Escolar Documentos
Profissional Documentos
Cultura Documentos
e
Document Name: ASTM D976: Standard Test Method for Calculated
Cetane Index of Distillate Fuels
CFR Section(s):
40 CFR 92.113
Standards Body:
Official Incorporator:
THE EXECUTIVE DIRECTOR
~~l~
Designation: 364/84
These test methods have been approved by the sponsoring committees and accepted by the cooperating societies in accordance with
established procedures.
This standard has been approved for use by agencies of the Department of Defense. Consult the DoD Index of Specifications and
Standards for the specific year of issue which has been adopted by the Department of Defense.
'1
1. Scope
1.1 The Calculated Cetane Index formula represents a
means for directly estimating the ASTM cetane number of
distillate fuels from API gravity and mid-boiling point. The
index value, as computed from the formula, is termed the
Calculated Cetane Index. 2
1.2 The Calculated Cetane Index is not an optional
method for expressing ASTM cetane number. It is a supplementary tool for predicting cetane number when used with
due regard for its limitations.
1.3 The Calculated Cetane Index formula is particularly
applicable to straight-run fuels, catalytically cracked stocks,
and blends of the two.
1.4 This standard does not purport to address all of the
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
NOTE I-This test method is temporarily retained because the
proposal to the U.S. EPA to control diesel fuel aromatics concentrations
via a 40 Calculated Cetane Index minimum is based on the correlation
between Test Method D 976 and aromatics concentration. Test Method
D 4737 is the preferred method as estimator of cetane number. Test
method D 976 is intended to be letter balloted for withdrawal from the
book of standards in 1993.
2. Referenced Documents
363
+ 774.74 D2
-0.554 B + 97.803 (log B)2.
where:
G = API gravity, determined by Test Method D 287 or
D 1298,
M = mid-boiling temperature, OF, determined by Test Method
D 86 and corrected to standard barometric pressure,
D = density at lSoC, g/mL, determined by Test Method
D 1298, and
4
4~ 0.976
CALCULATED CETANE INDEX
49
Based on Equation:
2
Calculated CI ~-420.34 + 0.016 G + 0.192 G log M
+ 65.01 (log M)2 - 0.0001809 M2
29 0"
/
0.79
47
//280
hIlO.,.PT.;$TE"'~
RAIoIGE
rn=-4iO
410-446
o.So
45
;/
/
1.t5
51 B- 55~
5S~ - ''0
590-626
626-662
65
'"
::~~
446-482
482-:518
/
/1.'
1.19
1.24
L28
1.32
1.37
662-698
CD
': 60
0.81
43
/
/
~I
55
/
' 0.82
41
"
O~
5U61111ClO
S UOVt 760
BtLO'ol";
roft
.. 119
""
""
,,:xl ,
I'<
50 Hsa
,-
i><
Eo<
H
39
~ .,
~
H
I><
...:
0.84
37
,," "
'"Z
H
.1'<
<=l / '"
35
0.85/
/
33
""
"0.86
31
0,.87
/ ,".
"
""
"
""
"
"
40
'"~
"
30 ~'
35
'"
20 ~
.
30
z
:;
" :E
00
0.88
29
',{
0.89
27
",,')
..
'0.90
~p.
0.91
23:
I,
EXAMPLE:
I'F
70~ tiM H~
(FO~~)
-:48.52
,:
-'
NOTE-The Ca:lcUI~ted Cet~ne Index equation rep;~sents a useful tool for estimating cetane number. Due to inherent limitations in its lapplication, index vaiues may not
be a valid substitute for ASTM Cetane Numbers as determined in :'a' test engine.
,/
, " ,'
,' . ,
'
. ' ,. ,
"" r
, 'FIG. 1
5. Limitations of Equation
:5.1. "The,~alculated Ceta,ne Index equatiQn possesses certain inherent limitations which must be recognized in its
application. These are:
5.1. 1,.iltis',hot applicable to fuels containing additives for
I'aisi:b.g cetatie number." . ;.
'"
..' .
.'
. 5.1.2, It is nota,pplicable to pure hydroCl;\fbo:Qs; syp,thetic
fuels, such as'certain produGts derived from shale oils and tar
sands,alkylates, Q1' cdal.:tar Pfoducts., , ; " ' d " , r ;1,", i
5.1. 3 S~Qstantia1 inaccuracies in correlation mai,Qccur jf
used for crude oils, residuals, orprodutts'having a volatility
of below 500Fend point.
:
6 Copies of the Nomograph for Calculated Cetane Index,8'h QY 'H in.)n size,
are available at a nominal cost from ASTM, 1916 Race St., Philadelphia, Pa.
19103. Request Adjunct No. 12-409760-12.
7 Annual Book ofASTM Standards. Vol 05.04.
364
~t 0976
6. Precision
The American Society for Testing and Materials takes no position respecting the validity of any patent rights asserted in connection
with any item mentioned in this standard. Users of this standard are expressly advised that determination of the validity of any such
patent rights, and the risk of infringement of such rights, are entirely their own responsibility.
This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years and
if not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standards
and should be addressed to ASTM Headquarters. Your comments will receive careful consideration at a meeting of the responsible
technical committee, which you may attend. If you feel that your comments liave not received a fair hearing you should make your
views known to the ASTM Committee on Standards, 100 Barr Harbor Drive, West Conshohocken, PA 19428.
365