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Jay Sau
September 9, 2014
Problem (1). Plancks radiation law using energy quantization.
Assume that the radiation in a box is described by a scalar potential (r),
where r = (x, y, z) is position in a box. The Hamiltonian for the scalar field is
written as
Z
H = dr[(r)2 + ((r))2 ],
(1)
where (r) = t (r) is the canonically conjugate momentum (dont be alarmed
if you dont know what this means) and we have chosen units where c = 1.
Since the scalar field is in a box of size L the field can be expanded in Fourier
modes as
X
(r, t) = (L/2)3/2
k (t) sin (kx x) sin (ky y) sin (kz z),
(2)
k
Note that the Hamiltonian is that of a set of decoupled oscillators one for each
wave-vector k with frequency (k) = |k|.
Assuming the Planck hypothesis, which is that each oscillator mode at k has
a discrete number of states with energy quantized as E(k) = n~(k) and the
Boltzmann distribution, show that the average energy per mode is
hE(k)i =
~|k|
.
e~|k|/kB T 1
(4)
Evaluate the average energy density per frequency mode per unit volume
X
P () = L3
hE(k)i((k) )
(5)
k
in the limit L by converting the sum into an integral over (k) and then
doing the integral over k in spherical coordinates. The result should be similar
to the Planck radiation formula.
1
1
1
1
1
.
(8)
(9)
(10)
j=
|i; yi =
(11)
j=