Escolar Documentos
Profissional Documentos
Cultura Documentos
Bi0pr0cessEngineering
0178515X9100024T
9 Springer-Verlag 1991
analogous to stepwise for the design of continuous flow sedimentation or thickening tanks.
In this technique, several computer programs have been set up in
order to reduce the data input, necessary for performing all intermediate calculations by computer. The data describing the settling of
particles and movement of the particle-liquid interface as a function
of time and operating conditions are the only data required. The
method predicts the time required to attain the prescribed underflow concentration, the rate of hindered settling subsidence, the area
required for clarification, the thickener area and dimensions. The
proposed method has been applied to illustrate the effect of different
chemical treatment doses on a typical industrial effluent from the
manufacture of starch and byproducts from American yellow corn.
cm
cm
cm
cm
cm
ACL
A L P H A ( c0
ATH
ATH1
B1
B2
B3
B4
B5
BT
BT1
CC
CO
CU
D
DIAM
DMIN
DT
DT1
HT
HT1
m 2
Q
SL
T1
T3
TM
TM1
TML
TMR
TMU
TU
List of symbols
AI
A2
A3
A4
A5
L1
LMAX
LMIN
NI
NO
PI
ZO
ZU
FI
m
m
m
point
m 2
m 2
cm. min- 1
cm - min- 1
cm - min - 1
cm - m i n - ~
m
m
mg/dm s
mg/dm 3
m
m
m
h
h
cm
min
HTR
cm
1 Introduction
250
H.A. Talaat et al.: A short cut procedure for continuous flow sedimentation
ZO
2 Theoretical approach
Coordinates of points
PointI (TMI,H/I)
Poinl2 (TMR,HTR)
Point3 (TU,ZU)
cm
%9
&.
~zz
~zu
Compessionzone
Line(2)
Point1~'~
~.~%'<
. I { P~
T2 TO
I
Time
min
Fig. l. Geometry index for the graphical analysis of interface settling curve
3 Software development
The flow diagram of the computer program for the graphical
design technique is based on the Linvil approach [1] and, is
illustrated in Fig. 2. The procedure adopted for developing
the software encompasses several steps described in the following sections.
B4
The equations describing the first falling, settling and compression zones have to be defined. Settling data are introduced in pairs of T M and H T for the three prementioned
zones. Using least square regression techniques, the relevant
functions are [11]:
~ r = A3 + (B3- TM).
-(T3" B3)
(1)
(2)
(3)
B4 =
H T - HT1
T M - - TM1
H T = A4 + (B4. T M ) .
l + ( m ' ~3)'
and
ALPHA=ARCTAN(~).
(8)
and
H T R = A 2 . T M R ~2 .
(10)
B1 - B3
(7)
Hence,
D E F F N F ( T M ) = ( A 2 . T M B Z ) - ( A 4 + B 4 9 TM)
T1 -
(6)
or
H T = A1 + (B1. T M ) ;
H T = A2 9 ( T M 82);
(5)
(4)
dHT
B 5 = d T M = A2 9 B2 [TM (~z-t)] ;
(11)
H T = A5 + (B5. T M ) .
(12)
CO 9Z O
CU
(13)
/input/
/
/
O,CU,ZO,Q
251
l
Calculate the coordinates
of intersection (TMI,HTI)
of the two straight lines
(I &2 )
Fitting data by
least square
regression
I
ISubroutine 2
Solving simultaneous
eqns. by inversion
method
Subroutinel 1
(TM1,HI1)
Point no. 2
Input
/
TML, TMU
CC,NI
Subroutine 3
Locating roots
by bisection
method
eqns. (9 &lO)
(THR,HTR)
Point no.2
/
Print eqns of line1, /
curve 1,line 2, line 3
(THR,HIR),
line 4, ZU, TU
i
Ca[curate thickener
area (ATH) eqn.(15)
i
Calculate area of
clarification (ACL)
eqn. (16)
Settling data
/
_L/
(TM,HT)
ZO, ZU,TU, ATH,ACL~--~
O,D, LI,BTI,D I A M ~
i
J Calculate
V
Calculate
D,DIAM,NO
I
Fig. 2. Flow diagram of the computer program for the graphical design technique
,.9=
252
H.A. Talaat et al.: A short cut procedure for continuous flow sedimentation
ru
(14)
B5
ACL-
Q (TU/60)
(ZO/IO0)'
4 0.6[Bl[ "
(15)
(22)
The constraint is L1/BT1 > 20. If this condition is not satisfied, then BT1 is reduced automatically until the constraint
is satisfied providing that the ratio L1/BT1 does not exceed
the value 5.
For circular tanks, the diameter is first calculated based
on A T H for one tank and a consecutive trial and error
calculation is executed to obtain the adequate diameter and
number of tanks.
DMIN
'
(17)
5.1 Experimental batch settling
L = (LMIN+ LMAX)/2.
(19)
The approximate width B T of the tanks is taken primarily as one fourth the approximate length (L).
The number of tanks can be calculated from:
ATH
B T . L"
(18)
NO =
ATH1
L1 = - BTI
(16)
Dr1 = 2 4 . - SL
(20)
100
9 Ref. [5]
cm
* Ref. [7]
80 ~
9 Ref. [8]
70
6O
,o
40
30
",, \.
ZO
".--~c:~.
'J~mA--m--m -- m-- m - - m--m.,..m
10 -~,,....
ATH1 = A TH/NO .
t It
20
40
60
1 1 ~
~ q klt
It
~tll
llt
(21)
253
TU [min]
Reference
No.
Reported
[7]
[5]
[8]
[1]
12
37.5
112
11
ATH
Calculated
[m2]
ACL[m 2]
Reported
11.82
38.49
94.66
11.62
Calculated
781.41
46.88
Reported
77.68
46.19
660.28
49.38
31
32
Calculated
26.4
31.25
307.66
33.06
Wastewater characteristics
- suspended solids
-
5200
4.7
1.909
1.015
31.2
40.69
4.11
pH
viscosity
density
solids composition
mg/dm 3
c.p
g/cm 3
starch %
protein %
fats %
1600
mgldm~
\ L
.
~200-J"
Coagulants
- lime
- ferric chloride
- lime+ferrous sulphate
50-1600 mg/dm 3
800 1600 mg/dm 3
(50, 150 rag/din 3) to
(120, 350 mg/dm 3)
- lime + aluminium sulphate
(800, 150 mg/dm 3) to
(800, 330 rag/din 3)
- Tests batch settling in graduated cylinders
sample volume
2
dm 3
- time of experiment
3 hours for settling curve.
Final height after
24 hours.
Table
Ferrous Z U
sulphate
dose
[mg/dm 3] [mg/dm 3] [ c m ]
Lime
dose
50
70
80
100
120
50
150
250
300
400
150
200
250
300
350
-
3.41
3.75
3.85
3.78
3.96
3.76
4.15
4.11
4.45
4.45
4.82
Supernatant Area
(SS) concen- A T H
tration
[mg/dm 3]
[mz]
DIAM
1614
1156
1102
1110
1048
1075
715
766
205
236
traces
12.87
12.78
12.59
13.26
12.71
14.03
13.29
14.04
15.66
15.40
16.07
130.21
128.32
124.50
138.02
126.79
154.50
138.68
154.75
192.49
186.96
202.65
:!L
200
~ y I ////
'\I/J
9
600
/i_)
/
A,Lime
Lime-FerFfcchloride
II'l#,/
1000 mgldm31000
Superncltant concentration
Set
Set
Set
Set
A
B
C
D
comprises
comprises
comprises
comprises
[m]
Results
and
discussion
The developed design technique has been utilised to investigate settling characteristics o f starch industry liquid waste.
Some commercial chemicals have been utilised to accelerate
removal of suspended solids. The calculated areas tend to
indicate slight increase o f the required settler areas as the
dose is increased due to increased a m o u n t o f solid deposition and, hence, more purified overflows. Such explanation
m a y be confirmed by the measured supernatant suspended
solids (SS) concentration at different chemical dosing rates
assuming constant underflow concentration, as depicted in
Fig. 4 for the four investigated sets A, B, C and D.
F o r sets A and B, the m a r k e d increase in the calculated
settler areas as the doses increase is coupled with a decrease
in supernatant (SS) concentrations.
254
H.A. Talaat et al.: A short cut procedure for continuous flow sedimentation
Wastewater
Initial
TU
Conc.
[mg/dm3] [min]
ATH
ACL
Tank dimensions
[m2]
[m2]
Circular
Rectangular
No.
DIAM
No
Length
Width
Wastewater
without
chemicals
5200
31.2
135.8
38.8
13.2
23.3
5.8
Wastewater*
5200
44.3
184.8
51.3
13.1
27.2
6.8
Supernatant*
1080
19.8
102.8
30.6
11.4
20.3
5.1
|
9 Wastewater with coagulants
401~&
cm~
9 Wastewater
30]~i~
a) Settling with no chemical aid requires small area. However, the conditions of overflow are still unacceptable.
b) Chemical treatment manifests an apparent increase in the
required settler areas. However, the amount of separated
solids are increased and the conditions of the overflow
are improved.
c) The proposed scheme for suspended solids removal may
involve two separate settlers, one for the readily settling
solids and the other for the slowly settling ones. In latter
cases the use of chemicals would be advantageous.
d) Additional work is still needed to investigate the effect of
other chemical flocculants and specially recently developed polymers.
20 \
0
0
I
10
20
1
30
I
40
I
I
50
60
T M ~
I
70
I
80
I
min
I
100
Fig. 5. Sedimentation test data for starch industry liquid waste for
calculating thickener and clarifier design parameters
For set C, the results show that increasing the chemical
treatment with lime and ferrous sulphate leads to insignificant changes in supernatant concentrations and consequently in settler design.
Set D data showed that about 800 mg/dm 3 of lime in
addition to 200-250 mg/dm 3 aluminium sulphate are sufficient to attain a clearer supernatant (43 mg/dm3).
Figure 5 manifests the settling curves of a flowrate of
100 m3/h of wastewater (5200 kg/m 3) before and after treatment with lime and ferric chloride mixture (800, 200 mg/
dm 3 respectively).
The design features for a typical system are depicted in
Table 4.
Appendix [II] represents typical printout results for the
sludge and supernatant including chemical doses, settling
data, operating conditions, and design features (TU, areas
of thickener and clarifier, number of tanks and their dimensions).
References
255
Appendix I
c-dc
(A1.2)
where
A = cross-sectional area perpendicular to direction of solids
movement;
T = time.
By solving f o r / i and neglecting d#,
d#
d~
#'
(AI.3)
2 2
(AI.8)
t2
and
a 1
#2-
(A1.1)
where
(c) -f(c).
(A1.4)
(AI.5)
and
(A1.6)
where Z 2 is the interface height at time T 2 . The layer concentration c 2 can be calculated by the following expression:
Co Z o
C2 -- Z 2 Ac # 2 T2 "
(AI.7)
Z2 .
(A1.9)
(A1.10)
q'
A (Zl - Z2)
T2
(AI.11)
Not all the liquid will move through the interface. Some
will accompany the solids to the underflow. The actual volume of liquid passing through the interface is equal to the
volume which would be released in the concentration of the
solids from the interface concentration c 2 to that of the
underflow c~. The corresponding volume of liquid in a batch
analysis would be
V= A (Z1
Z 2
fi2 =T22'
#2 T 2 = Z 1 - -
Z~),
(A1.12)
where
Z, = height of the sludge interface, if all the solids in the
system were at an undertow concentration of c,.
The time required for a volume of water V to flow
through a layer of concentration, c 2 would be
v
T:--=
q'
A(z~-z.)
[A ( Z 1 - Z 2 ) ] / T z"
(A1.13)
256
H.A. Talaat et al.: A short cut procedure for continuous flow sedimentation
Rearranging terms,
T
Appendix II
Chemical treatment
T2
Z 1 --Z u
Z 1 -g
Chemical 1
Concentration
gm/lit
Chemical 2
gm/lit
Concentration
Lime
800
Aluminium
sulphate
330
T=T,.
Zone 1
qc o=
co Z oA
r.
qT.
Zo'
(Al.17)
where
0
1
2
3
4
5
6
7
37.89
36.37
34.48
32.21
29.18
26.43
23.68
21.6
7
8
9
10
12
14
17
20
26
30
35
45
55
65
21.60
20.08
18.95
18.00
16.67
15.54
14.21
13.36
12.10
11.56
10.99
10.41
9.85
9.66
L.
The thickening capacity is generally expressed in terms of
unit area, the units of which are square feet per ton o f solids
per day. U n i t area m a y be c o m p u t e d from
Unit a r e a = ( 2 . 3 2 x 10 -2)
Zone 3
X
(A1.16)
and
A=
Zone 2
T~
e ol
(Al.18)
o "
65
75
85
95
120
150
9.66
9.47
9.28
9.09
9
8.89
Operating conditions
Waste water flowrate
Initial solid concentration
Underflow solid concentration
= 100m3/hr
= 5200 g/m 3
---41600 g/m 3
Design features
Time required to attain underflow concentration = 44.29 rain
Area of thickener
= 194.83 m 2
Area of clarifier
= 51.31 m z
Tank dimensions
Circular
Rectangular
No
Depth
m
Diam
m
No
Depth
m
Length
m
Width
m
15.75
27.92
6.98
Zone 2
Zone 3
0
2
3
4
5
6
32.1
28.9
24.07
19.26
12.84
8.99
6
7
8
9
10
11
12
13
14
15
16
17
18
8.99
7.38
6.74
6.26
5.94
5.78
5.46
5.30
5.13
4.97
4.81
4.81
4.65
22
54
76
4.49
3.53
3.14
Time
Area
Area
Tank
Circular
Rectangular
No
Depth
m
Diam
m
No
Depth
m
Length
m
Width
m
11.43
20.25
5.06
Operating conditions
Waste water flowrate
Initial solid concentration
Underflow solid concentration
257
= 100 m3/hr
= 1080 g/m 3
= 16250 g/m 3