Escolar Documentos
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TECHNICAL MANUAL
(b)
Sulphuric Acid
Solar Oil
Caustic
Catalyst
Finish Product Storage for
-
Coal Tar
Ammonium Sulphate
Naphthalene
Sulphur
The By-product plant is equipped with adequate flexibility from the point of view of design,
operation and maintenance. Adequate standby facilities are ensured for uninterrupted and smooth
operation of the plant.
Page 1
TECHNICAL MANUAL
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Page 2
TECHNICAL MANUAL
Coke Oven Gas (COG) generated from battery gets separated from tar & liquor in
downcomer and is sucked by the exhauster through Primary Gas Cooler (PGC) &
Electrostatic Tar Precipitator (E.T.P.). In primary gas cooler, gas is cooled indirectly
first by cooling water followed by chilled water to 20 to 22 Deg C from about 82 0C
(saturated). The primary gas coolers have tubes horizontally placed with certain
inclination in a rectangular vertical box. The Coke Oven Gas flows in the shell side
and cooling water/chilled water flow in the tube side of PGC. Most of the tar-liquor
condensate is separated from C.O.Gas in the PGCs.
Cooling tower & chilled water plant have been installed for catering the requirement
of primary gas cooler and Heat-exchangers of other units. The chilled water plant is
housed in a separate room. Cooling tower & chilled water plant have standby
provision.
System of hot tar-liquor emulsion flushing is there for each PGC for removal of
naphthalene deposit on outside of water tubes. Arrangement of LP steam & Nitrogen
purging to PGC are also made.
(ii)
(iii)
Exhauster
Electric Motor driven exhauster sucks the coke oven gas leaving ETP and discharge
the same with a positive head. The discharge head shall be worked out depending upon
the pressure drops in the downstream equipment and desired pressure (700 mm to
1000 mmWG) of CO Gas at the Battery Limit of By-Product. The temperature of CO
Gas at the discharge of exhauster should be kept minimum. Suction requirement for
upstream of exhauster upto battery is 500 mm WG (indicative).
TECHNICAL MANUAL
comer to Solid Decanter; to Tar Decanter, Coal water tank and then back to Gas collecting
main via Ammoniacal/flushing liquor pump. Part of coal water is used for HPLA system in
battery. Excess coal water is sent to Ammonia stripper via Gravel filter.
Major portion of tar content in Coke oven gas is condensed in Gas main by flushing liquor/
Ammoniacal liquor. The tar together with flushing liquor, gas condensate and coal fines
from coke oven flowing through gas collecting main goes to solid decanter. The coal fines
mixed with tar & flushing liquor is known as sludge. The solid decanter serves to separate
sludge from Ammoniacal liquor and tar by settling. Sludge being heavier, settle at the
bottom of solid decanter and sludge is continuously scrapped off by scrapping conveyors
into barrel/ trolley from where it is removed by a dumper/truck. The Ammoniacal liquor and
tar from the decanter overflows into tar decanter. The Ammoniacal liquor from tar decanter
goes to gas mains of battery. Part of this liquor is used for HPLA system also. Surplus
Ammoniacal liquor is generated due to moisture present in the coal. This excess
Ammoniacal liquor is sent to Ammonia stripper via Gravel Filter.
The tar from the tar decanter flows continuously to the Tar Storage Tank for despatch.
Major Technological Equipment/Facilities for Gas Condensation Plant.
This plant comprises of the following major technological equipment
EQUIPMENT
CAPACITY
Primary Gas Cooler
2W+1S
24000
Nm3/Hr
for
Each PGC
Exhauster (650 Kw, 6.6 KV)
1W+1S
47500
Nm3/Hr
Decanter
1W+1S
Flushing Liquor Pumps
2W+1S
525 Nm3/Hr
E.T.P
1W+1S
47500
Nm3/Hr
Centrifugal Pumps for transferring 1 W + 1 S
tar, liquor etc
Tar Storage Tanks
1W+1S
1600 M3
Cooling Tower
2W+1S
Cooling Water Pump
4W+3S
Chilled Water Plant
2W+1S
Chilled Water Pump
1W+1S
Gravel Filter
1W+1S
Heat Exchanger
To prevent gaseous emission from various vessels, tanks equipment & vents, a suitable
pollution control measures are taken.
Page 4
TECHNICAL MANUAL
TECHNICAL MANUAL
Page 6
TECHNICAL MANUAL
2nd claus reactor stage. Before the process gas is led into the 2nd claus reactor stage, it is reheated to enter the claus reactor with the required temperature.
The process gas, leaving the 2nd claus reactor stage is also cooled in the sulphur condenser,
released from liquid sulphur in the 2nd sulphur separator and directed as tail gas to the crude
gas main ahead of the primary coolers. By this mode of operation the combined process is
free from emissions.
The following reactions take place during the process.
NH3 + O2 (N2) + H2O
HCN + O2 (N2) + H2O + CO2
H2S + O2 SO2 + H2O
NH3 N2 + (H2)
HCN + H2O N2 + (H2) + (CO)
H2S + O2 SO2 + H2O + 519 KJ
2H2S + SO2 3/x Sx + 2H2O + 147 KJ
H2S + O2 SO2 + H2O + 519 KJ
2H2S + SO2 3/x Sx + 2H2O + 147 KJ
The produced liquid sulphur from the boiler, the sulphur condenser and the two sulphur
separators is led via a sealing pot to a storage tank to process further for producing Sulphur
blocks.
Major Technological Equipment/Facilities
EQUIPMENT
NH3 and H2S Scrubbing Unit
H2S Scrubber
1W
NH3 Scrubber
1W
CAPACITY
47500 Nm3/Hr
Gas Processing
47500 Nm3/Hr
Gas Processing
TECHNICAL MANUAL
1W
1W + 1 S
8W+8S
Page 8
TECHNICAL MANUAL
The Naphthalene rich solar oil fed to the Naphthalene stripper where naphthalene is stripped
off by steam. Almost naphthalene free solar oil is taken out from stripping column for reuse
in Naphthalene scrubber after proper cooling.
The vapour coming out from Naphthalene stripper contains Naphthalene with oil & water
vapour which is condensed in water cooled condenser. Naphthalene rich oil getting
separated from water in a separator is allowed to cool in water jacketed Naphthalene tray.
Naphthalene crystallises by indirect cooling. The oil content in the Naphthalene is 1 % max.
Contaminated water from separator goes back to tar separator unit.
Major Technological Equipment/Facilities Naphthalene Scrubbing unit)
EQUIPMENT
Naphthalene Scrubber
Naphthalene Scrubber
1W
CAPACITY
47500 Nm3/Hr
Gas Processing
Coke Oven Gas Processing Capacity: 47460 Nm3/hr (Indicative) Including Charging
gas and Tail Gas
ii)
b)
d)
iii)
iv)
Raw Coke Oven Gas Composition & Impurities at the inlet of By-Product Plant
(Indicative):
a) Composition of Raw Coke Oven Gas (% by Volume):
Page 9
TECHNICAL MANUAL
Hydrogen
: 52-59
Carbon monoxide
: 6-7
Carbon dioxide
: 3-4
Oxygen
: 0.3-0.7
Methane
: 24-28
Nitrogen
: 4-7
CnHm
: 1.5-2.5
b) Impurities of Raw Coke Oven Gas (gm/Nm3):
Tar
: 100-120
Benzol Hydrocarbons
: 30-36
Hydrogen Sulphide
: 3-4
Ammonia
: 10-12
Naphthalene
: 8-10
v)
Impurities in clean Coke Oven Gas (At the outlet of By-Product plant)
Residual Impurities
gm/Nm3
Tar
: 0.02 (Max.)
Hydrogen Sulphide
: 0.80 (Max.)
Ammonia
: 0.03 (Max.)
Naphthalene
: 0.05 (Max.)
Benzol Hydrocarbons
: 28-34
vi)
vii)
viii)
ix)
:
:
:
:
33.83 kg/TDC
15.04 kg/TDC
1.05 kg/TDC
0.11 kg/TDC
:
:
:
:
Purity of Naphthalene
Content)
:
:
:
1.55 T/Hr
49 Kg/hr
415 Kg/hr
Chemical Consumptions:
i Sulpuric Acid
ii Solar Oil or Wash Oil
iii Caustic Soda
Page 10
(Min.Oil
TECHNICAL MANUAL
Page 11
TECHNICAL MANUAL
SLUDGE
RECIRULATIO
N
UNDER
FLOW
TAR/O
IL
SKISKIM
SEPA
EF
SKIMME
MMMED
RATIO
TAR &
FL
D TAR &
N
ED OIL
DISSO
pHN
AMM
EU
TANK EQUALI
OIL
TO
TA SUMPLVED
SATION
ADJU
ONIA
a OIL
NT
SLOP
R/O
TANK
AIR
STRIP
BACTE STME
O
TANK
WITH
FLOAT
NT
PING
IL
RIAL
H
SKIMM
ATION
TANKTOWE
CULTUR
AMM
ER
UNITE
1
R
TREATE
ONIA
MAG BACTERI PREPA
ACI
D
AER
FIXIN
NUT
SETTL NESI AERAAL
SETTL
RATION ATIO
G D
SEWAGE
ING UM TION
ING
RIE
TANK
CULTUR
N
CUM
TREATE
TANKTANKTANKNT
SLUD
TAN
pH
CAR
E
II
II
I
D
GE
K-I
ADJU
SLUDGE
BON
PREPAR
EFFLUE STME
SUMP
RECIRUL
ATE
ATION
EXC
NT
-I THICK
NT
ATION SLUD
TANK
SLUD
SLUD
ESS
OVE
NED
GETANK
GE
GE UND RFL
SLU
SLUD
DRYI
SUMP
THICK ER
GE
NG
DGE
OW
NER
EXC
SUMP
BED
ME -II
FLO
AERA
SLUDGE
DENIT
SETTL
ESS
TH RIFIC
W
TION
ING
FOR
OVE
SLU
AN ATION
TANKTREATE
TANKDISPOS
RFL
DGEIII
III
OL TANK
D
OW
SLUDGE
SUMP-III
AL
EFFLUE
NT FOR
AERATIO
DISPOS
N TANK
AL
1
TECHNICAL MANUAL
Aeration Tank I
Settling Tank I
Aeration Tank II
Settling Tank II
De-Nitrification Tank
Settling Tank - III
Aeration Tank - III
Sludge Sumps
Thickener
Sludge Drying Bed
Chemical House, MCC Room, PLC Room, Office, Laboratory, Chemical Dosing Units
Treated Effluent Collection Sump
Slop Oil Tank
Biological Culture Tank
TECHNICAL FEATURES
Capacity: 40 m3/hr Un-treated Effluents from BPP and COB # 11 and 50 m3/hr Treated Sewage
Water from STP.
TREATMENT SCHEME:
Effluents generated from Coke oven and By-Product Plant (COB#11 complex) contains
pollutants such as Ammonia, phenol, Tar & oil, cyanide etc. Main function of BOD Plant is to
remove tar and oils by physical and chemical systems and subsequent biological degradation of
Phenols , Ammonia and cyanide.
Initially effluents are received in tar & oil separation tank. The capacity of the tank is suitable for
one hour detention period. The effluent collected in this collection sump pumped to subsequent
tar-oil separator. Tar-oil separator unit is provided with skimming facilities. From this unit effluents
flow by gravity to equalization tank.
The equalization tank capacity with residence time of 24 hours for designed flow of 40 m3/Hr. The
equalization tank consists of three compartments, two compartments each having six hours holding
while the third compartment having twelve hours holding capacity. The equalization tank is
provided with necessary tar/oil skimming arrangement, and epoxy painting in the inside faces of
each compartment.
From the equalization tank effluents are pumped to dissolve air floatation unit for removal of
emulsified oils. This unit consists of recirculation pump, air compressor and all other required
accessories. A skimmed tar & oil sump is also provided for collection and storage of skimmed tar &
oil.
Since the skimmed tar & oil contains major portion as water, this skimmed tar & oil is pumped to
slop oil tank for separation of water & tar / oil. In the slop oil tank skimmed tar & oil allowed to
remain for few days for separation of tar and oil. Tar/oil floating on the top surface is taken out
through tapping connection provided for this and sent for secondary use. Water from the bottom of
the tank taken out and sent back to the treatment plant.
From the dissolved air flotation unit effluents flow by gravity to pH adjustment tank. Alkali is
added to raise the pH around 11. This tank is provided with agitator and pH indicating instrument.
pH adjusted effluents are pumped to ammonia stripping tower.
Page 13
TECHNICAL MANUAL
Stripping of ammonia is carried out in an ammonia stripping tower. The tower is of induced draft
cross flow type and provided with suitable packing, effluent distribution piping, collection basin,
adequate capacity aeration fan and all other accessories.
The ammonia stripped effluents from collecting basin sent to ammonia fixing cum pH
adjustment tank. The residual free ammonia is fixed and pH is brought down to neutral pH by
addition of sulphuric acid. The tank is provided with agitator and pH indicating instrument.
Effluents form ammonia fixing tank are pumped to 1 st stage aeration tank i.e. aeration tank-I. Under
normal operation condition part of treated effluent or treated sewage water is added at the outlet
of ammonia fixing cum pH adjustment tank at the rate of 40 m3/hr before entering into the
biological treatment facilities. The aeration tank-I is aerated along with the return sludge by
mechanical surface aerator. The tank is made of RCC and necessary arrangements are provided in
the tank for receiving the return sludge and required nutrients.
The effluents from aeration tank-I flow to settling tank-I where solid particles are settled out.
Overflow from settling tank-I flow to aeration tank-II whereas the underflow is taken to sludge
sump-I. The settling tank is of RCC construction and
provided with necessary scrapping
arrangement, overflow weir, inlet and sludge outlet pipes, constant bleed arrangement and all other
accessories required. From the sludge sump-I sludge is recirculated to aeration tank 1 and excess
sludge is disposed to sludge thickener inlet.
The aeration tank-II is used as 2 nd stage of the activated sludge process. The tank consists of
aerators and other facilities for receiving the return sludge and required magnesium carbonate
solution. Bacterial culture tanks provided at the platform of aeration tanks.
Effluents from aeration tank-II flow to settling tank-II. The settling tank-II is similar to settling
tank-I. Facilities for collecting settled sludge from settling tank-II and pumping it to aeration tank-II
& sludge thickener inlet, sump is provided.
The nitrified effluents from aeration tank-II flow to nitrification tank. The tank is operated under
anaerobic condition. Requisite quantity of methanol is added as carbon source. Effluents from denitrification tank flow to settling tank-III. The settling tank-III is similar to settling tank-I. Similar
facilities for collecting settled sludge from settling tank-III and pumping it to sludge thickener inlet,
sump, and pumps provided.
From the de-nitrification tank, effluent flow to aeration tank-III, where surface aerators are
provided in the aeration tank to supply required dissolved oxygen in the treated effluent before
disposal.
A sludge thickener is provided for thickening the excess sludge received from different sludge
sumps. The thickener is provided with sludge collection arrangement and all other accessories. The
overflow from sludge thickener is fed at the inlet of aeration tank-I
The underflow from sludge thickener is collected in a thickened sludge sump from where it is
pumped to sludge drying bed unit for dewatering of the sludge.
DESIGN SPECIFICATION:
pH
Temp.
Phenol
Inlet Concentration
7.5 to 9.0
50 - 60 Deg. C
500 mg/l
Page 14
Outlet Concentration
6.0 to 8.0
Ambient Temp
1 mg/l
TECHNICAL MANUAL
50 mg/l
100 350 mg/l
500 mg/l
-
Page 15
0.2 mg/l
10 mg/l
Ammonical N2 :50mg/l
100 mg/l
30 mg/l
250 mg/l
TECHNICAL MANUAL
SLUDGE
RECIRULATIO
N
UNDER
FLOW
TAR/O
IL
SKISKIM
SEPA
EF
SKIMME
MMMED
RATIO
TAR &
FL
D TAR &
N
ED OIL
DISSO
pHN
AMM
EU
TANK EQUALI
OIL
TO
TA SUMPLVED
SATION
ADJU
ONIA
a OIL
NT
SLOP
R/O
TANK
AIR
STRIP
BACTE STME
O
TANK
WITH
FLOAT
NT
PING
IL
RIAL
H
SKIMM
ATION
TANKTOWE
CULTUR
AMM
ER
UNITE
1
R
TREATE
ONIA
MAG BACTERI PREPA
ACI
D
AER
FIXIN
NUT
SETTL NESI AERAAL
SETTL
RATION ATIO
G D
SEWAGE
ING UM TION
ING
RIE
TANK
CULTUR
N
CUM
TREATE
TANKTANKTANKNT
SLUD
TAN
pH
CAR
E
II
II
I
D
GE
K-I
ADJU
SLUDGE
BON
PREPAR
EFFLUE STME
SUMP
RECIRUL
ATE
ATION
EXC
NT
-I THICK
NT
ATION SLUD
TANK
SLUD
SLUD
ESS
OVE
NED
GETANK
GE
GE UND RFL
SLU
SLUD
DRYI
SUMP
THICK ER
GE
NG
DGE
OW
NER
EXC
SUMP
BED
ME -II
FLO
AERA
SLUDGE
DENIT
SETTL
ESS
TH RIFIC
W
TION
ING
FOR
OVE
SLU
AN ATION
TANKTREATE
TANKDISPOS
RFL
DGEIII
III
OL TANK
D
OW
SLUDGE
SUMP-III
AL
EFFLUE
NT FOR
AERATIO
DISPOS
N TANK
AL
1
Page 16