Escolar Documentos
Profissional Documentos
Cultura Documentos
5. methane production
- may be burned to generate heat
or power
CO2 + H2O
Soluble BOD
1 kg
Aerobic process
0.5 kg
New biomass
0.5 kg
CH4 gas
Biodegradable COD
1 kg
Anaerobic process
> 0.9 kg
New biomass
< 0.1 kg
Process Description
A. Conventional
B. High-Rate
(=30-60 days)
(no mixing)
(~15 days)
(complete mix)
Gas out
(CH4 & CO2)
Influent
Influent
scum layer
supernatant
active layer
stabilized solids
sludge
hydrolysis
Complex
organics
Short-chain
soluble
organic
monomers
acid
forming
bacteria
Organic acids:
(acetic, proprionic,
formic, etc.)
acetogenesis
(waste conversion)
methane
forming
bacteria
CO2
CH4
methanogenesis
(waste stabilization)
Methane Bacteria
Methane bacteria
- very sensitive to small concentrations of O2
- slow growth rate
- low rate of organic utilization
C*H4 + CO2
CH4 + 2H2O
Note: Microbiologists no longer consider methanogens to be in the bacterial domain. Recent RNA
sequencing places methanogens in the domain Archaea. In fact, humans are more closely
related to cucumbers than methanogens are related to bacteria.
n a b
n a b
Cn H a Ob + n H 2O + CO2 + + CH 4
4 2
2 8 4
2 8 4
alkalinity
temperature
Stimulatory/Inhibitory Effects
Mod. Inhibit.
Strong Inhibit.
Sodium
100 - 200
3500 - 5500
8000
Calcium
100 - 200
2500 - 4500
8000
Magnesium
75 - 100
1000 - 1500
3000
Ammonia
Nitrogen
Concentration
(mg/L)
Effect on
Anaerobic
Treatment
50 200
Beneficial
200 1000
No adverse effect
1500 3000
Inhibitory at
higher pH levels
Above 3000
Toxic
Unbalanced Systems
Indicators:
volatile fatty acids (VFA) conc.: most important or utilized indicator
pH (related to VFA, CO2
CO2 in gas increasing
total gas production decreasing
waste treatment/stabilization decreasing
Factors:
temperature
organic loading (waste strength)
nature of waste