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Industrial Energy Systems Laboratory, Ecole Polytechnique Fdrale de Lausanne, CH-1015 Lausanne, Switzerland
EDF R&D, Eco-efciency and Industrial Process Department, Centre des Renardires, F - 77818 Moret sur Loing Cedex, France
a r t i c l e i n f o
a b s t r a c t
Article history:
Received 15 August 2011
Accepted 23 November 2011
Available online 10 December 2011
The aim of process integration is to increase the efciency and to reduce the energy consumption, operating
costs and CO2 emissions of an industrial process. The proposed methodology is applied to a real case study
of a cheese factory with non-simultaneous process operations and uses the time average approach
combined with restricted matches. This work focuses on appropriate heat pump integration and two
different integration strategies are proposed. In the rst option, process modications and direct heat
exchange between the process and heat pump streams are not allowed, which means that the integration of
heat pumps has to be realized through intermediate heat transfer networks. On the contrary, in the second
option, direct heat exchange and process modications are possible. The results of both options are
analyzed and compared for the French and German context. Depending on the industrial constraints and
the location, it is shown that the nal choice of new heat pump installations may be different. Saving
potential in operating costs is higher for option 2 where the cost savings can be higher than 40% for both
countries. Furthermore the potential CO2 emissions and primary energy savings are compared.
2011 Elsevier Ltd. All rights reserved.
Keywords:
Pinch analysis
Utility integration
Industrial heat pumps
Total site
Restricted matches
Time average approach
1. Introduction
When studying the energy efciency of an industrial process,
the analysis of heat pump integration has to be considered as part
of a complete methodology, beginning from the data collection and
modeling of all process unit operations up to the nal utility integration. The use of pinch analysis techniques allows identication
of heat recovery potential in the process. Opportunities to integrate
heat pumps and other utility systems can be identied by analyzing
the grand composite curve. The curve shows the enthalpy
temperature prole of the heat to be supplied to the process and of
the heat excess to be evacuated by a cold utility. Heat pump integration became interesting in the late 80s and the early 90s due to
increasing fuel prices. For example, the rules for optimal placements of a heat pump in an industrial process have been introduced
by Linnhoff and Townsend [8] in 1983. Later, Wallin and Berntsson
[13] demonstrated that, characteristics of both, industrial process
and heat pumps, must be taken into account. Kapustenko et al. [5]
analyzed heat pump integration based on selected streams of
a cheese factory. Also Pavlas et al. [11] analyzed heat pump integration for a gasication process. However, both approaches are
limited to ammonia refrigeration cycles. Recently Kapil et al. [4]
* Corresponding author.
E-mail address: helen.becker@ep.ch (H. Becker).
1359-4311/$ e see front matter 2011 Elsevier Ltd. All rights reserved.
doi:10.1016/j.applthermaleng.2011.11.050
Nomenclature
DTmin=2
Q_
Q_ *
A
B
COP
du
dtot
ep
f
InvC
M
mCO2
OpC
PR
T
U
eel
ef
119
Subscripts
c
Cold streams
cog
Co-generation engine
h
Hot streams
hp
Heat pump
ref
Reference value
u
Index for unit
Superscripts
120
DTmin=2u
*
Q_ h=c
UA
(1)
*
Q_ h=c
DTmin=2ref
Q_
(2)
h=c
Combining Eqs. (1) and (2), the DTmin=2u for each unit and their
streams can be deduced. The DTmin=2ref is considered to be 2 C and
is used for all permanently working units. For all other units, the
DTmin=2u value is calculated with Eq. (3).
dtot
DTmin=2ref ;
du
DTmin=2u x
(3)
Q_ h=c $dtot
M
qh=c
PH
PH
PH
Effect 1
Effect 2
Effect 3
T1
P1
T2
P2
T3
P3
(4)
Milk inlet
PH
steam
product
steam
condensates
evapo tech
pasto1
pasto2
pasto3
pasto4
pasto5
proc6
proc7
proc8
proc9
proc10
heat
CIP
Name
other_c1
other_h1
other_h2
evapo_c1
evapo_h1
evapo_h2
evapo_h3
pasto1_c1
pasto1_c2
pasto1_h1
pasto2_c1
pasto2_h1
pasto3_c1
pasto3_c2
pasto4_c1
pasto4_c2
pasto5_c1
proc6_c1
proc6_c2
proc6_c3
proc7_c1
proc8_c1
proc9_c1
proc10_c1
heat_c1
clean_c1
121
Energy
Electricity Fuel
Tin
[ C]
Tout
[ C]
Heat load
[kWh/t]
DTmin=2u
100
5
0.3
100
44
44
44
6
48
75
79
54
74
6
69
8.5
66
105
78
95
15
70
35
32
35
85
190
0.5
2.5
190
5
25
44
48
75
4
85
4
80
28
75
26
76
105
78
95
55
70
35
25
35
85
367.8
307
56.9
993.7
32.9
198.1
627.8
568.2
344
904.6
5
41.9
84.1
308.2
32.1
83.3
54.2
131
49.6
49.6
40.4
62.6
33.8
175.5
153
238
2.0
2.0
2.0
3.1
3.1
3.1
3.1
3.6
3.6
3.6
6.8
6.8
2.9
2.9
4.5
4.5
2.9
2.8
2.8
2.8
2.0
2.0
2.0
2.0
2.0
2.0
[ C]
Support
Water Air Inert Gas
Sub-system "all"
Raw
materials
Heat transfer
units (HTU)
Energy
services
Products
Byproducts
1.7
Sub-system 1n
Heat transfer system (HTS) of
parent sub-system 1n
Sub-system
2n
1.8
3.4
Sub-system 1nn
Heat transfer system
(HTS) of parent
sub-system 1nn
Sub-system
2nn
1.5
2.3
Sub-system Sub-system
1nnn
2nnn
1.4
1.4
Heat losses
1
1
1
1
1
1
Solids
Water
Waste
Gas
3. Case study
First, the maximum heat recovery is computed. Exergy losses
can be visualized on Fig. 5a, which shows the hot and cold Carnot
composite curves. The process grand composite curve, presented in
Fig. 5b, is used to dene optimal temperature levels for the energy
conversion system (utilities).
Considering the self-sufcient pockets of Fig. 5b, it can be
deduced that the heat recovery between process streams concerns
process streams below the pinch point. As process streams without
heat exchange restrictions are mainly involved, the heat recovery
penalty of restricted matches due to non-simultaneously process
operations is rather small. The penalty can be evaluated by
comparing the case with heat exchange restrictions and no indirect
heat recovery to the case without any heat exchange restrictions.
The use of intermediate heat transfer networks could only recover
a small amount of heat. The exact penalty due to non-simultaneous
operations can be evaluated using the methodology presented in
Becker and Marchal [2]. In fact, the penalty of 27 kW h/t corresponding to 1% of the hot utility and 3% of cold utility, is quite small
and can be neglected in the following. This means that no supplementary heat transfer units will be integrated to reduce this penalty.
Regarding the necessary temperature levels for heat supply on
Fig. 5b, following utility types are proposed to the process:
122
Fig. 5. Minimum energy requirements. (a) Hot and cold composite curves using the Carnot scale, (b) Grand composite curve.
evaluated: boiler (Case 1a), boiler and heat pump (Case 1b), boiler
and engine (Case 1c) and boiler, heat pump and engine (Case 1d).
For heat pump integration option 2 (Cases 2,3 and 4) the evaporation units are modeled in the thermodynamic representation:
MVR and boiler (Case 2a) and MVR, boiler and engine(Case 2b). For
Cases 3a/b and Cases 4a/b the evaporation unit is rst modied.
For all cases, the on-site available utilities (boiler, refrigeration
and cooling water) are integrated. The rst lines of Table 3 indicates
the selected option and additional proposed utilities.
3.1. Option 1 - No process modications allowed
In the rst approach, the process can not be modied. Thus, the
direct heat exchange between a potential heat pump and the
process is not allowed. The approach presented in appendix is
applied. In the higher level two sub-systems (in this case the
process and the heat pump) cannot exchange heat directly. Moreover, heat cannot be exchanged directly between different periods
and hence the process operation units of different periods are
dened in independent sub-systems (e.g. evaporation unit,
pasteurization units) of the sub-system process. The evaporation
unit can therefore not directly exchange heat with the pasteurization units or the heat pump, but it is possible to exchange heat with
the other process units. Satisfying the required temperature levels,
a closed cycle heat pump using the refrigerant R245fa has been
chosen. By analyzing the shape of the grand composite curve,
appropriate operating conditions for the heat pump and the
intermediate heat transfer units can be estimated. Simultaneously,
Saving potentials higher than 200% are not displayed on this graph
Saving potentials higher than 200% are not displayed on this graph
Savings [%]
150
200
Cost
Fuel
Electricity
CO2 emissions
Primary energy
150
Savings [%]
200
100
50
Cost
Fuel
Electricity
CO2 emissions
Primary energy
100
50
50
50
1a
1b
1c
1d
2a
2b
Case
3a
3b
4a
4b
1a
1b
1c
1d
2a
2b
3a
Case
3b
4a
4b
FR
DE
Euro/
c
fuel
kWh
c
Euro/
el
kWhel
c
Euro/
el
kWhel
CO2el kg/
kWhel
Eprel MJ/
kWhel
0.0392
0.0500
0.0620
0.1080
0.0496
0.0864
0.092
0.631
11.788
10.945
utility, heat pump and heat transfer units are considered in the
MILP model to dene the corresponding optimal ow rates that
minimize the operating costs. The potential of a closed cycle heat
pump without direct heat exchange is illustrated in Fig. 8a. The
saving potential can be increased by minimizing the minimum
temperature difference in the heat exchangers between the heat
pump and the intermediate heat transfer uids. The advantage of
this approach is that only the investment costs related to the heat
pump, heat exchangers and pipes have to be accounted. The
process itself remains unchanged. Thus, the safety and product
quality aspects are also maintained.
3.2. Option 2 - process modications allowed
In the second option, process modications are allowed. This
leads to more heat pump integration opportunities. For example,
operating pressures of the process can be modied to improve heat
recovery, and mechanical vapour re-compression (MVR) units can
replace the thermal vapour re-compression unit. Case 2 replaces
the thermal vapour re-compression with a mechanical vapour recompression. The layout and the pressure levels of the evaporation effects are kept. The steam leaving the third effect at about
60 C is compressed mechanically to 74 C. As the DT is less than
18 C, a dynamic compressor is suitable and therefore selected
(Fig. 8b). In Case 3, all effects are realized in parallel and mechanical
vapour re-compression is integrated. The temperature difference
for a mechanical vapour re-compression in Fig. 8c is small (<10 C).
The pressure levels of the ve effects are adapted, so that all effects
evaporate at about 70 C. In Case 4, the pressure of effects are
modied and mechanical vapour re-compressions are included:
rst the new temperature levels have to be dened. Assuming that
123
the heat exchange area in the effects will not be changed, the
temperature levels of effects 4 and 5 are reduced (see Eq. (5)). The
new temperature levels are 48 C (effect 4) and 32 C (effect5).
Theoretically, it could be possible to raise waste heat at 32 C with
a heat pump to satisfy a part of the heat demand in effect 1.
However, high temperature lifts make such heat pump integration
not optimal. The use of successive mechanical vapour recompressions between the different effects have therefore been
preferred (Fig. 8d). The temperature of effect 5 is quite low. If these
operating conditions can not be reached in the unit, it could also be
possible to raise the temperature levels of all effects.
Q_ U*A* Tvap Tprod
(5)
Table 3
Process integration results for France (FR) and Germany (DE).
Case
1a
1b
1c
1d
2a
2b
3a
3b
4a
4b
Option
hp
cog
hp cog
mvr
mvr cog
mvr
mvr cog
3mvr
3mvr cog
126.0
166.0
2895.0
2895.0
194.0
194.0
e
e
602.6
707.2
15314.4
15150.8
e
e
e
e
e
e
e
e
e
e
97.8
127.3
2358.5
2358.5
86.6
86.6
955.3
955.3
484.4
531.0
11.6
11.6
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
87.6
117.4
1921.7
1921.7
197.1
197.1
672.7
672.7
406.3
512.6
11.0
10.8
246.8
246.8
794.6
794.6
0.0
0.0
0.0
0.0
4.0
4.1
95.9
117.7
2527.1
2758.6
63.2
234.2
945.2
968.9
504.6
409.5
10.6
9.9
0.0
0.0
0.0
0.0
334.4
716.0
413.4
552.7
11.2
3.0
87.6
114.6
1921.7
2293.0
197.1
0.0
672.7
798.0
406.3
463.2
11.0
10.3
246.8
133.4
794.6
456.9
0.0
326.7
0.0
410.5
4.0
3.5
88.9
117.9
2023.7
2023.7
154.8
154.8
1003.6
1003.6
423.0
506.5
10.9
10.8
239.1
239.1
516.7
516.7
0.0
0.0
0.0
0.0
3.0
2.8
85.5
93.3
3041.6
3041.6
L680.3
L680.3
1017.1
1017.1
551.8
185.1
5.7
6.2
264.5
264.5
565.9
565.9
1880.4
1880.4
961.7
961.7
6.4
2.3
86.2
117.7
1770.5
1770.5
270.2
270.2
464.1
464.1
382.5
528.2
11.2
10.9
641.9
641.9
1256.9
1256.9
0.0
0.0
0.0
0.0
5.5
6.7
81.3
94.0
2605.3
2605.3
419.9
419.9
469.8
469.8
487.6
261.3
6.8
7.1
651.7
651.7
1274.2
1274.2
1546.9
1546.9
846.9
846.9
6.6
3.3
69.4
95.3
1394.9
1394.9
237.0
237.0
512.9
512.9
303.6
431.3
9.1
8.9
525.9
525.9
1160.3
1160.3
0.0
0.0
0.0
0.0
2.1
1.9
65.5
79.6
1893.0
1893.0
174.6
174.6
516.3
516.3
366.3
272.2
6.5
6.6
539.1
539.1
1185.4
1185.4
927.2
927.2
628.6
628.6
2.9
1.9
Utilities
OpC [e/t]
ef [kWh/t]
eel [kWh/t]
Cooling [kWh/t]
mCO2 [kg/t]
ep [MJ/t]
E_ hp kW
InvChp [ke]
E_ cog kW
InvCcog [ke]
PR [years]
FR
DE
FR
DE
FR
DE
FR
DE
FR
DE
FR
DE
FR
DE
FR
DE
FR
DE
FR
DE
FR
DE
124
Fig. 8. Comparison of Carnot composite curves. (a) Integrated composite curves Case 1d, (b) Integrated composite curves Case 2b, (c) Integrated composite curves Case 3b, (d)
Integrated composite curves Case 4b.
COP
Q_ H
E_
hp
(6)
Type
Fluid [kW]
Teva [ C]
Tcond [ C]
E_ hp=mvr [kV]
COP [-]
1b FR/DE
1d FR
1d DE
2a FR/DE
2b FR/DE
3a FR/DE
3b FR/DE
4a FR/DE
4a FR/DE
4a FR/DE
4b FR/DE
4a FR/DE
4a FR/DE
HP
HP
HP
MVR
MVR
MVR
MVR
MVR1
MVR2
MVR3
MVR1
MVR2
MVR3
R245fa
R245fa
R245fa
water
water
water
water
water
water
water
water
water
water
30
30
30
57
57
66
66
28
46
57
28
46
57
90
90
90
74
74
74
74
36
52
74
36
52
74
386
386
209
239
264
642
652
141
92
294
141
92
307
3.6
3.6
3.6
14.8
14.8
32.3
32.3
28.5
40.4
14.8
28.5
40.4
14.8
PR InvCtot =B
Although these denitions are widely used in industry, theoretically they are only correct for a heat pump having its heat source
at ambient temperature. It is important to note that a heat pump
with a high COP can even be counterproductive when it is not
appropriately integrated. In order to be compatible with the well
known conventions, the COP will be related to a performance of the
heat pump machine by using this denition. But to be rigorous
when comparing heat pump cycles, global results and the exergy
efciency is preferably used.
0:9
InvC f $1500$1600:1 $E_ hp
2
InvC 0:68* 0:0391$E_ cog 850:89$E_ cog 306016
0:8
125$E_ cog $1477:7=1068:3
125
(7)
The authors wish to thank ECLEER for supporting this research
and collaborating in its realization.
(8)
(9)
126
fu
q
rk
yu
E_ el;u
E_ f ;u
~cu
cel
cf
cu
nf
nk
nps
ns
nsub
nu
yu $fumin f u yu $fumax
f u Q_ h;s;k;u
ns
c;s;k
X
cs;k 1
hs;k 1
R_ s;k 0
Subscripts
hts
Index for heat transfer system
k
Temperature interval
s
Index for sub-system
(A.5)
ck 1:::; nk
R_ s;1 0 R_ s;nk1 0
R_ s;k 0
cs 1:::; nsub
ck 2:::;nk
A:6
cs 1:::;nsub
(A.7)
Fobj min@dtot $@
nf
X
f 1
_
c
el E el
nu
X
c
f
nu
X
u1
f u E_ f ;u
E_
c
el el
11
(A.1)
f u cu AA
u1
Eq. (A.2) states that the total electricity import and the produced
electricity by the process have to be greater or equal to the process
electricity consumption. The overall electricity balance is given by
Eq. (A.3). Both equations are necessary to distinguish the price for
electricity import and export.
nu
X
f u E_ el;u E_ el
u1
nu
X
f u E_ el;u 0
(A.2)
Q_ htss;s;k 0
Q_ htss;s;k 0
system Q_ htss;s;k . R_ s;k is the cascaded heat to the lower temperature interval k in sub-system s.
The heat cascade for the heat transfer system (hts) for each
f u Q_ h;hts;k;u
u1
f u E_ el;u E_ el E_ el
u1
nu
X
f u E_ el;u 0
(A.3)
u1
E_ el 0
E_ el 0
(A.4)
c
el
c
el
ered to unit u by the fuel (e.g. natural gas) and E_ el;u is the nominal
electricity demand () or excess () of unit u. cu is the nominal
operating cost per hour of unit u (excluding the fuel and electricity
costs of unit u).
nsX
c;hts;k
chts;k 1
nsubhts
X k
Q_ htss;s;k
s1
cs 1:::;nsub
(A.8)
hhts;k 1
nu
X
ck 1:::;nk
R_ hts;k 0
nsubhts
X k
Q_ htss;s;k R_ hts;k1
(A.9)
s1
127
_ R
_ are replaced
All heat loads and energy consumptions Q_ ; E;
with their corresponding specic values q;eel ;rk . And Eqs.
(A.2)e(A.12) can be solved using the specic values.
f u Q_ h;hts;k;u Q_ hts1;k R_ hts;k1 R_ hts;k
hhts;k 1
nsubhts
X k
Q_ htss;s;k 0
References
s1
nsX
c;hts;k
(A.11)
chts;k 1
nsubhts
X k
Q_ htss;s;k 0
s1
(A.12)
Appendix A.2. Adaptation when using time average approach
With heat exchange restrictions in different levels, the combination of restricted matches due to industrial constraints and
restricted matches due to batch operations become possible. Using
mean values, heat loads and energy quantities are expressed in
kWh per tons of produced cheese [kWh/t]. By convention, small
letters are used for specic quantities. The nominal unit operating
cost cu has therefore to be expressed in Euro/t (new: ~cu ) and the
previous formulation has to be adapted. The objective function has
been re-written in Eq. (A.13).
0
Fobj OpC min@
nf
X
f 1
c
f
nu
X
u1
!
f u e
f ;u
c
e c
el eel
el el
nu
X
1
f u ~cu A
u1
(A.13)