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Jiangsu Key Laboratory of Urban and Industrial Safety, Institute of Safety Engineering, School of Urban Construction and Safety Engineering,
Nanjing University of Technology, Nanjing 210009, Jiangsu, China
b
State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process, School of Resources and Environmental Engineering,
East China University of Science and Technology, Shanghai 200237, China
a r t i c l e i n f o
a b s t r a c t
Article history:
Received 31 August 2010
Received in revised form
23 June 2011
Accepted 26 June 2011
More specic and accurate probabilistic models of the numbers of fragments generated respectively by
Boiling Liquid Expanding Vapor Explosions (BLEVEs), Mechanical Explosions (MEs), Conned Explosions
(CEs), and Runaway Reactions (RRs) of a horizontal cylindrical vessel were developed using the
maximum entropy principle based on historical accident data. The theoretical results from the four
probability density functions were compared to the observed data, and the numbers of fragments followed discrete exponential distributions in the interval [1, 9]. Beside the summary of the probabilistic
distributions of the other random variables in the process of fragment projection, the effects on the
fragment trajectory and target terms were investigated using a parametric approach. The results showed
that using the complete model, wind shear, turbulence, and absence of fragment rotation caused the
fragments to impact within shorter distances; fragment rotation and lack of wind decreased the probability of impact within a given distance, but the rupture probability of the target was not affected by
fragment rotation or wind. The probabilistic condence intervals of fragment range, impact, and target
penetration became narrower with the number of simulation runs, but the accuracy of the results
increased. The probability of fragment impact increased with the volume of the target vessel and the
degree of lling of the explosion vessel, but did not depend on the kind of explosion. The probability of
target rupture increased slowly with the degree of lling of the explosion vessel, but was little inuenced
by the volume of the target vessel or the kind of explosion.
2011 Published by Elsevier Ltd.
Keywords:
Domino effect
Industrial explosion
Monte-Carlo simulations
Number of fragments
Parametric approach
1. Introduction
In chemical process industries, the domino effect is a wellknown cause of major accidents (Antonioni, Spadoni, & Cozzani,
2009; Cozzani, Antonioni, & Spadoni, 2006; Nguyen, Mbarki,
Ami Saada, Mercier, & Reimeringer, 2009). An accidental event
which starts at one unit may damage another through heat radiation, blast waves, or projectiles. In reality, a sudden explosion can
generate many fragments which can be projected over long
distances, threaten other sites located in the vicinity, and lead to
more severe consequences due to the nature of the domino effect.
Fragment projection in an explosive accident is one important
cause of the domino effect on chemical process equipment
(Pietersen, 1988). The overall domino effect caused by fragments is
composed of a set of elementary cycles, and each cycle includes
* Corresponding author. Mail Box 13, No. 200 Zhongshan North Road, Nanjing
University of Technology, Nanjing 210009, China. Tel.: 86 25 83587421; fax: 86
25 83239973.
E-mail addresses: jcjiang@njut.edu.cn, j_c_jiang@163.com (J. Jiang).
0950-4230/$ e see front matter 2011 Published by Elsevier Ltd.
doi:10.1016/j.jlp.2011.06.029
D. Sun et al. / Journal of Loss Prevention in the Process Industries 25 (2012) 114e126
Bosch & Weterings, 1997; Zhang & Chen, 2009). In recent work
(Mbarki, Mercier, et al., 2009; Mbarki, Nguyen, et al., 2009;
Mbarki et al., 2007, 2008; Nguyen et al., 2009), the mechanical
and kinetic features of the source terms (random variables such as
number of fragments, shape, and mass) were investigated, and the
corresponding probabilistic distributions were developed using the
maximum entropy principle for the source terms. In the fragment
trajectory term, trajectory equations for the fragments were
proposed, and the ground distributions of the fragments were
assessed. In the target term, probabilistic models of fragment
impact were developed, a calculation of the impact probability was
carried out, and its effects on the probability of impact were evaluated. As for target damage, a simplied plastic model for evaluating the probability of rupture with high reliability was proposed,
and its inuence on penetration depth was investigated. However,
in the analysis described above (Mbarki, Mercier, et al., 2009;
Mbarki, Nguyen, et al., 2009; Mbarki et al., 2007, 2008; Nguyen
et al., 2009), for the source terms, i.e. the development of a probabilistic model for the number of fragments from a horizontal
cylindrical vessel explosion, available accident data were scarce, and
only BLEVEs (Boiling Liquid Expanding Vapor Explosions) resulting
in fragment projection had been considered; for a spherical vessel
explosion, a uniform distribution of the number of fragments within
the interval from 1 to 19 was assumed. Furthermore, the characteristics of fragment ight, impact, and penetration into nearby
facilities, i.e., the fragment trajectory and target terms, still need to
be improved. Generally speaking, the accuracy of quantitative risk
analysis for industrial sites relies intimately on the hypotheses and
the adequacy of the models developed for the whole domino-effect
sequence. On the basis of these ndings (Mbarki, Mercier, et al.,
2009; Mbarki, Nguyen, et al., 2009; Mbarki et al., 2007, 2008;
Nguyen et al., 2009), improvements was made to dene more
specic and accurate probabilistic models of the number of fragments from a horizontal cylindrical vessel explosion by collecting
and analyzing data from past accidents leading to fragment
projection. The objectives were to recommend a more reasonable
probability density function for the number of fragments from
a spherical vessel explosion, to reach more specic conclusions after
reviewing the reference works on the source terms, and then to
explore the effects of the algorithms (movement approach, fragment rotation, wind, and number of simulation runs) on the fragment trajectory and target terms (the ground distributions of
fragments, the probability of impact between the fragments and the
target, and the rupture probability of the impacted target) and the
inuence of the calculation parameters (the objective volume, the
degree of lling of the source vessel, and the kind of explosion) on
the target term (the probability of fragment impact and the rupture
probability of the target) using Monte-Carlo simulations including
the improved source terms, the kinematics of projectiles, and
probabilistic models of fragment impact, penetration, and damage.
3. Source terms
An industrial explosion may generate many fragments with
various features, which can be considered as random variables:
number of fragments (N), shape and size (fP), mass (m), initial
velocity at departure (vO), initial departure angles (horizontal and
vertical angles, q and 4), aerodynamic coefcients (lift and drag
coefcients, CL and CD), and degree of lling of the source vessel (f).
3.1. Number of fragments, N
3.1.1. Case of horizontal cylindrical vessel explosion
In recent work (Mbarki, Mercier, et al., 2009; Mbarki, Nguyen,
et al., 2009; Mbarki et al., 2007, 2008; Nguyen et al., 2009), the
115
Table 1
Accident data for horizontal tank from Gubinelli and Cozzani.
Source: Gubinelli and Cozzani
(2009a,b)
Number of fragments
1
[5e9]
Explosion category
BLEVE
Number of events
56
35
ME
Number of events
CE
Number of events
RR
Number of events
Number of fragments
4
Number of events
9
17
11
5
11
11
17
10
12
116
D. Sun et al. / Journal of Loss Prevention in the Process Industries 25 (2012) 114e126
Table 3
Overall number of events for the four explosion categories for horizontal tanks and the corresponding observed probabilities of number of fragments.
Explosion category
Number of fragments
1
BLEVE
Number of events
Observed frequency
50
0.1931
98
0.3784
78
0.3012
24
0.0927
3
0.0116
2
0.0077
3
0.0116
0
0
1
0.0037
ME
Number of events
Observed frequency
0
0
6
0.7500
1
0.1250
1
0.1250
0
0
0
0
0
0
0
0
0
0
CE
Number of events
Observed frequency
0
0
9
0.9000
0
0
0
0
1
0.0200
0.0200
0.0200
0.0200
0.0200
RR
Number of events
Observed frequency
2
0.2857
3
0.4286
1
0.1429
0
0
1
0.02856
0.02856
0.02856
0.02856
0.02856
(1)
E1
9
X
i$PiObserved
(2)
i E1 2 PiObserved
(3)
i1
E2
9
X
i1
PN exp l0 l1 N l2 N 2
8P
2
>
1
> exp l0 l1 i l2 i
>
>
D
>
<P
i$exp l0 l1 i l2 i2 E1
>
D
>
>
P
>
>
: i E1 2 $exp l0 l1 i l2 i2 E2
(4)
(5)
PN exp 2:16 0:97N 0:24N 2
p:d:f : of the number of fragments from BLEVE
PN exp 6:26 4:80N 1:01N 2
p:d:f : of the number of fragments from ME
PN exp 0:93 0:11N 0:05N 2
p:d:f : of the number of fragments from CE
PN exp 0:20 0:72N 0:03N 2
p:d:f : of the number of fragments from RR
D. Sun et al. / Journal of Loss Prevention in the Process Industries 25 (2012) 114e126
117
Fig. 1. Theoretical and accident probabilities versus number of fragments from BLEVE, ME, CE, and RR.
E
1
g1=g
p0
p
p1
g 1 0
fV
p1
p1 g 1
Ek cE
vO
p
2Ek =m
(10)
(11)
(12)
118
D. Sun et al. / Journal of Loss Prevention in the Process Industries 25 (2012) 114e126
Table 4
Features of source terms and their probabilistic distributions.
Features of source terms
N: Number of fragments
m: Fragment mass
vO: Departure velocity
(multiplicative factor c)
q: Horizontal departure
angle
f: Degree of lling of
source
source vessel, V the volume of the source vessel, and c a multiplicative factor.
The trajectory of the fragments projected from the exploded
vessels results from the combined effects of inertia, gravitation, and
aerodynamics (drag and lift). Let (O, X, Y, Z) be the set of system
axes used for the trajectory description, and let O be the departure
point for a generated fragment. The fragment trajectory can be
described as shown in Fig. 2 (Mbarki, Nguyen, et al., 2009). After
the fragment has been projected, an impact is possible with any
potential target that crosses its trajectory.
For fragment movements, the complete movement approach is
used (Mbarki, Mercier, et al., 2009; Mbarki, Nguyen, et al., 2009;
Mbarki et al., 2007, 2008; Nguyen et al., 2009):
The same mass for all the fragments (Mbarki, Mercier, et al., 2009)
Exponential distribution (Mbarki, Mercier, et al., 2009; Mbarki,
Nguyen, et al., 2009)
Uniform distribution within the interval [0 e360 ] (Mbarki,
Mercier, et al., 2009; Mbarki, Nguyen, et al., 2009)
8
2
q
>
_ y_ 2 z_ 2
4
q
4
q
$cos
$cos
1
$k
$sin
$cos
$
x
k
x 0
>
D
L
>
<
2
2
2
q
_
_
_
kD $cos4$sinq 1 $kL $sin4$sinq $ x y z y 0
>
>
>
: 1q $k $sin4 k $cos4
$ x_ 2 y_ 2 z_ 2 z g 0
D
L
(13)
et al., 2009; Mbarki et al., 2007, 2008; Nguyen et al., 2009), the
impact probability between the projectiles and the potential target
can be calculated. Monte-Carlo simulations were run to evaluate
the probability of impact, Pimp, in the light of Eq. (14):
PNsim PN
s1
Pimp
nj; s
N
and nj; s
Nsim
if Vtarget XVfragment sf
otherwise
j1
(14)
D. Sun et al. / Journal of Loss Prevention in the Process Industries 25 (2012) 114e126
119
Table 5
Characteristics of source and target vessels in Nanjing Chemical Industry Park of
China.
Source A
Type
Horizontal
cylindrical
vessel
200
Volume/m3
Vessel diameter/m
2.8
Failure pressure/MPa 1.20
Atmospheric
0.1
pressure/MPa
Mass/kg
25,429
Wall thickness/m
0.024
Center coordinates
(0, 0, 0)
Critical residual
e
thickness/m
Source B
Target A
Target B
Spherical
vessel
Spherical
vessel
Spherical
vessel
1000
6.2
1.01
0.1
800
5.8
0.98
0.1
2400
8.3
1.26
0.1
121,886
88,761
0.026
0.020
(40 m, 0, 0) (0, 40 m, 6 m)
e
0.004
22,4301
0.029
(0, 40 m, 9 m)
0.006
s
Ec 2=3
2 4
dP cos h dP cos h tan h
p
fu 3u
hP
for the case hs0
2 tan h
(15)
hP
Ec
pdP fu 3u
2=3
(16)
(17)
120
D. Sun et al. / Journal of Loss Prevention in the Process Industries 25 (2012) 114e126
Fig. 3. Theoretical simulations using complete and simplied models versus range.
VWi ri ; t
r2
G0i
1 exp i
2pri
4yt
!!
(18)
uW
ns
X
xWi
i1
wW
ri
VWi
ns
X
zWi
i1
ri
VWi
(19)
(20)
q
where xWi x xWi0 , zWi z zWi0 , ri x2Wi z2Wi , and xWi0
and zWi0 are the coordinates of the vortex center.
The time spectrum of the turbulent velocity can be calculated
using Drydens atmospheric turbulence model (Liu et al., 2006):
8
L
1
>
>
Fuu u s2u u
>
>
>
p
vT 1 Lu =vT u2
>
>
>
2
>
>
>
< Fvv u s2 Lv n1 12Lv =vT uo
v
2
pvT
1 4Lv =vT u2
>
>
>
>
>
>
L
1 12Lw =vT u2
>
>
Fww u s2w w n
>
o2
>
p
v
>
T
:
1 4Lw =vT u2
(21)
where Lu, Lv, and Lw are respectively the turbulence scales of the
three directions; su , sv , and sw are the turbulence intensities in the
three directions; vT is the velocity of the fragment when it passes
through the turbulence eld; and u is the time frequency.
In the models described above, the wind velocity can be
assumed constant because the velocity of the fragment is much
larger than the wind velocity and its variations. Therefore, variations in the wind eld can be neglected according to the frozen
eld hypothesis (Liu et al., 2006).
As discussed above, the results for the distributions of the
fragments on the ground with no wind and with wind shear and
turbulence were obtained without fragment rotation (Fig. 5). The
results show that wind shear and turbulence caused the fragments
to impact in shorter distances than under no-wind conditions for
Sources A and B, and that the ground distributions of the fragments
with wind shear were almost the same as those with turbulence.
Fig. 4. Theoretical simulations with no rotation and with rotation versus range.
D. Sun et al. / Journal of Loss Prevention in the Process Industries 25 (2012) 114e126
121
Fig. 5. Theoretical simulations with no wind, wind shear, and turbulence versus range.
Fig. 6. Theoretical simulations with different numbers of simulation runs versus range.
range of 0e100 m corresponding to 103, 104, 105, 106, 107, 108, 109, and
1010 simulations for Source A were: [0.13104, 0.16818], [0.14466,
0.15645], [0.14844, 0.15217], [0.14964, 0.15082], [0.14975, 0.15012],
[0.15017, 0.15029], [0.15013, 0.15017], and [0.15038, 0.15039]; the
condence intervals of the probabilities in the range of 0e100 m
corresponding to 103, 104, 105, 106, 107, 108, 109, and 1010 simulations
for Source B were: [0.15376, 0.17617], [0.16141, 0.16849], [0.16373,
0.16598], [0.16452, 0.16523], [0.16487, 0.16509], [0.16495, 0.16502],
[0.16483, 0.16485], and [0.16484, 0.16484]. These results demonstrate
that the probabilistic condence interval became narrower with
122
D. Sun et al. / Journal of Loss Prevention in the Process Industries 25 (2012) 114e126
Fig. 8. Comparison of rupture probabilities of the target with no rotation and with rotation.
Fig. 9. Comparison of probabilities of impact with no wind, with wind shear, and with turbulence.
D. Sun et al. / Journal of Loss Prevention in the Process Industries 25 (2012) 114e126
123
Fig. 10. Comparison of rupture probabilities of the target with no wind, with wind shear, and with turbulence.
124
D. Sun et al. / Journal of Loss Prevention in the Process Industries 25 (2012) 114e126
D. Sun et al. / Journal of Loss Prevention in the Process Industries 25 (2012) 114e126
125
126
D. Sun et al. / Journal of Loss Prevention in the Process Industries 25 (2012) 114e126
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