MATHEMATICS

PAPER : CT-1
TARGET DATE : 10-04-2014
PAPER LEVEL : MODERATE TO TOUGH
SYLLABUS : Fundamentals of Mathematics-I, Quadratic Equation

Paper-1 CT-1
S.No.

Subject

Nature of Questions

No. of Questions Marks Negative

Total

SCQ

10

30

MCQ

20

16 to 20

Integer (double digits)

20

21 to 30

SCQ

10

30

31 to 35

Physics MCQ

20

1 to 10
11 to 15

Maths

36 to 40

Integer (double digits)

20

41 to 50

SCQ

10

30

51 to 55 Chemistry MCQ

20

20

56 to 60

Integer (double digits)

Total

Total

60

210

SCQ
1.

Sol.

2.

Sol.

1
. If b = a3 + a4 + a5 + a6 and
[BALG]
logn 1001
c = a11 + a12 + a13 + a14 + a15. Then value of (b c) is equal to
1
ekuk n, 1 ls cM+h iw.kkZad la[;k gS rFkk ekuk an =
;fn b = a3 + a4 + a5 + a6 vkSj c = a11 + a12 + a13 +
logn 1001
Let n be an integer greater than 1 and let an =

a14 + a15 rc (b c) dk eku cjkcj gS (A) 1001

(B) 1002
(C) 2
an = log1001n
b = log10013 4 5 6 and c = log1001(1112131415)
3 4 5 6

(b c) = log1001

11

12

13

14

15

1
= log1001(1001) = 1

(D*) 1

The number of integral values of 'a' for which both roots of the equation x 2x a = 0 lie between the
2
2
roots of equation x 2x + a 11a + 12 = 0, is
[QELR]
2
2
2
2
'a' ds iw.kkZad ekuksa dh la[;k ftlds fy, lehdj.k x 2x a = 0 ds nksuksa ewy lehdj.k x 2x + a 11a + 12 = 0 es
ewyksa ds e/; fLFkr gS (A) 0
(B) 1
(C*) 2
(D) 3
2
2
Let be the root of x 2x a = 0
ekuk lehdj.k x2 2x a2 = 0 ds ewy gS
2
2
2 = a
2
2
2
2
and roots of x 2x a = 0 lie between roots of x 2x + a 11a + 12 = 0
2
2
2
2
rFkk x 2x a = 0 ds ewy lehdj.k x 2x + a 11a + 12 = 0 ds ewyks ds e/; fLFkr gS
2
2
2
2
2 + a 11a + 12 < 0
2 = a
2
2
a + a 11a + 12 < 0
2
2a 11a + 12 < 0
(2a 3)(a 4) < 0
3
a , 4
2
number of integral values of 'a' is = 2
'a' ds iw.kkZad ekuksa dh la[;k = 2 gS

-1

Sol.

If x = 2 + 3i, then value of x x + 10x + 3x 5 is equal to

;fn x = 2 + 3i rc x4 x3 + 10x2 + 3x 5 dk eku cjkcj gS (A) 127
(B) 122
(C) 120
x = 2 + 3i
2
2
(x 2) = 9 x 4x + 13 = 0
4
3
2
2
2
x x + 10x + 3x 5 = (x 4x + 13)(x + 3x + 9) 122
= 122

4.

The complete solution set of inequation

3.

(ex 2)(x 2 5x 4)

0 dk
(x 2 5x 6)
(A) (, 1] [n 2,2) (3, 4]
(C*) (,n 2] [1, 2) (3, 4]

vlfedk

Sol.

(e x 2)(x 2 5x 4)
(x 2 5x 6)

[BAGQ]
(D*) 122

0, is

[BAIR]

lEiw.kZ gy leqPp; gS&

(B) (,n 2] (1, 2) (3, 4]
(D) [n 2, 1] (2, 3) [4, )

(e x 2)(x 1)(x 4)
0
(x 2)(x 3)

x (,n 2] [1, 2) (3, 4]

5.

1
1

Product of the roots of the equation 2 x 2 2 9 x + 14 = 0, is

x
x

lehdj.k 2 x 2
Sol.

1
1

9 x + 14 = 0 ds
2
x
x

(A) 5
(B) 2
Given equation become nh xbZ lehdj.k
4
3
2
2x 9x + 14x 9x + 2 = 0
product of roots ewyksa dk xq.kuQy = 1
Alter
1
Let ekuk x +
=t
x

ewyksa dk xq.kuQy gS (C) 10

(D*) 1

2 t 2 2 9t + 14 = 0 2t 9t + 10 = 0
2

t = 2,
1
= 2 or
x

5
2

1
5
=
x
2
1
x = 1, x = 1 or x = 2,
2
product of roots = 1
ewyksa dk xq.kuQy = 1
x+

6.

The number of integral values of x satisfying 4 x 3.2x

2

4 x 3.2x
(A) 5
Sol.

x+

4x 1

4 x 3.2x

x
2

[QEMS]

(C*) 4

(D) 2

4 x 1 0

22x 2 0

2x

22x 4.2x

4x 1 is

4 x 1

22x 3.2x

dks larq"V djus okys x ds iw.kkZad ekuksa dh la[;k gS (B) 3

4 x 3.2x

22x 2 0

2x (2 x 4.2x ) 2 x (2 x 2x 2 ) 0
2

-2

(2x 4.2x )(2x 2x ) 0

(2x 4.2x ) 0

2x 4.2x
2
2
x x + 2 x x 2 0
(x 2)(x + 1) 0 x [1, 2] 4 integers
7.

Sol.

iw.kkd

Complete set of real values of k for which kx x + 9 x < 0 x R is

[QEGR]
(A) (0, )
(B) k (, )
(C) k (, 1]
(D*) no such real k exists
2
k ds okLrfod ekuksa dk lEiw.kZ leqPp; ftlds fy, kx x + 9 x < 0 x R gS (A) (0, )
(B) k (, )
(C) k (, 1]
(D*) k dk dksbZ okLrfod eku fo|eku ugh
Roots are real as product of roots negative
2

ewy okLrfod gS rFkk ewyksa dk xq.ku_.kkRed gSA

Alter
2
x + x(k 1) + 9 < 0
D<0
2
(k 1) 4 (1)(+9) < 0
2
(k 1) + 36 < 0
No real k exists
k dk dksbZ okLrfod eku fo|eku
8.

Sol.

ugha
2

If the equation (a + a 30)x + (b 1)(a 2a 15)x + (b 6b + 5) = 0 has more than two different
solutions for x, then number of possible ordered pairs (a, b) is
[QEGR]
2
2
2
2
;fn lehdj.k (a + a 30)x + (b 1)(a 2a 15)x + (b 6b + 5) = 0 ds x ds fy, nks ls vf/kd gy j[krs
rc (a, b) ds laHkkfor fer ;qXeksa dh la[;k gS (A) 1
(B) 2
(C*) 3
(D) 4
for more than two different solution, the equation must be an identity and for that

gS

nks ls vf/kd gy ds fy, lehdj.k ,d loZlfedk gksxh

2
2
2
a + a 30 = 0 and vkSj (b 1)(a 2a 15) = 0 and vkSj (b 6b + 5) = 0
a = 6, a = 5 and vkSj b = 1, a = 5, a = 3 and vkSj b = 1, b = 5
possible ordered pairs (a, b) are
lefor fer ;qXe (a, b) gS
(5, 1), (5, 5), (6, 1)
three possible ordered pairs (a, b) are there.
rhu laHkkfor fer ;qXe (a, b) gS
9.

If , , are the roots of the equation 2x 7x + 3x 1 = 0, then the value of (1 )(1 )(1 ) is
;fn lehdj.k 2x3 7x2 + 3x 1 = 0 ds ewy , , gS rks (1 2)(1 2)(1 2) dk eku gS [QETE]
39
39
(A) 39
(B) 39
(C)
(D*)
4
4

Sol.

2x 7x + 3x 1 = 0

b
g

2x 7x + 3x 1= 2(x )(x )(x ) ..(i)

(i) put x = 1 j[kus ij, we get
2(1 )(1 )(1 ) = 3 .(ii)
(ii) put x = 1 in (1) esa j[kus ij, we get
2(1 )(1 )(1 ) = 13 2(1 + )(1 + )(1 + ) = 13 (iii)
multiply (2) and (3), we get
2
2
2
4(1 )(1 )(1 ) = 39
3

10.

The complete solution set of the inequation

1
log1/ 2 | x |

> 1 is

[BAMS]

-3

vlfedk

1
> 1 dk
log1/ 2 | x |

lEiw.kZ gy leqPp; gS -

1
(A) 2, , 1 (1, 2)
2

Sol.

1
(B) 2, , 2
2

1
(C*) (2, 1) 1, , 1 (1, 2)
2

2
1
>1
log1/ 2 | x |

(D)

log1/ 2 | x | < 1 but ijUrq log1/2|x| 0

1 < log1/2|x| < 1 but ijUrq |x| 1 x 1, 1
1
2 > |x| >
2
1

< |x| < 2

2

1
x (2, 1) 1, , 1 (1, 2)
2

MCQ
11.

If range of expression

x 2 12
(x R) is (, a] [b, ) and let the solution of the equation
2x 7

a.x loga b bloga x b3 is x = c, then

[QEGR]
(A) (a + b) and c are both prime
(B*) (a + b) and c are coprime number
(C*) (a + b + c) is a perfect square
(D) a + b = c
x 2 12
;fn O;atd
(x R) dk ifjlj (, a] [b, ) gS rFkk lehdj.k a.x loga b bloga x b 3 dk gy x = c gS
2x 7
(A) (a + b) vkSj c nksuksa vHkkT; gSA
(B*) (a + b) rFkk c lgvHkkT; la[;k gSA
(C*) (a + b + c) ,d iw.kZ oxZ gSA
(D) a + b = c
Sol.

Let ekuk y =

rc -

x 2 12
2
x 2xy + 7y 12 = 0
2x 7

D0
2
4y 4 1 (7y 12) 0
2
y 7y + 12 0
y (, 3] [4, )
a = 3 and vkSj b = 4

equation becomes 3.x log3 4 4log3 x 64

lehdj.k 3.xlog 4 4log x 64 ls

3

3(4
4

log3 x

log3 x

)4

log3 x

64

16 log3 x = 2

x=9=c
12.

26
a
such that a > b, then the value of
is
5
b
(B*) a rational number
[BALG]
(D) a prime number
a
gy bl izdkj gS fd a > b rc
dk eku gS
b

Let a and b are the solutions of the equation 51log4 x 5 1log1/ 4 x

(A*) an even number
(C*) a composite number

ekuk a vkSj b lehdj.k 51 log x 51log

4

1/ 4

26
5

ds

-4

(A*) le la[;k
(C*) la;qDr la[;k
Sol.

5.5log4 x 5 1.5 log4 x

(B*) ifjes; la[;k

(D) vHkkT; la[;k
26
5

Let ekuk 5log4 x = t

1
26
2
5t +
=
25t 26t + 1 = 0
5t
5
1
t = 1 or t =
25
log4x = 0 or ;k log4x = 2
1
x = 1 or ;k x =
16
a

= 16
b
13.

Sol.

If ax + bx + c = 0 has imaginary roots and a,b,c R, then which of the following options are CORRECT?
;fn ax2 + bx + c = 0 ds dkYifud ewy gS rFkk a,b,c R, rc fuEu esa ls dkSuls fodYi lgh gS ?
[QEGR]
2
(A) ax + bx + c > 0 x R
(B*) a(a b + c) > 0
2
2
2
2
(C*) a(ax + bx + c) > 0 x R
(D*) a + c + 2ac > b
D<0
2
(ax + bx + c) will be of same sign as that of 'a'
2
(ax + bx + c) 'a' ds leku fpUg dk gksxk
C is correct lgh gS
2
(B) Let ekuk f(x) = ax + bx + c
D<0
Two graphs are possible nks vkj[ks laHko gS
2

a > 0 and rFkk f(1) > 0 a b + c > 0

a(a b + c) > 0
1

a < 0 and rFkk f(1) < 0 a b + c < 0

a(a b + c) > 0
(D)

14.

a + c + 2ac b > 0
2
2
(a + c) b > 0
(a b + c)(a + b + c) > 0
f(1) f(1) > 0 true lR; see the above two graphs
The value of

nks vkjs[k mij fn[kk;s vuqlkj

6anb loga2 b logb2 a

is
e( na )( nb )
(A*) independent of a (B*) independent of b
6a nb loga2 b logb2 a
dk eku gS e( na )( nb)
(A*) a ls Lora=k
(B*) b ls Lora=k

[BALG]
(C) dependent on a

(D) dependent of b

(C) a ij

(D) b ij

fuHkZj

fuHkZj

-5

Sol.
15.

Sol.

6a nb loga2 b logb2 a
ena nb

1
1
6.a nb . loga b. logb a
6 3
2
2
=
= =
nb
4 2
a

Identify which of the following statement(s) are 'CORRECT' ?

[QEGR]
c
2
(A*) For ax + bx + c = 0, (a 0) if 4a + 2b + c = 0, then roots are 2 and
.
2a
2
2
2
(B) If is repeated root of ax + bx + c = 0, (a 0) then ax + bx + c = (x ) .
2
(C*) For ax + bx + c = 0, (a 0, a,b,c Q) imaginary roots occur in conjugate pair only.
2
(D*) If f(x) = ax + bx + c, (a 0) has finite maximum value and both roots of f(x) = 0 are of opposite sign,
then f(0) > 0.
fuEu esa ls dkSulk dFku lgh gS ?
c
2
(A*) ax + bx + c = 0, (a 0) ds fy, ;fn 4a + 2b + c = 0 rc ewy 2 vkSj
gSA
2a
2
(B) ;fn , ax + bx + c = 0, (a 0) dk iqujko`
fk ewy gS] rc ax2 + bx + c = (x )2.
2
(C*) ax + bx + c = 0, (a 0, a,b,c Q) ds fy, dkYifud ewy dsoy la;qXeh gksrs gSA
2
(D*) ;fn f(x) = ax + bx + c, (a 0) fu;r vf/kdre eku j[krk gS rFkk f(x) = 0 ds nksuksa ewy foijhr fpUg ds fpUg
rc f(0) > 0.
2
(A) 4a + 2b + c = 0 ax + bx + c = 0 has one root as 2
c
other root will be
2a
2
2
(B) ax + bx + c = a(x )
(C) coefficients are rational coefficients are real.
imaginary roots occur in conjugate pair
(D)

f(0) > 0

Integer Type
16.

If x R then absolute difference between the maximum and minimum values of the expression
x 2 14x 9
is
[QEGR]
x 2 2x 3
x 2 14x 9
;fn x R rc O;atd 2
ds vf/kdre vkSj U;wure ekuksa dk fujis{k vUrj gS&
x 2x 3

Ans. 09
Sol.

x 2 14x 9
x 2 2x 3
2
x (y 1)+ 2x(y 7) + 3(y 3) = 0 .(i)
Case-1 : If y = 1, then equation (i) becomes
1
12x 6 = 0 x =
which is real tks fd okLrfod
2
y = 1 is possible laHko gSA
Case-2 : If y 1, then D 0
2
4(y 7) 4(y 1).3(y 3) 0
2
2
y 14y + 49 3(y 4y + 3) 0
2
2y 2y + 40 0
2

y + y 20 0

5 y 4

Absolute difference = 9
fujis{k vUrj = 9
Let ekuk y =

gSA

-6

gS]

17.

If a,b R, then the smallest natural number 'b' for which the equation x + 2(a + b)x + (a b + 8) = 0 has
unequal real roots for all a R, is
[QENR]
;fn a,b R, rc U;wure izkd`
r la[;k 'b' ftlds fy, lehdj.k x2 + 2(a + b)x + (a b + 8) = 0 ds lHkh a R ds
2

fy, vleku okLrfod ewy gS&

Ans.
Sol.

18.

05
2
D = 4(a + b) 4 1 (a b + 8)
2
2
= 4[a + 2ab + b a + b 8]
2
2
= 4[a + a(2b 1) + (b + b 8)]
for unequal real root for all a R
lHkh a R ds fy, lHkh vleku okLrfod
D>0 aR
2
2
(2b 1) 4 1 (b + b 8) < 0
2
2
4b 4b + 1 4b 4b + 32 < 0
8b + 33 < 0
8b > 33
33
b>
8
smallest natural value of b is = 5
b dk U;wure izkd`
r eku = 5

ewy gS

Let the product of all the solutions of the equation

(log3 3 3x logx 3 3x )log3 x3 = 2 be k, then find the

value of 18k.

ekuk lehdj.k

[BALG]
(log3 3x logx 3x )log3 x
3

=2

ds lHkh gyksa dk xq.kuQy k gS rc 18k dk eku Kkr dhft,

Ans. 02
Sol.
squaring we get

oxZ djus ij

log3 (3x)1/ 3
1/ 3
log3 (3x)
3log3x = 4
log3 x

Let ekuk log3x = t

1 (t 1)(t 1)

.3t = 4
3
t
t + 1 = 2
1
x = 3 or x =
27
product of roots

xq.kuQy ds ewy =

1
=k
9

18k = 2
19.

If a, b and c are real numbers such that a2 + 2b = 7, b2 + 4c = 7 and c2 + 6a = 14, then find the value of
a 2 b2 c 2
.
2

[BAMS]

;fn a, b vkSj c okLrfod la[;k bl izdkj gS fd a2 + 2b = 7, b2 + 4c = 7 vkSj c2 + 6a = 14 gS] rks

dk eku Kkr dhft,A
Ans. 07
Sol.
a2 + b2 + c2 + 6a + 4c + 2b = 14
(a + 3) 2 + (b + 1)2 + (c + 2)2 = 0
a = 3, b = 1 and vkSj c = 2
so

blfy,

a 2 b2 c 2
9 1 4
=
=7
2
2

-7

a2 b 2 c 2
2

20.

Find the number of integral values of 'm' less than 50, so that the roots of the quadratic equation
2
mx + (2m 1)x + (m 2) = 0 are rational.
[BAMS]
2
50 ls NksVs m ds iw.kkd ekuksa dh la[;k Kkr dhft, tcfd f}?kkr lehdj.k mx + (2m 1)x + (m 2) = 0 ds ewy

ifjes; gSA
Ans.06
Sol.
D = 4m + 1
now for roots to be rational must be perfect square of a rational number
but since m is an integer it will be perfect square of an integer.
2
so let blfy, ekuk 4m + 1 = k , k
k2 1
for m to be an integer k must be odd
4
k = 1, 3, 5, 7, 9, 11, 13
but ijUrq m 0 There are 6 possible integral values of m.
m=

-8

JEE ADVANCED (CT 1)

Date : - 10/8/2014

Test Syllabus : Mathematical Tools, Rectilinear Motion, Projectile Motion & Relative Motion complete

Paper-1 CT-1
S.No.

Subject

Nature of Questions

1 to 10

No. of Questions Marks Negative

Total

SCQ

10

30

MCQ

20

16 to 20

Integer (double digits)

20

21 to 30

SCQ

10

30

MCQ

20

36 to 40

Integer (double digits)

20

41 to 50

SCQ

10

30

51 to 55

Chemistry MCQ

20

20

Maths

11 to 15

Physics

31 to 35

56 to 60

Integer (double digits)

Total

Total

60

210

PAPER-1
SECTION-1 : (Only One option correct type)
[k.M1 : (ds
oy ,d lghfodYi dkj)
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct.
bl [k.M es
a10 cgq
fodYi 'u gS
A R;s
d 'u es
apkj fodYi (A), (B), (C) vkS
j (D) gS
] ftues
alsds
oy ,d

lghgS
A

SCQ_(10)
21.

If the tangent on the curve y

then the value of k is

;fn o y
eku gksxkA

Soln.

(A*)

1
2

(A)

dy
dx

kx 2 (;gkW k

(A) cos
Soln.

(C)

B rFkk R
1

A
R

(C) 2

2k(1) = 1

It is given that A R

A R

1
4

(D) 4

tan 45o

At x = 1 ij

22.

,d fu;rkad gS) ij x = 1 ij [khaph xbZ Li'kZ js[kk +x v{k ls 45 dks.k cukrh gks rks k dk
(B)

2k x

kx 2 (where k is a constant) at x = 1makes an angle 45o with +x-axis,

B and R

1
2

A . Then the angle between A & B is

A fn;k gqvk gS] rks A & B ds e/; dks.k gksxkA

(B) cos

B
A

(C*) tan

R
A

(D) sin

R
A

tan =

R
A

= tan1
23.

R
A

i 2 j k and A B

If there are two vectors A and B such that A B

, then the angle between

(i k)

A and B is .

gS, rks A rFkk B ds e/; dks.k

;fn nks lfn'k A rFkk B bl izdkj gS fd A B i 2j k rFkk A B ( i k)
gksxk
(A) 30 o
Soln.

(B) 45o

(C) After solving

(C*) 60 o

(D) 120 o

gy djus ij :-

2A = 2i+ 2j
2B = 2j+ 2k

i j , B

A.B
AB

cos

24.

j k

1
2

cos

60o

A particle moves in a straight line. Its speed (v) increases linearly with time. If the initial speed of the
4

particle is vo and its speed at t = 4 sec is 4vo, then

vdt is equal to
0

,d d.k ljy js[kk ij xfr'khy gSA bldh pky (v) le; ds lkFk js[kh; :i ls c<+rh gSA ;fn d.k dh izkjfEHkd
pky vo rFkk t = 4 lSd.M ij pky 4vo gks rks
(A) 4 v o
Soln.

(B) 6 v o

4
0

vdt dk eku gksxkA

(C) 8 v o

(D*) 10 v o

(D) acceleration Roj.k = a

4v0 = v0 + a (4)
a=

3v 0
4

vdt
0

v0 3v0 t dt
0

Vdt

Vo ( 4)

1 3Vo
( 4 )2
2 4

= 10 v o
25.

A ball is thrown vertically upwards. The velocity at one fourth of the maximum height is 10 3 m/s. then
the velocity with which the ball was thrown is .

,d xsan /okZ/kj ij dh rjQ iz{ksfir dh tkrh gSA vf/kdre~ WpkbZ dh ,d pkSFkkbZ WpkbZ ij bldk osx
10 3 m/s gks rks xsan dk iz{ksi.k osx gksxkA
(A) 5 m/s
Soln.

(B) 10 m/s

(C) 15 m/s

(D*) 20 m/s

(D) Let u be velocity of throwing and h be maximum height.

ekuk u iz{ksi.k osx rFkk h vf/kdre~ WpkbZ gSA

u2
2g

Then rc h

V2

u2

2as

10 3 m/s
h
h
4

u
2

u2

(10 3 )

26.

h
4

2
2g. u
2g(4)

u2

300

u2

2( g)

400

20m/s .

A particle is moving on a curve given by y = 2 sin2x( x& y are in meters). The x-component of velocity is
always 2 m/s. If the particle starts from origin at t = 0, then displacement (in meters) of the particle from
t = o to t

sec is

,d d.k o y = 2 sin2x( x rFkk y ehVj esa gSA) ij xfr'khy gSA osx dk x ?kVd ges'kk 2 m/s jgrk gSA ;fn t = 0
ij d.k ewy fcUnq ls xfr izkjEHk djrk gks rks t = o ls t
(A*)
Soln.

(A) x
y

(B)

V xt

2 sin( 2

2
)

2 m

lSd.M rd d.k dk foLFkkiu (ehVj esa) gksxkA

(C) 0 m

(D)

2
0

Displacement foLFkkiu =
27.

A particle is moving along a straight line with uniform acceleration

m/s. then distance travelled by it in 3rd second of motion is

5 m / s 2 and initial velocity 12.5

,d d.k lh/kh js[kk ij le:i Roj.k 5 m / s 2 rFkk izkjfEHkd osx 12.5 m/s ds }kjk xfr'khy gSA 3rd (rhljs)
lSd.M esa xfr ds nkSjku blds }kjk r; dh xbZ nwjh Kkr djksA
(A) 1 m

(B) 0

(C*) 1.25 m

(D) 2 m

Soln.

(C)

V = u + at = 0
0

12.5 5 t

t = 2 sec

2.5 m/s

t = 2.5 sec
V=0

t = 3 sec
2 .5 sec (i-e particle turns back)

t 2.5 sec (vFkkZr~ d.k okil

Distance travelled in 3rd sec
3rd lSd.M esa r; nwjh

28.

2.5 10
2

ykSVsxkA)

1
= 1.25 m
2

A particle is projected with speed u m/s from origin O along y-axis as shown in figure. If the acceleration
where a is constant, then the equation of trajectory of the particle is
of the particle is (a
i aj)

fp=kkuqlkj ,d d.k dks ewy fcUnq O ls y v{k ds vuqfn'k pky u m/s ds }kjk iz{ksfir fd;k tkrk gSA ;fn d.k dk
(tgkW a fu;r gS) gks rks d.k ds iFk dk lehdj.k gksxkA
Roj.k (a i aj)
Y

(A) y

Soln.

(B)

(B*) (y

x)2

2xu2
a

(C) (x

y)2

2yu2
a

(D) x 2

y2

2xu2
a

1 2
at .. (i)
2

1 2
at .. (ii)
2

ut

y x
, putting in equation (i)
u

y x
, lehdj.k (i) esa j[kus ij
u
(y

29.

1 ax 2
2 u2

x)2

2xu2
a

Two particles are projected simultaneously with the same speed u m/s in the same vertical plane with
angles of projection 30 and 60 . At what time (after start) their velocities will become parallel ?

nks d.kksa dks leku /okZ/kj ry esa ,d lkFk leku pky u m/s }kjk e'k% 30 rFkk 60 ds iz{ksi.k dks.k ij iz{ksfir
fd;k tkrk gSA iz{ksi.k ds fdrus le; i'pkr~ buds osx ,d&nwljs ds lekUrj gks tk;sxsa ?
(A*)

u
3 1 g

sec

(B)

u
3 1 g

sec

(C)

u
3g

sec

(D)

3u
sec
2g

Soln.

(A)

u sin 30o

u sin 60o

gt
o

gt
o

u cos 30

u cos 60

3 1 g

30.

A particle is thrown vertically upwards with initial speed u m/s (with respect to lift) inside a lift moving
downwards with constant velocity. Its time of flight is T sec. Again the particle is thrown vertically
upwards with same initial speed u m/s. (with respect to lift) inside a lift moving upwards with constant
acceleration g/2, then new time of flight is

uhps dh rjQ fu;r osx ls xfr'khy fyV ds vUnj ,d d.k dks fyV ds lkis{k /okZ/kj ij dh rjQ izkjfEHkd
pky u m/s ls iz{ksfir fd;k tkrk gSA bl le; bldk mMM~;u dky T lSd.M gSA vc nwckjk ij dh rjQ fu;r
Roj.k g/2 ls xfr'khy fyV ds vUnj d.k dks fyV ds lkis{k /okZ/kj ij dh rjQ leku izkjfEHkd pky u m/s
ls iz{ksfir fd;k tk;s rks bl d.k dk u;k mM~M;u dky gksxkA
(A)
Soln.

T
sec
2

(D) T

T'

(B) 2T sec

(C)

3T
sec
2

(D*)

2T
sec
3

2u
g

2u
g g/ 2

2 2u
3 g

2T
3

SECTION-2 : (One or more option correct type)

[k.M2 : (,d ;kvf/kd lghfodYi dkj)
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct.

bl [k.M es
a5 cgq
fodYi 'u gS
A R;s
d 'u es
apkj fodYi (A), (B), (C) vkS
j (D) gS
] ftues
alsds
oy ,d ;k
vf/kd lghgS
A

MCQ._(5)
31.

A particle is projected at an angle with the horizontal from a point O on a plane which is inclined at an
angle to the horizontal. The particle is moving horizontally when it strikes the plane at a point A.

,d d.k dks fcUnq O ls {kSfrt ls dks.k ij urry ij iz{ksfir fd;k tkrk gSA urry dk {kSfrt ls urdks.k
;fn urry dh fcUnq A ij d.k ds Vdjkrs le; ;g {kSfrt fn'kk esa xfr'khy gks rks
A
u

Fixed

gSA

(A) Time of flight T

2u sin
g

sec

mMM~;u dky T

2u sin
g

lSd.M gSA

(B*) Maximum height of the particle

u 2 sin 2
2g

d.k dh vf/kdre~~ WpkbZ

u2 sin cos
g

ehVj gSA

(B, C, D)
T

u sin
g

Hmax

2u sin (
g cos

tan

= 2 tan

tan 1 ( 2 tan )

u2 sin 2
2g

OB (u cos ) (T) =

32.

tan 1 ( 2 tan )

(D*)
Soln.

ehVj gSA

u2 sin cos
g

(C*) Horizontal range OB =

{kSfrt ijkl OB =

u 2 sin 2
2g

u2 sin cos
g

t
i (sin t) j t 2k where t is time. Then which of the following is (are)

The vectors A is given by A

correct ?

lfn'k A fuEu }kjk fn;k tkrk gSA

A

ti (sin t) j t 2k

(A*) A (at t

dA
(at t
dt

(C*) A

(A) A (t

(C) A

1)

1 ij )

dA
(t
dt

tgkW t le; gS] rks fuEu ls dkSuls fodYi lgh gS ?

1)

(B*)

1 ij )

(D*) A

(B)

dA
(at t
dt
dA
(at t
dt

dA
(t
dt

(D) A

1)

dA
(t
dt

1)

1 ij )

1 ij )

j 2k

j 2k

Soln.

(A, B, C, D)
t
i sin t j t 2 k

1)
i sin t j k

A(t

dA
dt

dA
(t
dt
dA
dt

dA
dt

33.

dA
dt

(i

1)

A.

cos t j 2 t k
j 2 k)

(i
(i k)

1 2

j ) 2 k)

i j

k)

A car is travelling north along a straight road at 50 km hr 1 . An instrument in the car indicates that the
wind is directed towards east. If cars speed is 80 km hr1, then instrument indicates that the wind is
directed towards south east. Then angle made by winds direction is given by.

[RL - TD]

,d dkj lh/kh lM+d ij mkj fn'kk ds vuqfn'k 50 km hr 1 dh pky ls xfr'khy gSA dkj esa yxk gqvk ;a=k iznf'kZr
djrk gS fd gok iwoZ fn'kk dh rjQ izokfgr gSA ;fn dkj dh pky 80 km hr1 gks rks ;a=k gok dh fn'kk nf{k.k&iwoZ
dh rjQ iznf'kZr djrk gS rks gok dh fn'kk }kjk cuk;k x;k dks.k gksxkA
(A)

tan

(C)

tan

(A)

tan

(C)

tan

3
Nof E
5

(B*)

1
Nof W
2

(D)

3
5

iwoZ ls mkj dh rjQ

(B*)

tan

1
2

if'pe ls mkj dh rjQ

(D)

= tan1(5)

Sol. (B)
VWG = Vx
i Vy j
VWC1 is towards east
VWC1

iwoZ dh rjQ
Vy
Vx
50

Vy = 50 m/s ; Vx > 0
VWC2 is towards south-east

tan

5
Nof E
3

= tan1(5) N of E
1

5
3

iwoZ ls mkj dh rjQ

iwoZ ls mkj dh rjQ

nf{k.k iwoZ dh rjQ

VWC2

Vy
Vx
45

80
Vx = 30 m/s

50

30
tan
34.

5
Nof E
3

A particle moving in a straight line with constant acceleration has speeds 7 m/s and 17 m/s at A
and B points respectively. If M is the mid-point of AB, then which of the following is (are) correct?

ljy js[kk ij fu;r Roj.k ls xfr'khy d.k dh fcUnq A rFkk B ij pky e'k% 7 m/s rFkk 17 m/s gSA ;fn AB js[kk
dk e/; fcUnq M gks rks fuEu es ls dkSulk@dkSuls fodYi lgh gSA
(A*) the speed of particle at M is 13 m/s
M

ij d.k dh pky 13 m/s gSA

(B*) the average speed between A and M is 10 m/s

A

rFkk M ds e/; vkSlr pky 10 m/s gSA

(C) the average speed between M and B is 14 m/s

M

rFkk B ds e/; vkSlr pky 14 m/s gSA

(D*) the ratio of the time to go from A to M and that from M to B is 3 : 2.

A
Soln:

ls M rd rFkk M ls B rd tkus esa fy;s x;s le; dk vuqikr 3 : 2 gSA.

(A,B,D)
V=7

VM2
17
VM

35.

7
2

2 ax

.......(i)

VM2 2ax

.......(ii)

V=17
B

13 m / s

Vavg AM

7 13
2

Vavg MB

13 17
2

13

17

13

10 m / s
15 m / s

a t1
at 2

A man swims at a speed V1

t1 : t 2

3:2

3
i 6 j km / hr relative to water. If the water flows with a speed

V2 5
i km / hr . If the width of the river is d
(A*) path of man is straight line.

500m j .Then
(B*) time of crossing the river is 5 min.

(C) velocity of man is 10 m/s.

(D) drift of man in the direction of flow is 600 m.

,d O;fDr ikuh ds lkis{k pky V1

3
i 6 j km / hr ls rSj ldrk gSA ;fn ikuh V2

gSA ;fn unh dh pkSM+kbZ d 500m j gks rks

(A*) O;fDr dk iFk ljy js[kh; gSA
(C)
Soln:

O;fDr dk osx 10 m/s gSA

(B*)

5
i km / hr pky ls izokfgr

unh dks ikj djus esa yxk le; 5 min gSA

(D) izokg

dh fn'kk esa O;fDr dk foLFkkiu 600 m gSA

(A, B)
Resultant path of man is straight line.

O;fDr dk ifj.kkeh iFk ljy js[kh; gSA

VM

VMR

VM

10 km / hr

VR

500 60
6 1000

Drift fopyu

8
i 6 j km / hr
25
m/ s
9
5 min
5
1000
60

2000
m.
3

SECTION-3 : (Integer value correct Type)

[k.M 3 : (iw
.kk
d eku lghdkj)
This section contains 5 questions. The answer to each question is a Two digit integer, ranging from
00 to 99 (both inclusive).

bl [k.M esa 5 'u gSaA R;sd 'u dk mkj 00 ls 99 rd nksuksa 'kkfey ds chp dk nksva
d ks
aokykiw
.kk
d gSA

Integer_(5)_(Double Digit)
36.

A ball is projected with speed 10 m/s from ground at angle 300 with the vertical. After some time it
again fall on the ground, then the magnitude of average velocity of the ball in this interval (in m/s) is
,d xsan dks tehu ls 10 m/s dh pky ls /okZ/kj ls 30 dks.k ij iz{ksfir fd;k tkrk gSA dqN le; i'pkr~ ;g
okil tehu ij fxjrh gS] rks bl le;kUrjky esa xsan dk vkSlr osx dk ifjek.k (m/s esa) Kkr dhft,A
Ans. 05
Soln : (5)

Vavg
37.

ucos

10cos 60o

5m / s

If a, b, c are three vectors having magnitudes 1, 2, 3 respectively such that a

a .b

b.c

Kkr dhft, :
Ans. 07
Soln : (7)

a2

b2

0 then value of

c . a is :

;fn a, b, c rhu lfn'kksa dk ifjek.k e'k% 1, 2, 3 bl izdkj gS fd

c2

2 a.b b. c c . a

a .b b . c

c .a

a2

b2
2

0
c2

0 gks

rks a . b b . c c . a dk eku

a .b b . c

38.

a2

c .a

b2
2

c2

1 4 9
2

A particle moves along the curve y 2

2 x where x

the magnitude of the acceleration of the particle at t

,d d.k o
t
Ans.

01

Soln:

(1)

2 x ds

y2

t2
2

vuqfn'k xfr'khy gS ;gk x

t2
(x & y are in meters), (t is time in sec). Then
2
2 sec (in m/s2) is

gSA (x o y ehVj esa gS), (t le; lsd.M esa gS) A rks le;

2 sec ij d.k ds Roj.k dk ifjek.k (m/s2 esa) Kkr dhft,A

t2
2

Vx

dx
dt

y2

2x

ax
y2

1
t2

Vy

ay

1 m /s 2

ax

39.

The velocity of a particle is given by V = (2 + 3x) m/s(x is position in meters). Then the acceleration of
2
m is (in m/s2).
the particle at x
3
2
m ij d.k dk Roj.k (m/s2
,d d.k dk osx V = (2 + 3x) m/s (fLFkfr x ehVj esa gS) }kjk fn;k tkrk gSA rks x
3
esa) Kkr dhft,A
Ans. 12
Soln : (12)

dv
dx

a at x

40.

6 9x
12 m / s 2

23

The velocity vector of a particle moving in xy plane is given by V t

i x j where t is time and x is
position. If initially the particle was at origin, and equation of trajectory (path) of the particle is
ax 3 by 2 , then the value of (a + b) is

ry esa xfr'khy d.k dk osx lfn'k V t i x j }kjk fn;k tkrk gS ;gk t le; rFkk x fLFkfr gSA ;fn izkjEHk
esa d.k ewy fcUnq ij gks rFkk d.k ds iFk dh lehdj.k ax 3 by 2 }kjk nh tk;s rks (a + b) dk eku Kkr dhft,A
xy
Ans.
Soln:

11
(11)
At t = 0, x = 0, y = 0 ij

t
i x j

dx
dt

dy
dt

t2
2

t2
2

t3
6

Eliminating t dks
2x 3

izfrLFkkfir djus ij

9 y 2 (i-e. equation of path

iFk dh lehdj.k)

a = 2, b = 9

11

Course : (ELPD )
Test Type : CT-1
Paper-1
Paper-2

Test Date : 10.08.2014

Time Duration : 3 Hrs.
Time Duration : 3 Hrs.
Paper Level - Moderate to Tough

SYLLABUS :
Introduction to chemistry , Atomic structure
( Upto Heisenberg uncertainity principle)

SYLLABUS SCHEDULED
SR.
NO.

TOPIC NAME

SYLLABUS
SCHEDULED
WEIGHTAGE
(BY FC)
(I)
(II)

WEIGHTAGE IN
PAPER-1
(BY FACULTY)

WEIGHTAGE IN
PAPER-2
(BY FACULTY)

1.

2.

Introduction to chemistry

30%

30%

Atomic structure
( Upto Heisenberg
uncertainity principle)

70%

70%

Organic chemistry

SYLLABUS :

IUPAC nomenclature and Structural isomerism complete.

SYLLABUS SCHEDULED
SR.
NO.

1.

TOPIC NAME

SYLLABUS
SCHEDULED
WEIGHTAGE
(BY FC)
(I)
(II)

WEIGHTAGE IN
PAPER-1
(BY FACULTY)

WEIGHTAGE IN
PAPER-2
(BY FACULTY)

IUPAC nomenclature and

Structural isomerism
complete

Test Pattern :

1
Page #

Paper-1 CT-1
S.No.

Subject

1 to 10

Nature of Questions

No. of Questions Marks Negative

Total

SCQ

10

30

MCQ

20

16 to 20

Integer (double digits)

20

21 to 30

SCQ

10

30

31 to 35

Physics MCQ

20

20

11 to 15

Maths

36 to 40

Integer (double digits)

41 to 50

SCQ

10

30

51 to 55 Chemistry MCQ

20

56 to 60

20

Integer (double digits)

Total

Total

60

210

P a p e r-2 C T -1
S .N o.

S u bje ct

1 to 7

N a tu r e o f Q u e sti o n s

N o . o f Q u e sti o n s M a rk s N e g a ti v e

T o ta l

M CQ

28

C o m p re h e n s io n (3 C o m p . x 2 Q . )

18

M TC

24

M CQ

28

C o m p re h e n s io n (3 C o m p . x 2 Q . )

18

3 0 to 3 2

M TC

24

3 3 to 3 9

M CQ

28

18

24

8 to 13

M a th s

1 4 to 1 6
1 7 to 2 3
2 4 to 2 9

4 0 to 4 5

P h y si c s

C h e m i stry C o m p re h e n s io n (3 C o m p . x 2 Q . )

4 6 to 4 8

M TC
T o ta l

Physical paper1
SCQ(6)
MCQ(3)
Integer(Double)(3)
Physical paper 2
MCQ (4)
Comp.(3 x 2Q)(2)
MTC (4 vs 4) (2)

48

T o ta l

2 10

Organic paper 1
SCQ(4)
MCQ(2)
Integer(Double (2)
Organic paper 2
MCQ(3)
Comp. (3 x 2Q) (1)
MTC((4 vs 4)(1)

2
Page #

JEE (ADVANCED) CHEMISTRY PAPER SKELETON

Faculty Name : HM SIR

Test Name : JB&JB* (CT-1)

PA PER - 1
DIFFICULTY LEVEL :

S.
No.

TYPE

(P)

41

SCQ

(P)

Atomic structure

Bohr model

42

SCQ

(P)

Atomic structure

Photo electric
effect

43

SCQ

(P)

Atomic structure

44

SCQ

(P)

Mole concept

45

SCQ

(P)

Atomic structure

46

SCQ

(P)

Mole concept

47

SCQ

(O)

IUPAC

48

SCQ

(O)

IUPAC

49

SCQ

(O)

50

SCQ

(O)

51
52

MCQ
MCQ

(P)
(P)

IUPAC
Structural
isomerism
Mole concept
Atomic structure

53

MCQ

(P)

Atomic structure

54

MCQ

(O)

IUPAC

55

MCQ

(O)

IUPAC

56

Double
Integer
Type

(P)

Atomic structure

Quantum theory

57

Double
Integer
Type

(P)

Atomic structure

Photo electric
effect

58

Double
Integer
Type

(P)

Mole concept

Avg. atomic mass

59

Double
Integer
Type

(O)

IUPAC

60.

Double
Integer
Type

(O)

Isomerism counting

(I)

(O)

TOPIC(S)

SUBTOPIC(S)

Bohr model

Easy (E), Moderate (M),

Tough (T)

E
M

de-Broglie

Bohar model
H-spectrum deBroglie

E
M
T

Faculty preparing the TEST PAPER should fill it according to paper pattern and submit it with finalisaion of
paper at SMD.

3
Page #

Physical paper-1
SCQ(6)
41.

Sol.

th

area

42.

rd

The ratio of area of 4 circular orbit of He+ ion to that of 3 orbit of Li2+ ion is :
(ATS(P))
th
rd
He+ vk;u dh 4 o Li2+ vk;u dh 3 o`
kkdkj d{kk ds {ks = kQy dk vuq i kr fuEu gS &
(A*) 64 : 9
(B) 4 : 3
(C) 8 : 3
(D) 3 : 4
n A 4 ZB2
44 32
64
= 4
=
9
nB4 Z 2A
3 22
r2 , r

n2
Z

r2 , r

{ks= kQy

n2
Z

Light of wavelength 2 falls on a metal having work function hc/ 0. Photoelectric effect will take
place only if:
(ATS(P))
dk;Z Qyu hc/ 0 ;q D r ,d /kkrq ij 2 rja x }S / ;Z dk iz d k'k vkifrr gks r k gS A iz d k'k fo|q r

iz H kko ds o y rHkh mRiUu gks x k tc%

(A)

(B)

2 0

(C*) 2

(D)

0/

Sol.
43.

An electron in a hydrogen like species jumps from an energy level to another energy level in such
a
a way that its kinetic energy changes from 'a' to . The change in total energy of electron will be :
4

,d gkbMkstu leku Lih'kht esa ,d bysDVkWu ,d tkZ Lrj ls vU; tkZ Lrj esa bl izdkj LFkkukUrfjr
gksrk gS] fd bldh xfrt tkZ 'a' ls
(ATS(P))
3
(A*) + a
4
Sol.

(B)

Change in total energy =

a
4

rd ifjofrZr gksrh gS] rks bldh dqy tkZ esa ifjorZu gksxk :

3
a
8

(C) +

3
a
2

(D)

3
a
4

a
( a)
4

a
4

dqy tkZ esa ifjorZu = ( a)

=
44.

3
a
4

LPG contains n-butane and isobutane. Mass of carbon in 14.5 Kg of LPG.

LPG n-C;wVsu o vkblksC;wVsu j[krk gSA LPG ds 14.5 Kg esa dkcZu dk nzO;eku fuEu
(A) 3 Kg

Sol.

mass of Carbon dkcZu

(B*) 12 Kg

dk nzO;eku =

(C) 14.5 Kg
14.5
58

gS &

(Mole-1(P))
(D) 10 Kg

48

= 12 Kg
45.

Calculate ratio of de-Broglie wavelength of O2 molecule to He atom if ratio of their kinetic energy
is 1 : 18.
O2 v.kq o He ijek.kq dh Mh&czksXyh rjax}S/;Z dk vuqikr ifjdfyr dhft, ;fn budh xfrt tkZ dk

vuqikr 1 : 18 gksa&
(A) 3 2 : 1

(B*) 3 : 2

(C) 2 : 3

(D) 1 : 3 2

4
Page #

h
Sol.

O2

O2

=
=

He

46.

2 32 KE1
4 KE 2
32 KE1 =

4 18
3
32 1 = 2 .

Sol.

He

2 4 KE 2

Which of the following has maximum volume at STP STP ij fuEu esa ls fdldk vk;ru vf/kdre gksrk gS&
(A) 2 gm molecules of CH4
(B) 28 gm of CO
(C*) 5 gm H2
(D) 200 gm of H2O
STP ij fuEu esa ls
(A) 2 gm CH4 v.kq

Sol.

h
&

(Mole-1(P))

fdldk vk;ru vf/kdre gksrk gS&

(B) 28 gm CO v.kq

(C*) 5 gm H2 v.kq
(A) volume of CH4 = 2 22.4 = 44.8 liter.
(B) volume of CO = 1 22.4 = 22.4 liter.
(C) volume of H2 = 2.5 22.4 = 56 liter.
(D) volume of H2O = 200 ml.
(A) CH4 dk vk;ru = 2 22.4 = 44.8 yhVj.
(B) CO dk vk;ru 1 22.4 = 22.4 yhVj.
(C) H2 dk vk;ru = 2.5 22.4 = 56 yhVj.
(D) H2O dk vk;ru = 200 ml.

(D) 200 gm H2O v.kq

SCQ(4)

Cl
47.

IUPAC name of compound

is

(IUPAC(O))

Br
(A) 7-Bromo-3-chloro-5-(1,1-dimethylethyl)-3-ethyl-7-methyl-5-(2-methylpropyl)nonane
(B*) 3-Bromo-7-chloro-5-(1,1-dimethylethyl)-7-ethyl-3-methyl-5-(2-methylpropyl)nonane
(C) 3-Bromo-7-chloro-7-ethyl-3-methyl-5-(1,1-dimethylethyl)-5-(2-methylpropyl)nonane
(D) 3-Bromo-5-(1,1-dimethylethyl)-5-(2-methylethyl)-7-chloro-7-ethyl-3-methylnonane

Cl

;kSfxd dk IUPAC uke gS

Br
(A) 7-czkseks-3-Dyksjks-5-(1,1-MkbZesfFky,fFky)-3-,fFky-7-esfFky-5-(2-esfFkyizksfiy)
(B*) 3-czkseks-7-Dyksjks-5-(1,1-MkbZesfFky,fFky)-7-,fFky-3-esfFky-5-(2-esfFkyizksfiy)

uksusu
uksusu

(C) 3-czkseks-7-Dyksjks-7-,fFky-3-esfFky-5-(1,1-MkbesfFky,fFky)-5-(2-esfFkyizksfiy)uksusu
(D) 3-czkseks-5-(1,1-MkbesfFky,fFky)-5-(2-esfFky,fFky)-7-Dyksjks-7-,fFky-3-esfFkyuksusu

5
Page #

Sol.

3-Bromo-7-chloro-5-(1,1-dimethylethyl)-7-ethyl-3-methyl-5-(2-methylpropyl)nonane
3-czkseks-7-Dyksjks-5-(1,1-MkbZesfFky,fFky)-7-,fFky-3-esfFky-5-(2-esfFkyizksfiy) uksusu

48.

CH2COOH
|
The IUPAC name of HOCCOOH is
|
CH2COOH

;kSfxd

CH2COOH
|
HOCCOOH
|
CH2COOH

(IUPAC(O))

dk lgh IUPAC uke gS %&

(A) 3-Carboxy-3-hydroxypentanedicarboxylic acid

(B) 2-Hydroxypropane-1,2,3-trioic acid
(C) 3-Hydroxypropane-1,2,3-tricarboxylic acid
(D*) 2-Hydroxypropane-1,2,3-tricarboxylic acid

Sol.

(A) 3-dkcksZDlh -3-gkbMksDlhisUVsuMkbdkcksZfDlfyd vEy

(B) 2-gkbMksDlhizksisu -1,2,3-VkbZvksbd vEy
(C) 3- gkbMksDlhizksisu -1,2,3- VkbZdkcksZfDlfyd vEy
(D*) 2- gkbMksDlhizksisu -1,2,3- VkbZdkcksZfDlfyd vEy
1
CH2COOH
2|
HOCCOOH
3|
CH2COOH
2-Hydroxypropane-1,2,3-tricarboxylic acid

gy%

1
CH2COOH
2|
HOCCOOH
3|
CH2COOH
2-

gkbMksDlhizksisu -1,2,3- VkbZdkcksZfDlfyd vEy

Cl

49.

CHCCl3 is

The IUPAC name of

(IUPAC(O))

Cl

6
Page #

Cl

CHCCl3

;kSfxd dk lgh IUPAC uke gS %

Cl
(A) Dichlorodiphenyltrichloroethane
(B) Trichloromethylbis-(4 chlorophenyl) methane
(C*) 1,1,1-Trichloro-2,2-bis(4-chlorophenyl) ethane
(D) 2,2,2-Trichloro-1,1-bis(4-chlorophenyl) ethane
(A) MkbZDyksjksMkbQSfuy MkbZDyksjks,sFksu
(B) VkbZDyksjksesfFkyfcl-(4 DyksjksQsfuy) esFksu
(C*) 1,1,1-VkbZDyksjks -2,2-fcl (4-DyksjksQsfuy) ,sFksu
(D) 2,2,2-VkbZDyksjks -1,1-fcl (4-DyksjksQsfuy) ,sFksu
Cl
2 1
CHCCl3

Sol.

Cl
1,1,1-Trichloro-2,2-bis(4-chlorophenyl) ethane
1,1,1- VbZDyksjks -2,2-fcl (4-DyksjksQsfuy) ,sFksu

COOH

COOCH3
and CHO

50.

are :

CHO
(Isomerism(O))
(A) Identical compounds
(C*) Functional isomer
COOCH3
rFkk CHO

Sol.

(B) Positional isomer

(D) Chain isomer

COOH

gS :

CHO
(A) le:ih ;kSfxd
(B) fLFkfr leko;oh
(C*) f;kRed leko;oh
(D) J`
a[kyk leko;oh
Both compounds having same molecular formula but different functional group.

nksuksa ;kSfxdksa ds v.kqlw=k leku gS ysfdu f;kRed lewg fHkUu&fHkUu gSA

MCQ(3)
51.

Which of the following samples contain 5 NA atoms :

(Mole-1(P))
(A*) 22.4 L of CH4 at STP
(B*) 1 gram molecules of N2O3
(C*) 1.25 moles of P4
(D) 0.5 NA molecules of Ethene (C2H4)

fuEu esa ls dkSuls uewus 5 NA ijek.kq j[krs gSa %

(A*) STP ij 22.4 L CH4
(C*) 1.25 eksy P4

(B*) N2O3 ds 1 xzke v.kq

(D) ,Fkhu (C2H4) ds 0.5 NA v.kq

7
Page #

Sol.

Sol.

52.

(A) mole of CH4 = 1

number of atoms = 5NA
(B) mole of N2O3 = 1
number of atoms = 5NA
(C) mole of P4 = 1.25
number of atoms = 5NA
(D) number of atoms in C2H4 = 3NA
(A) CH4 ds eksy = 1
ijek.kqvksa dh la[;k = 5NA
(B) N2O3 ds eksy = 1
ijek.kqvksa dh la[;k = 5NA
(C) P4 ds eksy = 1.25
ijek.kqvksa dh la[;k = 5NA
(D) C2H4 esa ijek.kqvksa dh la[;k = 3NA
Which of the following options is/are independent of both n and Z ?
Un = Potential energy of electron in nth orbit

(ATS(P))

KEn = Kinetic energy of electron in nth orbit

= angular momentam of electron in nth orbit
vn = Speed of electron in nth orbit
n

fn = Frequency of revolution of electron in nth orbit

Tn = Time period of revolution of electron in nth orbit

fuEu esa ls dkSuls fodYi n rFkk Z nksuksa ij fuHkZj ugh djrk gS@gSa\
Un = nth d{kk esa bysDVkWu dh fLFkfrt tkZ
KEn = nth d{kk esa bysDVkWu dh xfrt tkZ
th
n = n d{kk esa bysDVkWu dk dks.kh; laosx
vn = nth d{kk esa bysDVkWu ds ?kw.kZu dh xfr
fn = nth d{kk esa bysDVkWu ds ?kw.kZu dh vko`
fk
th
Tn = n d{kk esa bySDVkWu ds ?kw.kZu dk vkorZdky
KEn
(A*) U
n
Sol.

(B*)

vn
n

(C*) Tn

Fn

(D*)

fn

v n2

KEn
1
(A)
=
Un
2
(B)

rn v n

(C) Tn
(D)

53.

rn

fn =

v n2

fn

n2
z
n3

z
n

1
=1
n

z2

=1
z2
n3
n z2
n2
n3

z2

=1

Electron in a sample of H atoms are returned to ground state from an excited state so that change
in de-Broglie wavelength of electron corresponding to the transition of maximum energy = (
8
0.529) . Select correct options
(ATS(P))
(A*) Number of orbit of original excited state is 5.
(B) Total number of different spectral lines in visible region is 4.
(C*) Total number of different spectral lines in infrared region is 3.
(D*) Change in angular momentum of electron corresponding to the transition of minimum energy
=

8
Page #

,d izkn'kZ esa bySDVkWu ,d mksftr voLFkk ls vk| voLFkk esa ykSVdj vkrs gSa rkfd vf/kdre tkZ dh
lae.k ds laxr bySDVkWu dh Mh&czksXyh rjax}S/;Z esa ifjorZu = ( 8 0.529) . gks tk,A lgh fodYi dk
p;u dhft,A
(A*) ewy mksftr voLFkk ds fy, d{kk dh la[;k 5 gSA
(B) n`
'; {ks=k esa fofHkUu LiSDVy js[kkvksa dh dqy la[;k 4 gSA
(C*) vojDr {ks=k esa fofHkUu LiSDVy js[kkvksa dh dqy la[;k 3 gSA
(D*) U;wure tkZ ds lae.k ds laxr bySDVkWu ds dks.kh; laosx esa ifjorZu = gSA
n
Sol.
1
2 r0
=
(n1)
z
n1=4
n = 5.
Total number of lines in IR region = 3.
IR {ks=k esa js[kkvksa dh dqy la[;k = 3
Change in angular momentam (5

dks.kh; laosx esa ifjorZu (5

4) =

4) =

h
=
2

h
=
2

MCQ(2)
54.

Which of the following is/are represent correct IUPAC name?

(IUPAC(O))
NC

CN
Ethenetetracarbonitrile
CN

C=C
NC
CHO
(B*) |
Ethanedial
CHO
CHO
(A*)

(C*) OHC

CHO Methanetetracarbaldehyde
CHO
O

O
(D*)

3,3-Di(1-Oxoethyl)pentane-2,4-dione
O
O

fuEu esa ls dkSulk@dkSuls ;kSfxdksa ds le{k fn;s x;s IUPAC uke lgh gS\
(A*)

NC
NC

CHO
(B*) |
CHO

C=C

CN
CN

,sFkhuVsVkdkcksZukbVkby

,FksuMkb,sy

9
Page #

CHO
(C*) OHC

CHO

esFksuVsVkdkcsZfYMgkbM

CHO
O
O
3,3-MkbZ (1-vkWDlk,fFky) isUVsu -2,4-MkbZvksu

(D*)
O
O
Sol.

(A)

NC

2 1
C=C

CN
Ethenetetracarbonitrile
CN

NC
1CHO
(B) |
,Fksu Mkb,sy
2 CHO
CHO
1

(C) OHC

CHO Methanetetracarbaldehyde

CHO
O
O

1
4

3 2

(D)

3,3-Di(1-Oxoethyl)pentane-2,4-dione
O

5
O

gy%

(A)

NC

2 1
C=C

CN
CN

NC
1CHO
(B) |
,FksuMkbZ,sy
2 CHO
CHO
1

(C) OHC

,sFkhuVsVkdkcksZukbVkby

CHO esFksuVsVkdkcsZfYMgkbM

CHO
O
O

1
4

(D)

3 2

3,3-MkbZ (1-vkWDlk,fFky)

isUVsu -2,4-MkbZvksu

5
O

55.

and
Which is/are true about above two structures.

(IUPAC & Structural Isomers(O))

(A*) Index of hydrogen deficiency of each is 3

(B*) Both are metamers.
10
Page #

(C) Both are chain isomers

(D*) Both have same general formula.

rFkk
mijksDr nks lajpukvksa ds fy, dkSulk@dkSuls dFku lR; gS %
(A*) izR;sd
(B*) nksuksa
(C)

esa gkbMkstu U;wurk dk lwpdkad rhu gSA

e/;ko;oh gSaA

nksuksa J`
a[kyk leko;oh gSaA

(D*)

nksuksa leku lkekU; lw=k j[krs gSaA

Integer(Double)(3)
56.

Ans.
Sol.

Sol.

57.

An LED of powers X watt emits twice as many photons at 1000 nm as another LED of power 5
watt at 400 nm in one second. Find X.
(ATS(P))
1 lSd.M esa X okWV 'kfDr dh ,d LED }kjk mRlftZr 1000 nm ds QksVksuksa dh la[;k] 5 okWV 'kfDr dh vU;
LED }kjk mRlftZr 400 nm ds QksVksuksa dh la[;k dh rqyuk esa nqxquh gksrh gS] rc X Kkr dhft,A
04
LED 2
Time = 1 second LED 1
;
5 1
Energy = X 1 = XJ
;
5J
= 1000 nm
;
= 400 nm
no. of photons = 2n
;
no. of photon = n
hc
hc
X 2n
;
5 n
1000
400
2 400 5
X
= 4.
1000
LED 2
le; = 1 lSd.M LED 1
;
5 1
tkZ = X 1 = XJ
;
5J
= 1000 nm
;
= 400 nm
QksVkWuksa dh la[;k = 2n
;
QksVkWuksa dh la[;k = n
hc
hc
X 2n
;
5 n
1000
400
2 400 5
X
= 4.
1000
Threshold frequency of a metal is 0. When light of frequency = 3 0 is incident on the metal
plate, maximum kinetic energy of emitted photoelectron is x. When frequency of incident radiation
is 5 0, kinetic energy of emitted photoelectron is y. If threshold energy of metal is z. Find value of
x

y
z

: (ATS(P))

11
Page #

,d /kkrq dh nsgyh vko`

fk 0 gSA tc /kkrq IysV ij vko`
fk = 3 0 dk izdk'k vkifrr gksrk gS] rks mRlftZr
izdk'k] bySDVkWu dh vf/kdre xfrt tkZ x gSA tc vkifrr fofdj.k dh vko`
fk 5 0 gS] rks mRlftZr izdk'k
bySDVkWu dh xfrt tkZ y gSA ;fn /kkrq dh nsgyh tkZ z gS] rks
Ans.
Sol.

36
x 3h
y

5h

2h

4h

y
z

dk eku Kkr dhft,A

z
58.

= 36.

An element ex ist in thr ee isotop ic form : 6 0 A, 62 A and 64 A.

Re lative a bunda nce of 60 A = 30 % b y m o le.
If aver age atom ic m ass of A' is 62.6 u, find o ut the sum of % a bundanc e (b y mole)
of 60 A and 6 4 A.
(Mol-1)(P))
;fn ,d rRo] rhu leLFkkfud :i 6 0 A, 6 2 A rFkk 64 A esa ik;k tkrk gSA
6 0 A dh vkisf{kd ckgqY;rk = 30 %
;fn A' dk vkSlr ijek.oh; nzO;eku 62.6 u gS] rks 60 A o 64 A dh izfr'kr ckgqY;rk eksy@eksy esa dk

;ksx Kkr dhft,&

Ans .

90

Sol.

Av era ge atomic m ass =

x = 60%
m ole% of

Sol.

vkSlr

(30 60) (70 x) 62 (x 64)

100

60

64

A + mole% of A = 9 0
(30 60) (70 x) 62 (x 64)
ijek.oh; nzO;eku =
100
x = 60%
60
A dk eksy % + 6 4 A dk eksy % = 90

Integer(Double)(2)
59.

The sum of number of functional group and index of hydrogen deficiency in the following
compound is -

fuEu ;kSfxd eas f;kRed lewg o gkbMkstu U;wurk dk lwpdkad dh la[;k dk ;ksx gSA
(IUPAC(O))
OH
N
O

NH2

COOH

Ans.
Sol.

19
Index of hydrogen deficiency = 15
Functional group = 4
gkbMkstu U;wurk dk lwpdkad = 15
f;kRed lewg = 4

60.

How many isomers are possible of molecular formula C7H16 having word root pent.
(Isomerism(O))
C7H 16 v.kqlw=k j[kus okys ;kSfxd ftldk ewy 'kCn isUV gS] ds fdrus leko;oh lEHko gS\
05

Ans.

12
Page #

Sol.

C
|
CCCCC
|
C

CCCCC
| |
C C

CCCCC
|
|
C
C

C
|
CCCCC
|
C

CCCCC
|
C
|
C

13
Page #