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METB113
Sem 1 2015/2016
METB113
MID -TERM TEST
SEMESTER 1 2015/2016
TIME: 10.00 11.00 AM
DATE: 12 JULY 2015
NAME
ID NO
SECTION
LECTURER
Marks:
Question
Marks Obtained
Marks Allocated
10
10
10
Total
30
Question 1:
Page 1 of 7
Test 1
METB113
Sem 1 2015/2016
a) Explain the differences between primary bond and secondary bond in materials.
Primary bond arises from either transfer or sharing of electrons (valence electrons)
between the atoms in materials.
It is strong interatomic forces that can vary from very high energy (ionic bond) in
ceramic to very low energy (covalent bond) in polymer.
Can be directional (covalent) or non-directional (ionic, metallic).
Secondary bond (van der Waals) is intermolecular forces.
Secondary bonding arises from dipole interactions between the molecules.
Small energy at 10-42 kJ/mol.
Directional only due to the dipole interactions.
[4 marks]
Page 2 of 7
Test 1
METB113
Sem 1 2015/2016
Figure 1
i) What are the type of materials that are formed between positive ions and negative
ions as shown in Figure 1?
[1 Mark]
Ionic material
[5 Marks]
Ionic bond are formed by strong electrostatic force (Coulombic force) between the
cation and anion. Lattice energies and melting temperature of ionically bonded
solids are high. Metal oxides especially MgO has the highest bonding energies at
ca. 3932 kJ. Ionic solids are hard (do not dent), rigid (do not bend or stretch),
strong (hard to break, brittle (deform little before fracture) due to strong
electrostatic force that holds the ions together.
Page 3 of 7
Test 1
METB113
Sem 1 2015/2016
b) Prove the relationship between the length of the cube side a and the atomic radius R is
a=
4R
2
[2M].
[0.5 Mark]
4 R= 2 a
a=
4R
2 [0.5 Mark]
c) Calculate the Atomic packing factor of FCC [2M]. What is the significant of this number?
[1M]
Page 4 of 7
Test 1
METB113
Sem 1 2015/2016
[0.5
Mark]
[0.5
Mark]
[0.5
Mark]
[0.5
Mark]
Page 5 of 7
Test 1
METB113
Sem 1 2015/2016
a) Describe and illustrate the solidification process of a pure metal in terms of the
nucleation and growth of crystals.
[4Marks]
Answer
Steps of solidification:
Nucleation: Formation of stable nuclei [1M]
Growth of nuclei: Formation of grain structure [1M]
[2M]
[1Mark]
Answer
Homogeneous Nucleation [0.5M]
Heterogeneous Nucleaction [0.5M]
[1Mark]
Page 6 of 7
Test 1
METB113
Sem 1 2015/2016
Solid solution is a simple type of alloy in which elements are dispersed in a single
phase.
2 types of solid solutions: substitutional and interstitial [1 M]
d) Explain the differences between a substitutional solid solution and an interstitial solid
solution.
Answer
Substitutional:
Solute atoms substitute for parent solvent atom in a crystal lattice.
The structure remains unchanged.
[2M]
Interstitial:
Solute atoms fit in between the voids (interstices) of solvent atoms.
Solvent atoms in this case should be much larger than solute atoms.
[2M]
-END OF QUESTION-
Page 7 of 7
[4Marks]