Escolar Documentos
Profissional Documentos
Cultura Documentos
24 g of zinc metal are dissolved in a 1 M HCl solution. How many coulombs have been
produced by the anodic process?
2.
A sheet of carbon steel one meter wide by three meters long has lost 40 g to corrosion
over the past six months. Convert that mass loss to a penetration rate of the steel in mm
units. What would be the total corrosion current associated with such a corrosion rate?
(carbon steel density = 7.8 g/cm3)
3.
An electrochemical measurement shows a uniform corrosion current density for a nickel base
alloy 400 of 23.2 A/cm2. Calculate the equivalent corrosion rate in mpy for this alloy.
(The equivalent weight of nickel base alloy is 30.12 g/mol and the density is 8.84 g/cm3)
4.
The Figure below represents a simplified version of the Pourbaix diagram of Zink in
water. .
When Zinc corrodes in water, the following species can be present over the complete range of
pH and potential: H+, H2, O2, OH-, H2O, Zn, Zn2+, Zn(OH)2 and ZnO22-! Relevant E values are:
Zn/Zn2+, 0.76 V; Zn/Zn(OH)2, -0.439 V; Zn/ ZnO22-, +0.441 V; H2/H+, 0 V; O2/H2O, 1.226
V (all values measured against SHE).
(a)
(b)
(c)
(d)
(e)
5.
6.
7.
8.
9.
Using the mixed potential theory and appropriate polarization diagrams (Tafel plots),
determine the effect of the following parameters on the corrosion potential and corrosion
rate of a Metal M corroding to dissolved M+ in an acid solution:
(a) increasing the exchange current density i0 of the anodic reaction
(b) increasing the exchange current density i0 of the cathodic reaction
(c) increasing the concentration of dissolved H+
(d) increasing the Tafel constant of the anodic reaction.
10.
A. M. Wilson (2015)