Alkyl Halides

No

Questions

Which of the following reagent cannot be used for preparing alkyl

chloride from alcohol

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HCl+anhd.ZnCl2

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NaCl

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PCl5

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SOCl2

Aryl halides are less reactive towards nucleophilic substitution

reactions as compared to alkyl halides due to
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The formation of less stable

carbonium ion

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Resonance stabilization

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Larger carbon-hydrogen bond

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The inductive effect

Which of the foolowing with aqueous KOH will give acetaldehyde?

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1,2-Dichloroethane

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1,1-Dichloroethane

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Chloroacetic acid

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Ethyl chloride

DDT is formed from

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Benzene and chlorobenzene

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Chloral and chlorobenzene

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Chloral and benzene

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Chlorobenzene and chlorine

Ethyl chloride on treatment with aqueous alkali gives

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Ethane

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Ethene

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Ethanal

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Ethanol

Reaction of ethylamine with chloroform in alcoholic KOH produces

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CH3OH

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CH3NC

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C2H5NC

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C2H5CN

What happens when CCl4 is treated with AgNO3 solution

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NO2 will be evolved

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A white ppt. of AgCl will form

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CCl4 will dissolve in AgNO3 solution

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Nothing will happen

Th most reactive compound for electrophilic nitration will be

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Benzyl choride

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Benzoic acid

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Nitrobenzene

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Chlorobenzene

For the carbylamine reaction we need hot alc.KOH and

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Any amin and chloroform

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Chloroform and Ag powder

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A primary amine and chloroform

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A mono alkyl amine and

trichloroethane

The reaction between primary amine, chloroform and alcoholic

caustic potash is called
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Wurtz reaction

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Frankland reaction

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Cannizzaro's reaction

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Carbylamine raction

Benzene hexachlride is used as

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Dye

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Antimalerial drug

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Antibiotic

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Insecticide

Cl2 reacts with CS2 in presence of AlCl3 to form

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CHCl3

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CCl4

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C2H5Cl

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C2H6

Which of the following does not give iodoform test

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Ethanol

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Ethanal

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Acetophenone

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Benzophenone

The reaction of 4-bromobenzyl chloride with NaCN in ethanol lead to

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4-Bromobenzyl cyanide

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4-Cyanobenzyl chloride

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4-Cyanobenzyle cyanide

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4-Bromo 2-cyanobenzyl chloride

C-X bond is strong in

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CH3Cl

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CH3Br

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CH3F

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CH3I

The final product formed by distilling ethyl alcohol with excess of Cl2
and Ca(OH)2 is
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CH3CHO

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CCl3CHO

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CHCl3

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(CH3)2O

C3H8 + Cl2------light---------->C3H7Cl + HCl is an example of

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Elimination

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Substitution

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Addition

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None of these

Which of the following compounds on oxidation gives benzoic acid

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Chlorophenol

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Chlorotoluene

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Chlorobenzene

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Benzyl chloride

Chloroform reacts with NaOH to give

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CH3COONa

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Sodium oxalate

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CH3OH

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HCOONa

When ethyl iodide and n-propyl iodide are allowed to react with
sodium metal in ether, the number of alkanes that could be produced
is
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Only one

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Two alkanes

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Three alkanes

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Four alkanes

Iodoethane reacts with sodium in ether, the product formed is

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Pentene

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Propyne

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Butene

( )

Butane

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Which of the following reacts with chloroform and base to form

phenyl isocyanide
( )

Nitrobenzene

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Phenol

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Chlorobenzene

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Aniline

Replacement of Cl of chlorobenzene to give phenol requires drastic

conditions but chlorine of 2,4-Dinitrochlorobenzene is readily
replaced because
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NO2 makes the electron rich ring at

ortho and para positions

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NO2 withdraws electrons at meta

position

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NO2 donates electrons at m-position

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NO2 withdraws electrons at ortho and

para positions

1,3-Dibromopropane reacts with metallic zinc to form

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Propene

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Propane

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Cyclopropane

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Hexane

C6H6Cl6 can be obtained from

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HCl and benzene

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Cl2 and benzene and AlCl3

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Cl2 and benzene in diffused light

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NaOCl and benzene

Ethyl alcohol gives ethyl chloride with the help of

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SOCl2

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NaCl

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Cl2

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KCl

Chlorobenzene on heating with aqueous NH3 under pressure in the

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presence of cuprous chloride gives

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Benzamide

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Nitrobenzene

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Aniline

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Chloroaminobenzene

2-Bromopentane is heated with potassium ethoxide in ethanol. The

major product obtained is
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2-Ethoxypentane

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Pent-1-ene

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Cis-Pent-2-ene

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Trans-Pent-2-ene

1-Chlorobutane on reaction with alcoholic potash gives

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But-1-ene

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Butan-1-ol

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But-2-ene

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Butan-2-ol

Butanenitrile is formed by reaction of KCN with

( )

Propyl alcohol

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Butyl chloride

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Butyl alcohol

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Propyl chloride

Ethyl bromide on treatment with alcoholic KOH gives

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Ethylene

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Ethanol

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Acetic acid

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Ethane

Benzene reacts with chlorine to form benzene hexachloride in

presence of
( )

Nickel

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AlCl3

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Bright sunlight

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Zinc

Gammexane is
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Chlorobenzene

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Benzyl chloride

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Bromobenzene

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Benzene hexachloride

Tetrabromoethane on treatment with alcoholic zinc gives

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Ethylbromide

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Ethane

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Ethene

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Ethyne

Sn1 reaction of alkyl halides leads to

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Retention of configuration

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Recemisation

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Inversion of configuration

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None of these

How many monochlorobutanes will be possible on chlorination of nbutane

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Which halide among the folowing is used as methylating agent

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CH3I

( )

C2H5Cl

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C2H5Br

( )

C6H5Cl

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Cyanoform is_______acid in nature than the chloroform

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Stronger

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Weaker

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Amphoteric

( )

Neutral

To get DDT, chlorobenzene has to react with one of the following

compounds in the presence of cnc.H2SO4
( )

Trichloroethane

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Dichloroacetone

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Dichloroacetaldehyde

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Trichloroacetaldehyde

Alkyl halides raect with Mg in dry ether to form

( )

Magnesium halide

( )

Grignard's reagent

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Alkene

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Alkyne

Which of the following will have the maximum dipole moment

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CH3F

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CH3Cl

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CH3Br

( )

CH3I

On warming with silver powder, chloroform is converted into

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Acetylene

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Hexachloroethane

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1,1,2,2-tetrachloroethane

( )

Ethylene

The reaction of an alkyl halide with RCOOAg produces

( )

Ester

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Ether

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Aldehyde

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Ketone

Unpleasant smell of carbylamine is ontained when chloroform and

alcoholic KOH are heated with
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Any aromatic amine

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Any primary amine

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Any amine

( )

Any aliphatic amine

When primary amine racts with chloroform in ethanolic KOH, then the
product is
( )

An isocyanide

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An aldehyde

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A cyanide

( )

An alcohol

Grignard reagent is nor prepared in aqeous medium but prepared in

ether medium because
( )

The reagent is highly reactive in ether

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The reagent does not react with water

( )

The reagent becomes inactive in

water

( )

The reagent reacts with water

Most reactive halide towards Sn1 reaction is

( )

n-Butyl chloride

( )

sec-Butyl choride

( )

ter-Butyl chloride

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Allyl chloride

A set of compounds in which ractivity of halogen atom in the

ascending order is

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Chlorobenzene, vinyl chloride,

chloroethane

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Chloroethane, chlorobenzene, vinyl

chloride

( )

Vinyl chloride, chlorobenzene,

chloroethane

( )

Vinyl chloride, chloroethane,

chlorobenzene

When chloroform is boiled with NaOH it gives

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Formic acid

( )

Trihydroxymethane

( )

Acetylene

( )

Sodium formate

Allyl chloride on dehydrochlorination gives

( )

Propadiene

( )

Propylene

( )

Allyl alcohol

( )

Acetone

Among the following the most reactive towards alcoholic KOH is

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CH2=CHBr

( )

CH3COCH2CH2Br

( )

CH3CH2Br

( )

CH3CH2CH2Br

Which compound give +ve iodoform test

( )

Butanol-1

( )

Butan--al

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Butanol-2

( )

2-pentanone

Which reperesents nucleophilis aromatic substitution reaction

( )

Reaction of benzene with Cl2 in

sunlight

( )

Benzyl bromide hydrolysis with water

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Reaction of NaOH with

dinitrofluorobenzene

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Sulphonation of benzene

Which of the following compounds gives trichloromethane on

distilling with bleaching powder
( )

Methanal

( )

Phenol

( )

Ethanol

( )

Methanol

Tertiary alkyl halides are pratically inert to substitution by Sn2

mechanism because of
( )

Insolubility

( )

Instability

( )

Inductive effect

( )

Steric hindrance

Alkyl halides react with lithium dialkyl copper reagents to give

( )

Alkenes

( )

Alkyl copper halides

( )

Alkanes

( )

Alkenyl halides

Which of the following undergoes nucleophilic substitution

exclusively by Sn1 mechanism
( )

Benzyl chloride

( )

Ethyl chloride

( )

Chlorobenzene

( )

Isopropyl chloride

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