Escolar Documentos
Profissional Documentos
Cultura Documentos
Spring 2015
Homework Set # 5
Deadline:
Problem 2
The thermal expansion coefficient, , and the isothermal compressibility, , of a gas are
given by the following expressions:
CP CP CV / CV
1 V
T
k1
V T P
CV
k2
1 V
V P T P
Problem 4
You have already seen that you can take Legendre transforms of dU to get dH, dA, and dG
(where A and G are the Helmholtz energy and the Gibbs energy, respectively). Legendre
transforms are a mathematical tool to transform any function while retaining information
content. In this problem, you will see how to take the Legendre transform of S, called
(the Greek letter Xi, pronounced zi or ksi, with a long i" sound.)
(a) Write a differential expression for dS as a function of U and V
(c) The function is defined as the Legendre transformation of S(U ,V) with respect
to U and V. Write the macroscopic (as opposed to the differential) expression for
in terms of S, U, V, P, and T, using your answer from part (b). What are the natural
variables of ?
2
]
(1/) /
]
(/) 1/
and
Problem 5
Consider a process where carbon dioxide is throttled from 1600kPa and 60C to
atmospheric pressure.
(a) What is the residual enthalpy (HR /RTc) and residual entropy (SR /R) for the inital
condition?
Assume the truncated Virial equation describes the state of carbon dioxide initially such
that
GR/RT=Z-1=BP/RT
for the initial state where B is the first Virial coefficient.
(b) Find the final temperature of the gas. Note that the process is carried out in an
isenthalpic manner and we assume carbon dioxide to be an ideal gas at the final
state
(c) What is the total change in entropy for this process?