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Second PUC Chemistry March, 2014 Question

Paper
SubSect Code
: 34 {NS)
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Englteh Verslan

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co

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Ao -3- /q

2ot

',,Instnrc.hons .'.

1(

,i} The question paper

.:

faur' Parts, All parts

g.

cornpulsory.
3

are

t.

Part.B carries

l0 mafks.

lo

Part A carries l0 marks. Each question carrles one mark.

Eaeh qugstton carrtes troo marks.

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Pa-rt C carries 15 marks. Each quesflopr carries three

marks. Feirt D carries 35 marks. Each question carries..ftue
marKs.
3

il

wherever necessary.

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tv)

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Use log tables and the simple calculator if necessary.

-

,,

:i

'

.p

ed

t Llse of scientiftc catrculators'is. not atlowed )'

I.

.Answer all the questions. Each question

es one mark.

Arrswer each question in one word or in one sentence ) .

2..

Mention 'the enthalpy of mixing (

A mrx

1Ox1=1O

H ) vdlue to form an

solution.

Itt

Wtrat. is a secondary cell ?

4,

For the reaction ZHI--+ H z 4.'l r, Write,itq molecularity.

lnlitll$*l{u,ilffiilfl ffi ffi t}ffi ffi tlfi

l
L

j
1

balanced chemical equations and draw diagrams

iil) Write

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Subject Code : 34 (NS)
t'

Write the catalyst used in the decomposition of potassium chlorate to

get potassium chloride and oxygen.

6.

Name the refining method used to produce semiconductors-

7.

Give a,reason for chemical inertness of Noble gases.

8.

H aC

g.

- F + AgBr. Name the reaction,

H rC

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- Br + AgF +

co

5.

Mention the hybridised state of caqbonyl carbon atom.

9.
:

which is the nitrogenous base present only in RNA. but not in DNA ?

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ib

10.

Answer anylftue of the following. Each question carries tu.ro marks.

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IL

-B

PART

Sx2=lO

ed

I t. Aluminium c,rystallises in an..i[cc structure: Atomic radius of the metal

is 125 pm. calculate the edge length of unit cell of the metal.
l

.p

t2. what is molar conductivity ? How is it'related to the conductMty of q

solution whose concentration is C mol m - 3 ?

13. Define collision frequency. Give an example for Pseudo-first order

reacUon.

14. what is I.anthanoid contraction

15.

? Mention one of its consequences.

Complete the following reactions

i) R-CH2-oH a-Z?n-'

ill

ililrilIililil ilI

Iffi ilfl

ililtffillililll]t lilIilil

teireqqul

.::.....

Pag'e lO

qf l5

1r

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Subject Code : Ba NS)

'

example.

co

L7. What are food preservatives ? Give an

16. ExpfAin Rosenmund's reduction of 'benzoyl chloride.

PART
any

fiue of the following. Each question carrie s ttvee marks.

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Answer

bx3= l5

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III.

-C

lo

g.

r8. Mention a drug which can act, both, as an analgesic as well as an

antipyretic. Narne an artificial sweetening agent.

r9. Draw labelled diagram of Hall-Heroult Elctrolytic cell for

the

extraction of aluminium. write anode and cathode reactions.

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20- For the manufacture of Ammonia by Haber's process. write the

ed

equation and optimum conditions for malcmum yield of ammonia.

2L. Write the equations for

the action of so 2 with chlorine in the presence of charcoal

.p

i)

the action of SO g with concentrated sulphuric acid

rii)

the action of ozone- with lead sulphide.

Complete the following equations

22.

ii)

( cold
u,

and dilyte

2FeSO4+HzSO++Clr-+

ru,

ilt

Iilil Iililil[l

ilflililfl ilfl lllililfl ffit ililItil

t9"igs--_qLl

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Subject Code : 34 (NS)

23. Explain the manufacture

g.

24. With reference to the first row transition series

co

of potassium dichromate from chr:omite ore

lo

name the metal which possesses maximum number of oxidation

I

ii)

among Zn+ 2 and Cu

+2

uI.,

between Tl2 + and V2 +, which ion contains more number of

ib

states.

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which is colourless

nl,

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25. Using Valence Bond theory, account for tLre geometry and magnetic
-.
property of rui ( CN 1

( Given

Atomic number of Ni = 28
-vt

.p

26, Give the IUPAC name

. isomers of

IV.

o, ( Nns

or:[ti(*ro)p lt*

Draw cis and trans

) zctz]

DART
r ____

Arrswer any three of the following. Each question carries../ftue marks.

. 27. a
b)

gxb= l5

Calculate the packihg efficiencyrin simple cubic lattice,

,3

What is l'renkel defect ? Give ayr example.

\.

[ltfltffi flili[fffiffi

ilfiruffi ffi u ll ]t

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Subiect pode : 34
a)

on dissolving 2.34 g ,of solute in

4o g of ,benzene, the boiling

2r8.

(NS)

- I. calculate the molar

mass

g.

value for benzene is'2.53 K kg mol

co

point of'solution was higher than that of benzene by o.gl K, Ku

of the solute.

a)

Draw labelled diagram of Standard Hydrogen Electrode ( SHE

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State Henry's law. Write its mathematical

ib

29.

Write its half cell reaction and Eo

ik

Calculate ArGO for the following reaction

o"l;)

* Aslont

3
:

o"ijn, * A("ri.,

.E3ru = + 0.03 V,-'F = 96'500, C ).

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( Given :
.l

The rate of a particular reaction doublgs when the temperature

ed

a)

value.

).

b)

30.

form.

b)

changes from 3oo K to. Blo I(. calculate the energy of activation

.p

of the reaction.

I Given : R = 8.314 JK-

I mol-1

b) show that the half-life

].

per'iod of

a first order reaction

independent of initial concentration of reacting rspecies.

3I.

a)

Give any three

i)

differ.ences between physisorption and

chemisorption.
b)

is

Mentlon the role -bf alum in the,purification of drinking

watei.

u,

Give an example for oil dispersed in water

rill[lillll{ffiil1lilll!t lllilillililililffiiltIItil

emulsion.
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Subject.Code,: 34 {NS)

{qpwer

an}r

jbur,of the following, Each.quesqo*,carriSs-fiue marks.

V.

,:

32. a) i)

co

4x5=2iO

write the equations for the steps rn s

Nl mechanism of the

g.

conversion of tert.but}rl.bromide into tert.butyl alcohol.

ii) Haloarenes are l""q

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reactwe., toward-s : nucleophtlic

substituuon reactions than Haloalkanes. Give a reason. S

Explain the preparation of 'phenol,

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33, a)

ii) rClt"!*r."@
ri)

f,rom. Cumer

r-e.

,.....,

ed

OH

.p

o+zn4

E4plain Willtamson's ether sylrthesls,

a)

i)

Hsw do you convert benzoic ."idll to henzamide ? Writerthe

reaction.

ii)

Complete the reaction

b)

34.

()
a

Anhydrous AICI3I HCI

b)

ilHtil+{fr{

what happens when carbonyl compounds are treated with

tffiffiffillm

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co

;,,w:

he'

:. ':.:..,, ,

,,,

::,.H:

lo

Hs,.c:,,y,

g.

,,,

ald

C oH

.p

ed

ia

ik

ib

CH oNH z

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