Escolar Documentos
Profissional Documentos
Cultura Documentos
Class ______________
Date _________
DataStudio
ScienceWorkshop (Mac)
ScienceWorkshop (Win)
Electrochemistry
C29 Electroplating.DS
C29 Electroplating
C29_ELEC.SWS
Equipment Needed
Qty
Equipment Needed
Qty
Protective gear
PS
Balance (SE-8723)
Qty
5 10 cm
Beaker, 1 L
Clamp, buret (SE-9446)
250 mL
Metal spoon
Graduated cylinder
Towel, paper
Whatistherelationshipbetweenthemolesofcopperatomsoxidizedfromacopperwireandthe
numberofelectronsthatpassedthroughthewire?
TaketimetoanswertheWhatDoYouThink?question(s)intheLabReportsection.
Background
In1832,MichaelFaradayobservedthattheamountofsubstanceundergoingoxidation
orreductionatanelectrodeinanelectrochemicalcellduringelectrolysisisdirectly
proportionaltotheamountofelectricitythatpassesthroughthecell.Thisstatementis
knownasFaradaysLawofElectrolysis.Thequantitativeunitofelectricity,now
calledthefaraday,istheamountofelectricitythatreducesonegramequivalent
weightofasubstanceatthecathodeofanelectrochemicalcellandoxidizesonegram
equivalentweightofasubstanceattheanode.Thiscorrespondstothegainorloss,and
thereforethepassage,ofAvogadrosnumberofelectrons.
Thefaradayisequivalentto96,487coulombs(amperexseconds).
Theequationforthereductionofcopper(II)ionsatthecathodeis:
Cu2++2e>Cu
Onemoleofcopperionsneedstwomolesofelectronstoformonemoleofcopperatoms.
1moleofions+2molesofelectrons>1moleofatoms
63.55g(copperions)+2faradays>63.55g(copperatoms)
Fromthisequationweseethat63.55gramsofcopperplateoutontothecathodeforeverytwo
faradaysofelectriccharge.Ofcourse,thesameamountofcopperwouldoxidizefromtheanode.
C29
p. 219
Student Workbook
012-07005A
FaradaysLawofElectrolysissuggeststhat31.77gramsofcopperplateoutfor96,487coulombs
(onefaraday)ofelectriccharge.
p. 220
C29
Name _____________________
Class ______________
Date _________
SAFETY REMINDERS
For You To Do
UsethePowerAmplifiertosendacurrentthroughelectrodes(acopperwireandametalspoon)
thatareimmersedinacoppersulfatesolution.UsetheDataStudioorScienceWorkshopprogram
torecordthecurrent,voltageandamountoftime.Measuretheamountofcopperthatoxidizes
fromthecopperwire(theanode).Usethesoftwaretointegrateunderthecurveofcurrentversus
timetodeterminetheamountofcharge.
Comparetheamountofchargetothemassofcoppertodeterminethefaraday.
PART I: Computer Setup
1.
ConnectaScienceWorkshop750interface
tothecomputer,turnontheinterface,and
turnonthecomputer.
2.
ConnecttheDINplugofthePower
AmplifiertoAnalogChannelAonthe
interface.DONOTturnonthePower
Amplifieryet.
3.
Openthefiletitledasshown;
DataStudio
ScienceWorkshop (Mac)
ScienceWorkshop (Win)
C29 Electroplating.DS
C29 Electroplating
C29_ELEC.SWS
TheDataStudiofilehasaGraphofcurrentversustime,aDigitsdisplayofcurrent,anda
SignalGeneratorwindow.ReadtheWorkbookdisplayformoreinformation.
TheScienceWorkshopdocumenthasaGraphdisplayofcurrentversustimeandaSignal
Generatorwindow.
Datarecordingissetatonemeasurementpersecond(1Hz)andwillstopautomaticallyat
3600seconds(60minutes).
C29
p. 221
Student Workbook
012-07005A
TheSignalGeneratorissettooutput6.00VDC(directcurrent).TheON/OFFbuttonis
settoAutosotheSignalGeneratorwillstartautomaticallywhenyoustarttocollectdata
andstopautomaticallywhenyoustopcollectingdata.
p. 222
C29
Name _____________________
Class ______________
Date _________
YoudonotneedtocalibratethePowerAmplifier.
1.
Put250mLof1molarcoppersulfate,CuSO4,solutionintothebeaker.
2.
Carefullymeasureandrecordthemassofthepieceofheavygaugecopperwire.
3.
Useanalligatorclipadaptertoattachoneendofapatchcordtooneendoftheheavy
gaugecopperwire(theanode).Connectthepatchcordtothepositive(red)outputterminal
ofthePowerAmplifier.
4.
Attachoneendofanotherpatchcordtooneendofthespoon(thecathode).Connectthe
patchcordtothenegative(black)outputterminalofthePowerAmplifier.
5.
Useclampstosuspendtheheavygaugecopperwireandthespoononthesupportrods.
Positiontheendofthewireandthespoonsotheyareimmersedinthesolutioninthe
beaker.
To Power
Amplifier
To Power
Amplifier
Spoon
Copper Wire
Copper
Sulfate
Solution
C29
p. 223
Student Workbook
012-07005A
1.
Whenyouarereadytobegin,turnontheswitchonthebackofthePowerAmplifier.
2.
Beginrecordingdata.(Hint:ClickStartinDataStudioorclickRECin
ScienceWorkshop).
ThePowerAmplifieroutputwillautomaticallystartwhendatarecordingbegins.
3.
Datarecordingwillcontinueforsixtyminutesandthenstopautomatically.
4.
Whendatarecordingiscomplete,turnofftheswitchonthebackofthePowerAmplifier.
5.
Carefullylifttheheavygaugecopperwirefromthesolutionandremovethepatchcord.
6.
Drythecopperwiresonocoppersulfatesolutionremainsonthewire.
7.
Carefullymeasureandrecordthenewmassofthecopperwire.
8.
Disposeofthesolutionasinstructed.
1.
UsethebuiltinanalysistoolsintheGraphtofindtheareaunderthecurveofcurrent
versustime.
Hint:InDataStudio,clicktheStatisticsmenubutton(
)and
thenselectAreafromthemenu.InScienceWorkshop,clickthe
Statisticsbutton(
menubutton(
)toopenthestatisticsarea.ClicktheStatistics
)andselectIntegration.
2.
Recordthevaluefortheareaunderthecurrentversustimecurve.Thisisthenumberof
coulombs(ampereseconds)ofelectricity.
3.
Useyourdatatocalculatethenumberofcoulombsperfaraday.
Record your results in the Lab Report section.
p. 224
C29
Name _____________________
Class ______________
Date _________
Whatistherelationshipbetweenthemolesofcopperatomsoxidizedfromacopperwireandthe
numberofelectronsthatpassedthroughthewire?
Data Table
Item
Amount
difference in mass
coulombs (Amps*sec)
Calculations
Calculatethenumberofcoulombsperfaradayusingthenumberofcoulombsofelectriccharge
andthedifferenceinmassofthecopperanode:
# coulombs
coulombs 31.77g
=
=
faraday
g
faraday
Questions
1.
Howdoesyourcalculatedvalueforafaradayofchargecomparetotheacceptedvalue?
measured accepted
100% .)
(Remember, percentdifference
accepted
Theacceptedvalueis96,487coulombsperfaraday.
2.
C29
Howwouldyourresultsbedifferentifyouhadusedasilverwireandasilversolutionto
silverplatethespoon?
1999 PASCO scientific
p. 225
p. 226
Student Workbook
012-07005A
C29
Name _____________________
3.
Class ______________
Date _________
IfthePowerAmplifierproducedaloweraveragecurrentbuttheoveralltimeremainedthe
same,howwouldthiseffectthefollowingmeasurementorcalculations?
More
Same
Less
4.
Youonlymeasuredthemasslostbythewire.Whatdoyouthinkwasthechangeinthe
massofthespoon?
5.
ThebluecolorofthecoppersulfatesolutionisduetotheCu+2inthesolution.Ifthe
experimentwouldcontinuetorunwellpastthesixtyminutes,whatwouldhappentothe
colorofthecoppersulfatesolution?Explainyourreasoning.
C29
p. 227