Solutions

1
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AIITS-HCT-VII (Paper-2)-PCM (Sol)-JEE(Advanced)/16
JEE(Advanced)-2016
ANSWERS, HINTS & SOLUTIONS
HALF COURSE TESTVII
(Paper - 2)
Q. No.
PHYSICS
CHEMISTRY
MATHEMATICS
1.
2.
3.
A, C
4.
5.
6.
7.
8.
B, C, D
A, B, C, D
9.
A, C, D
B, C, D
A, B
10.
A, C, D
A, D
A, B, C
11.
B, C
A, C
12.
13.
14.
15.
16.
1.
(A s); (B r); (C
q); (D p)
(A s); (B q); (C
r); (D p)
1.
(A q); (B r); (C
t); (D r)
1
(A p, q, r, t); (B
p, q, t); (C p, q, s,
t); (D p, q)
(A p); (B t); (C
q, r, t); (D p)
4
2.
3.
4.
5.
6.
2.
(A s); (B r); (C
r); (D s)
3
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2
Physics
PART I
Hints & Solution

SECTION A
1.
VP cos = u cos
usin VP sin
ucos sin
t
=
u sin
g
cos
=
2.
u sin( )
gcos
Just before the particle moves to inclined

surface, we resolve its velocity along and
normal to the plane.
ucos
ucos
After impact
Before impact
usin
For the trajectory of the particle to sharply change from the horizontal line to the inclined line, the
impact of the particle with inclined plane should reduce the u sin component of velocity to zero.
Hence the particle moves up the incline with speed u cos .
Hence as increases, the height to which the particle rises shall decrease.
3.
By balancing force along horizontal and vertical direction

N1 sin + N2 sin = (N1 N2) cos
(1)
(N1 N2 ) cos + (N1 + N2 ) sin = W + mg (2)
Balancing torque about centre
(N1 + N2 ) a = b mg
(3)
By solving (1), (2) and (3)
aW
M =
2
(b(1 )sin a)g
2R
4.
F=
m
GM dx
GMm
R
=
x2
2R 2
N2
dx m
R
R
5.
aA = g sin 37
Spring is at its natural length
Hence aB = g sin 37 = 6 m/s2
6.
Total mass melted is 10 gm

Total heat in 100 sec 10 80
800
= 8 Cal/sec.
Heat given to ice/sec
100
T
Rate of Rise of temp = (10)(1)
= 8,
sec .
T
= .8C/sec.
sec.
3
7.
The KE of given section AP and PB will be equal if MI of each section AP and section PB about A is
same.
x
x2
L2
x2
IAP= (x)
IPB= IAB IAP = (x)
(x)
3
3
3
P
B
A
3
3
3
L
x
L x
IAP= IPB
=
3
3
3
3
L
L
or x3 =
or x = 1/ 3
2
2
8.
If S is the distance between them at any time :
S2 = (4 2sin t)2 + (3 2 cos t)2

= 29 (16 sint + 12 cos t)
.... (1)
S will be 3 cm only when
16 sint + 12 cost = 20
4 sint + 3 cost = 5
4
3
sint +
cost = 1 sin (t + 37) = 1
5
5
Now the only solution is t=53 so only once in a time period, it will be 3 cm.
(B) By equation (1), S varies between 3 cm and 7 cm.
(C) Maximum magnitude of force is 2A.
(D) Kinetic energy is not conserved.
9.
% Rise in area will be 0.4%

% Rise in vol will be 0.6%
0.2
1 100 D = [1 + 80] D
0.002
1
=
0.25 10 4 C 1
80
400
10.
Slope of displacement time graph is velocity and rate of change of velocity is acceleration.
11.
That wire will break first whose stress reaches the breaking stress (for that material) first.
F
F
Stress =
where F is the tension in the wire. F is same in both the wires.
A r 2
1
Thus stress 2 for the wire of smaller radius, the stress is more.
r
Thus the wire with smaller radius will break first.
If rA < rB, then wire A will break first.
If rA > rB, then wire B will break first.
If rA = rB, either of them could break.
12.
dl dx i dy j

F dl xy 2 dy
on the path, x = y so F dl y 3 dy
4
y2
W y 4 y1 y 42 y14
4
4
y1 = 0; y2 = 3.00 m
1
So W (2.50)(3)4 50.6 J
4
L
(14-16). Kx 0 A g Mg 2Mg 0
2
L
K(x0 x) A x g Mg 2Mg 3Ma

2
g
amplitude
SECTION C
2.
Mg T = Ma
T mg = ma
2Mmg
T=
(M m)
T
2Mmg
A A(M m)
2mg
2 109
m
A 1
M
M=2
F/ A
b a
,r b
x
dy / dx
L
r = b tan x, A = (b x tan )2
L
L
F
dx
dy
0
Y 0 (b x tan )2
L = 103m = 1mm
3.
Y=
4.

|| = | v (B ) |
i
j
k
= (2i) 0
1
2 4
0 3/5 4/5
5.
In fluid frame ball is moving with constant velocity (terminal) and resultant of all forces acting on it
zero.
(A) Buoyant force
(B) viscous force
(C) mg
2 ( 0 )gr 2 2 900 10
vt

25 10 4 = 50 m/s
9
9
0.1
6.
2Av = 2F
F
A
2
3
3r
v 2
3
v = 30 m/s
5
Chemistry
PART II
SECTION A
2.
Strength of H bond: 2 10 kcal or (8 42 kJ)
3.
It may be possible that few particles of gas A have higher velocities than that of few particles of gas
B.
4.
96 ppm of SO 24 = 100 ppm of CaCO3 so 384 ppm of SO 24 = 400 ppm of CaCO3
5.
6.
LiF is insoluble in water but not because of its covalent character rather its high lattice energy which
is not easily compensated by its hydration energy.
7.
H /H2 O
O3
Zn
H /
OH
(Major)
for all IR region
6
& UV region
5
4
3
2
1
5
4
3
2
1
for Balnmer series
Total lines
for Lyman series
8.
6
5
4
3
2
1
w
w
&d
M
V
9.
All are extension of PV = nRT, n
10.
(B) and (C) are amphoteric.
12.
The carbocation formed will be 3, hence will be more stable.
13.
Compound (D) will form most stable carbocation on protonation.
14.
All other molecules are symmetrical.
15.
It contains only one lone pair so no chances of lp lp repulsion.

In CO2 & CH 4 there are no lone pairs and in XeF2 two lone pair are there so lp lp repulsion is also
present.
16.
Shape of I3 is linear despite of the presence of 3 lone pairs.
6
SECTION C
1.
CH 2
O
2.
CH2
CH2
CH2
In Cu2 S 2 , In FeS2 1 , In Na 2S2O3 2

In Na 2S2O 4 3
OH
3.
OH
OH
OH
OH
CH3
4.
A n
AO3
x n
x 6 1 x 5
number of electron releases in oxidation = (5 n)
equivalent of An+ = 2 (5 n)
equivalent of MnO4 = 0.8 5
2 (5 n) = 0.8 5
n=3
5.
2B
4
at eq. 2 x
2x = 2 so x = 1
4 2x
K eq
6.
CH3
2x x
2
2 x 4 2x
2C
2x
4
1
4
Either 7 1 or 6 1 or 5 1 or 4 1 or 3 1 or 2 1
Only one transition can be obtained at a time as only single atom is given.
7
Mathematics
PART III
SECTION A
1.
It represent 3 different non concurrent lines hence can represent a triangle
2.
3.
Let a, 3 be two number the

A1 + A2 = a + b
p < 0 let p = q, q > 0, so p1/3 = q1/3 (1)1/3

1/3
= q
1/3
=q w
1/3
=q w
x yw zw 2
1
so given expression is
= w2
2
xw yw z w
G1G2
ab
H1H2
G1G2
1
1
1 1
H1 H2 a b
H1 H2 A1 A 2
4.
Mid point of the chord intercepted by hyperbola is same as mid point of the chord intercepted
between asymptotes.
h 1 2 4 k 2 6 2
2
2
2
2
(h, k) (1, 2).
line intersect asymptote at one point only hence it is the centre of hyperbola.
5.
Let y = sin3A + sin3B + sin3C for sin3A to be non positive

2
we have 2 < 3A < 3
<A<
3
since A + B + C = all of sin3A, sin3B, sin3C cant be negative.
Let us take sin3A = 1 A =

sin3A = 1, sin3B = 1 and sin3C = 0 is possible
2
the minimum value is 2.
6.
Sum of 7 digits = a multiple of 9

Sum of number 1, 2, 3, 4, 5, 6, 7, 8, 9 = 45 so two left should also have sum of 9.
The pair of left numbers is (1, 8), (2, 7), (3, 6), (4, 5).
with each pair left number of 7 digit number = 7!
So with all 4 pairs = 4 7! .
7.
If p is a prime such that 100 > p >
200
, then p and 2p but not 3p belong to [1, 2, , 200].
3
While just p belongs to (1, 2, , 100), so p does not divide 200C100 but consider 61 the largest prime <
200
3
61 3 divides 200! but only 61 divides 100!.
200
Hence 61 divides C100.
8
2 2
8.
In the expansion of (a x + 2bx +c)

2
n
the sum of the coefficients = (a + 2b +c)
2
Let f() = a + 2b +c
2
2
Its discriminant = 4b 4ac = 4(b ac ) < 0
Hence, f() < 0 or f() > 0 for all R
If a > 0 then f() > 0 (a2 + 2b + c)n > 0
2
n
If c > 0 i.e. f(0) > 0 f() > 0 (a + 2b + c) > 0
2
n
If a < 0 then f() < 0 (a + 2b + c) < 0 if n is odd
If c < 0 i.e. f(0) < 0 f() < 0 (a2 + 2b + c)n > 0 if n is even.
9.
Roots of x +x +1 = 0 are complex cube roots of unity,

so h(w) = h(w2) =0
2
2
w f(1) + w g(1) = 0 and w f(1) + wg(1) =0
f(1) = g(1) = 0.
10.
11.
abc
b H.M
3
a + c > 2b
a2 c 2
2
2
2
Also
a 2c 2 a + c > 2ac > 2 b ( G.M. > H.M)
2
a2 + c 2 > 2b2 .
Hence y +
12.
2 and |sinx + cosx|
2.
1
= 2 and sinx + cosx =
y
Solving it, we get sin( + ) = sin
2 , which is possible for y = 1, x = /4.
cos2 cos = 0 =
3
,
2 2
5
tan = 1, ,
.
2
4 4
3
3 7
(ii) =
tan = 1, ,
.
2
4 4
(i) =
13.
Let cosA + cosB + k cosC = y

C
C
A B
2k sin2 2cos
sin 2 y k = 0. As D 0
2
2
1
1
A B 1
k(y k) cos2
k.
2 y
2
2
2k
1416. Let the roots of z 3 + az 2 + bz + c = 0 be , , , then

1 1 1
|c| = || = 1 and | + + | =

= | + + | = |a|
|a| = |b| and |c| = 1
also, |a| = | + + | 3
1
k1
2
3
2
3
2
thus z + |a|z + |b|z + |c| = z + (2k + 1)z + (2k + 1)z + 1
put |a| = 2k + 1, where
9
= (z + 1)(z + 2kz + 1).

It
has
roots
and
k k 2 1
since
k2
1,
we
have
k 2 1 i 1 k2
k k 2 1 k 2 1 k 2 1.
so, all the roots have modulus 1.
SECTION B
1 (A).
(B)
y2 = 4x
2
Clearly, if P (at , 2at) then by symmetry,
2
Q (at , 2at)
Equation of tangent is
O
T
ty = x + at2
2
(x1, 0)
for t, y = 0, x1 = at
and equation of normal is
3
y = tx + 2at + at
2
for R, y = 0, x2 = (2a + at )
2
Here, a = 1 x1 = t and x2 (2 + t2)
2
2
x2 = 3 = 2 + t t = 1 t = 1
Take t = 1, then x1 = 1, PM = 2at = 2 1 1 = 2
RT = x1 + x2 = (1 + 3) = 4
1
Area of quadrilateral PTQR = 2 4 2 = 8 sq. units.

2
Length of latus rectum + tangent PT = 4a +

=41+
P(at2, 2at)
R(x2, 0)
Q(at2, 2at)
S1
02 4( 1) 4 2 6 units.
(C)
Clearly, RT will be the diameter of circle

Circumference = ( diameter)
4
= RT =
1.
4
(D)
Since in the part (1), we have found x2 (2a + at ) > 2a,

For three real normals, x2 > 2a = 2 1 = 2
i.e. x2 > 2.
2. (A)
sp =
(if t 0)
p
2A (p 1)d a
2
2a
2A (p 1)d
(1)
p
2b
(2)
2A (q 1)d
q
2c
(3)
2A (r 1)d
r
Multiply (1), (2) and (3) by (q r), (r p) and (p q) and add
a
(q r) 0 .
p
so
10
(B)
Let common ratio be taken as k and a be the first term

r1
R = Tr = ak
st
st
R = a k (r1)(st)
tr
tr (s1)(tr)
Similarly, s = a k
rx
rs (t1)(rs)
T =a k
.
Multiplying the above three and knowing that
AmAnAp = Am+n+p
st tr rs
0 0
R S T = a k = 1.
(C)
x = a + (m 1)d = AR
n1
y = a + (n 1)d = AR
z = a + (p + 1)d = AR p1
y z = (n p)d, z x = (p m)d, x y = (m n)d
m1
yz
zx
xy
= ARm 1
(n p)d
ARn1
(p m)d
ARp1
(mn)d
= A0R0 = 1.
(D)
a = AR p1, b = ARq1, c = ARr1 for G.P.

1
1
1
a=
for H.P.
, b
, c
A1 (p 1)D
A1 (q 1)D
A1 (r 1)D
1 1
(1)
(q r)D
b c
log a = log A + (p 1) log R
= (log A log R) + (log R)
(2)
1 1
b c loga D log A logR q r DlogR p q r 0
c b

loga 0
bc
multiplying by abc
a b c loga 0 .
SECTION C
1.
Let a d, d, a + d be roots then

a d d a d 12
a4
solve
a
b
d
a
28
d 3
2.
|d|=3
2
Let root of x 3x + c = 0 be , and that of x cx + b = 0 is ,

=
4 b2 4c r
c 2 4b so = gives (b + c)(b c) = 4(c b)
(b + c) = 4.
n n 1
c1
c
c
2 2 ... n n
.
c0
c1
cm
2
3.
We know that
6.
For sum of coefficients put x = 1 and so we get ( 1)35 = (1 )35 = 1.

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AIITS-HCT-VII (Paper-2)-PCM (Sol)-JEE(Advanced)/16

Hints & Solution

Just before the particle moves to inclined

By balancing force along horizontal and vertical direction

Total mass melted is 10 gm

If S is the distance between them at any time :

S2 = (4 2sin t)2 + (3 2 cos t)2

% Rise in area will be 0.4%

K(x0 x) A x g Mg 2Mg 3Ma

Strength of H bond: 2 10 kcal or (8 42 kJ)

96 ppm of SO 24 = 100 ppm of CaCO3 so 384 ppm of SO 24 = 400 ppm of CaCO3

for all IR region

for Balnmer series

for Lyman series

All are extension of PV = nRT, n

(B) and (C) are amphoteric.

The carbocation formed will be 3, hence will be more stable.

Compound (D) will form most stable carbocation on protonation.

All other molecules are symmetrical.

It contains only one lone pair so no chances of lp lp repulsion.

Shape of I3 is linear despite of the presence of 3 lone pairs.

In Cu2 S 2 , In FeS2 1 , In Na 2S2O3 2

It represent 3 different non concurrent lines hence can represent a triangle

Let a, 3 be two number the

p < 0 let p = q, q > 0, so p1/3 = q1/3 (1)1/3

Let y = sin3A + sin3B + sin3C for sin3A to be non positive

Let us take sin3A = 1 A =

Sum of 7 digits = a multiple of 9

If p is a prime such that 100 > p >

In the expansion of (a x + 2bx +c)

Roots of x +x +1 = 0 are complex cube roots of unity,

2 and |sinx + cosx|

Solving it, we get sin( + ) = sin

2 , which is possible for y = 1, x = /4.

Let cosA + cosB + k cosC = y

1416. Let the roots of z 3 + az 2 + bz + c = 0 be , , , then

put |a| = 2k + 1, where

= (z + 1)(z + 2kz + 1).

Area of quadrilateral PTQR = 2 4 2 = 8 sq. units.

Length of latus rectum + tangent PT = 4a +

Clearly, RT will be the diameter of circle

Since in the part (1), we have found x2 (2a + at ) > 2a,

Let common ratio be taken as k and a be the first term

a = AR p1, b = ARq1, c = ARr1 for G.P.

Let a d, d, a + d be roots then

Let root of x 3x + c = 0 be , and that of x cx + b = 0 is ,

c 2 4b so = gives (b + c)(b c) = 4(c b)

For sum of coefficients put x = 1 and so we get ( 1)35 = (1 )35 = 1.

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