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13 April 2015
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13 April 2015
Aim
To use a standard sodium carbonate solution to determine the molarity of a solution of
Hydrochloric acid.
Requirements
Equipment
Electronic balance
White tile
25 mL pipette
Spatula
2 250 mL beaker
Teat pipette
Watchglass
Glass funnel
Burette
Chemicals
Sodium carbonate (AR)
Safety Precaution
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HCl. The burette was filled with HCl solution until the zero mark. Adjust the level and record
the first reading. A white tile was placed under the burette. A pipette was rinsed with sodium
carbonate solution. 25mL of the standard solution was pipetted into a clean 250mL conical
flask. 1 drop of methyl orange was added to this solution. Acid from the burette was added to
the flask while shaking. Acid was no longer added when the first permanent colour change
was added. The above steps were repeated to obtain 3 concordant titres.
Results
Results
Rough
First titration
Second titration
Third titration
Final reading
28.0
28.7
28.9
28.7
First reading
Titre
28.0
28.7
28.9
28.7
Calculations
nNa2CO3 = mNa2CO3MNa2CO3
= 1.302g(22.992+12.01+15.993)
=0.01229mol
CNa2CO3 = nNa2CO3 VNa2CO3
= 0.01229mol 0.25L
=0.04916mol/L
nNa2CO3 used = 0.04916mol/L0.025L = 0.001229mol
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Hydrochloric acid
Volume(V)
25ml
28.77ml
Concentration(C)
0.04916mol/L
0.08544mol/L
Number of moles(n)
0.001229mol
0.002458mol
Mole ratio
Observation
After adding the indicator to the colourless Na2CO3 solution, it turned yellow. When HCl was
added, certain parts of the Na2CO3 solution turned pink. However, after shaking the flask, the
solution became yellow again. After adding about 27.5ml HCl, the colour change became
more persistent, thus HCl solution was added drop by drop, until adding one specific turned
the solution orange. When a permanent colour change was observed, HCl was no longer
added to the solution.
Discussion
1) Explain how the concentration and/or purity of the solution would be affected if
(a) the volumetric flask was not rinsed with distilled (or RO) water first:
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This will affect the purity of the solution.The volumetric flask may contain some residue on
its surface. This would contaminate the Na2CO3 solution. A standard solution has to have
high purity, therefore, volumetric flask needs to be rinsed with distilled water.
(b) some sodium carbonate was spilled on the balance pan during weighing.
This will make sodium carbonate less concentrated. Amount of Na2CO3 on the watch glass is
less than the weighed mass.Thus the amount of sodium carbonate dissolved in the solution is
lesser, and since volume of the solution remains constant, the concentration of the solution
will be lesser than what is calculated.
(c) not all of the sodium carbonate was washed into the flask - some remained in the funnel
or on the watch glass.
This will make the sodium carbonate less concentrated. The amount of sodium carbonate
dissolved in the solution is lesser, and since volume of the solution remains constant, the
concentration of the solution will be lesser than what is calculated.
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(f) the volumetric flask was not shaken after the final addition of water
This does not affect the overall concentration, as the number of moles of Na2CO3 dissolved in
water remains constant. Hoewever, the solution will not be homogenous, thus different parts
of the solution will have different concentrations. Therefore, different batches of Na2CO3
drawed from the volumetric flask will have differing concentrations.
2) Explain what effect each of the following would have on the value calculated for the
concentration of HCl.
a) Not rinsing the pipette with sodium carbonate solution
This will make the concentration greater. The water used to rinse the pipette remains in the
pipette, and it will dilute Na2CO3 solution. Thus lesser HCl is needed to neutralize Na2CO3.
When calculating, the number of moles of HCl (n) does not change, but volume (v) decreases.
c = n/v, so the concentration will be greater.
This will make the concentration smaller. A greater volume of HCl is added and recorded.
When calculating, the number of moles of HCl (n) remains constant but the volume of HCl (v)
increases, c = n/v, so the concentration will be smaller.
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Errors
To reduce random errors, an average of the readings should be taken. If the averages of three
readings are needed, more than three readings should be recorded. Using only three values
that are closest to each other, take the average of these readings.
Systematic error can come about from human error (eg. human reaction time, disability for a
human to judge whether a permanent colour change has occurred because the colourings
were too light.) It can also be caused by the precision in the measuring tools used. A burette
can only measure up to two decimal places, therefore volume read may not be as accurate as
what the actual volume was. Accuracy is important to eliminate systematic errors, thus
instruments with high precision needs to be used.
Conclusion
The molarity of hydrochloric acid is 0.08544mol/L.