Você está na página 1de 8

g5.-DEC--?

WA

A9136

FROt't 6?

27

653?Fe,66

TO

P,6?

59A9502

SAFETYDATA SHEET
HARZ{DOUS SUBSTANCE PROCEDURE SHEDT
N,N-T,IMETHYLAItf U,IND
Aooording to EC Dircctivc 9l/lSSiEEC

F ffitlg

Date :

l2lttL 200j

l. ldontiffcrtio! ofthc

sub$tance
ofthe product
Product namc
I N,N-Din:ethyleniljne
lde nlifrcation

Uee of the substaacelpteparctron

Chcmical for synthesls

2.Corlpo$tlon/l onmtion

on lngrgdlonts

Synottynt
Dirnthyl sminobenzone

:1Ll.69-7
: 12l.lE g/mol
i CSH1 lN

CAS-No.

M
Formula

l{ill

Chemicalformuls
3.

i C6H5N(CH])2

8C-Index-rr-o, 612-016-00-0
ICSC No.
0871
RTCS No.
8x472500

U.l.l. Code

H8zard! Id.niincation

INTUUTIONT

Mtf

deprcsg the central nervous E stcm (CNS) a.nd decrease


the abiliry of the

ll::1:: ":qel: o*,s

wirh btood hemoerobrn ,. ro,rn

,r",r,**1ioi,rr

lrrii

an"_'i"r"r,

cannor panrcrpatc rn or)gcn llanspon. Sufficienl i:oncentmlion$


oimelhemoslohjll in tbc
blood can rcsul( in suffocarion in ihe presencc ot oxygen.

.trr/M CoDtact may cause j}liratior. Skin absorpdon ofN,N-dimcthylnniline


may resuh jn
cyanosis
rind CNS dcprcssion.

LYSI Contar* may cause ilritation. product can be rapidlr, abrorbed


throtg{r
n.uco.'u;
"
mcmbranes eod ski! causiog CNS deprcssitn 6na lypo*i,
1"yan;"j.

T0

,EC-ZMA A9130 FHll 62 21 6536066

,LVGESflOtr'r hEestion

will

causc

hForia

5989562

F.03

and Cr.-S deprssion.

SIGNS AND SYMPTOMS: MelhemoglobinemiB can cau$e blu coloradon ofrhe Iips, nail beds
sr1d cyelids (cyaaosis flom reduced hemoglobin in rhc blood). headache, dizzjrless, weakness,
1'ast Iabored breatiing, itcreasad pulse, lcthErg/, Iols of coordinati on, cerdiac arest, com4 and

dselh,

MEDICAI CONDITTONS AQORAVATED

BY E"YPO-SI/RE| Anemid and orher blood

disardcls,
CJIRO,V/C: Long-lerm cxposMe may advcFely affect the ljve., spleen, kidneys. and blood.
TITRGET ORGANS: BIood, liverj kidneyc. CvS, Cr.vS

Aid Me.sur.,r
INH|LAT|OII: kemovc to fresh air, lf brcafiing i6 diffculr, oxyger should be administered by
a qualified professiooal. If breathing has stopped, a cerrilicd professiorral shoull givc CpR.
4. FirEt

Scck immediale mcdisgl ansntion,

.fff,ry: lmmediaEly rcmove contimitrated clothing and ritrse skiD rhorouetrlv with laroe
Dounts ofwater for at least 15 minutes. Tborowh cleonsing ofenrirc r.intaminaterl arca
inciuding halr, scalg nails, nosEils snd e{ canals, is ofutlnost i&portancc. Ifirritadon persrss,
or .xposure is exte$ive or of Long duration, seek medical attention.

tyli:

Flush eyes with large amouots of lukcw.m watcr fhr


$!ek rnedical artention.

l -5

minules. IfiEirarioR persisls.

,VCESnO:lrrlstedistclyinducvotnirintsiftictimjsconscious.Vomidngismosrcffqcrive
il'induccd wirhin 30 rninures following ilgsdon. Scck irnmcdjarc nedica.l irtendon.
Nou to Phltician: Blood meticmoglobin if exposure or degre ofcyarosis is in do$bt. Avoid
aspirin o! spidnlite pmducts for complaints ofheadaohe. Advise padcnr to avoi,j a.lcohol fo,

2':

days. ln case ofskin .bsorptio& symptorns rDay be deldyod. M;hernpgobinemia nMy


rcquir treasnefl wirh methylene blue. Exchango lransfusion may be rcquiired in severe
or
urucspoltsivE cass.

re-ligbtlng mEssurer
&lit4ble e\tinguishlng hed:4; powder, foanL spray \{arer.
Fl

Spaclal rlcts: Combustiblc. Formation ofcxpiosi.! mixhrrcs possiblc wjth air. Developmdnr
of hazardous combustion gascs or vapouls possible in the event gf !ire. Thc following may
delelop iD evenr offilc: nitroged oxids.

6. Accidcutal Ralrrre M...ur.r


Evacuatr and isolalc hazald a!ca, Deny cntry to ursuthorized and unprotecred iudividtuls.

Clcar.tp pcrsoBel should wear penonal protectivc cquipmca! approptale for

\r

rhe magnirude

ofexpoaule. Ventilare ara and stay upwind. .Absorb small spills wirh suilabte ir'tert sorbent
rnEtcrial (i.9. Speedy dry, venniculite, etc ) Scoop, sbovel, or s\,veep into cloan, dry tightly
closed cottailtr fof latcr disposa.l. Absorbcd matdial fu|s larne heal$ and fire haT,ards al
ploduct, handlc aod dispose arcordingly. Dike largc spills $cll ahead of liquid for later recycle
or disposel, Rinsc arca ofspill wkh watcr. Do not allow spillcd producr or clean-up watef,s to
gotc! walolwayg aod swcrg.

7,

l{sldlhg rlld 3torage

rdlirg !
Iat safe hatdliag: Avoid ggnglation ofvapours/aercsols. Work

Noler

ltnde! hood. Do DoL

irrhalc substance.

StoragerTighdyclosed.Lnawell"venlilatedplace.AF1Jdegreeto.r.2ide8r,.

E.

Expoouro con trnolr/prrorsl protcctlo!

SpealJic

c o ntro

I.

paramc

ter

EC
Name

N,N-Dimerhylaniline
i C 3 towitg possible ca.rcioogenic effecb tbr man. '
r

Carci$ogenic

Perso nal proteuive e4 uipnent :


Proteqive clothing should be selcctcd spccificaUy for lhe working place, depcnding on
coruenbarion and qualtiry oftbe hazardous substance$ handled. The rcsistarce qltlle
Fotective ol0thing t0 chemic&ls should be ascrrailcd with the rpspecdvg supp]ir,

RespiruIory protection rcqdred when vlpours/acrosols arc gcncrarcd. Filter A (acc. to


DIN 3181) for vapurs oforganic coorpounds.
Eye

prctectioni rc4rkeA

Hand proteclion:

In full

contact:

Glove

tBaterial;
thickness:
timc:

Layer
Ereak*uough

buryl rubber
0.7

mlll

>480 Min,

-DEC-2@A 49t37

FRtl'l 52 21

In splaih conract:

nrarerial:
fticknessi
Breaktlrowh time:

Glwc

Laycr

PH

1.:j
value
At l-2gAI{2O

IE

653S5666

F. @5

59s95A2

narural latex

0.6mm
>60 Min.

..

,,r(20 desre}:
'.1.4
.
viscosity dyndmic .
t.2o
ilo a.g!j
mpa"s
L
Mctting point':i:, r . 1.,,:.; : l,...
ZIS:
Jc.gre;
Boilinfioinr ' :
(t0r3 hpd).
192-1ts ;6;;
Ignhion rempelature
Ignition
remperature .:
. ,,r ;
3?0
ociee (DIN5l79a)
dclEe
.

Flash

poinr

.:

.,

.i.
1,

Explosion limits

ii
VapoLE prEssule

85
'EJI

u"io

iofN sits8)

deorce o.c
oc
degree

o.c.

.1 7
uPDcr.":, (2odcSr.t);
dcsr.r). . .0.53
,.,
0,s3
'.(20

.:.:
Kelalrvevapour'd,onsrly
vapour'&iuir!
:.i

Relarive

?5.

- t!1
-,4,17,

v i. . ..,.,..(20 dcgrd) 0.96


!*li
Solubility in ;'.Wsrcr ,... , I20
(lu osgcc)
Li'
dggrcc) t.2
Ethalol

hPe

gcml
EJI

iiecly sotuble
ftety $olublc

Ethcr

LogPow: j,.,,.,
:

Vol%

..,

2.31. :

(experimental)

.D..-&Jd

OSIJZ

10.

TO

l-ld-!'l 62 21 b5Jtbu/:b

P.86

59tF:5ti2

Slability tEd rercrivity

Conditior,s to be avoided
Stroug hcating.
Subt/4l','ces to be ayolded
Oxidizjlg agoDt, acid$, acid haiido!,

I lazdrdow

decomposit io h pr oduct s

In the evcnt

offirc

adydddrs, halogms, nitriles, oirrous acid.

Furthet tnJbnation
Light-sensitive
Explesiblc with ah h a vaporous/gaseous sraid.

ll, Toxicological in lnlornstioo


Aafie todcitt
LCJ0
LD50
LD50
LDLo

(inhalation, rat): >5.1 mgil/4 h.


(dcrmal, rabbit): 1700 mg/l..g.
(oral, rar): t 120 Erg&g.
(oral, hrrnn)j 50 !B/kg.

Spccific symptoms in animal srudies:


(rabbit)i l"rritaiiolls.
Skir ilritsrion tesr (rabbit)r Slighr iritarions.
F,yc hritatio$ test

d"".i"iilabl ro us do nor conform wi$ rhr labclting prrscribed


Il]9 tus
]!krln'*
!U
oossrcrl whlch have Dor been published.

by rhr EC. The

g"bact!,e ro lhronic toxici!y


The calsiltogenic potcntiai rcquiles

ifther clarifcujon,

Bactcrial murageDicity: Ames &sr: lregative.

het pticologbal infot matiott


Affcr irhalatiotr ofvapou.rs/acrosols: Risk of absoFtion,
Aftsr skin contsct Rist of absoryrion. Sligh iri:aiion sympton$.

Fu

Aner eye contact: lrntadonG.


Affc! swallowing: Naus!, vomiting,

Loss

ofwcighq cj,anosi6, abso.ptiou.

I l-l' ,:ij:,1, 1 '' i;;Aii"r'r


JAkAnrA

,t .. ,' '-

'

'l

-DLC-ZVAA

U9rJ2

'1l]

FREt'r 6? 27 653EE866

=9d1*2

P.A?

olhcr notes:

following Epllies tc 4romatic a$ines in gcdcrdl: systemic cflect: oethaemoglobinaemia


witl headeche, cerdiac d'$hythnta, droP in blood !r.sstl!e, dyspno"o, aod spasms' pnncipal
Th

symptom: ryarpsis (blue discolgralio[ of tbe blood).

The product should be handlcd with thr care usual whcn dalilg \"ith chtmicals

I 2. Ecological hiorm{llolr
Biologic dogradation.
Biodoradation:ro% /28 d Zsl$-Wellens tesr. Easily liminablc.

Biodegradable.

\1trc[ inuoduccd propsrly, no impaiments in the function of

adapted biologieal

wa.ite.qfler-Eau:ent plants arE tir be cxpccted,


Bchavior in ervircnme ntel companments:
Slightly bioaccwnulativi (DCF<30).
Dislribulion: tog p(o/w): 2.3 I (expelimcntal)
No apl,recisbla boatcumulaiiol pstenlial is to be extcotcd (log P(o/w) 1-3).
Ecotoxic effec'ts:
Toxic for sque'tic orgenisms. May oause loog_term advclsg eflects in thc aquaric snvironmcntBiological Btrec6:
Fisb toxicity:,P.gomela5 LC50: 65 6 mgn /96 h
Daphoia loxicity: Daphnia magna EC50: 5mgll /48 h.
Algcal toxicity: Desmode$mus sub$picatus lC50: 340 mg/l /96 h
Bactsial roxicity: Pholobcctedunr Phospbore{m EC 50: I ! 6 mg4 130 inin microtox te$!

trlher ccologic
8OD

dinc:

10 7o from

TOD /5 d; COD 96

9/o

from TOD; TODr 2.640 mgg.

Do not allow !o cntgr waters, \ta$e waRr, or sojl!

13, Disposul

co$idcrrtiong

Chpmicals mEsl be disposocl of in conlliance with the rcspgglivd national r8ulatiotls,

Packagiltg,
Ploducr packsging flust be disposrd of in comPlidncc with thc country'speci:nc rsgulglions or
must br passcd to a packaging retrtn sy8teF.

F-,:li"i.gg

r-DEC-znE

A9t32 FR}I

10

62 21 6$45065

59aa54?

I
14.

Trrtr.tDort lntortttstion
t"""t1-n e^nn. ruD - LJN 2253 N,N-DII{FTHYLAITLII\' 6 l '

i*J

'! ranspon by

rivct AND, ADNR not tasted

'Iranspolt by s.a IMDO, GGvSec

Traosport by air CAO, PAX

-lN

2253

N,N'DlMtTlIYLANlLiN' 6 1' n

Ems 6.1'0

N,N'DIMETIIYLAMLIN,

6'

1'

UN'-

2253'

ll

and in the form


The traDsro{ reguleti{rns are citc.d according to infeflationdl logul*tian$
ore not
coufltries
ir
other
national
dcvisiions
apqrticatti h G;unsny (GGVSE) Possiblc

considered.

Regul.torY iolormrdon
Lalglllng according lo EC Dlrectl\es
15,

Svmbol

'

T
N

R-nhrascs: 2tt24/25-4()'51153

Toxic
DanEerou lbr the cnvironmer:l
Toxic by jnhaladon, in co[racl with skin ajrd
Limired evidence of a c8rcinogenic effecL Toxic to
aquatic crgtllishs' may cause long-te l everce eilects

if

in

the aqualic envitorunent'

AJler cooract wilh sKn, wash imoediaeli:wirh plcnry of


and gloves ln
warcr. Weor suitable plcnty of watir. W.qr $uittrblg p$tecdve clothing
(show the
acctrtent or ifyou icel unwell, scck medical Ed"icr immcdiately

s-nhrases: 28-3613745-61
cese of

labl whore po6slblg). Avoid rclease to the cnviro[mcnt Refc! 1o

lpecitl

instructiontsafety data
shccrs-

EC-No.:

204'493'5

EC label

Re&/ced labelling ( I 999/4 S/DC'Ar t. I 0'4)

Toxic
S\rbol:
' N T
Dangcrous ftrt thc cnviroruncnt
23n4D5-40 Toxic by inhrlEtio& in contact taith slin and if
R.DhnNes:
'
swallowcd, Limited Qvidenc of a crtcinogmic effect

aers

FRo'r 6221 EE36ec6

TO 59tl95tE

-49

Vf*-^"
36R7-45.

Wear suitabte ProEcrive clofiing and glovcs, ln casc of


accidenror ifyou fel unwell, seek melical advice irDmediarely (show the label where
possible),

S-phrase$:

llTTfiT.Tn:il,h{iA
Jr.ian ra
L_

I
J

TOIFL

P- @9

Você também pode gostar