E,

i*{F Fr{?}ii

CH
.

20. Name the alkanes that have the following molecular or structural formrlas' 25.1

. cH3cH2cH3

TI TTi
nnn

3' Draw a structural formula for ea

the molecular formula C5H16. Nr

ithe,
'i
e''hone

2-dimethfPentane
1,3

o.

3-methylbutaae

C.

3,4-dimethYlbutane

Give
a.

pound.25.2

Draw all the stmctural isomers

molecrla formtda Cull14. Name
(For converdence, You maYwisl
the cabon skeleton fo each str

*rrb Draworre structural isomerof a

derved i

38'

compound.25.3

3l, Why are e following narees incorrect? What

are the correct aames? 25'l
b.

CHr:161r69,
I

i"'

3ll. Draw stnrctures for the alil groups

from methane, ethane, and propane.2S-.1

a.

CH"
a.

t-

cH3-cH-cH3
I

CHs

-dimeth-vlProPane

CH.
I

e IUPAC name for each compound-

b.

25.1

cH3-cH-cH-cH3
I

cH1-cH-cH2
tl curIJv
rJ
e

CH2
I

.L 5
v

b.

cH3-cH-cH-CH3

CHA

II

CH3 CH3
.

c.

CHS

l"i

CH._CH_CH,_C}I_CH
tl
II

CH3-CH-CHz-CHz

ll
CHZ

CHzCH3

CH2CH3

rl[fur*+t'itl,t

cHtcHz)scH,
HHHHH
lliil
c. H-C-C-C-C-C-F
--

/Unzun3

,rt-t\

2E. Draw candensed structural formrfas for pentane and hexane. .Assume tlrat rbe C-H and
C-C bonds are understood- 25.1

b.

L,fr3\

cH2 cz

ll

cl{3

CH3

cH3

3. Draw a stnctural formula or ca

CHs
33. Why are alkane molecules nonpolar? 25.1

,.jtkbtat.for each of e following alkene

and rrns forms if the compt

-nliit1v.b{cx
structual formula for
metric isomers 2S'3
hab qrP
methene. Ex.laitl.25.2
i " a.2-pentene
t. 2-methyl-2-pentene
35, Give a systematic name for these alkenes' 25'2
t. 3-ethyl-2-pentene
a. CH3CH:CH2
tll. Show how lack of rotation abol
b. cH3.
'Qt'kn<arbondouble bond ieads to ge
,H
\n^/
,zu-t\
ni*rtorcsm. Use the isomers of 2-p
CH,CH3
H
25.3
Ta,ne to illustate your answet.

34. you

caffiot draw

c. CH3CHCHzCH:CHz
I

CH

,'ip52
f . po ail molecules have stereoiso
rjI,{/latrr.25.3

7G8

Chapter2S

n- you draw a suuctural isomer of bexane

&n

i8. Y{rite $tru$ural fornulas fcr the foowing

comPounds,

cabon? 25'3
tf*Urnl thathas an aEYemetric

a, propyfre
b. cyclohexane

t3i"* o roo.*t* for each compound' 25'4

a. p-diethYlbenzeae
. 2-methYt-3-PhenYlPentane

t. 2-PhenYlProPane

p-xylene
d. t0luene

,e.

&uin
1,

rurry

oth of these structues represeilt

2-diethYlbenz ene. 25.4

for the complete combus"qo",ion

, tioa "of"r,
octane {CB}IId.25.5
l{** *uru *ounals in oder of increasing
and
: hardness: bituminous coal. peat, ligrrite'
antlEacite coal.25.5

poteutial use? 25.5

a.ethene

e. ethYne

!.ProPane

d-cYclobutane

53, Compare ese three molecular structues'

Wbicbwould you expectto be most stable?

whv?

l_i
"--4

i*"u., tlr. chemical struure of coal' 25'5

How does the amount of sulfur in coal affect its

in the
5il. The seven organic chemicals produced

I iffi ffi HIHTL$""T:ffi # ;'j*

},lA51lftY

'.:For eacb hydrocarbon picrured below'

"

the aert three higher horrologs of

52, Draw electron dot strucnues for each

CH2CH3

iri

tt

1,l-dtPhenYlhexane

co*Pound.

\\y'\cH,cH3

,.1

2,3-dimethfpentane

l.

51, Name

fi,.\CH,CH3

i*iipT

2,2,4-aimett4{Pertne

a.

ethane.
CHZCH

,r,

rt.

identiS

,yp" oiu"nding and name the compound'

given'
ioUowing questions based on the data
mounl

lnnical
Ethylene I
Proovbne i

15'9
8'4

ureldichloride I

68

|
eztnt i
Eitytbenzen. I
yinrcnroroe i

6'3
5s

EttrVtene

#l
,..
::..'

lt

il

(b)
a.

Pralt*tl

(liiBs st f)

43
37

How many trillion kilograms of aromatic

comPounds were Produced?

. Of the total mass of all seven compounds

produced, what prcent bymass wa made

up of aliPhatic comPounds?

S, Are

these nTo structure geometric isoners?

Explain

CHs.
tc:cl C}tz

H/

tH

H,.

,H

,c:c,

cH;

tH,