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Chemical Thermodynamics
Thermodynamics
First Law of
Thermodynamics
Second Law of
Thermodynamics
Entropy
Entropy
3) Temperature increases
Example:
Fe(s) at 0 oC Fe(s) at 25 oC
4) For Gases ONLY, when
Volume increases or Pressure
decreases
Examples:
Entropy
Entropy
Rotational
Translational
N2O4(g) 2 NO2(g)
Spontaneous Processes
Entropy
Entropy
Spontaneous Processes
Second Law of
Thermodynamics
Third Law of
Thermodynamics
Third Law of
Thermodynamics
Standard Entropies
Standard Conditions:
Standard Entropies
The temperature
dependence of free
energy comes from the
entropy term.
Entropy Changes
Minimum Enthalpy
Exothermic Rx, DH = negative
1. If DG is negative
DG = maximum amt of energy
free to do
work by the reaction
Maximum Entropy
More disorder, DS = positive
2. If G is positive
DG = minimum amt of work
needed
to make the reaction
happen
At Equilibrium
DGo = zero
TDSo
Or:
DGo = kJ/mol
DHo = kJ/mol
DSo = J/mol-K
= (-)
(+)
Therefore: DHo =
DSo = DHo
T
DGo = - RT ln K
DGo = - RT ln K
Relationships