Escolar Documentos
Profissional Documentos
Cultura Documentos
Hydrocarbon Conversion
Reactors to Control Pressure
Drop Increases
Dr. Ken J. Mills, Dr. Thomas Szymanski,
Saint-Gobain NorPro
Mohammed Q Raza,
National Methanol Company, Ibn Sina
Agenda
Introduction
Causes of pressure drop increase
Costs of pressure drop rise
Avoidance of pressure drop increase
MacroTrap guard bed media
An example at Ibn Sina
Compagnie de Saint-Gobain
Saint-Gobain NorPro
Graded Denstone
support media
Feed
Feed
Main catalyst
(supplied by
others)
Main catalyst
(supplied by
others)
Denstone
support media
Denstone deltaP
support media
Agenda
Introduction
Causes of pressure drop increase
Costs of pressure drop rise
Avoidance of pressure drop increase
MacroTrap guard bed media
An example at Ibn Sina
Compagnie de Saint-Gobain
Saint-Gobain NorPro
Agenda
Introduction
Causes of pressure drop increase
Costs of pressure drop rise
Avoidance of pressure drop increase
MacroTrap guard bed media
An example at Ibn Sina
Compagnie de Saint-Gobain
Saint-Gobain NorPro
Agenda
Introduction
Causes of pressure drop increase
Costs of pressure drop rise
Avoidance of pressure drop increase
MacroTrap guard bed media
An example at Ibn Sina
Compagnie de Saint-Gobain
Saint-Gobain NorPro
Avoidance
Drop Increase
Measure
Particulate deposition
Install macroporous guard bed
material
Iron sulfide gum deposition
Catalyst / absorbent breakage
Stronger, more robust materials
Bed support breakage
Agenda
Introduction
Causes of pressure drop increase
Costs of pressure drop rise
Avoidance of pressure drop increase
MacroTrap guard bed media
An example at Ibn Sina
Compagnie de Saint-Gobain
Saint-Gobain NorPro
Agenda
Introduction
Causes of pressure drop increase
Costs of pressure drop rise
Avoidance of pressure drop increase
MacroTrap guard bed media
An example at Ibn Sina
Compagnie de Saint-Gobain
Saint-Gobain NorPro
100
90
80
70
60
50
40
30
20
10
0
.001
.01
.1
10
100
1000
Composition
C1/C2 = 75 / 25%
C4, C5 up to 1%
6 10ppm sulfur
compounds
Contaminants
Rust (tramp iron)
Carbon dust
Heavy hydrocarbons
Guard bed
10mm MacroTrap media
rings (directly on top of the
catalyst bed)
Catalyst
Commercial
hydrodesulfurization
catalyst
7X magnification
2008670062
2008670063
2008670076
Location
Al203
Top of Layer
93
Bottom of Layer
94
Unused Rings
97
CaO
Fe2O3
K2O
SiO2
TiO2
0.1
3.6
0.1
2.8
0.1
0.1
2.8
0.1
2.8
0.1
0.1
0.1
0.1
2.8
0.1
Intensity
Fe
Al
Edge
Center
Agenda
Introduction
Causes of pressure drop increase
Costs of pressure drop rise
Avoidance of pressure drop increase
MacroTrap guard bed media
An example at Ibn Sina
Compagnie de Saint-Gobain
Saint-Gobain NorPro
Chemistry
Proper raw material selection critical for superior physical
performance
Chemistry engineered to maximize matrix strength and chemical
resistance
Microstructure
Engineered microporosity allows resistance to rapid
depressurization and increases thermal shock resistance
Agenda
Introduction
Causes of pressure drop increase
Costs of pressure drop rise
Avoidance of pressure drop increase
MacroTrap guard bed media
An example at Ibn Sina
Compagnie de Saint-Gobain
Saint-Gobain NorPro
30.0
25.0
20.0
15.0
10.0
5.0
0.0
500
700
900
1100
1300
1500
1700
Preferred Denstone
Brand Ceramic
Support Media
Process
Petroleum Refining
Hydrocracking
2000 / deltaP
Hydrotreating
Preferred Denstone
Brand Ceramic
Support Media
Ammonia Plants
Desulfurizers
99 / deltaP
57 / 2000 / deltaP
Secondary Reformers
99 / deltaP
Hydrogenation
57 / 2000 / deltaP
Low-Temperature Shift
99 / deltaP
Reforming
57 / 2000 / deltaP
High-Temperature Shift
99 / deltaP
Methanator
99 / deltaP
Isomerization
Claus Reactors
57 / deltaP
57 / 2000 / deltaP
Petrochemical
Dryers
2000 / 57 / deltaP
Hydrocracking
57 / 2000 / deltaP
LPG Treaters
57 / 2000 / deltaP
Hydrotreating
57 / 2000 / deltaP
LNG Prepurifiers
57 / 2000 / deltaP
Oxidation
57 / 2000 / deltaP
Claus Reactors
57 / 2000 / deltaP
Absorbers
57 / 2000 / deltaP
Desulfurizers
57 / 2000 / deltaP
Molecular Sieve
57 / 2000 / deltaP
Separations
99 / deltaP
Polymerization
99 / deltaP
Acid Plants
Separations
57 / 2000 / deltaP
Industrial Gases
Dryers
57 / 2000 / deltaP
Agenda
Introduction
Causes of pressure drop increase
Costs of pressure drop rise
Avoidance of pressure drop increase
MacroTrap guard bed media
An example at Ibn Sina
Compagnie de Saint-Gobain
Saint-Gobain NorPro
Agenda
Introduction
Causes of pressure drop increase
Costs of pressure drop rise
Avoidance of pressure drop increase
MacroTrap guard bed media
An example at Ibn Sina
Compagnie de Saint-Gobain
Saint-Gobain NorPro
rings 52%
spheres 40%
Dense media
for efficient
hold-down
Low cost,
low activity,
non-porous
ceramic
formulation
Sizes
available
55 lb/ft3 / 885
kg/m3
Non-reactive
composition
10mm (3/8)
13mm (1/2)
19mm (3/4)
25mm (1)
Cost
% of Total
Cost
$6,494
0.4%
$61,341
3.9%
5.0%
Main Catalyst - 54
$1,495,646
95.0%
$11,052
0.7%
Agenda
Introduction
Causes of pressure drop increase
Costs of pressure drop rise
Avoidance of pressure drop increase
MacroTrap guard bed media
An example at Ibn Sina
Compagnie de Saint-Gobain
Saint-Gobain NorPro
Construction
Products
$16.4BN
Building
Distribution
$28.8BN
2007 Sales:
43.4BN; $64.2BN
>200,000 employees
North America Sales
$8.6BN
Packaging
$5.2BN
Ceramics
Grains
& Powders
Abrasives
Plastics
Textile
solutions
Agenda
Introduction
Causes of pressure drop increase
Costs of pressure drop rise
Avoidance of pressure drop increase
MacroTrap guard bed media
An example at Ibn Sina
Compagnie de Saint-Gobain
Saint-Gobain NorPro
Saint-Gobain NorPro
Technology driven ceramic solutions for
hydrocarbon processing industries
Catalytic Products
Proppants
Process Ceramics
Guanghan, China
Fort Smith, AR
Daisy, TN
Dubai, UAE
Caracas & Puerto
Bryan, TX
Plant
HQ
Ordaz, Venezuela
Beijing, China
Thank You!