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SR IPL
ASSIGNMENT
DT:15-04-2014
1.
Which of the following best explains why concentration cells must be run under non-standard
conditions in order for them to do electrical work?
A) concentration cell cannot do electrical work at 25oC.
B)The change in free energy for a concentration cell is always negative under standard
conditions.
C) Concentration cell has a cell potential equal to zero under standard conditions.
D) A concentration cell can only do electrical work when either NH3 or NaOH is added
2.
Eo
Cr 3 3e Cr ;
E o 0.74V
Eo
for?
A) -1.68V
3.
B)1.68V
C)-0.20V
D)0.20V
(B) 129.3 kJ
4.
Alkali metals dissolve in liquid NH3 and form blue coloured solution which is conductive due to
ammoniated electrons. The conductivity is
A) Lower than that of completely ionized metal salt in water
B) Higher than that of completely ionized metal salt in water
C) Low than that of fused metal salt
D) Equal to conductivity of liquid metal
5.
fumarate
i)
ii)
fumarate
A) -28.95 kJ
6.
2
2 H 2e succinate , E 0 0.03V
1
and
. Calculate
G 0
C) -75.27 kJ
D) -40.53 Kj
Eo
1.23 V ; E o
1.70 V
2
MnO /MnO
MnO /Mn
4
2
2
Given that
under acidic
conditions. An acidic solution of MnSO4 is mixed with KMnO4 solution. The incorrect
statement(s) among the following regarding this system is/are
(I) A stable compound of the stoichiometry Mn(MnO4)2 is formed.
(II) A precipitate of MnO2 is formed.
(III) KMnO4 loses its pink colour.
(IV) A redox reaction with a standard cell potential of +0.47 V occurs.
(A) I
(C) I, IV
Cd | Cd ( NO ) , KCN || Cd ( NO ) | Cd
32
32
(0.05 N ) (2 N ) (0.09 N )
7.
2NKCN
9 1022
(B)
(A)
8.
1.88 1019
1.44 1020
(D)
2.88 1020
Given :
G f
at 298 K
(A) 456 mV
G f
(H+ + Cl)(aq) =
130.79
kJ mol1
(B) 654 mV
(C) 546 mV
9.
(C)
Cd
(D)279.6 mV
(A) 1.048 V
(B) 0.04 V
(C) 0.604 V
(D) emf depends on x and cannot be determined unless value of x is given
10.
11.
MnO 4 / Mn 2
Ag(s) +
1
2
Cl2(g)
AgCl(s)
Would be
(a) 110kJ mol1
E 0Cl
2 / Cl
Given
G 0,E0 0
G 0,E 0
Pt,H
A)
B)
Pt,H
Pt H
C)
D)
Cu / Cu 2
Sn / Sn2
concentration in Cu chamber is
15.
x
10
The standard reduction potential for the half cell.(Give your answer as numerical)
NO3(aq) + 2H+(aq) + e
. Calculate
18.
Calculate the potential of an indicator electrode versus the standard hydrogen electrode which
originally 0.1M MnO4 and 0.8M H+ and which has been treated with 90% of the Fe 2+ necessary
to reduce all the MnO4 to Mn2+.(Give your answer as numerical)
MnO4 + 8H+ + 5e
19.
Cd / Cd2
0.402V, E0
Fe2+ / Fe3
0.771V
[log 6 = 0.778]
20.
[1 + 4]
When a rod of metallic lead was added to a 0.01 M solution of [Co(en) 3]3+, it was found that
68% of the cobalt complex was reduced to [Co(en)3] 2+ by lead.
i) Find the value of K for Pb + 2[Co(en)3]3+
Pb2+ + 2[Co(en)3] 2+
ii) What is the value of Eo [Co(en)3]3+|[Co(en)3] 2+
Given: Eo (Pb2+|Pb) = - 0.126 V(Give your answer as numerical)
SOLUTIONS
1. C
10.
2. B
(b)
MnO 4
3. A
4. B
+ 5e + 8H+
5. D
6.A
7.B
Mn2+ + 4H2O
Ered =
o
Ered
0.059
5
E ored
Ered(initial) =
log
[Mn 2 ]
8
[MnO 4 ][H ]
[Mn 2 ]
0.0591
log
8
5
[MnO 4 [X]
Let [H+]initial = X
[H+]final =
X
X
2
100 10
8.D
9.A
E ored
Ered(final) =
0.0591
[Mn 2 ] 1016
log
5
[MnO 4 ] [X]8
Ered(final) Ered(initial) =
0.0591
5
This Ered decreases by 0.189 V. The tendency of the half cell to get reduced is its
oxidising power. Hence the oxidising power decreases by 0.189V
11.A
(a)For the cell reaction
Ag(s) +
1
2
Cl2(g)
AgCl(s)
E0 = 1.14V
or E = E0
0.0592
log PCl1/22
1
PCl2 0
NO2(g) + H2O(l)
0.059
[Pr oducts]
log
n
[Re ac tan ts]
0.059
1
log 2
2
(8)
= 0.78
= 0.833V
Substituting this value for case (b)
0.059
1
log 7 2
2
(10 )
E = 0.78
= 0.78 0.059 7 = 0.367V
16.
G nFE
1
PbCl2
2
Ag
1 96500 0.49
4.2
= 11260 cal
S
[1]
d(G)
dE
nF
dT
dT
96500
( 1.8 10 4 )
4.2
= 4.14 cal/degree
[1]
H of the reaction
H = G + TS
= 11200 + 298 (4.14)
= 12494 cal
[1]
This heat of reaction is the algebraic sum of the heats of formation of the components.
H HAs
1
1
HPbCl2 HPb HAgCl
2
2
12494 0
1
1
86000 0 HAgCl
2
2
= 30506 cal/mole
[1]
Ecell
ESCE(redn) EHydrogen(redn)
=
= 0.2422 0.0591 log [
[H ]
= 0.2422 + 0.0591 pH at
25C
[1]
pH log[H ] log(0.1) 1
[1]
20 0.1 2 millimole
= 0.5 millimole
0.5
0.5
M pH log
1.95
45
45
18.
2.5 2
= 0.3574V
[1]
H2 (1atm) + 2e
Cathode half cell:
MnO4 + 8H+ + 5e
Initial Conc.:
0.1
0.8
0
Alter Complete
reaction with Fe+2
0.1
0.1
100
0.8
0.1 90
8
100
(0.01)
(0.08)
So, electrode potential of indicator electrode
Mn+2 + 4H2O
0
0.1 90
100
(0.09)
EoMnO / Mn2
EMnO / Mn2
4
0.0591
[Mn2 ]
log
5
[MnO-4 ] [H ]8
0.0591
(0.09)
log
5
(0.01) (0.08)8
= 1.51
= 1.51
0.0591
9
log
5
1.67 10 9
0.0591
log
5
= 1.51
(5.36 109)
= 1.51 0.1149
= 1.395 V
Thus, potential of an indicator electrode versus the SHE is 1.395 V because ESHE = 0
19.
Cd(s) 2Fe3
Cd
2
2Fe2
0.059
[Cd2 ][Fe2 ]2
log
2
[Fe3 ]2
[1]
to act as electrochemical cell,
E0cell
Ecell 0
0.059
[Cd2 ][Fe2 ]2
log
2
[Fe2 ]2
[1]
Here
1.173
or,
0.059
0.6[Fe2 ]2
log
2
[Fe3 ]2
[Fe2 ]
39.76 log0.6 2log[
[Fe3 ]
log
[1]
[Fe2 ]
[Fe2 ]
19.99log
20 (approx.)
[Fe3 ]
[Fe3 ]
or,
[Fe2 ]
[Fe3 ]
1 1020
[1]
20.
i) [Co(en)3]3+ = 0.0032, [Co(en)3]2+ = 0.0068 , [Pb2+] = 0..0034
Pb Co en
2
2 1
3
3 1
3
Co en
K=
On putting the various known values , we get
K = 0.0154
ii) G10 = -nFEcell = -2.303 RT log K.
From here we get, Ecell = -0.0536 V
From which we can calculate E [Co(en)33+/[Co(en)32+] = 0.18V