DAILY PRACTICE PROBLEMS (DPP)

TARGET : IIT-JEE 2012

Subject : Physical/Inorganic Chemistry

Date : 03/05/10

DPP No. 7

Class : XI

Course : VIKAAS (A)

DPP No. -1 For Week "03-05-10 to 08-05-10"

Total Marks : 34
Single choice Objective ('1' negative marking) Q.1 to Q.3
(3 marks 3 min.)
Short Subjective Questions ('1' negative marking) Q.4 to Q.5 (3 marks 3 min.)
Subjective Questions ('1' negative marking) Q.6
(4 marks 4 min.)
Comprehension ('1' negative marking) Q.7 to Q.11
(3 marks 3 min.)

1.

Sol.

Max. Time : 34 min.

[9, 9]
[6, 6]
[4, 4]
[15, 15]

Two flask of equal volumes are evacuated. At the same temperature and pressure one is filled with gas A and
other with gas B. The weight of gas B was found to be 0.8 g while the weight of gas A is found to be 1.4 g. The
weight of one molecule of B is :
(A) 1.4 times as that of A
(B) 0.4 times as that of A
(C*) 0.57 times as that of A
(D) 0.8 times as that of A
For two gases, volume, pressure and temperature are equal, hence moles of two gases must be equal.
so nA = nB

1 .4 0 .8

M A MB
MB =

0 .8 M A
= 0.57 MA.
1 .4

2.

Number of gold atoms in 300 mg of a gold ring of 20 carat gold (Au = 197; pure gold is 24 carat) are :
(A) 4.5 1020
(B) 6.8 1015
(C*) 7.6 1020
(D) 9.5 1020

Sol.

For 24 carat, no of gold atoms

For 20 carat, no of gold atoms

300 10 3
NA
197

300 10 3 20 N A

197
24
= 7.64 1020 atoms.

3.

Volume at NTP for 0.44 g of CO2 is the same as that of :

(A*) 0.02 g of hydrogen gas
(B) 0.085 g of ammonia gas
(C) 320 mg of sulphur dioxide gas
(D) none of these

Sol.

Volume of CO2 at NTP =

0.44
22.4 L = 0.01 22.4 L
44

0.02
22.4 L = 0.01 22.4 L
2
Copper metal reacts with nitric acid. Assume that the reaction is :
3Cu(s) + 8HNO3(aq) 3Cu(NO3)2 (aq) + 2NO(g) + 4H2O()
If 18.75 g Cu(NO3)2 is eventually obtained, then how many grams of nitric oxide, NO, would have also formed
according to the preceeding equation :
2 g.
3Cu (s) + 8HNO3 (aq) 3Cu(NO3)2 (aq) + 2NO(g) + 4H2O()
Volume of H2 at NTP =

4.

Ans.
Sol.

Mole of Cu (NO3)2 =

18.75
= 0.1
187 .5

Mole of NO = [Mole of Cu(NO3)2]

Mass of NO =

2
0 .2
=
3
3

0 .2
30 = 2g
3

[1]

5.
Ans.
Sol.

Calculate the atomic weight of a metal that forms an oxide having the empirical formula M 2O 3 and
containing 68.4% of the metal by weight. Identify the metal :
52 Cr.

2M
68.4

2 M 16 3 100
M = 51.9 = 52. Element is chromium (Cr).

6.

Ans.
Sol.

Haemoglobin contains 0.25% iron by weight. The molecular weight of Haemoglobin is 89600. Calcuate the
weight of K4[Fe (CN)6] that can be produced if all the iron atoms from 4.48 kg haemoglobin are converted into
K4[Fe(CN)6] through a series of reaction.
73.6g
100 g haemoglobin has
= 0.25 g Fe
89600 g --------- -------- -------- =

0.25 89600
= 224 g Fe
100

1 mol of Haemoglobin has =

224
mol Fe atoms = 4 mol Fe.
56

4480g
Now mole of haemoglobin given = 89600g / mol = 0.05 mol
mol. wt of K4[Fe(CN)6] = 368 g/mol
Applying POAC for Fe atoms mole of Haemoglobin 4 = mole of K4[Fe(CN)6] 1
0.05 4 =

weight of K 4 [Fe(CN)6 ]
1
368g / mol

weight of K4[Fe(CN)6] = 0.05 4 368 g

= 73.6 g

Comprehension :

Read the following passage carefully and answer the questions. (Q.7 to Q.11)
Large quantities of Hydrogen are required these days in industry for various purposes. Water is found to be
the cheapest raw material from which hydrogen can be obtained. One of the important methods for the
commercial production of hydrogen is Lanes process in which steam is passed over hot iron. Iron
decomposes steam with formation of magnetic oxide (Fe3O4) and hydrogen.
4H2O Fe3O4
+ 4H2
steam
magnetic
oxide
Iron is regenerated by reducing magnetic oxide with water gas (it is a mixture of CO & H2 in 1:1 mole ratio)
(i)

3Fe

4CO2
4H2O
(steam recovered)
[Equal amounts of magnetic oxide react in steps (ii) and (iii)] Steam so produced is again used in the
previous step in which magnetic oxide is produced :
[At. wt. Fe = 56]
(ii)
(iii)

Fe3O4
Fe3O4

+
+

4CO
4H2

3Fe
3Fe

+
+

7.

How many grams of iron are needed in order to produce 11.2 liter of H2 gas at S.T.P :
(A) 56 g
(B*) 21 g
(C) 42 g
(D)nonedksbZugha

Sol.

Moles of H2 produced =
mole of Fe needed =
mass of Fe needed =

8.

11.2
1
=
22.4
2

3
1

4
2
3
1

56 = 21 g.
4
2

How many gram water gas is needed in order to recover all the iron in previous problem
(A) 14 g
(B*) 7.5 g
(C) 15 g
(D) none

[2]

Sol.

Total iron recovered =

3
mole
8

it is equally recovered in (ii) and (iii) hence

Sol.

4 3
1

=
3 16
4

moles of H2 needed =

4 3
1

=
3 16
4

mass of water gas needed =

moles of steam needed =

10.

moles of CO needed =

1
(28 + 2) = 7.5 g
4
How many gram steam is consumed in order to produce 11.2 liter H2 gas at S.T.P :
(A*) 9 g
(B) 36 g
(C) 18 g
(D)dksbZugha

9.

3
mole of Fe is produced in both the reaction.
16

mass =

11.2
1
=
22.4
2

1
18 = 9 g.
2

Sol.

If iron is recovered in step (ii) & (iii) with 80% efficiency, than how many gram iron is recovered if initially
56 g iron is taken
(A*) 44.8 g
(B) 80 g
(C) 448 g
(D) 4.48 g
mass of iron recovered = 56 0.8 = 44.8 g.

11.

How many liter H2 gas is produced in step (i) at STP in the above problem
(A) 22.4 litre

Sol.

(B*) 29.86 litre

Moles of H2 gas produced =

(C) 2.986 litre

(D) 89.6 litre

4
3

volume of H2 gas at STP =

4
22.4 = 29.86L.
3

[3]