COSHH Information

Physical
Inorganic
Organic

rmation

al
ic
c

R1

R2

Explosive when dry.

S1

Risk of explosion by shock, friction,

fire or other sources of ignition

S2

R3

Extreme risk of explosion by shock,

friction, fire or other sources of
ignition.

S3

R4

Forms very sensitive

metallic compounds.

S4

explosive

Heating may cause an explosion.

R5

S5
Explosive with or without contact
with air.

R6
R7
R8

R9
R10

S6
May cause fire.

S7

Contact with combustible material

may cause fire.
Explosive
when
mixed
combustible material.

S8

with

Flammable.

S9
S12

Highly flammable.
R11

S13

Extremely flammable.
R12
R14

R15

R16
R17

S14
Reacts violently with water.
Contact
with
water
liberates
extremely flammable gases.
Explosive when mixed with oxidizing
substances.
Spontaneously flammable in air.

S15

S16

S17
S18

R18
R19
R20

In
use,
may
form
flammable/explosive
vapour-air
mixture.
May form explosive peroxides.
Harmful by inhalation.

S20
S21
S22

Harmful in contact with skin.

R21
R22
R23

S23
Harmful if swallowed.
Toxic by inhalation.

S24
S25

Toxic in contact with skin.

R24

S26
Toxic if swallowed.

R25

S27

Very toxic by inhalation.

R26
R27
R28

R29

S28
Very toxic in contact with skin.
Very toxic if swallowed.
Contact with water liberates toxic
gas.

S29
S30

S33

Can become highly flammable in

use.
R30
R31

S35
Contact with acids liberates toxic
gas.

S36

R32

Contact with acids liberates very

toxic gas.

S37

Danger of cumulative effects.

R33
R34

S38
Causes burns.

S39

Causes severe burns.

R35

S40
Irritating to eyes.

R36

S41

Irritating to respiratory system.

R37

S42

Irritating to skin.

R38

S43

Danger of very serious irreversible

effects.
R39

S45

Limited evidence of a carcinogenic

effect.
R40

S46

Risk of serious damage to eyes.

R41

S47
May
cause
inhalation.

sensitization

by

R42
R43

R44
R45

R46

S48
May cause
contact.

sensitisation

by

skin
S49

Risk of explosion if heated under

confinement.
May cause cancer.
May
cause
damage.

heritable

S50
S51

genetic
S52

Danger of serious damage to health

by prolonged exposure.
R48

S53

May cause cancer by inhalation.

R49

S56

Very toxic to aquatic organisms.

R50

S57

Toxic to aquatic organisms.

R51

S59

Harmful to aquatic organisms.

R52

S60
May cause long-term adverse effects
in the aquatic environment.

R53

S61

Toxic to flora.

R54

S62

Toxic to fauna.
R55

S63
Toxic to soil organisms.

R56

S64
Toxic to bees.

R57

R58

S 1/2
May cause long-term adverse effects
in the environment.

S 3/7

Dangerous for the ozone layer.

R59

S 3/9/14
May impair fertility.

R60

S 3/9/49

May cause harm to the unborn child.

R61

S 3/9/14/49

Possible risk of impaired fertility.

R62

R63

S 3/14
Possible risk of harm to the unborn
child.

S 7/8

May cause harm to breastfed babies.

R64

S 7/9

Harmful: may cause lung damage if

swallowed.
R65

R66
R67

S 7/47
Repeated exposure may cause skin
dryness or cracking.
Vapours may cause drowsiness and
dizziness.

S 20/21
S 24/25

Possible risk of irreversible effects.

R68

S 27/28
Reacts
violently
with
water,
liberating
extremely
flammable
gases.

R 14/15

S 29/35

Contact with water liberates toxic,

extremely flammable gas.
R 15/29

R 20/21

S 29/56
Harmful by inhalation and in contact
with skin.
Harmful by
swallowed.

inhalation

and

S 36/37

if

R 20/22

S 36/39
Harmful in contact with skin and if
swallowed.

R 21/22

S 37/39
Harmful by inhalation, in contact
with skin and if swallowed.

R 20/21/22

S 36/37/39

Toxic by inhalation and in contact

with skin.
R 23/24
R 24/25
R 23/25

S 47/49
Toxic in contact with skin and if
swallowed.
Toxic by inhalation and if swallowed.

R 23/24/25

Toxic by inhalation, in contact with

skin and if swallowed.
and

in

R 26/27

Very toxic by inhalation

contact with skin.
Very toxic
swallowed.

and

if

R 26/28

R 26/27/28

by

inhalation

Very toxic by inhalation, in contact

with skin and if swallowed.

R 27/28

Very toxic in contact with skin and if

swallowed.

R 36/37
R 36/38

Irritating to eyes and respiratory

system.
Irritating to eyes and skin.

R 37/38

Irritating to respiratory system and

skin.

R 36/37/38

Irritating to eyes, respiratory system

and skin.

R 39/23

Toxic: danger of very

irreversible
effects
inhalation.

R 39/24

Toxic: danger of very serious

irreversible effects in contact with
skin.

R 39/25

R 39/32/24

serious
through

Toxic: danger of very serious

irreversible effects if swallowed.
Toxic: danger of very serious
irreversible
effects
through
inhalation and in contant with skin.

R 39/23/25

Toxic: danger of very serious

irreversible
effects
through
inhalation and if swallowed.

R 39/24/25

Toxic: danger of very serious

irreversible effects in contact with
skin and if swallowed.

R 39/23/24/25

Toxic: danger of very serious

irreversible
effects
through
inhalation, in contact with skin and if
swallowed.

R 39/26

Very toxic: danger of very serious

irreversible
effects
through
inhalation.

R 39/26/27

R 39/27

R 39/28

R 39/26/28

R 39/27/28

Very toxic: danger of very serious

irreversible
effects
through
inhalation and in contact with skin.
Very toxic: danger of very serious
irreversible effects in contact with
skin.
Very toxic: danger of very serious
irreversible effects if swallowed.
Very toxic: danger of very serious
irreversible
effects
through
inhalation and if swallowed.
Very toxic: danger of very serious
irreversible effects in contact with
skin and if swallowed.

R 39/26/27/28

R 68/20

R 68/21

R 68/22

R 68/20/21

Very toxic: danger of very serious

irreversible
effects
through
inhalation, in contact with skin and if
swallowed.
Harmful: possible risk of irreversible
effects through inhalation.
Harmful: possible risk of irreversible
effects in contact with skin.
Harmful: possible risk of irreversible
effects if swallowed.
Harmful: possible risk of irreversible
effects through inhalation and in
contact with skin.

R 68/20/22

Harmful: possible risk of irreversible

effects through inhalation and if
swallowed.

R 68/21/22

Harmful: possible risk of irreversible

effects in contact with skin and if
swallowed.

R 68/20/21/22

Harmful: possible risk of irreversible

effects through inhalation, in contact
with skin and if swallowed.

R 42/43

May
cause
sensitization
inhalation and skin contact.

R 48/20

Harmful: danger of serious damage

to health by prolonged exposure
through inhalation.

R 48/21

Harmful: danger of serious damage

to health by prolonged exposure in
contactwith skin.

R 48/22

Harmful: danger of serious damage

to health by prolonged exposure if
swallowed.

R 48/20/21

Harmful: danger of serious damage

to health by prolonged exposure
through inhalation and in contact
with skin.

R 48/20/22

by

Harmful: danger of serious damage

to health by prolonged exposure
through inhalation and if swallowed.

R 48/21/22

R 48/20/21/22

Harmful: danger of serious damage

to health by prolonged exposure in
contact with skin and if swallowed.
Harmful: danger of serious damage
to health by prolonged exposure
through inhalation, in contact with
skin and if swallowed.

R 48/23

Toxic: danger of serious damage to

health
by
prolonged
exposure
through inhalation.

R 48/24

Toxic: danger of serious damage to

health by prolonged exposure in
contact with skin.

R 48/25

Toxic: danger of serious damage to

health by prolonged exposure if
swallowed.

R 48/23/24

Toxic: danger of serious damage to

health
by
prolonged
exposure
through inhalation and in contact
with skin.

R 48/23/25

R 48/24/25

R 48/23/24/25

R 50/53

R 51/53

R 52/53

Toxic: danger of serious damage to

health
by
prolonged
exposure
through inhalation and if swallowed.
Toxic: danger of serious damage to
health by prolonged exposure in
contact with skin and if swallowed.
Toxic: danger of serious damage to
health
by
prolonged
exposure
through inhalation, in contact with
skin and if swallowed.
Very toxic to aquatic organisms, may
cause long-term adverse effects in
the aquatic environment.
Toxic to aquatic organisms, may
cause long-term adverse effects in
the aquatic environment.
Harmful to aquatic organisms, may
cause long-term adverse effects in
the aquatic environment.

Keep locked up
Keep out of the reach
of children
Keep in a cool place
Keep away from living
quarters
Keep
contents
under ... (appropriate
liquid to be specified
by the manufacturer)
Keep under ... (inert
gas to be specified by
the manufacturer)
Keep container tightly
closed
Keep container dry
Keep container in a
well-ventilated place
Do not keep
container sealed

the

Keep away from food,

drink
and
animal
feedingstuffs
Keep away from ...
(incompatible
materials
to
be
indicated
by
the
manufacturer)
Keep away from heat
Keep
away
from
sources of ignition
No smoking
Keep
away
from
combustible material
Handle
and
open
container with care

When using do not eat

or drink
When using do not
smoke
Do not breathe dust
Do
not
breathe
gas/fumes/vapour/spr
ay
(appropriate
wording
to
be
specified
by
the
manufacturer)
Avoid
skin

contact

with

Avoid
eyes

contact

with

In case of contact with

eyes,
rinse
immediately
with
plenty of water and
seek medical advice
Take off immediately
all
contaminated
clothing
After
contact
with
skin,
wash
immediately
with
plenty
of
(to
be
specified
by
the
manufacturer)
Do not
drains

empty

into

Never add water to

this product
Take
precautionary
measures
against
static discharges
This material and its
container must be
disposed of in a safe
way
Wear
suitable
protective clothing

Wear suitable gloves

In case of insufficient
ventilation
wear
suitable
respiratory
equipment
Wear
protection

eye/face

To clean the floor and

all
objects
contaminated by this
material use ... (to be
specified
by
the
manufacturer)
In case of fire and/or
explosion
do
not
breathe fumes

During
fumigation/spraying
wear
suitable
respiratory equipment
(appropriate wording
to be specified by the
manufacturer)

In case of fire use ...

(indicate in the space
the precise type of
fire-fighting
equipment. If water
increases the risk add:
Never use water)

In case of accident or
if you feel unwell seek
medical
advice
immediately
(show
the
label
where
possible)

If swallowed, seek
medical
advice
immediately and show
this container or label
Keep at temperature
not exceeding ...C (to
be specified by the
manufacturer)
Keep wetted with ...
(appropriate material
to be specified by the
manufacturer)
Keep only in
original container

the

Do not mix with ... (to

be specified by the
manufacturer)
Use only in
ventilated areas

well-

Not recommended for

interior use on large
surface areas
Avoid
exposure

Obtain
special
instructions
before
use
Dispose
of
this
material
and
its
container
to
hazardous or special
waste collection point
Use
appropriate
containment to avoid
environmental
contamination
Refer
to
manufacturer/supplier
for
information
on
recovery/recycling

This material and its

container must be
disposed
of
as
hazardous waste
Avoid release to the
environment. Refer to
special
instructions/safety
data sheet
If swallowed, do not
induce vomiting: seek
medical
advice
immediately and show
this container or label

In case of accident by
inhalation:
remove
casualty to fresh air
and keep at rest
If swallowed, rinse
mouth
with
water
(only if the person is
conscious)
Keep locked up and
out of the reach of
children.
Keep container tightly
closed in a cool place.
Keep in a cool, wellventilated place away
from (incompatible
materials
to
be
indicated
by
the
manufacturer).
Keep only in the
original container in a
cool,
well-ventilated
place.

Keep only in the

original container in a
cool,
well-ventilated
place away from
(incompatible
materials
to
be
indicated
by
the
manufacturer).
Keep in a cool place
away
from

(incompatible
materials
to
be
indicated
by
the
manufacturer).
Keep container tightly
closed and dry.
Keep container tightly
closed and in a wellventilated place.
Keep container tightly
closed
and
at
a
temperature
not
exceeding oC (to be
specified
by
the
manufacturer).
When using do not
eat, drink or smoke.
Avoid contact
skin and eyes.

with

After
contact
with
skin,
take
off
immediately
all
contaminated
clothing, and wash
immediately
with
plenty of (to be
specified
by
the
manufacturer).
Do not empty into
drains; dispose of this
material
and
its
container in a safe
way.

Do not empty into

drains, dispose of this
material
and
its
container
at
hazardous or special
waste collection point.
Wear
protective
and gloves.

suitable
clothing

Wear
protective
and
protection.

suitable
clothing
eye/face

Wear suitable gloves

and
eye/face
protection.
Wear
suitable
protective
clothing,
gloves and eye/face
protection.
Keep only in the
original container at a
temperature
not
exceeding oC (to be
specified
by
the
manufacturer).

Experiment
1
2
3
4
5
6
7
8
9

Experiment 1 - Techniques and Errors

Deionised water
Sodium Hydroxide
R35
Hydrochloric Acid
R34
R37
Bromocresol Green indicator
Potassium Iodate
R8
R 36/37/38
S26
Potassium Iodide
R22
R 36/38
S26
Ascorbic Acid
Starch Indicator
Dehydroascorbic acid
R22
Sodium Chloride solution

No classified Hazards
Causes severe burns.
Causes burns.
Irritating to respiratory system.
No classified Hazards
Contact with combustible material may cause fire.
Irritating to eyes, respiratory system and skin.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Harmful if swallowed.
Irritating to eyes and skin.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
No classified Hazards
No classified Hazards
Harmful if swallowed.
No classified Hazards

Experiment 2 - Kinetics of a Clock Reaction

Ammonium Persulfate
R8
R22
R 36/37/38
R 42/43
S22
S24
S26
S37
Ammonium Sulfate
Sodium Thiosulfate pentahydrate
Potassium Iodide
R22
R 36/38
S26
Deionised water
EDTA solution
Starch solution

Contact with combustible material may cause fire.

Harmful if swallowed.
Irritating to eyes, respiratory system and skin.
May cause sensitization by inhalation and skin contact.
Do not breathe dust
Avoid contact with skin
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable gloves
No classified Hazards
No classified Hazards
Harmful if swallowed.
Irritating to eyes and skin.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
No classified Hazards
No classified Hazards
No classified Hazards

Experiment 3 - Kinetcis of an Iodination Reaction

Iodine solution
Acetone
R11
R36
R66
R67
Sulfuric acid
R35
Deionised water
Sodium Acetate
Starch indicator
Sodium Thiosulfate Solution

odination Reaction
No classified Hazards
Highly flammable.
Irritating to eyes.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Causes severe burns.
No classified Hazards
No classified Hazards
No classified Hazards
No classified Hazards

Experiment 4 - Therodynamics of Solutions

Sodium Acetate trihydrate
No classified Hazards
Deionised Water
No classified Hazards

Experiment 6 - Introduction to Solution Chemistry and techniques

EDTA
R36
Deionised water
Calcium carbonate solution
Hydrochloric acid
R34
R37
Compound A solution
Compound B solution
Sodium Hydroxide
R35
GBHA indicator
R 36/37/38
S26
S36
Sodium Chloride solution
Ethyl Acetate
R11
R36
R66
R67
Phosphoric acid
R34
S26
S45

lution Chemistry and techniques

Irritating to eyes.
No classified Hazards
No classified Hazards
Causes burns.
Irritating to respiratory system.
Unknown so treat as hazardous
Unknown so treat as hazardous
Causes severe burns.
Irritating to eyes, respiratory system and skin.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing
No classified Hazards
Highly flammable.
Irritating to eyes.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Causes burns.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
In case of accident or if you feel unwell seek medical advice immediately (show the label where po

Experiment 7 - Vacuum Line Techniques

Nitrogen gas cylinder
Compressed gas
Liquid Nitrogen
Cryogenic burns

Experiment 8 - Introduction to electrode potentials

Platinum solution
R10
R 20/21
R38
S 36/37
Chloroplatinic acid
R25
R34
R 42/43
Nitric acid
R8
R35
S23
S26
S36
S45
Deionised water
Zinc Nitrate
R8
R22
R 36/37/38
S17
S26
Copper sulfate
R22
R 36/38
R 50/53
Silver chloride
R50
Potassium Chloride
Hydrochloric acid
R34
R37
Sulfuric acid
R35

electrode potentials
Flammable.
Harmful by inhalation and in contact with skin.
Irritating to skin.
Wear suitable protective clothing and gloves.
Toxic if swallowed.
Causes burns.
May cause sensitization by inhalation and skin contact.
Contact with combustible material may cause fire.
Causes severe burns.
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer)
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing
In case of accident or if you feel unwell seek medical advice immediately (show the label where po
No classified Hazards
Contact with combustible material may cause fire.
Harmful if swallowed.
Irritating to eyes, respiratory system and skin.
Keep away from combustible material
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Harmful if swallowed.
Irritating to eyes and skin.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Very toxic to aquatic organisms.
No classified Hazards
Causes burns.
Irritating to respiratory system.
Causes severe burns.

Experiment 9 - UV-Vis Spectroscopy

Deionised water
Cough Sweets
Dichloromethane
R40
R 36/37/38
R67
Standard dye solution
Coffee beans

ctroscopy
No classified hazards
Unknown composition, treat with caution
Limited evidence of a carcinogenic effect.
Irritating to eyes, respiratory system and skin.
Vapours may cause drowsiness and dizziness.
Unknown composition, treat with caution
Unknown composition, treat with caution

Experiment
Week 1
Week 2
Week 3
Week 4
Week 5

Week 1 - Practical Techniques

Cinnamic acid
R 36/37/38
S26
S36
2-hydroxycinnamic acid
R22
R 36/37/38
S26
3-hydroxycinnamic acid
R 36/37/38
S26
S36
4-hydroxycinnamic acid
R 36/37/38
S26
S36
1,4-dichlorobenzene
R36
R40
R 50/53
S 36/37
S46
S60
S61
Fluorenone
Benzil
R 36/37/38
Sodium Hydroxide
Benzoin
Ethyl acetate
R11
R36
R66
R67
Magnesium sulfate
Trans-anethole
R43
Para-anisaldehyde
Benzoic acid
R40
p-Toluidine
R 23/24/25
R40
R36
R43
R50
Thymol
R34
R 51/53
R22
Methyl benzoate
R22
S36
Iron chloride solution
R22
R38
R41
S26
S39
Ethanol
R11

Diethyl ether

R12
R19
R22
R66
R67

Irritating to eyes, respiratory system and skin.

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing
Harmful if swallowed.
Irritating to eyes, respiratory system and skin.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Irritating to eyes, respiratory system and skin.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing
Irritating to eyes, respiratory system and skin.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing
Irritating to eyes.
Limited evidence of a carcinogenic effect.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Wear suitable protective clothing and gloves.
If swallowed, seek medical advice immediately and show this container or label
This material and its container must be disposed of as hazardous waste
Avoid release to the environment. Refer to special instructions/safety data sheet
No classified hazards
Irritating to eyes, respiratory system and skin.
No classified hazards
No classified hazards
Highly flammable.
Irritating to eyes.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
No classified hazards
May cause sensitisation by skin contact.
No classified hazards
Limited evidence of a carcinogenic effect.
Toxic by inhalation, in contact with skin and if swallowed.
Limited evidence of a carcinogenic effect.
Irritating to eyes.
May cause sensitisation by skin contact.
Very toxic to aquatic organisms.
Causes burns.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Harmful if swallowed.
Harmful if swallowed.
Wear suitable protective clothing
Harmful if swallowed.
Irritating to skin.
Risk of serious damage to eyes.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear eye/face protection
Highly flammable.

Extremely flammable.
May form explosive peroxides.
Harmful if swallowed.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.

Week 2 - Chemistry of Unsaturated Organic compounds

c. Sulfuric acid
R35
2-benzylpyridine
R36
c. Nitric acid
R8
R35
S23
S26
S36
S45
Sodium hydroxide solution
Diethyl ether
R12
R19
R22
R66
R67
Magnesium sulfate
Sodium bromide
Cinnanic acid
R 36/37/38
S26
S36
Sodium perborate
R61
R22
R8
R37
R41
R62
S53
S45
Glacial acetic acid
R10
R35
Benzyl alcohol
R 20/22
1,3-dibromopropane
R10
R22
R38
R 51/53
Diphenylmethane
Diethyl adipate
Benzaldehyde
R22
S24
Ethylene glycol
R22
pentamethylbenzene
R11
R 36/37/38
S16
S26
S36

Organic compounds
Causes severe burns.
Irritating to eyes.
Contact with combustible material may cause fire.
Causes severe burns.
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer)
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing
In case of accident or if you feel unwell seek medical advice immediately (show the label where po
No classified hazards
Extremely flammable.
May form explosive peroxides.
Harmful if swallowed.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
No classified hazards
No classified hazards
Irritating to eyes, respiratory system and skin.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing
May cause harm to the unborn child.
Harmful if swallowed.
Contact with combustible material may cause fire.
Irritating to respiratory system.
Risk of serious damage to eyes.
Possible risk of impaired fertility.
Avoid exposure Obtain special instructions before use
In case of accident or if you feel unwell seek medical advice immediately (show the label where po
Flammable.
Causes severe burns.
Harmful by inhalation and if swallowed.
Flammable.
Harmful if swallowed.
Irritating to skin.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
No classified hazards
No classified hazards
Harmful if swallowed.
Avoid contact with skin
Harmful if swallowed.
Highly flammable.
Irritating to eyes, respiratory system and skin.
Keep away from sources of ignition No smoking
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing

Week 3 - Reaction mechanisms

Sodium
R15
R34
R14
ethyl acetate
R11
R36
R66
R67
ethanol
R11
Hydrochloric acid
R34
R37
Sodium chloride solution
Magnesium sulfate
L-(+)-alanine
Sodium Nitrite
R8
R25
R50
Diethyl ether
R12
R19
R22
R66
R67
Dibromocinnamic acid
R34
S26
S 36/37/39
S45
Potassium carbonate
R22
R 36/37/38
S26
S36
butanone
R11
R36
R66
R67
Sodium iodide
R 36/38
R50
Acetone
R11
R36
R66
R67
Bromopentane
R10
R 36/37/38
S26
S36
Sodium bisulfite
R22
R31
R41

Contact with water liberates extremely flammable gases.

Causes burns.
Reacts violently with water.
Highly flammable.
Irritating to eyes.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Highly flammable.
Causes burns.
Irritating to respiratory system.
No hazards Classified
No hazards Classified
No hazards Classified
Contact with combustible material may cause fire.
Toxic if swallowed.
Very toxic to aquatic organisms.
Extremely flammable.
May form explosive peroxides.
Harmful if swallowed.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Causes burns.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell seek medical advice immediately (show the label where po
Harmful if swallowed.
Irritating to eyes, respiratory system and skin.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing
Highly flammable.
Irritating to eyes.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Irritating to eyes and skin.
Very toxic to aquatic organisms.
Highly flammable.
Irritating to eyes.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Flammable.
Irritating to eyes, respiratory system and skin.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing
Harmful if swallowed.
Contact with acids liberates toxic gas.
Risk of serious damage to eyes.

Week 4 - Carbonyl Chemistry

Ethyl acetoacetate
Toluene

ethane-1,2-diol
p-Tolueonesulphonic acid monohydrate
Sodium hydroxide
Potassium carbonate

Magnesium sulfate
Fluorenone
Ethanol
Sodium borohydride

Diethyl ether

Meta-toluic acid

Thionyl chloride

diethylamine

R36
S26
R11
R63
R 48/20
R65
R38
R67
R22
R 36/37/38
R22
R 36/37/38
S26
S36

R11
R15
R 24/25
R34
S22
S26
S 36/37/39
S43
S45
R12
R19
R22
R66
R67
R22
S22
S 24/25
S36
R14
R 20/22
R29
R35
S26
S 36/37/39
S45
R11
R 20/21/22
R35
S3
S16

S26
S29
S 36/37/39
S45
Alumina
Petroleum ether

R12
R38
R 51/53
R65
R66
R67

Irritating to eyes.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Highly flammable.
Possible risk of harm to the unborn child.
Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Harmful: may cause lung damage if swallowed.
Irritating to skin.
Vapours may cause drowsiness and dizziness.
Harmful if swallowed.
Irritating to eyes, respiratory system and skin.
No classified hazards
Harmful if swallowed.
Irritating to eyes, respiratory system and skin.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing
No classified hazards
No classified hazards
Highly flammable.
Contact with water liberates extremely flammable gases.
Toxic in contact with skin and if swallowed.
Causes burns.
Do not breathe dust
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing, gloves and eye/face protection.
In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water incr
In case of accident or if you feel unwell seek medical advice immediately (show the label where po
Extremely flammable.
May form explosive peroxides.
Harmful if swallowed.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Harmful if swallowed.
Do not breathe dust
Avoid contact with skin and eyes.
Wear suitable protective clothing
Reacts violently with water.
Harmful by inhalation and if swallowed.
Contact with water liberates toxic gas.
Causes severe burns.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell seek medical advice immediately (show the label where po
Highly flammable.
Harmful by inhalation, in contact with skin and if swallowed.
Causes severe burns.
Keep in a cool place
Keep away from sources of ignition No smoking

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Do not empty into drains
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell seek medical advice immediately (show the label where po
No classified hazards
Extremely flammable.
Irritating to skin.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Harmful: may cause lung damage if swallowed.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.

Week 5 - Green chemistry and organometallic compounds

Benzoin
Magtrieve
R36
S26
S36
Petroleum ether
R12
R38
R 51/53
R65
R66
R67
Toulene
R11
R63
R 48/20
R65
R38
R67
Potassium hydroxide
R35
R22
2-chlorobenzaldehyde
R34
Magnesium turnings
R11
R15
S 7/8
S43
Calcium chloride
R36
S22
S24
Iodine crystal
R 20/21
R50
S23
S25
S61
Anhydrous ether
R12
R19
R22
R66
R67
Bromobenzene
R10
R38
R 51/53
S61
Ethereal ketal solution
R 36/37/38
S26
Magnesium sulfate
Acetone
R11
R36
R66
R67

c. Hydrochloric acid

R34
R37

d organometallic compounds
No classified hazards
Irritating to eyes.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing
Extremely flammable.
Irritating to skin.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Harmful: may cause lung damage if swallowed.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Highly flammable.
Possible risk of harm to the unborn child.
Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Harmful: may cause lung damage if swallowed.
Irritating to skin.
Vapours may cause drowsiness and dizziness.
Causes severe burns.
Harmful if swallowed.
Causes burns.
Highly flammable.
Contact with water liberates extremely flammable gases.
Keep container tightly closed and dry.
In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water incr
Irritating to eyes.
Do not breathe dust
Avoid contact with skin
Harmful by inhalation and in contact with skin.
Very toxic to aquatic organisms.
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer)
Avoid contact with eyes
Avoid release to the environment. Refer to special instructions/safety data sheet
Extremely flammable.
May form explosive peroxides.
Harmful if swallowed.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Flammable.
Irritating to skin.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment. Refer to special instructions/safety data sheet
Irritating to eyes, respiratory system and skin.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
No classified hazards
Highly flammable.
Irritating to eyes.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.

Causes burns.
Irritating to respiratory system.

Experiment
1
2
3
4
5

Experiment 1 - Interhalogen compounds

Chlorine gas
R23
R 36/37/38
R50
Iodine
R 20/21
R50
S23
S25
S61
Diethyl ether
R12
R19
R22
R66
R67
Dichloromethane
R40
R 36/37/38
R67

alogen compounds
Toxic by inhalation.
Irritating to eyes, respiratory system and skin.
Very toxic to aquatic organisms.
Harmful by inhalation and in contact with skin.
Very toxic to aquatic organisms.
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer)
Avoid contact with eyes
Avoid release to the environment. Refer to special instructions/safety data sheet
Extremely flammable.
May form explosive peroxides.
Harmful if swallowed.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Limited evidence of a carcinogenic effect.
Irritating to eyes, respiratory system and skin.
Vapours may cause drowsiness and dizziness.

Experiment 2 - Electrochemical synthesis

Potassium Hydrogen sulfate
R34
R37
S26
S 36/37/39
S45
Potassium peroxodisulfate
R8
R22
R 36/37/38
R 42/43
S22
S24
S26
S37
Ethanol
R11
Diethyl ether
R12
R22
R66
R67
Chlorine gas
R23
R 36/37/38
R50
Hydrochloric acid
R34
R37
S26
S45
Sulfuric acid
R35

Causes burns.
Irritating to respiratory system.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell seek medical advice immediately (show the label where po
Contact with combustible material may cause fire.
Harmful if swallowed.
Irritating to eyes, respiratory system and skin.
May cause sensitization by inhalation and skin contact.
Do not breathe dust
Avoid contact with skin
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable gloves
Highly flammable.
Extremely flammable.
Harmful if swallowed.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Toxic by inhalation.
Irritating to eyes, respiratory system and skin.
Very toxic to aquatic organisms.
Causes burns.
Irritating to respiratory system.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
In case of accident or if you feel unwell seek medical advice immediately (show the label where po
Causes severe burns.

Experiment 4 - Transistion metal complexes

Sodium hypochlorite solution
R34
R50
R31
Sodium sulfite
Potassium thiocyanate
R 20/21/22
R32
R 52/53
S13
S 36/37
S46
S61
Ammonium sulfide solution
R10
R31
R34
R50
S26
S 36/37/39
S45
S61
Sodium perborate
R61
R22
R8
R37
R41
R62
S53
S45

mplexes

Causes burns.
Very toxic to aquatic organisms.
Contact with acids liberates toxic gas.
Contact with acid liberates toxic gas
Harmful by inhalation, in contact with skin and if swallowed.
Contact with acids liberates very toxic gas.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Keep away from food, drink and animal feedingstuffs
Wear suitable protective clothing and gloves.
If swallowed, seek medical advice immediately and show this container or label
Avoid release to the environment. Refer to special instructions/safety data sheet
Flammable.
Contact with acids liberates toxic gas.
Causes burns.
Very toxic to aquatic organisms.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell seek medical advice immediately (show the label where po
Avoid release to the environment. Refer to special instructions/safety data sheet
May cause harm to the unborn child.
Harmful if swallowed.
Contact with combustible material may cause fire.
Irritating to respiratory system.
Risk of serious damage to eyes.
Possible risk of impaired fertility.
Avoid exposure Obtain special instructions before use
In case of accident or if you feel unwell seek medical advice immediately (show the label where po

Experiment 5 - Nickel (II) Complexes

Salicyladehyde
R 21/22
R 36/38
R68
R52
S26
S 36/37/39
sec-butylamine
R11
R 20/22
R35
R50
S9
S16
S26
S28
S 36/37/39
S45
S61
dimethyl glyoxime solution
R11
R40
R 36/37
R19

Harmful in contact with skin and if swallowed.

Irritating to eyes and skin.
Possible risk of irreversible effects.
Harmful to aquatic organisms.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing, gloves and eye/face protection.
Highly flammable.
Harmful by inhalation and if swallowed.
Causes severe burns.
Very toxic to aquatic organisms.
Keep container in a well-ventilated place
Keep away from sources of ignition No smoking
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
After contact with skin, wash immediately with plenty of (to be specified by the manufacturer)
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell seek medical advice immediately (show the label where po
Avoid release to the environment. Refer to special instructions/safety data sheet
Highly flammable.
Limited evidence of a carcinogenic effect.
Irritating to eyes and respiratory system.
May form explosive peroxides.

e possible)