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Bytheendofthistopic,youshouldbeableto:
1. Describethephysicalpropertiesofmetals;
2. Differentiatethestructuresofmetalsandalloys;
3. Describethechemicalreactionsofmetals;
4. Identifytheorderofreactivityofmetals;
5. Describethemethodofextractionofironandaluminium;and
6. Discusstheusesofmetals.
X INTRODUCTION
41
TOPIC 2 METALS
Have you ever seen coins such as the ones in Figure 2.1? Gold and copper were the
first metals discovered in the earth, since 6,000BC. Gold and copper coins have been
used since ancient civilisation. Gold articles were found extensively in antiquity
mainly as jewellery such as bracelets and rings. The symbol for gold is Au from the
latin aurum meaning shining dawn. The use of copper in antiquity was of more
significance than gold as the first tools, implements and weapons were made from
copper. The symbol for copper is Cu and comes from the latin cuprum meaning from
the island of Cyprus.
Currently, there are 86 known metals. Scientists have categorised metals into three
groups alkali metals, alkali earth metals and transition elements. You can explore the
names and symbols of all known metals in the Periodic Table of the Elements.
SELF-CHECK 2.1
1.
2.
3.
2.1
Metals consist of positive ions embedded in moving clouds of electrons (Figure 2.2).
The negatively charged electrons attract all the positive metal ions and bond them
together with strong electrostatic forces of attraction as a single unit called metallic
bond.
42
TOPIC 2 METALS
2.1.1
Figure 2.3: The positions of the positive ions in a metal before and after a
force has been applied
[Source:http://www.chemis
try.org/materi_kimia/struktur_atom_dan_ikatan/jenis_struktur_atom/s
truktur_logam/]
x
They have high densities, as the atoms are arranged in order and closely
packed together as can be seen in Figure 2.4.
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TOPIC 2 METALS
Different metals show different types of packing and in doing so they produce the
arrangement of atoms shown in Figure 2.5.
Atom of metal A
Atom of metal B
Figure2.6:Structureofanalloy
[Source:http://www.chem.qmul.ac.uk/surfaces/scc/scat6_4.htm]
44
TOPIC 2 METALS
Alloys are formed by mixing the molten substances thoroughly. But why make alloys?
The reasons why alloys are made are:
(a) To increase the strength and hardness of a pure metal. The presence of the
atoms of other elements disrupts the orderly arrangement of the pure metal.
The layers of metal atoms are prevented from sliding over one another easily.
This makes alloys stronger and harder than pure metals.
(b) To increase the resistance to corrosion of a pure metal. Alloying can prevent
metals from corrosion. This is because alloying helps to prevent the formation
of oxide layer on the surface of the metal (We will discuss the reaction of
metals in subtopic 2.2).
(c) To improve the appearance of a pure metal. Alloying helps to keep the metal
maintain the glossy nature of the surface as it prevents the formation of the
metal oxide.
Table 2.1 shows some of the more common alloys with their composition.
45
TOPIC 2 METALS
1.
2.
Copper starts off with the oxygen in copper oxide. However, iron is more reactive, so
it takes the oxygen away from copper. We say that iron has displaced (kicked out)
the copper.
Copper oxide + iron
CuO(s)
iron oxide +
+ Fe(s) CuO(s)
copper
Cu(s)
This is a displacement reaction. It shows us that iron is more reactive than copper.
There actually will not be a reaction between iron oxide and copper because copper is
less reactive than iron.
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TOPIC 2 METALS
You can now try some other displacement reactions as in Experiment 2.2.
Experiment 2.2
Metal/
Metal
oxide
Zinc
Iron
Copper
Magnesium
Zinc
oxide
Iron
oxide
Copper
oxide
Reaction Table
3.
4.
From Experiment 2.3, you can observe that lithium moves slowly on the surface of the
water, while sodium melts to become a small sphere, move rapidly and randomly on
47
TOPIC 2 METALS
the water surface with a hissing sound as it reacts. Potassium gets so hot that it lights
the hydrogen gas that water gives off. It burns with a lilac flame, move very rapidly
and randomly on the water surface with a hissing and popping sound. The colourless
solution formed turns red litmus paper to blue.
The chemical equation for the reaction of lithium with water is as follows:
Lithium +
2Li(s)
Water
2H2O (l)
Lithium hydroxide
2LiOH (aq)
Hydrogen
H2 (g)
SELF-CHECK 2.3
Write the word and symbol equations for sodium and potassium
reacting to water.
In the case of magnesium, this metal normally reacts slowly with water. But we
can speed up the reaction by heating up the water to make steam as in Experiment
2.4.
Experiment 2.4
1.
2.
The magnesium reacts strongly with the steam. It leaves white magnesium oxide in
the test tube. Hydrogen gas is given off.
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TOPIC 2 METALS
Magnesium +
Mg (s)
Steam
+ H2O (g)
Magnesium oxide
MgO(s)
+
+
Hydrogen
H2 (g)
The oxygen atom in H2O has swapped partner! It start off with hydrogen, but ends
up with magnesium.
Table 2.2 gives the different observations when metals react with water and steam.
Table 2.2: Reaction of metals with water and steam
T
Reaction with Water
Reaction with Steam
a Metals
Fizz, giving off hydrogen gas and Explode
b Potassium
leaving an alkaline (hydroxide)
Sodium
l
solution.
Lithium
e
Calcium
React, giving off hydrogen gas and
2 Magnesium Very slow reaction.
forming the metal oxide.
(Aluminium
is
protected
by
a
layer
Aluminium
.
of
aluminium
oxide
on
its
surface).
Zinc
2
Iron
3.
Notice that copper does not react with hydrochloric acid. However, the other metals
tested do react. For example, magnesium:
49
10 X
TOPIC 2 METALS
Magnesium
Mg (s)
MgCl2 (aq)
Hydrogen
H2 (g)
Calcium
Magnesium
Aluminium
Zinc
Iron
x
x
Tin
Lead
Copper
No reaction.
ACTIVITY 2.1
Discuss why we never add potassium, sodium or lithium to acid.
50
TOPIC 2 METALS
Potassium
Na
Sodium
Li
Lithium
Ca
Calcium
Mg
Magnesium
Al
Aluminium
Zn
Most reactive
Zinc
Fe
Iron
Sn
Tin
Pb
Lead
Cu
Copper
Ag
Silver
Au
Gold
Pt
Platinum
Least reactive
ACTIVITY 2.2
Figure shown is a message from
the Lonely Hearts section of the
Zoo of the World. Can you come
up with your own mnemonic
sentence to help you remember
the Reactivity Series?
51
11
12 X
2.3
TOPIC 2 METALS
In the earlier sub-topic, we learned about the Reactivity Series. We will now look at
how to get metals from their ores. This includes iron, which is the most widely used of
all metals. Figures 2.8 and 2.9 show iron ore and the mining of iron ore.
2.3.1
Extraction of Iron
52
TOPIC 2 METALS
Carbon is important in the extraction of iron. Carbon is a non-metal, but we can put it
into our Reactivity Series of metals. It is placed in between aluminium and zinc. This
means that carbon can displace any metal below aluminium in the Reactivity Series
(Figure 2.10).
Potassium
Na
Sodium
Li
Lithium
Ca
Calcium
Mg
Magnesium
Al
Aluminium
CARBON
Zn
Fe
Zinc
Iron
Sn Tin
Pb Lead
extracted using carbon
Cu Copper
Ag Silver
Au Gold
Pt Platinum
Figure2.10:ThepositionofcarbonintheReactivitySeries
We get carbon from coal. Coal is cheap and there is plenty of it at present. We use
coke (a cheap form of carbon which is made from coal) as one of the raw materials
besides iron ore (mainly haematite- iron(III) oxide) and limestone (to get rid of sandy
waste) in the process of extracting iron. We use blast furnace to get the iron from its
ore. Figure 2.11 shows the diagram of blast furnace used to extract iron.
x This carbon dioxide reacts with more hot coke to produce carbon monoxide
gas.
CO2 (g) + C(s) 2CO(g)
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13
14 X
TOPIC 2 METALS
x The carbon monoxide then reacts with iron oxide to get iron.
Fe2O3(s) + 3CO(g) 2 Fe(l) (s) + 3CO2 (g)
At the high temperature (up to 1900C) in the furnace, the iron is in molten form
(liquid). So, it sinks to the bottom of the furnace. The iron then will run off into
mould. The molten slag floats to the top of the iron. The slag is tapped off, cooled and
used for making roads.
2.3.2
Extraction of Aluminium
54
TOPIC 2 METALS
As shown in the Reactivity Series (refer Figure 2.10), the position of aluminium is
before carbon. This means aluminium is more reactive than carbon, so carbon cannot
be used to extract aluminium. So, how do we extract aluminium from its ore, bauxite,
which contains aluminium oxide, Al2O3?
Reactive metals can only be extracted from
their ores by electrolysis!
Figure 2.13 shows the electrolytic cell used for the extraction of aluminium.
55
15
16 X
x
x
x
TOPIC 2 METALS
Theoverallchemicalreactionis:
2Al2O3(l)4Al(l)+3O2(g)
Theoxygenliberatedattheanodewillreactwiththecarbonelectrode
toproducecarbondioxidegas.
C(s)+O2(g)CO2(g)
Consequently, the anode is corroded slowly and must be replaced
fromtimetotime.
Steel is used more than any other metal. It is important in the building industry. It is
used for girders and for the rods inside reinforced concrete. Steel tubes, called scaffold,
are used when buildings are made or repaired.
Steel is made mainly from iron. It has a small amount of carbon in it. The amount of
carbon affects its properties as can be seen in Table 2.4
Table 2.4: Types of Steel
Type of Steel
Mild steel
Amount of Carbon
0.2%
Hardness
Can be easily shaped
Medium steel
High-carbon
steel
0.3% to 0.6%
0.6% to 1.5 %
Hard
Very hard
Uses
Car bodies, wires,
pipe, bicycles
Girders, springs
Drills,
hammers,
other tools
Unfortunately, iron and steel rust. Is there a way to prevent this? You have learned about
alloy. How to make steel alloy?
However,stainlesssteelisexpensive.Ithasmainlybeenusedformakingsmall
items,suchasknivesandspoons.
ACTIVITY 2.3
Name20itemsthataremadeofstainlesssteel.
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TOPIC 2 METALS
Another metal that has many useful properties is aluminium. It conducts heat and
electricity well. It has low density for a metal. It does not corrode.
Platinum is used in catalytic converters, fitted to car exhausts. It cuts down the
amount of pollution from cars.
A radioactive isotope of cobalt is used to treat patients with cancer.
Figure 2.14 shows some uses of common metals around the home.
ACTIVITY 2.4
57
17
18 X
TOPIC 2 METALS
x
x
x
x
x
x
x
x
x
x
Blastfurnace
Carbon
Dilutedhydrochloricacid
Displacementreaction
Electrolysis
Heat
Metal
Metallicbond
Reactivityseries
Stainlesssteel
Steel
Water
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TOPIC 2 METALS
Earl, B., & Wilford, D. (2009). IGCSE chemistry. United Kingdom: Hodder
Education.
Eng, N. H., & Lim, Y. C. (2007). Focus Super Chemistry. Bangi: Penerbitan
Pelangi.
Farndon,J.(2003).Theelements:Aluminium.Malaysia:FederalPublications.
Ryan,L.(2001).Chemistryforyou.UnitedKingdom:StanleyThornes.
Sparrow,G.(2003).Theelements:Iron.Malaysia:FederalPublications.
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