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Board of Intermediate Education

Senior Inter - Chemistry
Model Paper (English Version)
Time : 3 Hours

Max. Marks: 60
SECTION - A

Note: 1) Very Short Answer type questions.

10 2 = 20

2) Answer ALL questions.

1.
2.
3.
4.
5.
6.
7.

What are lipids? Give one example.

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What is peptide linkage? Give an example.

How Paracetamol is prepared? Give equation.

What are antibiotics? Give an example.

State first law of thermodynamics. Give mathematical formulation of this law.

What is "Gibbs energy"?

Mention the names of monomers used in the preparation of

a) Bakelite b) Nylon c) Terylene

8.
9.
10.

d) Neoprene.

What is Williamson's synthesis? Give equation.

What is Cannizzaro reaction? Give equation.

How many moles of AgCl are produced on addition of AgNO3 solution to 1 M

CoCl3. 5 NH3 solution. How many moles of ions are formed by complete
ionization of 1 mole of CoCl3. 5 NH3?
SECTION - B

Note: 1) Short Answer type questions.

6 4 = 24

2) Answer any SIX questions.

11.

W solution of H2SO4.
Define Molality (m). What is the molality of 15% ___
W

12.

Derive Bragg's equation.

13.

Give Nernst equation for metal ion electrode and non metal electrode. Calculate
the electrode potential of the following single electrode.
Ag+ (0.01 M) /Ag; (E = 0.799 V)

14.

Define the terms order and molecularity of a reaction.

15.

What is emulsion? How are emulsions classified? Give examples.

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16.

Explain froth flotation process.

17.

Explain how Super Phosphate of Lime is manufactured?

18.

a) Write the formulae of the following compounds.

i) Tetra Ammine Copper (II) Sulphate
ii) Tri Chloro triammino Cobalt (III)
b) Write the IUPAC names of the following compounds.
i) K3[Fe(CN)6] ii) [Pt(NH3)6](SO4)2
SECTION - C

Note: 1) Long Answer type questions.

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2) Answer any TWO of the following.

19.

a) How is bleaching powder manufactured industrially?

b) Give the reactions of Ozone with the following.
i) Ag2O ii) KI iii) PbS iv) BaO2

20.

a) Explain four factors that influence the rate of reaction.

b) Explain the Lewis acid-base theory with suitable examples.

21.

a) Explain the preparation of Ethyl alcohol from molasses.

b) How Ethyl alcohol reacts with
i) CH3MgI

ii) CH3COOH

iii) Na metal

iv) H2SO4, 140C

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2 8 = 16

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ANSWERS
SECTION - A
1.

What are lipids? Give one example.

A:

Naturally occurring water insoluble oily compounds related to fatty acids, esters
of fatty acids.
e.g.: Fats, Waxes.

2.

What is peptide linkage? Give an example?

A:

Amide linkages present between amino acids is called peptide linkage.

e.g.: Alanyl glycyl alanine.

3.

How paracetamol is prepared? Give equation.

A:

Para amino phenol on acetylation gives paracetamol.

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OH

OH

NH2

4.
A:

(CH3CO)2O

CH3COOH

NHCOCH3

What are antibiotics? Give an example.

The chemical substance produced by microorganism that destroy or inhibit the

growth of disease causing micro organism is called antibiotic.
e.g.: PENICILLIN

5.
A:

State first law of thermodynamics. Give mathematical formulation of this

law.
Energy can neither be created nor destroyed but energy in a process may be
converted from one form to another form.
Q = W + E

6.
A:

What is Gibbs energy?

The difference between enthalpy (H) of a system and the product of absolute
temperature (T) of system and entropy (S) is called Gibbs energy.
G = H TS

7.

Mention the names of monomers used in the preparation of

a) Bakelite

A:

b) Nylon

c) Terylene

a) Bakelite : Phenol & HCHO

b) Nylon : Adipic acid & Hexa methylene diamine
c) Terylene : Terepthalic acid & ethylene glycol

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d) Neoprene

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d) Neoprene : 2 - chloro 1, 3 - butadiene
8.

What is Williamson's Synthesis? Give equation.

A:

C2H5Cl on reaction with Sodium ethoxide to form diethyl ether.

C2H5O Na + Cl C2H5 C2H5 O C2H5 + NaCl

9.

What is Cannizaro reaction? Give equation.

A:

Aldehydes having no - hydrogens reacts with strong alkali to undergo

disproportionation reaction.
H
O
H
H

conc.NaOH
C = O + C = O H C OH + H C OK

H
H
H

10.

A:

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How many moles of AgCl are produced on addition of AgNO3 solution to

1 M CoCl3. 5 NH3 solution. How many moles of ions are formed by
complete ionization of 1 mole of CoCl3. 5 NH3?
2 Moles of AgNO3 are formed on addition of AgNO3 to the complex. 1 Mole
CoCl3. 5 NH3 on complete ionization gives 3 moles of ions.

SECTION - B

11.

W solution of H SO ?
Define molality (m) ? What is the molality of 15% ___
2
4
W

A:

Number of moles solute present in one litre solvent is called molality.

Wt. of Solute 1000

m =
gram molar Wt. of Solute Wt. of Solvent

12.
A:

15 1000
=
= 1.8
98 85
Derive Bragg's equation.

ay
tr
rs y
Fi d ra
n
co
Se

A crystal has many planes.

Atoms or ions are arranged in
systematic geometry in these
planes. Atoms or ions are
arranged in these planes in
order. When X - rays incident
on these planes, they undergo
diffraction. When the waves

1st plane
2nd plane
3rd plane
X - ray diffraction at the atoms in a crystal plane

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are diffracted from these atoms or ions, they may have constructive or destructive
interference. From the figure, it is very clear that 1st and 2nd ray are travelling the
same distance up to A and D. Where as 2nd X - ray travels an extra distance
DB + BC (Path difference) than that of 1st X - ray. If the two waves are to be
present in the same phase, the path difference must be equal to the wave length
or an integral multiple of wave length.
DB
DB
In ADB triangle, sin = =
AB
d
DB = d sin
BC
BC
In ABC triangle, sin = =
AB
d
BC = d sin

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n = DB + BC = 2d sin

n = 2d sin is known as Bragg's equation.

13.

Give Nernst equation for metal ion electrode and non metal electrode.
Calculate the electrode potential of the following single electrode.
Ag+ (0.01 M)/ Ag; (E = 0.799 V)

0.0591
log C
A: For metal ion electrode E = E +
n

0.0591
For non metal ion electrode E = E log C
n
E = 0.799 V,
C = 0.01 M,
n=1
0.0591
... E = E + log C
n
0.0591
= 0.799 +
1

log [102]

= 0.799 (2 0.0591)

= 0.680 V.
14.

Define the terms order and molecularity.

A:

Order: The sum or the powers of the Concentration terms in the rate equation
of the reaction is called order. Order is determined experimentally. This can
have values including zero, negative, positive, fractional values.
Molecularity: Number of atoms or ions or molecules participating in rate
determining step. This is known theoretically from the reaction mechanism.

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This can have values 1 or 2 or 3.

15.
A:

What is emulsion? How are emulsion classified? Give examples.

Emulsion is a colloidal system in which both the dispersion medium and

dispersed phase are liquids.
Oil in water type emulsion: The emulsion in which oil is dispersed phase
and water is dispersion medium.
e.g.: Milk, Vanishing Cream.

Water in oil type emulsion: The emulsion in which water is dispersed phase
and oil is dispersion medium.
e.g.: Cold cream, Cod liver oil.

16.
A:

Explain froth flotation process.

Powdered Sulphide ore is taken in a tank. Water, pine oil frothing agent like
sodium ethyl xanthate are added to this ore. Contents are agitated by bubbling air.
The froth is formed and carries the ore particles with it. The gangue particles settle down at the bottom of the tank. The froth is stabilised by adding collectors.
They prevent the ore particles from wetting with water. Sulphide ore particles float
on water with froth. Copper pyrites, iron pyrites are concentrated by this method.

17.

Explain how super phosphate of lime is manufactured?

A:

Super phosphate of lime is a mixture of Calcium dihydrogen phosphate and

gypsum. It is manufactured by treating finely powdered phosphate rock or bone
ash with Chamber's acid (70% H2SO4).
Ca3(PO4)2 + 2 H2SO4 + 4 H2O Ca(H2PO4)2 + 2 (CaSO4. 2 H2O).
1. Mixer
2. Stirrer
3. Chamber acid
4. Valves
5. Brick work Dens
6. Waste gases

MANUFACTURE OF SUPERPHOSPHATE OF LIME

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In this process finely, powdered phosphate rock and calculated quantity of
Chamber's acid are taken into cast iron mixer. It is stirred with stirrer. The charge
is dumped alternatively into one of the Dens D1 or D2 with the help of the valves
V1 and V2. The reaction mixture is allowed in Dens for 24 to 36 hours. CaCO3,
CaF2 impurities are removed as CO2 & HF. Temperature of this mixture is raised
to 373 K. Final product is called super phosphate. To avoid waste hard mass
gypsum, it is converted into triple phosphate, which is completely soluble in
water and taken easily by the plants.

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Ca3(PO4)2 + 4 H3PO4 3 Ca (H2PO4)2

18.

a) Write the formulae of the following compounds.

i) Tetra ammine copper (II) sulphate
ii) Tri chloro triammine cobalt (III).

b) Write the IUPAC names of the following compounds

i) K3[Fe(CN)6]

A:

a) i) [Cu(NH3)4]SO4

ii) [Pt (NH3)6] (SO4)2

ii) [Co(NH3)3 Cl3]

b) i) Potassium Hexa Cyano Ferrate (III)

ii) Hexa amine platinum (IV) sulphate

SECTION - C

19.

a) How is bleaching powder manufactured

industrially.

b) Give the reactions of ozone with the following

i) Ag2O

A:

ii) KI

iii) PbS

iv) BaO2

a) Bleaching powder is prepared by Bachman's

plant. It consists cast iron tower. A number of
horizontal shelves fitted with rotating rakes are
present in it. Dry slaked lime is dropped through
the hopper present at the top. Cl2, hot air are sent
through inlets present at the bottom. According to
principle of counter currents, Ca(OH)2, Cl2 move
in opposite directions to form bleaching powder.
it is collected in the receiver.

Bachmann's plant preparation

of CaOCl2
1. Hot air inlet
2. Cl2 inlet
3. Hopper
4. Outlet gases
5. Horizontal shelves
6. Rotating rakes
7. Receiver
8. Bleaching powder

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b)

i) O3 reacts with Ag2O to give Ag

Ag2O + O3 2 Ag + 2 O2
ii) O3 oxidises moist KI to I2
2 KI + H2O + O3 2 KOH + I2 + O2
iii) O3 oxidises PbS to PbSO4
PbS + 4 O3 PbSO4 + 4 O2
iv) O3 reduces BaO2 to BaO
BaO2 + O3 BaO + 2 O2

20.

a) Explain the 4 factors that influence the rate of reaction.

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b) Explain Lewis acid - base theory with suitable examples.

A:

a) The chemical nature of the reactant: A reaction taking place between ionic
compounds is faster than the reaction taking place between covalent
_
compounds. The reaction between Ag+ & Cl is faster than the reaction.

N2 (g) + 3 H2 (g)

2 NH3 (g).

Because covalent compounds involve breaking of existing bonds and making of

new bonds take time.
Concentration of reactants: The rate of the reaction increases with the
concentration of reactants. If the concentration increases, number of molecules,
collisions among them increases to increase the rate.
dc
= K. Cn
dt
Effect of temperature: The rate of a reaction increases with increase in the
temperature of the reaction. For every rise of 10C, specific rate gets doubled.
Kt + 10C

2
KtoC
Effect of Catalyst: Reactions in presence of a positive catalyst, the path of the
reaction changes in which activation energy is low and rate of the reaction is
more.
MnO2
e.g.: 2 KClO3
2 KCl + 3 O2
b) Lewis Acid: Any substance that accepts electron pair to form a coordinate
covalent bond. e.g.: BCl3, BF3.

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Types of Lewis acids:
All cations: e.g.: Co+3, Fe+3
Elements with electron sextet: O, S
Molecules with multiple bonds: CO2, SO2
Molecules with available d-orbitals: SF4, SiF4
Molecules with incomplete octet: AlCl3, BCl3
Lewis base: Any substance that donates electron pair to form a coordinate
covalent bond. e.g.: H2O, NH3.
Types of Lewis bases:
All anions: F , Cl

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..
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Molecules with lone pairs: R .O. H, N H3.

Molecules with multiple bonds: C2H2, C2H4.

21.

a) Explain the preparation of Ethyl alcohol from molasses.

b) How ethyl alcohol reacts with

A:

i) CH3MgI

ii) CH3COOH

iii) Na metal

iv) H2SO4, 140C

Ethyl alcohol is prepared from the waste liquid molasses, left after the
crystallisation of sugar from sugarcane juice. Molasses contain 30-40%
sucrose. It is diluted with water to contain 10% sucrose. H2SO4 is added to
maintain
pH = 4. Ammonium sulpahate & Ammonium phosphate are added
as food for Yeast. It is allowed for fermentation for 1-3 days at 30C.

Reactions taking place during fermentation are

Invertase
C12H22O11 + H2O C6H12O6 + C6H12O6
Glucose

Fructose

Zymase
2 C2H5OH + 2 CO2
Glucose or Fructose
(wash)
C6H12O6

Wash on fractional distillation followed by distillation with CaO gives 100%

ethyl alcohol.
i)

It forms alkane on reaction with grignard's reagent.

C2H5O H + CH3 MgI CH4 + Mg(OC2H5)I

ii)

It forms ester on reaction with CH3COOH.

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H3O+
CH3CO OH + H OC2H5 CH3COOC2H5 + H2O
iii) It forms sodium ethoxide on reaction with Na
C2H5O H + Na 2 C2H5ONa + H2
C2H5O H + Na
iv)

It reacts with Conc. H2 SO4 at 140C to form diethyl ether.

Conc.H2SO4
C2H5 OH + H OC2H5 C2H5OC2H5 + H2O.
140C
(Prepared by A.N.S. Sankar Rao)

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