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Inter (Part-1) Lahore Board 2012

Chemistry
Time Allowed: 20 Minutes

Paper I (Objective Type)

Max. Marks: 17
(Group-I)

Note: Four possible answers A, B, C and D to each question are given. The choice which you think
is correct, fill that circle in front of that question with Marker or Pen ink. Cutting or filling two or
more circles will result in zero mark in that question. Write the letter A, B, C or D in the column
(write correct option) against each question also. If there is a contradiction in the bubble and hand
written answer, bubble option will be considered correct.
Q. 1
1. The mass of one mole of electrons is :
(A) 1.008 mg
(B) 0.55 mg
(C) 0.184mg
(D) 1.673 mg
2. The number of moles of C02 which contain 8.0 g of oxygen is:
(A) 0.25
(B) 0.50
(C) 1.0
(D) 1.50
3. The drying agent used in a desiccator is :
(A) AgCl
(B) NH4 Cl
(C) CaClf2
(D) AlClf 3
4. Pressure remaining constant, at which temperature the volume of a gas will become twice of
what it is at 0 C :
(A) 546C
(B) 200C
(C) 546 K
(D) 273 K
5. The partial pressure of oxygen in the lungs is :
(A) 760 torr
(B) 670 torr
(C) 159 torr
(D) 116 torr
6. The existence of an element in more than one crystalline form is called:
(A) Allotropy
(B) Isotropy
(C) Isomorphism
(D) Polymorphism
7. Acetone and chloroform are soluble in each other due to:
(A) Intermolecular hydrogen bonding
(B) Ion-dipole interaction
(C) instantaneous dipole
(D) Covalent bonding
8. The nature of the positive rays depend on :
(A) The nature of the cathode
(B) The nature of the anode
(C) The nature of the residual gas

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(D) The nature of the discharge tube

9. Splitting of spectral lines when atoms are subjected to strong electric field is called:
(A) Zeeman effect
(B) Stark effect
(C) Compton effect (D) Photoelectric effect
10. Which of the following molecule has zero dipole moment:
(A) NH3
(B) CHCl 3
(C) H20
(D) BF3
11. The number of bonds in nitrogen molecule is:
(A) One sigma and one pi
(B) One sigma and two pi
(C) Three sigma only
(D) Two sigma and one pi
12. If an endothermic reaction is allowed to take place very rapidly in the air, the temperature of
the surrounding air:
(A) Remain constant (B) Increases
(C) Decreases
(D) Remain unchanged
13. The term pH was introduced by:
(A) Henderson
(B) Sorenson
(C) Goldstein
(D) J.J. Thomson
14. Molarity of pure water is:
(A) 1
(B) 18
(C) 55.5
(D) 6
15. The oxidation number of chromium in K2Cr207 is:
(A) 14
(B) 12
(C) 6
(D) 13
16. Reduction always takes place at:
(A) Anode
(B) Cathode
(C) Both electrodes
(D) Salt bridge
17. In zero order reaction, the rate is independent of:
(A) Temperature of reaction
(B) Concentration of reactants
(C) Concentration of products
(D) Concentration of reactants and products

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Inter (Part-1) Lahore Board 2012

Chemistry
Time Allowed: 2.40 Hours

Paper I (Essay Type)

Max.Marks: 68
(GROUP-1)
SECTION-I

Q2. Write short answers to any EIGHT (8) questions:

16

1) One mg of K2Cr04 has twice the number of ions than the number of formula units when ionized.
2) 4.9 g of H2S04 when completely ionized in water have equal number of positive and negative
charges but the number of positively charged ions are twice the number of negatively charged
ions.
3) 23 g of sodium and 39 g of potassium have equal number of atoms in them.
4) The desiccator is a safe and reliable method for drying the crystals. Explain.
5) Media which are used for filtration should be sel on the basis of precipitates. Explain.
6) Hydrogen and Helium are ideal at room temperature SO2 and Cl2 are non-ideal. Explain.
7) Pressure of NH3 gas at given condition is less as calculated by Van der Waals equation than that
clculated by general gas equation.
8) Water vapours do not behave ideally at 273 K.
9) Some of the postulates of kinetic molecular theory of gases are faulty. Justify.
10)Vacuum distillation can be used to avoid decomposition of a sensitive liquid. Explain.
11)Heat of sublimation of iodine is very high. Justify
12)Earthenware vessels keep water cool. Explain.

Q3. Write short answers to any EIGHT (8) questions :

1) State Pauli-exclusion Principle.
2) Calculate mass of an electron when
e
1.758 1011 C.kg 1
m
3) What is Moseleys law?
4) Define Dipole Moment and give its SI unit.

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5) What is octet rule? Give two examples of compounds which deviate from it.
6) Draw labeled diagram of Bomb Calorimeter.
7) Define standard enthalpy of formation with a suitable example.
8) What are thermo chemical reaction, give their types?
9) Aqueous solution of CuSO4 is acidic in nature. Justify it.
10)Define Ebullioscopic Constant with one example.
11)Give two applications of electrochemical series.
12)Define rate of chemical reaction and give its units.

Q4. Write short answers to any SIX (6) questions :

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1) Explain why pi - bonds are more diffused than alpha - bonds.

2) The melting points, boiling points, heat of vapourizations and heat of sublimations of
electrovalent compounds are higher than covalent compounds. Explain.
3) Explain the terms reversible reaction and state of equilibrium.
4) The solubility of glucose in water is increased by increasing the temperature. Explain.
5) Define PH and POH
6) How does the change of pressure shifts the equilibrium position in the synthesis of ammonia?
7) Explain how impure Cu can be purified by electrolytic process.
8) A salt bridge maintains the electrical neutrality in the cell. Explain.
9) Differentiate between enthalpy change of reaction and energy of activation of reaction.

(SECTION - II)

Note: Attempt any THREE questions.

1. (a) What is difference between actual yield and theoretical yield? Why actual yield is less than
theoretical yield?
4
(b) Classify solids on the basis of bonding. How ionic solids arc formed? Give two properties of
ionic solids.
4
2. (a) Write the main postulates of VSEPR theory and explain the structure of ammonia on the
basis of this theory.
4

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(b) When 2.00 moles of H2 and 1.00 mole of 02 at 100 C and 1 torr pressure react to produce
2.00 moles of gaseous water, 484.5 KJ of energy is evolved? What are the values of (i) H (ii) E
for the production of one mole of H20(g)?
4
3. (a) 250 cm3 of a sample of hydrogen effuses four times as rapidly as 250 cm 3 of an unknown
gas. Calculate the molar mass of unknown gas.
4
(b) State and explain with an example, the Hesss law of constant heat summation.
4
4. (a) Write a note on synthesis of ammonia gas by Habers Process keeping in mind the
applications of chemical equilibrium in industry.
(b) How can you measure electrode potential of an element with the help of Standard
Hydrogen Electrode (SHE)?

4
4

5. (a) What are ideal solutions? Explain the fractional distillation of ideal mixture of two liquids 4
(b) How does Arrhenius equation help us to calculate the energy of activation of a reaction? 4