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An electrochemical cell
anode
(oxidation)
cathode
(reduction)
Zn Zn2+ Cu2+ Cu
E < 0 (negative)
G > 0 (positive)
[products]
RT
ln
nF
[reactants]
Half-Reaction
E (volts)
0.15
Sn4+(aq) + 2e- = Sn2+(aq)
0.16
Cu2+(aq) + e- = Cu+(aq)
2+
Cu (aq) + 2e = Cu(s)
0.34
0.52
Cu+(aq) + e- = Cu(s)
I2(s) + 2e- = 2I-(aq)
0.54
O2(g) + 2H+(aq) + 2e- =
H2O2(aq)
0.70
0.77
Fe3+(aq) + e- = Fe2+(aq)
+
Ag (aq) + e = Ag(s)
0.80
NO3-(aq) + 4H+(aq) + 3e- =
NO(g) + 2 H2O(liq)
0.96
1.07
Br2(liq) + 2e- = 2 Br-(aq)
O2(g) + 4 H+(aq)+ 4e- = 2 H2O(liq)1.23
Cr2O72-(aq) + 14 H+(aq) + 6e- =
2 Cr3+(aq) + 7 H2O(liq)
1.33
1.36
Cl2(g) + 2e- = 2 Cl-(aq)
Ce4+(aq) + e- = Ce3+(aq)
1.44
MnO4-(aq) + 8 H+(aq) + 5e- =
Mn2+(aq) + 4 H2O(liq)
1.51
H2O2(aq) + 2 H+(aq) + 2e- =
2 H2O(liq)
1.78
1.82
Co3+(aq) + e- = Co2+(aq)
F2(g) + 2e- = 2 F-(aq)
2.87
Most oxidizing
Most reducing
Half-Reaction
E (volts)
Li+(aq) + e- = Li(s)
-3.04
-2.92
K+(aq) + e- = K(s)
2+
Ca (aq) + 2e = Ca(s)
-2.76
-2.71
Na+(aq) + e- = Na(s)
Mg2+(aq) + 2e- = Mg(s)
-2.38
-1.66
Al3+(aq) + 3e- = Al(s)
2 H2O(liq) + 2e- =
-0.83
H2(g) + 2 OH-(aq)
2+
Zn (aq) + 2e = Zn(s)
-0.76
-0.74
Cr3+(aq) + 3e- = Cr(s)
Fe2+(aq) + 2e- = Fe(s)
-0.41
-0.40
Cd2+(aq) + 2e- = Cd(s)
Ni2+(aq) + 2e- = Ni(s)
-0.23
+
0.00
2 H (aq) + 2e = H2(g)
Most oxidizing
Most reducing
A+ + e- = A
B + e- = B-
more oxidizing
The reduction potential for A+/A will be less positive than that for B/B-
The sum of the oxidation states for all atoms in a species must
equal the charge on the species.
Acidic solution
Acidic solution
Basic solution
Acidic solution
MnO4- + 8 H+ + 5 e- = Mn2+ + 4 H2O
E = 1.49
Basic solution
MnO4- + 4 H+ + 3 e- = MnO2 + 2 H2O
E = 0.59
Acidic solution
HClO2 + 2 e- + 2 H+ = HClO + H2O
E = 1.674
E = -1.181
E = 0.493