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INTRODUCTION.
In this manual, the fundamental design rules that will ensure that steel sections and fabrications
are hot dip galvanized to the highest quality standards and at the lowest cost are featured. There
is additional supplementary information included in this 2nd Edition of the manual to provide
affect
information on important aspects of galvanizing that af
fect its durability in service. Industrial
stafff are available for consultation on detailed aspects of design on specific
Galvanizers' technical staf
projects.
GAL
VANIZING FUNDAMENT
ALS
GALV
FUNDAMENTALS
Hot dip galvanizing is an immersion process where steel sections and fabrications undergo the following
operations:
easing (removal of oil, organic materials, mill primers and paint)
1. Hot caustic degr
degreasing
ochloric acid pickling (removal of rust and mill scale)
2. Hydr
Hydrochloric
3. Rinsing (removal of pickling acid residues)
efluxing in zinc ammonium chloride solution (surface conditioning)
4. Pr
Prefluxing
.
Hot
dip galvanizing (at 455-460 degrees C)
5.
omate quenching (passivation of the zinc surface to prevent early oxidation)
6. Chr
Chromate
IMPOR
TANT DESIGN F
ACT
ORS
IMPORT
FACT
ACTORS
Hot dip galvanizing is a self inspecting process that
relies heavily on proper design to achieve a quality
result. The major difference between hot dip
galvanizing and all paint coatings is that hot dip
galvanized coatings can only be applied to
epar
ed surfaces.
perfectly pr
prepar
epared
- The zinc will not rreact
eact with the steel to form the
galvanized coating unless the surface of the steel
is perfectly clean .
- The hot dip galvanized coating will not form
unless the zinc can intimately contact the steel
surface.
Draining,
Dimension instability and
Design.
A consequence of poor venting; this RHS frame exploded due to moisture entrapment
If the air pockets are large enough, the steel item may
have sufficient boyancy to float on the surface of the
molten zinc.With hollow sections, a general rule is that
if the section contains more than 15% of its internal
volume as air because of inadequate venting, the item
will not sink in the zinc.
SAFETY NOTE:
Adequate hole sizes in sealed hollow sections in the correct locations ensures galvanizing quality.
Vessels with large internal volume requires large drain holes. This tank
contains over 10 tonnes of molten zinc when immersed
7.
NOTE: Water or process solutions enter hollow sections during fabrication or during the galvanizing
process. If the drain holes are not located at the lowest point in the fabrication;
- process chemicals will be trapped internally and cause an explosion hazard when immersed in the molten
zinc.
- zinc will be trapped internally and will freeze in the undrained area. This may interfere with assembly, it
will add to the weight of the item in service and it is a waste of zinc which adds to the cost of galvanizing.
Vent and drain holes must be located as close to the high and low points of the hollow section as
possible to prevent air locks, entrapment of pretreatment chamicals and zinc puddling
THE PRINCIPLES OF A
VOIDING DIST
OR
TION
AV
DISTOR
ORTION
When steel sections or fabrications are immersed in
molten zinc, their temperature is raised to that of the
molten zinc which is typically 455oC. The rate at
which the steel will reach this temperature across its
entire surface will depend on;
- the thickness of the individual sections making
up the item.
- the total mass of the item.
- the dimension of the item.
At galvanizing temperatures, there is no change to
steel's metallurgical microstructure and the
galvanizing process is not hot enough to have any
heat treating effects on the mechanical properties of
the steel after galvanizing.
The pattern of distortion in this 3 mm floorplate is clearly the result of the welding technique used.
Attatching the channels with fasteners after galvanizing would significantly reduce the risk of distorting
GAL
VANIZING RULES T
O A
VOID DIST
OR
TION
GALV
TO
AV
DISTOR
ORTION
1. Immerse the item as quickly as possible.
2. Keep the molten metal line as short as possible on the item.
3. Withdraw the work from the galvanizing bath as quickly and as steadily as possible
4. Air cool distortion prone items. Support the item during cooling on level supports. Do not water quench.
Classification of distor
tion pr
one items
distortion
prone
2. Medium risk. Light section roll formed products, long light walled conduit and tubing, fabrications containing assymetrical weldments or steel
of significantly different thickness, medium plate,
some double dipped items (8-16 mm).
.
Designing for optimum bath dimensions allows
large fabrications to be easily galvanized.
FACT
ORS AFFECTING GAL
VANIZING QUALITY AND SER
VICE
ACTORS
GALV
SERVICE
There are a number of factors in the nature of steelwork presented for galvanizing that impact on the galvanizers ability to provide a quality product and service. These are:
1. Surface condition of the steel: rusty
eviously galvanized.
rusty,, painted, pr
previously
Steel that is badly corroded will be slow to pickle and
removal of heavy rust on part of the surface may remain
on the surface to cause galvanizing defects. Badly rusted
steel should be abrasive blasted too remove heavy rust
areas prior to delivery for galvanizing.
Steel coated with old paint may not be able to be cleaned
effectively in the caustic pre-treatment. Paint remaining
on the surface will prevent the acid pickling the surface
and galvanizing defects will result.
Previously galvanized steel requires complete stripping
prior to galvanizing. While this can be done effectively,
there is a cost in additional handling and acid
consumption that will add to processing cost. For this
reason, incorporating pre-galvanized components into
fabrications to be galvanized should be avoided.
2. T
ype of pr
oduct; castings, old wr
ought ir
onType
product;
wrought
ironwork, brazed, solder
ed
or
riveted
assemblies.
soldered
Old wrought ironwork may be porous and allow
moisture into voids in the castings. Abrasive blasting
is the preferred method of surface preparation for this
material to minimise immersion in process chemicals.
Soldered items must not be galvanized. The solder will
melt out at galvanizing temperatures .
This jig of general work illustrates the variety of conditions that steel is received for galvanizing, including newly
manufactured, rusty and previously galvanized.
11
FACT
ORS AFFECTING GAL
VANIZING QUALITY AND SER
VICE (CONT
.)
ACTORS
GALV
SERVICE
(CONT.)
3. Steel metallurgy
The galvanized coating is formed by the steel reacting with the zinc at galvanizing temperature. The metallurgy of the steel combined with its surface condition will affect the appearance and the thickness of the
galvanized coating.
Steel composition: Most structural steels have low levels of alloying elements that are typically carbon, phosphorous, manganese, silicon and sulphur which total around 1% of the constituents. The balance is iron.
The effect of each of these elements is as follows:
1. Ir
on. Iron (Fe) is the major component in the zinc-steel reaction that forms the galvanized coating. Pure iron
Iron.
is not highly reactive with zinc. Very low alloy steels will produce below Australian Standard (AS 1650) thickness coatings with a smooth and shiny appearance.
2. Carbon. Carbon (C) does not have a significant effect on galvanized coating characteristics. High carbon
steels with tensile strengths over 1000 MPa may be affected mechanically through hydrogen embrittlement
caused by hydrogen absorption into the steel during pickling.
3. Manganese. Manganese (Mn) is a toughening element used in stee. It has little effect on coating appearance at
the levels found in structural steels. Steels with high manganese content may produce galvanized coatings with an
uneven brown or gold colouration and may produce thicker coatings that are less impact resistant.
4. Phosphor
ous. Phosphorous (P) is a very reactive residual element in structural steels that does not present a
Phosphorous.
problem at residual levels. It is found as an alloying element only in special electrical grades of steel which are
rarely galvanized. High phosphorous content will produce thick, brittle coatings.
5. Silicon. Silicon (Si) is the most common reactive alloying element in steel. Most hot rolled structural sections
do not have significant reactive silicon content. High silicon levels commonly occur in some plate products and
large diameter pipe and RHS which is produced from the same steel source. Thick, grey or unevenly coloured
galvanized coatings arise with this type of steel.
6. Sulphur
Sulphur.. Sulphur is a reactive residual element in structural steel that does not pose a problem at residual
levels. It is found as an alloying element in free machining steels. Threaded sockets and fittings manufactured
from high sulphur steel are sometimes incorporated into fabrications for galvanizing. Zinc and acid attack on the
steel may be severe with high sulphur steels.
12
FACT
ORS AFFECTING GAL
VANIZING QUALITY AND SER
VICE (CONT
.)
ACTORS
GALV
SERVICE
(CONT.)
4. Surface Pr
ofile
Profile
The rate of reaction between steel and zinc is also affected by the surface profile. Very smooth surfaces
such as those found on cold rolled sheet and tube products will have a relatively low rate of reaction and may
not produce galvanized coatings that comply with the
AS 1650 standard for minimum coating thickness.
Also, very smooth steel surfaces on reactive steels may
give rise to galvanized coatings that may flake or
peel on impact.
Hot rolled sections have a natural surface profile arising
from the presence of mill scale during rolling. The mill
scale is removed by pickling during the galvanizing
process leaving a steel surface that will generally
produce galvanized coatings in excess of the thickness
required by AS 1650.
5. W
eld quality
Weld
13
5. W
eld quality (cont)
Weld
14
6. Dimensions
Dimensioning fabrications to best suit available
galvanizing bath dimensions will ensure that;
a . The item can be hot dip galvanized at the lowest
cost and without delay.
b . The item can be presented to the molten zinc in a
way that optimises venting and draining to pro
duce the best possible surface finish.
c. The item that can be loaded efficiently into the
dipping jigs and produce a better quality finish.
Some dimensioning rules to consider ar
e:
are:
1. Long or deep items that require double-end
dipping will add 30% or more to the galvanizing
cost.
2. Three dimensional items have a low mass per unit
of volume cannot be processed as efficiently as
two-dimensional items.
3. Items that cannot be withdrawn from the molten
zinc at sufficient an angle will give rise to heavy
zinc buildups and drainage spikes.
Three-dimensional fabrications
require careful design to ensure
proper venting and draining and
awkward fabrications like these have
low weight per unit of volume,
which increases processing cost.
15
THREADED PAR
TS
PARTS
Galvanized fasteners should be used with hot dip
galvanized assemblies. When the item to be galvanized
contains threaded assemblies, the pitch diameter of
the female threads must be increased to permit hand
assembly after the addition of a galvanized coating to
the male parts. Internal threads and nuts must be tapped
oversize after galvanizing to accommodate the thickness
of the galvanized coating on the stud or bolt.
While the internal threads that are tapped after
galvanizing have no galvanized coating, the close
contact with the galvanized male threads provide
sufficient cathodic protection for adequate durability.
Items too long or too large to be centrifuged, such as
long threaded rods, may be wire brushed while hot to
remove any excess zinc from the threads.
The rrecommended
ecommended over
tapping for nuts and interior thr
eads is as follows:
overtapping
threads
Bolt or Stud Size
Minimum Over
tapping of FemaleThr
eads.*
Overtapping
FemaleThreads.*
12 mm and smaller
Over 12 mm to 25 mm
Over 25 mm
0.4 mm
0.53 mm
0.79 mm
*Applies to both pitch and minor diameters, minimum and maximum limits.
On threads over 38 mm it is often more practical, if design strength allows, to have the male thread
cut 0.79 mm undersize before galvanizing , so a standard tap can be used on the nut.
On hinges all adjacent surfaces must be ground 0.8 mm on both pieces to allow for thickness increase
during galvanizing.
16
MOVING P
AR
TS
PAR
ARTS
When a galvanized assembly incorporates moving parts
(such as drop-handles, shackles and shafts), a radial
clearance of not less than 1.6 mm must be allowed to
ensure full freedom of movement after the addition of
zinc during galvanizing.
Designs should provide additional clearance for moving
parts to allow for the pickup of zinc during galvanizing.
It is recommended that, whenever possible, work be
designed so that hinges can be bolted to frames, covers,
bodies, and the like after galvanizing.
17
Where permanent identification is needed there are suitable alternatives for marking steel fabrications to be
hot dip galvanized. Each will enable items to be rapidly identified after galvanizing and at the assembly
site. The three marking alternatives are:
1 Fixing a deep stamped steel tag (minimum thick ness - 2.5 mm) to the fabrication by seal-welded
directly to the item to be galvanized.
2. Stamping the surface of the item using die cut deep
stencils or series of center punch marks. These marks
should be placed in a standard position on each of
the members. They should be a minimum of 12 mm
high and 0.80 mm deep to ensure readability after
galvanizing. This method should not be used to mark
fracture critical members.
WET ST
ORAGE ST
AIN PREVENTION
STORAGE
STAIN
When steel is freshly galvanized, the surface of the
zinc is succeptible to reaction with rainwater and dew
on prolonged exposure in poorly ventilated conditions.
The stable oxidising carbonate films that form on the
surface of the zinc require the presence of carbon
dioxide for their formation. Galvanized steel that is
stacked or nested in wet conditions will inhibit the
formation of these stable films.
Wet storage stain or `white rust' occurs under these
conditions. Considerable coating damage may occur
with prolonged exposure to wet, poorly ventilated
environments.
2. Heavy staining
Brush off bulky oxidation products with a wire brush
or stainless steel pot scourer. Treat the affected surface
with a solution of 5% sodium dichromate, 0.1%
sulphuric acid, brushing with a stiff nylon bristle brush
for 30 seconds before thorough rinsing of the surface.
If the surface has been dulled and still has sufficient
galvanized coating present; to restore a bright finish,
apply a small amount of aluminium paint to a cloth
pad and rub over the surface to blend the damaged
area with the adjoining galvanized coating.
3. Severe staining
If severe staining has occurred to the extent that most
of the galvanized coating has been removed, it is
desirable to treat the affected area as damaged. The
surface should be prepared by buffing or wire brushing
and repaired with a high quality two-pack epoxy zinc
rich paint, applied to the damaged area to a minimum
dry film coating thickness of 100 microns. If extensive
severe white storage staining has occurrs, regalvanizing
of the item may be required.
19
1. Initial adhesion
2. Long term adhesion
Initial adhesion of the paint system is achieved by use
of a recommended pretreatment primer or self priming
finish on an uncontaminated surface, which provides a
base for subsequent coatings.
Long term adhesion depends on compatibility of the
pretreatment primer or finish coats with the galvanized
coating. Use of incompatible paint systems, or direct
application of unsuitable finishes without the correct
primer or pretreatment will result in premature paint
failure.
Preparation of galvanized steel surfaces for painting
Polyester powder coating over hot dip galvanizing provides a high performance architectural finish that can stand up
to UV exposure and wear. Pedestrian railings like this have been in service for nearly 10 years without maintenance.
22
GALVANIZING GLOSSAR
Y
GLOSSARY
Acid pickling: Hydrochloric acid is used to remove rust and mill scale from steel prior to galvanizing.
Alloy layers: The hot dip galvanized coating consists of a series of alloy layers of zinc-iron alloys, coated with
a layer of zinc. The alloy layers enhance the abrasion resistance and allow thicker coating to be applied.
Ash: Zinc oxidation products formed from the molten zincs reaction to air and the flux on the steel surface float
on the baths surface and is skimmed off as zinc ash which can then be processed to recover zinc metal and
compounds.
Bare spots: Defects in the galvanized coating due to inadequate cleaning prior to galvanizing.
Beam work: Dipping beams are used in the galvanizing process to support items suspended from the beam from
hooks or wire to minimise the non-productive steel entering the bath .
Brush blasting: Light abrasive blasting to prepare galvanized surfaces for painting. Mild abrasives such as
illmenite are required at low nozzle pressures (40 psi) to prevent damage to the galvanizing.
Centrifuge work: Small parts are galvanized by spinning or centrifuging in a bucket to throw off excess zinc. Used
for fasteners, washers, chain, brackets and bolts.
Cathodic protection: Zinc is more electrochemically reactive than steel and will corrode preferentially of steel is
exposed through the galvanized coating through cutting or damage.
Caustic degreasing: All work to be galvanized is first treated in a hot caustic bath to remove grease, oil, some types
of paint and organic material so that the steel can be pickled . Acid will not remove rust and oxides if organic
contamination is present on the surface.
Chain work: Large, long or awkward items dipped by suspending them on chains are classified as chain work in the
galvanizing process.
Clockwise fr
om top: 1. Alloy layers are shown in this micrograph of a galvanized coating on high silicon steel. 2.
from
Ash forms on the surface of the galvanizing bath and is skimmed off periodically. 3. Bare spots occur when
pretreatment is inadequate or air locks prevent the molten zinc contacting the stee; the cause of this particular defect.
4. Chain work is work that is too large to fit onti jigs or beams and is handles through the galvanizing process on
chains as individual items.
23
GAL
VANIZING GLOSSAR
Y (CONT
.)
GALV
GLOSSARY
(CONT.)
Chromate treatment: After steel is galvanized, it is quenched in water containing a small amount of sodium
dichromate which passivates the new zinc surface and prevents early oxidation of the surface.
Coating thickness: The hot dip galvanized coating thickness is determined by the metallurgy , surface condition
and section thickness of the steel. Australian Standard AS1650-1989 defines minimum coating thickness
standards for hot dip galvanizing.
Continuous galvanizing: Sheet, wire and some tube sections are continuously galvanized. The coating formed is
relatively thin and soft.
Corrosion rate: The corrosion rate of galvanized coatings is predictable so the life of the coating can be accurately
estimated in any known environment.
Double-dipping: Long or wide fabrications or sections can be galvanized by dipping each end or side sequentially.
Dross: Steel reacting with the zinc in the galvanizing bath forms dross which is a zinc-iron crystal that is heavier
than zinc and has a higher melting point. Dross must be periodically removed from the bottom of the galvanizing
bath to maintain operating depth.
Draining: All items to be galvanized must allow zinc to flow off or out of the items during galvanizing.
Duplex coating: When galvanized coatings are painted, duplex coating systems are formed which have durability
higher than that of the sum of the coatings used separately.
Electroplating: Thin zinc coating are applied by electroplating. Used for coating small parts and fasteners with
a smooth, bright coating but are unsuitable for exterior exposure.
Embrittlement: Embrittlement can be induced in some steel items during galvanizing due to excessive cold
working (strain ageing) or acid pickling (hydrogen embrittlement) of high strength steel.
24
GAL
VANIZING GLOSSAR
Y (CONT
.)
GALV
GLOSSARY
(CONT.)
Etch primers: Some galvanized coating primers
contain acid etching components to condition the zinc
surface for painting. These primers require careful
application to be successful.
Fluxing: Prior to entering the galvanizing bath and
after caustic degreasing and acid pickling, steel is
fluxed in a hot zinc ammonium chloride solution to
condition the surface for galvanizing.
Galvanizing: Coating steel by immersing it in molten
zinc either as a batch or continuous process.
Grey coatings: Certain types of steel can produce
dull grey galvanized coating. These coatings have no
free zinc on their surface and tend to be thicker and
less impact resistant than shiny coatings.
Hardness of galvanized coatings: The zinc
component of the galvanized coating is about half the
hardness of 250 grade steel. The alloy layers in a hot
dip coating are about twice as hard as 250 grade
steel.
Hydrogen embrittlement: Steel over 1000 mPa
yield strength may be prone to embrittlement from
hydrogen entering the steel crystals from acid
pickling.
Inclusions: Hot dip galvanized coatings may have
inclusions in the coating formed by dross crystals
floating in the molten zinc. They have no effect on the
coatings durability.
Jig: A steel frame which supports work during the
galvanizing process. Special jigs are designed for
specific products to optimise quality and productivity.
Magnetic testing: Galvanized coating thickness is
measured by magnetic flux instruments which
measure the distance from the surface of the coating
to the surface of the steel.
Metallising: Zinc wire or powder is melted in an oxyacetylene flame and sprayed onto a Class 3 Blast
steel surface. Metallising is a recommended repair
method for large damaged or uncoated areas of a
galvanized item.
Moving parts: The hot dip galvanized coating
thickness on small parts is typically around 100
microns. Clearances on moving parts should
accommodate this thickness on both surfaces plus an
allowance for irregularities in the coating.
Normalising: The galvanizing temperature (455
455
degrees C
C) is not high enough to effect the strength or
temper of steel but will have stress relieving effect in
welded items.
Passivation: Galvanizing is passivated by quenching
in a weak sodium dichromate solution to prevent
early oxidation of the zinc surface if exposed to dew
or rainwater.
25
GAL
VANIZING GLOSSAR
Y (CONT
.)
GALV
GLOSSARY
(CONT.)
Phosphorous: Steels containing high levels of
phosphorous (in conjunction with silicon) are very
reactive with molten zinc and will form thick, grey
coatings.
Powder coating: Polyester powder coating over
galvanizing is done by phosphate pretreating the
galvanizing then electrostatically applying polyester
powder and then fusing it in an oven.
Repairs: Damage to galvanized coatings can be
repaired with recommended zinc rich paint touch up
systems , with zinc repair sticks or by zinc metal
spraying.
Runs: When molten zinc drains off items as the work
emerges from the zinc bath, the zinc may freeze on the
surface to form runs or drainage spikes.
Silicon steel: Some steels with high levels of silicon are
very reactive with molten zinc and can form very thick
coating many times thicker than a standard coating.
The coatings thus formed are duller and more
susceptible to mechanical damage but will provide
extremely long service life.
Strain ageing: Severely cold-worked steel may
become brittle during galvanizing as a result of the heat
of the process accelerating the stress effects of the cold
work.
Venting: All hollow section must be correctly vented
to allow air and steam to escape during immersion in
the molten zinc. Items must allow zinc to flow in and air
to flow out to ensure that the item will sink in the zinc
and that molten zinc can contact all surfaces during
immersion.
Welding: Welding of galvanized steel requires correct
ventilation and the use of correct welding electrodes
and techniques.
White rust or wet storage stain: When steel is
freshly galvanized, the zinc is free of any protective
oxide film. If pure water (dew or rain) is in prolonged
contact with the zinc in this condition, the zinc will
react with the water to for zinc hydroxide; a bulky white
oxide deposit. Passivation after galvanizing along with
good ventilation and drainage will prevent white
storage staining.
Zinc carbonate film: This oxide film provides zincs
excellent atmospheric corrosion resistance and as this
coating thickens with weathering, the galvanizing
develops its characteristic soft grey appearance.
26
GENERAL INFORMA
TION ON GAL
VANIZED COA
TINGS
INFORMATION
GALV
COATINGS
This information has been pr
ovided to assist in the selection of zinc coated pr
oducts and materials for
provided
products
use in conjunction with hot dip galvanized pr
oducts.
products.
COA
TING CHARACTERISTICS OF GAL
VANIZED COA
TINGS.
COATING
GALV
COATINGS.
GAL
VANIZED COA
TING METHODS
GALV
COATING
There are a number of methods of applying zinc coatings and each will determine the coating s thickness
and its ultimate durabilty in a specific environments
2. MECHANICAL PLA
TING involves tumbling the
PLATING
items to be coated in zinc powder with glass beads and
special reducing agents to bond the zinc particles to the
steel surface.
1. Zinc electr
oplating
electroplating
2. Mechanical plating
3. Sherardising
4. Continuously galvanized sheet
5. Continuously galvanized wir
wiree
6. Galvanized pipe and tube
7. General or hot dip galvanizing
8. Zinc metal spraying
GAL
VANIZED COA
TING METHODS (CONT
.)
GALV
COATING
(CONT.)
6. GAL
VANIZED PIPE AND TUBE is produced by
GALV
two methods; one is semi-continuous where stock
lengths of tube are cleaned and passed continuously
ee
through a bath of molten zinc at 450 degr
degree
ees centigrade.
The other method is continuous where strip is formed
into tube from coil and the tube then passed through a
ees centigrade. This
bath of molten zinc at 450 degr
degrees
second method coats the exterior of the tube only.
Coating characteristics: The semi-continuously
applied coating is a conventional galvanized coating
ons
having a coating thickness typically around 65 micr
microns
which consists largely of zinc-iron alloy layers as the
free zinc layer is largely removed through air wiping
during the process. The continuous tube galvanizing
process produces a bright coating which is almost all
free zinc with very thin aloy layers, giving the product
good forming properties. Coating thickness is typically
12-25 micr
ons on the exterior of the tube only.
microns
30
FRICTION-GRIP BOL
TING GAL
VANIZED STEEL
BOLTING
GALV
These are:
1. Buffing the connecting surfaces during final
inspection to roughen the surfaces.
2. Galvanizing at higher temperature or deferring
quenching to produce fully alloyed `grey' coatings.
Steel metallurgy and section thickness will impact
on the effectiveness of this technique.
A large number of structures such as this have been been friction grip bolted satisfactorily after galvanizing.
Controlled galvanizing techniques combined with post galvanizing treatment of the connecting surfaces by
the galvanizer ensures that coefficients of friction in excess of 0.35 are obtained at the galvanized connections.
31
CORROSION RA
TES OF GAL
VANIZED COA
TINGS
RATES
GALV
COATINGS
In most environments, the corrosion rate of of
galvanized (and zinc) coatings is proportional to its
thickness.
When selecting components to be used in conjunction
with hot dip galvanized coatings, it is essential to
ensure that their coating thickness is equivalent to that
of hot dip galvanizing.
All pre-galvanized products have much thinner zinc
coatings than their hot dip galvanized equivalents. The
following basic rules should be applied:
1. Do NOT use zinc plated fasteners for heavy duty
applications.
2 Specify hot dip galvanized purlins and girts in hot
dip galvanized structures. Z300 galvanized coatings
on roll-formed structural sections are typically only
20 microns in thickness and have exposed steel at
cut edges. Coating life is typically 20% that of
equivalent section hot dip galvanized products.
3. Do NOT use continuously coated tube and sections
for heavy duty applications. These coatings are
typically 12 - 25 microns in thickness and the hollow
sections are not internally coated.
GAL
VANIZED COA
TING CORROSION RA
TES IN A
TMOSPHERIC ENVIRONMENTS
GALV
COATING
RATES
ATMOSPHERIC
Atmospheric Environment
Rural - dry, 600 mm annual rainfall or lower Residential - non-industrial, over 600 mm annual rainfall Tropical - over 1000 mm annual rainfall, high average humidity Industrial - External Industrial - Internal (fumes, vapour, steam) Coastal - 100 to 500 metres from ocean surf Marine - oceanfront / surfside -
32
1-2 microns
2-3 microns
5-8 microns
3-5 microns
5-8 microns
5-8 microns
8-15 microns
SURF
ACE AREA T
ABLES
SURFACE
TABLES
While hot dip galvanizing is usually priced in dollars per tonne, it is desirable to also convert this to
dollars per square metre to allow comparison with alternative coatings.
In addition, the conversion to square metres allows accurate estimation of weight increase through
the addition of the hot dip galvanized coating. The surface area per tonne can also be calculated
using the following formula:
Surface ar
ea per tonne
area
________ 255________
Section thickness in mm
Mass per square metre of steel can be calculated using the following formula:
Mass per squar
squaree metr
metree (kg/m2)
Section
thickness
mm
Mass/m 2
kg/m2
1 mm
2 mm
3 mm
4 mm
5 mm
6 mm
8 mm
10 mm
12 mm
15 mm
20 mm
25 mm
Surface ar
ea/tonne
area/tonne
m2/tonne
255
127
64
85
51
42
32
25
21
17
13
10
7.85
15.70
23.55
31.40
39.25
47.10
62.80
78.50
94.20
1117.75
17.75
157.00
196.25
Mass incr
ease
increase
%**
45 micr
ons (320 g/m2)
microns
55 micr
ons (390 g/m2)
microns
55 micr
ons (390 g/m2)
microns
70 micr
ons (500 g/m2)
microns
70 micr
ons (500 g/m2)
microns
70 micr
ons (500 g/m2)
microns
85 micr
ons (600 g/m2)
microns
85 micr
ons (600 g/m2)
microns
85 micr
ons (600 g/m2)
microns
85 micr
ons (600 g/m2)
microns
85 micr
ons (600 g/m2)
microns
85 micr
ons (600 g/m2)
microns
4.10%
2.85%
1.65%.
1.59%
1.25%.
1.05%
0.95%
0.75%.
0.65%
0.50%
0.40%
0.30%
* Hot rolled steel sections and heavier steel sections will generate galvanized coatings considerably
thicker than required by the AS 1650 Standard. To convert coating thickness in microns to equivalent
coating mass in grams per square metre (g/m2), use the following formula:
Coating mass (g/m2)
Coating thickness (micr
ons)
(microns)
=
=
** Actual zinc pickup after galvanizing will depend on average coating thickness and section design.
Poor drainage, zinc entrapment and large horizontal surfaces will result in higher zinc pickup.
NOTE: Actual zinc usage in hot dip galvanizing is significantly higher than physical zinc pickup.
Zinc usage in hot dip galvanizing is typically 5-7% of the mass of steel dipped because of zinc consumed
on jigs and in generating zinc ash and zinc dross in the galvanizing process.
33
INSPECTION OF GAL
VANIZED PRODUCTS
GALV
Australian Standard AS1650, Section 1.6 - Appearance (Page 5) defines the requirement for hot dip galvanized
coatings as follows:
The galvanized coating shall be continuous, as smooth and evenly distributed as possible, and free from defects that are detrimental
to the stated use of the coated article. Methods recommended for the renovation of damaged galvanized coatings or uncoated
areas are given in Appendix F (of AS 1650).
Notes:
1.
Defects cannot be completely quantified. When the presence, size or frequency of any defects in the coating are considered
manufacturer.This
to be of concern, appropriate arrangements should be made between the purchaser and the manufacturer
.This may be
achieved by the provision of acceptable samples or methods of test.
Where defects are present and the product is submitted for acceptance, the manufacturer should be able to demonstrate
fitness for purpose.
thicker,, less smooth coating is obtained on job galvanized articles compared with continuously galvanized sheet or wire.
2.
A thicker
3.
(Not applicable to general hot dip galvanized products)
4.
The finish of the coated object may be partly or wholly grey in colour for steels of certain composition or articles that are
slowly cooled after galvanizing. Provided that such a coating has adequate adhesion, the grey finish is not detrimental,
although premature staining may occur in service.
5.
Advice on the transport and storage of galvanized articles is given in Appendix G (of AS 1650)
GAL
VANIZED COA
TING APPEARANCE
GALV
COATING
AND DEFECTS
There are a number of common types of defects arising
from the hot dip galvanizing process. An explanation
of the causes of defects and variations in appearance
follows:
1. Ungalvanized weld ar
eas. Coating misses on weld
areas.
areas are caused by the presence of welding slag on the
welds. All welding slag must be removed by the
fabricator prior to despatch to the galvanizer. These
areas require repair.
INSPECTION OF GAL
VANIZED PRODUCTS (CONT
.)
GALV
(CONT.)
3. Dull gray or mottled coatings. Reactive steels will
generate thicker galvanized coatings that are duller than
standard coatings. These coatings have longer life
because of their greater thickness and their appearance
is a function of steel metallurgy and generally beyond
the control of the galvanizer.
4. Dr
oss pimples/inclusions. Dross is formed in the
Dross
galvanizing process in the form or zinc-iron crystals
on
(approx 95% zinc - 5% ir
iron
on) with a higher melting
point that the metal in the zinc bath. Dross trapped in
the galvanized coating may give the coating a rough or
gritty appearance. The presence of dross inclusions in
the coatings is not detrimetal to the coating's
performance as the corrosion resistance of zinc dross
is identical to that of the galvanized coating
5. White storage staining. After galvanizing, items
stored or stacked in wet, poorly ventilated conditions
will react with atmospheric moisture to form bulky
white zinc hydroxide deposits on the surface of the
galvanized coating.
35
INDUSTRIAL GAL
VANIZERS CAP
ABILITIES
GALV
CAPABILITIES
The galvanizing plants within the Industrial Galvanizers
Group galvanizers a wide variety of fabricated
steelwork. These examples illustrate the capabilities
within the group.
37
GAL
VANIC CORROSION
GALV
While hot dip galvanized coatings provide envelope
protection for steel, the zinc in the coating will also
protect the steel cathodically if the coating is
damaged and the bare steel exposed.
GENERAL INFORMA
TION ABOUT ZINC AND STEEL
INFORMATION
Steel
Zinc
Atomic weight
olled
Density
- rrolled
- cast
- liquid
Melting point
Boiling point
Thermal conductivity
65.37
7192 kg/m3
6804 kg/m3
6620 kg/m3
419.5oC
907oC
113 W/m.K
38
Atomic weight
55.85
Density
7850 kg/m3
Melting point
1540 oC
Boiling point
2900 oC
Thermal conductivity 57 W/m.K
Australia
AS 1650
AS 1214
AS 1250
AS 1394
AS 1074
AS 1397
Standards
AS 2312
AS 2331.1.3
British
American
A90
A123
A143
A153
A325
A384
A385
A394
A780
B6
E376
Canadian
G164-M
Standards
Society
for
Testing
and
Material
Association
39