Escolar Documentos
Profissional Documentos
Cultura Documentos
Agip Division
COMPANY SPECIFICATION
05489.MAT.COR.SDS
Rev. 2
March 1997
2
REV.
General Revision
DESCRIPTION
CORM
COMP.
IMPI
VERIF.
CORM
APP.
March 97
DATE
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been
sent.
Eni S.p.A.
Agip Division
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 2 di 21
FOREWORD
Rev. 2
General Revision
No. Sheets 21
March 1997
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
Eni S.p.A.
Agip Division
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 3 di 21
CONTENT
GENERAL
1.1
1.2
1.2.1
1.2.2
1.2.3
1.2.4
Scope
Reference Normative
European normative references
Normative references of ISO, IEC and national organizations
Normative references of other organizations
Company Normative
FUNCTIONAL REQUIREMENTS
2.1
2.2
2.3
2.4
2.4.1
2.4.2
2.4.3
2.4.4
2.4.5
2.4.6
2.4.7
Definitions
Symbols and Abbreviations
Operating Environment
Functional Requirements for Piping
Fabrication process
Chemical composition
Heat and product analyses
Hardness
Defect repair
Non complying pipes and fittings
In service non complying pipes and fittings
2.5
2.5.1
2.5.2
2.5.3
2.5.4
2.5.5
2.5.6
2.5.7
2.5.8
2.5.9
2.6
2.7
2.8
2.8.1
2.8.2
Ergonomics
Safety
Documentation
Piping
Pressure Wells Sheets
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
Eni S.p.A.
Agip Division
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 4 di 21
ADDITIONAL INFORMATION
3.1
3.1.1
3.1.2
3.1.3
3.2
3.2.1
3.2.2
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
Eni S.p.A.
Agip Division
GENERAL
1.1
Scope
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 5 di 21
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 6 di 21
Eni S.p.A.
Agip Division
1.2
Reference Normative
1.2.1
1.2.2
EN 10028
UNI 663
1.2.3
NACE MR0175
NACE TM0177
NACE TM0284
EFC 16
ASTM A 578
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 7 di 21
Eni S.p.A.
Agip Division
1.2.4
Company Normative
02555.VAR.COR.PRG
00190.PIP.MME.SDS
00191.PIP.MME.SDS
05490.EQP.MEC.SDS
Pressure vessels.
20197.VAR.COR.SDS
03587.MAT.COR.PRG
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 8 di 21
Eni S.p.A.
Agip Division
2.1
Definitions
Carbon steel
An alloy of carbon and iron containing up to 2% carbon and up to 1.65% manganese
and residual quantities of other elements, except those intentionally added in specific
quantities for deoxidation (usually silicon and/or aluminium).
Low alloy steel
Steel with a total alloying element content lower than about 5 %. This definition includes
micro-alloyed steels containing small quantities of elements able to form carbides and
nitrides, as niobium, titanium and vanadium
Micro-alloyed steel
Steel with a total alloying element content lower than about 5 %.
H2S containing environment
See Par. 3.2 in this document.
Vickers Hardness
Vickers hardness is the recommended test for measuring hardness at welds. It is
performed by applying a load ranging from 50 g to 30 kg on a pyramidal diamond tip
and measuring the size of the impression after removing the load.
2.2
2.3
Equivalent Carbon
Hydrogen Induced Cracking
Stress Corrosion Cracking
Sulphide Stress Cracking
Stepwise Cracking
Stress Oriented Hydrogen Induced Cracking
Soft Zone Cracking
Operating Environment
Piping and pressure vessels shall be suitable for operating at the environmental
conditions existing at the installation site as specified in the design datasheet.
2.4
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 9 di 21
Eni S.p.A.
Agip Division
2.4.1
Fabrication process
The steel shall be produced to be resistant to HIC (Hydrogen Induced Cracking) and
to SSC (Sulphide Stress Cracking).
The steel shall be produced by the basic oxygen process or by electric oven and with
low sulphur content.
All pipes and fitting shall be of the seamless type. The seamless pipes shall be hot rolled
and supplies in the as rolled conditions, normalised or normalised and tempered.
2.4.1.1
Cold working
For any pipe and fitting, cold working operations leading to a permanent outer fibre
deformation greater than 5 % are not admitted, if not followed by suitable heat
treatment.
When the permanent outer fibre deformation is greater than 5 %, resistance to Sulphide
Stress Cracking of cold worked materials shall be restored by normalisation and
tempering heat treatment. Also the stress relieving heat treatment at temperature of 620
C, or 650 C for micro-alloyed steels, is acceptable.
2.4.2
Chemical composition
2.4.2.1
Pipes
It is requested a sulphur content lower than 0.010 %.
The equivalent carbon calculated in accordance with the requirements of the EN 10028
norm:
CE = C +
Mn Cr + Mo + V Cu + Ni
+
+
6
5
15
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
Eni S.p.A.
Agip Division
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 10 di 21
the weld metal, at the fusion boundary and of the heat affected zone shall be within the
limits specified at Par. 2.4.4.
2.4.2.2
Fittings
It is requested a sulphur content lower than 0,025 %.
The equivalent carbon shall comply with the above specified limit.
2.4.3
2.4.4
Hardness
2.4.4.1
Base metal
An hardness is requested lower than 220 HV10.
A hardness test shall be performed for each heat. The hardness test shall be performed
on a through thickness metallographically prepared sample, at the following locations:
in correspondence to the internal diameter;
in correspondence to the midline;
in correspondence to the external diameter.
2.4.4.2
Girth welds
During the welding procedure qualification, hardness tests shall be performed in order to
verify the above specified limits.
Girth welds shall be performed by qualified personnel in accordance with procedures
suitable to meet the following hardness limits:
root side in contact with process fluid:
max 250 HV10
cap side, in contact with atmosphere:
max 275 HV10
The hardness tests shall be performed in correspondence to: weld metal, fusion
boundary and heat affected zone.
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
Eni S.p.A.
Agip Division
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 11 di 21
Materials used for welding shall have a nickel content lower than 2.2 %.
Hardness tests on girth welds performed by sampling on site, if requested, shall be
specified in the project documentation.
The post-weld heat treatment, at a temperature of 620 C or 650 C for micro-alloyed
steels, is requested when the above specified maximum hardness limits are not
respected.
The post-weld heat treatment shall be qualified by the stress corrosion cracking tests
specified in the Company Specification 03587.MAT.COR.PRG.
Number and type of samples and sampling procedure shall be defined case by case.
2.4.5
Defect repair
Defect repair by welding of the base metal of pipes and fittings is not allowed.
2.4.6
2.4.7
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 12 di 21
Eni S.p.A.
Agip Division
2.5
2.5.1
Fabrication process
The steel shall be:
produced by the basic oxygen process or by electric oven;
with low sulphur content;
calcium treated for inclusion control.
Steel produced by continuous casting and degassed under-vacuum are preferred.
2.5.1.1
Cold working
In case the cold working of the sheets during the bending phase was greater than 5 %,
same requirements defined for piping will apply.
2.5.2
Grade
P275
CEV
0.40
0.43
If products are proposed with greater equivalent carbon contents, but in any case lower
than those one specified in the Company Specification 00191.PIP.MME.SDS, an
exception can be granted based on the results of weldability and hardness tests. The
weld shall be performed with the same procedure adopted for the construction of the
vessel.
The maximum hardness of the weld metal, at the fusion boundary and of the heat
affected zone shall be within the limits specified at Par. 2.5.5.2.
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
Eni S.p.A.
Agip Division
2.5.3
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 13 di 21
2.5.4
2.5.5
Hardness
2.5.5.1
Base metal
An hardness is requested lower than 220 HV10.
A hardness test shall be performed for each heat. The hardness test shall be performed
on a through thickness sample, metallographically prepared in the following locations:
in correspondence to the external and internal sides;
in correspondence to the midline.
2.5.5.2
Welds
During the welding procedure qualification, hardness tests shall be performed in order to
verify the above specified limits.
Welds shall be performed by qualified personnel in accordance with procedures suitable
to meet the following hardness limits:
root side in contact with process fluid:
max 250 HV10
cap side, in contact with atmosphere:
max 275 HV10
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
Eni S.p.A.
Agip Division
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 14 di 21
The hardness tests shall be performed in correspondence to: weld metal, fusion
boundary and heat affected zone, root pass, filling pass and cap pass.
Materials used for welding shall have a nickel content lower than 2.2 %.
The post-weld heat treatment, at 620 C or at 650 C for micro-alloyed steels, is
requested when the above specified maximum hardness limits are not respected.
The post-weld heat treatment shall be qualified by tests to be defined among those ones
specified in the Company Specification 03587.MAT.COR.PRG.
2.5.6
Defect repair
Defect repair by welding is not allowed.
2.5.7
2.5.8
Eni S.p.A.
Agip Division
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 15 di 21
Ergonomics
Not applicable.
2.7
Safety
Not applicable.
2.8
Documentation
2.8.1
Piping
2.8.1.1
2.8.1.2
2.8.2
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
Eni S.p.A.
Agip Division
2.8.2.1
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 16 di 21
2.8.2.2
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 17 di 21
Eni S.p.A.
Agip Division
ADDITIONAL INFORMATION
3.1
Annexes and
environments
3.1.1
appendixes.
Corrosion
mechanisms
in
H2S
containing
Sulphide Stress Cracking (SSC) occurs on susceptible metallic materials when specific
conditions are met, normally represented by presence of H2S and mechanical stress
solicitations, applied or residual.
With reference to the conditions met in the oil and gas production, the environments
which lead to SSC of susceptible materials, in particular carbon and low alloy steels, are
defined acid by H2S or sour.
3.1.2
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
Eni S.p.A.
Agip Division
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 18 di 21
Cathodic protection, when applied, opposes to hydrogen escape from the metal matrix.
The most susceptible materials are rolled steels containing inclusions in the metal matrix,
in particular C-Mn steels containing manganese sulphide Type II inclusions.
The likelihood of HIC occurrence in seamless and forged pipes is lower than in welded
pipes.
3.1.3
Stress Oriented Hydrogen Induced Cracking (SOHIC) e Soft Zone Cracking (SZC)
SOHIC and SZC are related to both SSC and SWC.
SOHIC and SZC are related to both SSC and SWC. In SOHIC staggered small
cracks are formed approximately perpendicular to the principal stress (applied or
residual) resulting in a "ladder-like" crack array. The mode of cracking can be
categorises as SSC caused by a combination of external stress and the local straining
around hydrogen induced cracks. SOHIC has been observed in patent material of
longitudinal welded pipe.
Soft Zone Cracking is the name given to a similar phenomenon when it occurs
specifically in softened heat affected zones of welds in rolled plate steels. The
susceptibility of such weld regions to this type of cracking is thought to arise because of
a combination of microstructural effects caused by the temperature cycling during
welding and local softening in the intercritical temperature heat affected zone. This
results in strains within a narrow zone which may approach or even exceed the yield
strain.
SOHIC has caused service failures of pipelines in the past but there are no reported
failures by SOHIC in modern micro alloyed line pipe steels produced for service in H2S
with mandatory testing for SWC and SSC.
3.2
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 19 di 21
Eni S.p.A.
Agip Division
1000
3.2.1
Sour Service
100
10
1
0.0001
0.001
0.01
0.1
10
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 20 di 21
Eni S.p.A.
Agip Division
1000
Sour Service
100
10
1
0.0001
0.001
0.01
0.1
10
100
3.2.2
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.
05489.MAT.COR.SDS
Rev. 2
March 1997
Sheet 21 di 21
Eni S.p.A.
Agip Division
All situations outside the above specified limits define the non-sour domain, where also
susceptible materials can be used.
Conservatively, conditions within the sour / non-sour transition domain shall be regarded
as sour conditions.
7.5
6.5
Solution pH
Transition Region
5.5
4.5
Sour Service
3.5
2.5
0.0001
0.001
0.01
0.1
10
100
This document is property of Eni S.p.A. Divisione Agip. It shall neither be shown to Third Parties not used for purposes other than those for which it has been sent.