Escolar Documentos
Profissional Documentos
Cultura Documentos
Nov. 2014
Okino Lab.
What is plasma ?
electron
ion
100
ice
water
Solid
Liquid
a few 1000
water vapor
Gas
ionized gas
Plasma
Discharge frequency
Electrode
Pressure
Merits
Diculty
Low pressure
Atmospheric
Barrier discharge
Applications
Improvement of
Adhesion
Paintability
Sterilization
Corona discharge
Plasma bullet
Merit:
Low temperature
Problems:
plasma (left)
Acetone
Paper
Electronic substrate
Plastic
Glass
Fireworks or candles
don't be ignited.
No damage for
stocking.
air
He
N2
Before
After
Ar
O2
Acrylic resin
Glass
Semiconductor
Copper
Polyimide lm
PTFE(Teflon
Knit Cotton100
Rayon
Shading curtain
Woods
Natural rubber
Bamboo
Drawing paper
Floor tile
PF-DFMJ01
1mm
4
Treated
No-treated
(Oxide)
Copper oxide ~ 10 nm
Carry speed
(mm/sec)
10
50
100
200
1 ~ 2 nmNatural oxide
Copper
PAT.P
2011.9.29
Improvement of
Adhesion
Paintability
Sterilization
atmospheric pressure
good gluing !
PF-DFL
Sterilization of E.coli
,O2
N2
CO2
CO2
O2
N2O
,O2
N2O
CO2
60s
10s
600s
N2O
,O2
EZ2C
Air
CO2
2010/03/12
600s
60s
Ar
EZ2C
10
10s
60
EZ2C
2010/03/19
2010/03/17
600
2010/03/15
Sterilized
Not-sterilized
2010/03/15
2010/03/12
10s
60s
Ar+O2
ir
ir
Plasma gas
ir
600s
Sterilization of S.mutans
Confidential
Ar
N2
O2
Ar+O2
CO2
Air
Confidential
Confidential
Confidential
Effective for
highly resistant
bacteria
1O
O3
2.80 V
2 2.42 V
Effective for
viable bacteria
2.07 V
Ozone [M]
HO
OH radical [M]
H2O2
1.77 V
Ice !
Gas temperature ()
Start cooling
zero
90
Corona discharge
"Common" Low temp. plasmas
Barrier discharge
-100
Room
temp
100
Gas temperature ()
200
10
Nozzle tip
aqueous
solution
Droplet
Nebulizer head
14 pL~
Element
Absolute amountfg
Fe
360
Mg
92
63
Ca
26
Zn
0.91
Mn
0.73
to Mass Sprctrometer
to Mass
Sprctrometer
Touchable
Plasma
Sample
Flow
Estaron Mocha
MH+
195.10
Caffeine
2.0
1.0
Gas temp: 55
M = 194.19
[M+O]H+
211.10
2MH+
m/z
Saridon
isopropylantipyrine 150 mg
Ethenzamide 250 mg
B.P.319
B.P.302
Signal
[count]
Mass
Signal
[count]
MH+
231.18
Ethenzamide
Isopropylantipyrine
M = 165.19
M = 230.31
MH+
166.11
(M+O)H+
247.17
m/z
2MH+
461.35
Teflon
Deposited
chemical warfare agent
Ion trap
mass spectrometer
(Agilent technologies, 1100
Series LC/MSD trap)
C6H1235Cl3NH+
203.93
Signal [count]
Nitrogen mustard 3
C6H1235Cl237ClNH+
205.89
M = 204.53
C6H1235Cl37Cl2NH+
207.85
m/z
VX (Nerve gas)
Boiling point298
C11H26NO2PSH+
268.05
VX
Signal [count]
M = 267.4
m/z
Isopropylantipyrine on a fingher
He gas
200 ml/min
Discharge capacitor12 F
Discharge voltage380 V
Dischrge frequency20 Hz
Ion trap
mass spectrometer
Isopropylantipyrine 50 ppm
= 0.540 g
in 10L methanol
MH+
231.05
Isopropylantipyrine
Signal [count]
M = 230.31
m/z
2014.5.22
NIKKEI shimbun
2014.7.8
to Mass spectrometer
100 x 250 mm
500 m
N2
Helium
Argon
Neon
O2
CO2
Air
PAT.P
Iso Special
Fine Float
Matsuda Special
Black Stream Mark
Analytical Sciences
11 3 5 1 10 29 12 25 12 10 259
ISSN 0 9 1 0 - 6 3 4 0
Analytical
Analytical
Sciences
Sciences
Vol.
JAAS
Journal of Analytical Atomic Spectrometry
www.rsc.org/jaas
29
No. 12
2013
pages 11171230
Development of the atmospheric plasma soft-ablation method (APSA) for
elemental analysis of materials on heat-sensitive substrates.
T. IWAI, Y. TAKAHASHI, H. MIYAHARA, and A. OKINO (pp. 1141 1145)
ISSN 0267-9477
ISSN 0267-9477
COMMUNICATION
Kaori Shigeta et al.
Sample introduction of single selenized yeast cells (Saccharomyces cerevisiae) by
micro droplet generation into an ICP-sector field mass spectrometer for label-free
detection of trace elements
PAPER
Akitoshi Okino et al.
Fundamental properties of a non-destructive atmospheric-pressure
plasma jet in argon or helium and its first application as an ambient
desorption/ionization source for high-resolution mass spectrometry
Analytical Sciences
Dec. 2013
Plasma Factory