Health.

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page19 of27
ES4:Otherindustrialandprofessionaluses
ESidentifier
Versionno
Revisiondate
EC#
CAS#
ES4
01
28.10.2010
2078388
497198
1.Usedescriptors
1.1Industrialenduses
Sectorofuse:Norestriction(SUs020,23,24)
Environment:(EnvironmentalReleaseCategory)
Formulationofpreparations
ERC4
Industrialuseresultingininclusionintoorontoamatrix
ERC5
Industrialuseresultinginmanufactureofanothersubstance(useofintermediates)
ERC6a
Industrialuseofreactiveprocessingaids
ERC6b
Industrialuseofprocessregulatorsforpolymerisationprocessesinproductionofresins,rubbers,
polymers
ERC6d
Industrialuseofsubstancesinclosedsystems
ERC7
PROC1
PROC2
PROC3
PROC4
Sprayinginindustrialsettingsandapplications
PROC7
PROC8a
dedicatedfacilities
PROC8b
weighing)
PROC9

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page20 of27
Rollerapplicationorbrushingofadhesiveandothercoating
PROC10
Treatmentofarticlesbydippingandpouring
PROC13
PROC15
Lubricationathighenergyconditionsandinpartlyopenprocess
PROC17
Greasingathighenergyconditions
PROC18
HandmixingwithintimatecontactandonlyPPEavailable
PROC19
Potentiallyclosedprocessingoperationswithminerals/metalsatelevatedtemperature.The
processtemperatureishigherthanthemeltingpoint(Highfugacity)
Openprocessingandtransferoperationswithminerals/metalsatelevatedtemperature.The
processtemperatureishigherthanthemeltingpoint(Highfugacity)
Handlingofsolidinorganicsubstancesatambienttemperature
PROC22
PROC23
PROC26
Processes,tasks,activitiescovered:
Manufacturing,mixing,maintenance,loading,packaging,samplingandmonitoring.
1.2 Professional end uses

Marketsector:SU22(Professionaluses)
Sectorofuse:SU22(Professionaluses)
Environment:(EnvironmentalReleaseCategory)
Widedispersiveindooruseofprocessingaidsinopensystems
ERC8a
Widedispersiveindooruseofreactivesubstancesinopensystems
ERC8b
Widedispersiveindooruseresultingininclusionintoorontoamatrix
ERC8c
Widedispersiveoutdooruseofprocessingaidsinopensystems
ERC8d
Widedispersiveoutdooruseofreactivesubstancesinopensystems
ERC8e
Widedispersiveoutdooruseresultingininclusionintoorontoamatrix
ERC8f
Widedispersiveindooruseofsubstancesinclosedsystems
ERC9a
Widedispersiveoutdooruseofsubstancesinclosedsystems
ERC9b
PROC1
PROC2

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page21 of27
PROC4
PROC8a
dedicatedfacilities
PROC8b
weighing)
PROC9
Rollerapplicationorbrushingofadhesiveandothercoating
PROC10
Nonindustrialspraying
PROC11
Treatmentofarticlesbydippingandpouring
PROC13
PROC15
HandmixingwithintimatecontactandonlyPPEavailable
PROC19
Manufacturing,mixing,maintenance,loading,packaging,samplingandmonitoring.
Volatility
Dustiness
Solid
Notrelevant
Medium(PROCs1,2,3,4,8a,8b,9,15,19)
High(PROCs22and23)
Industrialenduses:ERC4,ERC5,ERC6a/6b/6d,ERC 7.
Professionalenduses:ERC8a/8b/8c/8d/8e/8f;ERC9a/9b.
Amountsused
Industrialuseupto100000tonnes/year.
Professionalusemuchlower
Uptocontinuous.
ControlthepHoftheliquideffluentiftheeffluentissenttoSTP.

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page22 of27
ValidforPROC14,7,8a,8b,9,10,11,13,15,17,18,19,22,23,26.
NotRelevant
Parameterdoesnotinfluenceexposure
estimationsforthisES
Amountsused
Frequencyanddurationofuse(ExposureFrequencyDuration)
Operationalconditions Process
Industrial
Professional
relatedtotheduration
Category
(DataField)
(DataField)
ofuse
PROC1
Lessthan15min/day
PROC2
Lessthan15min/day
>4hours/day(liquid
PROC3
mixture)
PROC4
>4hours/day
>4hours/day(liquid
PROC7
mixture)
PROC8a
15min/dayto1hour/day
PROC8b
Durationofexposureper
>4hours/day(liquid
PROC9
dayatworkplace[forone
mixture)
worker]
PROC10
>4hours/day
PROC11
>4hours/day
PROC13
PROC15
>4hours/day(liquid
PROC17
mixture)
>4hours/day(liquid
PROC18
mixture)
PROC19
Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page23 of27
ThetablebelowgivesthesummaryoftheenvironmentexposureestimationmadeintheChemicalSafetyReport:
Compartments
Aquatic
Negligible
Air(direct)
Smallreleasesmightbepossible
Soil(directonly)
Negligibleinallcasesexceptagriculturaluse
Maxapplicationuseratesofsodaashascoformulantinplantprotection
products:Professionalagricultural:0.0126kg/ha(tier1defaultuserate:1
kg/ha)
Routesofexposure
Dermalexposure
Explanation/sourceof
measureddata
(Characteristics,Duration
Frequency,OCandRMM
describedabove)
Industrial
estimated
exposure
concentrations
(mg/m3)
Professionalestimated
Exposureconcentrations
(mg/m3)
Notrelevant
Notrelevant
Nolocaleffectsandnosystemic
availabilityafterdermalcontact
PROC1
0.01
PROC2
0.5(solid)
PROC3
PROC4
1(solid)
5
PROC7
PROC8a
0.022
5
Inhalationexposure
PROC8b
PROC9
PROC10
PROC11
PROC13
PROC15
PROC17
PROC18
PROC19
5(solid)
5(solid)
5(solid)
0.022(liquid
mixtureonly)
0.022(liquid
mixture)
5
0.0044(liquid)
0.001(solid)
0.044(liquid)
0.1(solid)
0.044(liquid)
0.044(liquid)
5(solid)
0.088(liquid)
1(solid)
0.088(liquid)
0.044(liquid)
0.44(liquidmixtureonly)
PROC22
PROC23
Professionalagriculturalwith
solidmixture,outdoor,noPPE
(ECPAOWBTier1:defaultuse
rate)
1
1
0.088(liquid)
1(solid)
0.142(solid)

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page24 of27
4.1Environment.
4.2Health.

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page25 of27
ES5:Consumeruse
ESidentifier
Versionno
Revisiondate
EC#
CAS#
ES5
01
28.10.2010
2078388
497198
1.Usedescriptor
Consumeruse
Marketsector:SU21Consumeruses:Privatehouseholds(=generalpublic=consumers)
Sectorofuse:SU21Consumeruses:Privatehouseholds(=generalpublic=consumers)
Environment:
EnvironmentalReleaseCategory:ERC8a/b/c/d/e/f;ERC9a/b.
ProductCategory(PC):Norestriction(fromPC0toPC40)
ProcessCategory:Notapplicable
Cleaningactivities
Volatility
Dustiness
Solidordissolvedinwater
Notrelevant
Mediumforpowdereddetergents,lowfor
householdsoda
Laundrydetergentsandsurfacecleaners:30%
Machinedishwashingtablets:45%
Householdsoda(puresodiumcarbonatedecahydrate):37%contentofsodiumcarbonate
Surfacecleaningsprays:10%
Aircareproducts:5%(PC3)
Furniture,floorandleathercare:10%(PC31)
ConsumeruseERC8a/b/c/d/e/f;ERC9a/b.
Amountsused
Notrelevantastheexposureisestimatedtobenegligible
Notrelevantastheexposureisestimatedtobenegligible

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page26 of27
2.2.Controlofconsumersexposure
Amounts used
Householdsoda:37g/l(worstcase)
Frequency and duration of use
Householdsoda:onetimeperweek(frequency)and5min
(duration)(worstcase)
Keepoutofreachofchildrenandavoidcontactwitheyes.Incaseofcontactwitheyes,rinseimmediatelywithplentyof
waterandseekmedicaladvice.
ThetablebelowgivesthesummaryoftheenvironmentexposureestimationmadeintheChemicalSafetyReport,
referringtoHERA(2005a)andtoSpecificEnvironmentalReleaseCategories(SPERC)(AISE,2010).
Compartments
Aquatic
Negligible
HERA(2005a);seesection9.5.2.3.2
Air(direct)
Negligible
Soil(directonly)
Negligible
3.2Consumersexposureestimationandreferencetoitssource
ExposureshavebeencalculatedwiththesoftwaretoolREACT(ReachExposureAssessmentConsumerTool)
Longtermdermalexposuretoconsumers:
Productcategory
Ingredientfractionby
weight
Estimateduptakevalue
(mg/kgbwperday)
Laundryregular(AISEC1,PC35),Powder
0.3
1.56E02
Laundryregular(AISEC1,PC35),Liquid
0.3
2.29E02

Product
:SODIUMCARBONATE
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
PageNumber
:Page27 of27
Laundrycompact(AISEC2,PC35),Powder
0.3
1.60E02
Laundrycompact(AISEC2,PC35),Liquid/Gel
0.3
2.29E02
Laundryadditives(AISEC4,PC35),LiquidBleach
0.3
2.21E02
HandDishwashing(AISEC5,PC35)
0.3
3.12E04
Surfacecleaners(AISEC7,PC35),Gel
0.3
4.29E02
ThenegligibleinhalationhasbeenconfirmedforthelaundrywashingscenarioreportedbyHERA(2005a).
4.1Environment.
4.2Health.


Anexo IV Hojas de Seguridad

Enviado por

Dados do documento

Direitos autorais

Formatos disponíveis

Compartilhar este documento

Compartilhar ou incorporar documento

Opções de compartilhamento

Você considera este documento útil?

Este conteúdo é inapropriado?

Direitos autorais:

Formatos disponíveis

Anexo IV Hojas de Seguridad

Enviado por

Direitos autorais:

Formatos disponíveis

Monday, April 23, 2012

GAS NATURAL SDG S.A

Re: Compliance with EU Regulation on Registration, Evaluation, Authorization and Restriction of

Revision Date 15-FEB-2012

SAFETY DATA SHEET

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

2.2. Label elements

Classification (EC 1272/2008)

Classification (EC 1272/2008)

Miscible with water

Initial boiling point and boiling range

0.98 - 1.02 s.g @ 20C

pH-Value, Conc. Solution

9.2. Other information

Risk Phrases In Full

Revision Date 06-09-11

SAFETY DATA SHEET

Shale control agent.

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

Physical and Chemical Hazards Not classified.

2.2. Label elements

Causes serious eye damage.

Wear protective gloves/protective clothing/eye protection/face protection.

Supplementary Precautionary Statements

IF IN EYES: Rinse cautiously with water for several minutes. Remove

2.3. Other hazards

Classification (EC 1272/2008)

Colourless. to Straw. Yellow. / Brown.

Miscible with water

Initial boiling point and boiling range

1012 kg/m3 (1.012 g/cm3) @ 15 C

<0.931 kPa (<7mm Hg)

7.3 mm2/S (7.3 cSt) @ 40 C

Flash point (C)

> 140C PM Closed cup.

9.2. Other information

SECTION 10: STABILITY AND REACTIVITY

> 2000 mg/kg Rat

Acute Toxicity (Dermal LD50)

> 2000 mg/kg Rat

Risk Phrases In Full

Risk of serious damage to eyes.

Hazard Statements In Full

Causes serious eye damage.

Revision Date: 19-05-11

SAFETY DATA SHEET

Oil well drilling fluid additive. Lubricant

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

2.2. Label elements

Classification (EC 1272/2008)

POLYPROPYLENE GLYCOL, MONOBUTYL ETHER

Classification (EC 1272/2008)

Classification (EC 1272/2008)

0.96 - 1.01 @ 25C

Vapour Density (Air=1)

pH-Value, Diluted Solution

Flash Point (C)

>110 P/M Pensky-Martens.

9.2. Other information

REVISION DATE: 24-08-10

SAFETY DATA SHEET