Escolar Documentos
Profissional Documentos
Cultura Documentos
com
Chemistry Paper- I
PART II - CHEMISTRY
SECTION - I (One or More Options Correct Type)
D is wrong. Salt bridge ensure completion of circuit by movement of its ion without
being involved in any reaction.
23.
D is wrong because O2 and ethyl anthra quinol gives H2O2 which is diamagnetic.
Rest all form paramagnetic species.
Na + NH3 Na+ and ammoniated electron
K + O2 KO2 super oxide
Cu + HNO3 Cu+2 + NO + H2O
23. (ABD)
( 2I I2 + 2e) 3
6e + 6H+ + ClO3 Cl + 3H2O
________________________________________
6I + ClO3 + 6H2SO4 3I2 + Cl + 3H2O + 6HSO4
- 1 -
www. prernaclasses.com
24. Upon heating with Cu2S, the reagent(s) that give copper metal is /are
(A) CuFeS2
(B) CuO
(C) Cu2O
24. (C)
(D) CuSO4
25. (BCD)
26. The correct combination of names for isomeric alcohols with molecular formula C4H10O is /are
(A) tert-butanol and 2-methylpropan -2-ol
(B) tert- butanol and 1,1-dimethylethan-1-ol
(C) n-butanol and butan -1-ol
(D) isobutyl alcohol and 2-methylpropan-1-ol
26. (ACD)
CH3
CH3
CH3
CH2
CH2
CH2
OH , CH3
CH
CH3
CH2OH
OH ,
CH3
CH3
CH
CH2
CH3
OH
27. The reactivity of compound Z with different halogens under appropriate conditions is given below
:
mono halo substituted derivative when X2 = I2
OH
X2
C(CH3)3
27. (ABC)
- 2 -
www. prernaclasses.com
OH
OH
I2
C(Me)3
I
C(Me)3
OH
Br2
Br
C(Me)3
Br
OH
C
CI2
Cl
Cl
C(Me)3
Cl
28. An ideal gas in a thermally insulated vessel at internal pressure = P1, volume = V1 and absolute
temperature = T1 expands irreversibly against zero external pressure, as shown in the diagram.
The final internal pressure, volume and absolute temperature of the gas are P2,V2 and T2,
respectively. For this expansion,
Pext = 0
Pext = 0
Irreversible
P2, V2, T2
P1, V1, T1
Thermal insulation
(A)
28. (ABC)
q=0
(B)
T2 = T1
(C)
P 2V 2 = P 1V 1
(D)
P2V2 = P1V1
- 3 -
www. prernaclasses.com
30. In the reaction shown below, the major product(s) formed is /are
NH2
NH2
acetic anhydride
Product(s)
CH2Cl2
H
N
CH3
O
(A)
NH2
+ CH3COOH
H
N
(B)
+ CH3COOH
C
NH2
H
N
(C)
H
N
CH3
CH3
NH3CH3COO
CH3
+ H2O
H
N
(D)
CH3
NH2
30. (A)
NH2
CH3 C O C CH3
CH2Cl2
CH3
O
NH2
C
- 4 -
www. prernaclasses.com
C
32. In an atom, the total number of electrons having quantum numbers
n = 4, | ml | = 1 and ms = is
32.
(6)
n=4
l= 0 1 2 3
s p d f
0 2 2 2
33. The total number of distinct naturally occuring amino acids obtained by complete acidic
hydrolysis of the people shown below is
O
CH2
CH2 O
OH
33.
(4)
H N
HO
CH2
HO
C
O
H HO
O
C
OH
H
CH2
34. If the value of Avogadro number is 6.023 1023 mol1 and the value of Boltzmann constant is
1.380 1023 J K1, then the number of significant digits in the calculated value of the universal
gas constant is
34. (4) R = K N , Since K & N has 4 digits significant figure is 4.
35. A compound H2X with molar weight of 80 g is dissolved in a solvent having density of 0.4 g
ml1. Assuming no change in volume upon dissolution, the molality of a 3.2 molar solution is
35. (8) Mass of solvent = 400 g / L
m = (3.2 103) / 400 = 8.
- 5 -
www. prernaclasses.com
36. The total number(s) of stable conformers with non-zero dipole moment for the following
compound is (are)
Cl
Br
Br
CH3
Cl
CH3
CH3
Br
Br
Cl
CH3
CH3
Br
CH3
Br
C
36. (3)
Cl
Br
Cl
Br
CH3
CH3
Cl
Cl
Cl
K2Cr2O7, CuSO4, H2O2, Cl2, O3, FeCl3, HNO3 give iodine with KI solution.
Alkaline KMnO4 gives KlO3
39. Consider all possible isomeric ketones, including stereoisomers of MW = 100. All these
isomers are independently reacted with NaBH4 (NOTE : stereoisomers are also reacted
separately). The total number of ketones that give a racemic product(s) is/are
O
39. (5)
(A)
(B) O
(C)
O (D)
(E)
(F)
40. Among PbS, CuS, HgS, MnS, Ag2S, NiS, CoS, Bi2S3 and SnS2, the total number of BLACK
coloured sulphide is
40. (7) PbS, CuS, HgS, Ag2S, NiS, CoS, Bi2S3 are black precipitates.
- 6 -
www. prernaclasses.com