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a) explain the variation in physical properties of the elements in terms of
structure and bonding ( refer to variations in metallic character and
electrical conductivity)
b) describe the bonding of the tetrachlorides
c) explain the reactions of the tetrachlorides with water
d) discuss the trends in:- (i) bonding (ii) acid/base character (iii) thermal
stability of the oxides of oxidation states II and IV (make reference to E
values of the elements)
e) discuss the uses of ceramics based on silicon(IV) oxide
GROUP IV ELEMENTS
Group IV elements:C
Si
Ge
Sn
Pb
Variation in melting points and electrical conductivities of the elements
Property
m.p (K)
C
4003
Si
1683
Ge
1210
Sn
505
Pb
600
Ge
Sn
Pb
The tetrachlorides
The tetrachlorides of group IV elements are covalent, tetrahedral
molecules. These exist as liquids at rtp. The molecules exist as discrete
units with weak van der Waals forces between them and this results in
the liquids being quite volatile at room temperature. Within the molecule
are strong covalent bonds between the atoms involved.
Note that the larger the molecules, the LESS volatile they are
Shape of a tetrachloride of a group IV element (tetrahedral)
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SiO2 (s) + OH- (aq) SiO32- (aq) + H2O(l) It react with alkali to form
a salt and water
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Practice Questions
1.
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