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Structured Questions
Chemistry: Chapter 38 Rate of chemical reaction
Sections 38.138.2
1
In a chemical reaction A + B C, the amount of reactant A recorded at one-minute
intervals was shown below.
Time(t) (min)
Amount of A (mol)
(a)
(b)
(c)
(d)
0.800
0.400
0.200
0.100
Calculate the average rate of reaction (in mol s ) during the 6 minutes.
Plot a graph of amount of A against time.
According to the graph, what is the initial rate of the reaction?
According to the graph, what is the instantaneous rate at t = 3 min?
[5M]
2
In the reaction of excess magnesium and 10.0 cm3 of 2.0 M dilute hydrochloric acid,
hydrochloric acid was used up in 10 seconds and 48.0 cm3 of hydrogen was formed at
room temperature and pressure.
(a) Calculate the average rate of formation of hydrogen in cm3 s1.
(b) Calculate the average rate of decrease of HCl in
(i) M s1.
(ii) mol s1.
(c) Calculate the average rate of formation of magnesium chloride in mol s1.
[5M]
3
Consider the following reaction:
2NaHCO 3 (s) + H 2 SO 4 (aq) Na 2 SO 4 (aq) + 2H 2 O(l) + 2CO 2 (g)
When 3.5 g of sodium hydrogencarbonate was added to 25.0 cm3 of 3.0 M sulphuric
acid, the sodium hydrogencarbonate reacted and disappeared in 180 seconds.
(a) Which of the two reagents is in excess?
(b) Calculate the average rate of decrease of sodium hydrogencarbonate in g s1.
(c) Calculate the average rate of decrease of sulphuric acid in M s1.
(d) Calculate the average rate of production of carbon dioxide in g s1.
[7M]
4
Consider the following reaction:
82
0.8
0.4
0.2
0.1
0.05
0.025
0.0125
(a) Calculate the average rate of change in the amount of A in the mixture in mol
min1 throughout the reaction.
(b) Plot a graph of Amount of A against Time.
83
at various times in the course of the reaction. The graph as shown below is obtained.
Concentration of a reactant
X
YZ
0
Time
excess
Br 2 (aq) + HCO 2 H(aq) 2Br(aq) + 2H+(aq) + CO 2 (g)
(a) Suggest and explain ONE method to monitor the change in concentration of
Br 2 (aq) during the reaction.
(b) Sketch a graph to show the change of the physical parameter measured in part (a)
with time.
[6M]
8
A student finds that baking soda gives colourless bubbles when it is added to
hydrochloric acid. He wants to follow the progress of the reaction by measuring the
pressure change of the reaction system with time.
(a) Write a chemical equation to show the reaction involved.
(b) Draw a labelled diagram to show the experimental set-up.
(c) In the experiment, he used 30 cm3 of 2.0 M hydrochloric acid to react with 5 g of
baking soda. The pressure inside the container increased from 1.0 atm to 1.2 atm
in 2 minutes.
(i) Which of the two reactants is limiting? Explain your answer.
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0.30
0.15
0.10
12
0.063
16
0.043
20
0.027
85
excess
dilute
HCl
egg
shells
pressure
sensor
data-logger
computer
86
Pressure (kPa)
Time (s)
(f)
14
Consider the alkaline hydrolysis of ethyl ethanoate:
CH 3 COOCH 2 CH 3 (aq) + NaOH(aq) CH 3 COONa+(aq) + CH 3 CH 2 OH(aq)
The reaction progress is monitored by titrimetric analysis. At each 15-minute interval,
5.0 cm3 of the reaction mixture is transferred into a beaker and an excess fixed
amount of standard hydrochloric acid is added to it.
(a) What is the purpose of adding excess HCl to the reaction mixture?
(b) Describe how to find the amount of NaOH present in the reaction mixture.
(c) (i) State ONE alternative way instead of adding excess HCl to serve the same
purpose.
(ii) State ONE disadvantage of this alternative way.
[6M]
15
A student followed the progress of the reaction between a magnesium strip and excess
dilute hydrochloric acid. The set-up for the experiment was shown below.
87
gas syringe
magnesium strip
Volume of X
collected (cm3)
17
29
36
42
44
44
44
(a)
(b)
(c)
(d)
88
19
Consider the following reaction in an open system:
ZnCO 3 (s) + 2HCl(aq) ZnCl 2 (aq) + H 2 O(l) + CO 2 (g)
(a)
(b)
(c)
(d)
Time (min)
12.0
6.05
2.23
0.82
0.30
10
0.11
20
Suggest method(s) that can be used to measure the rate of reaction of the following
reactions. (There may be more than one method in each of the following reaction.)
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cotton thread
plunger
gas syringe
stopwatch
90
(e) The volumes of X collected are recorded at one-minute intervals. The results are
shown below.
Time (t)/min
Volume of X
collected/cm3
17
29
37
42
44
44
44
Do you expect the reaction to have completed by the sixth minute? Explain
briefly.
(f) Plot a graph for Volume of X collected against Time.
(g) Sketch the graph for Mass of magnesium ribbon against Time.
[10M]
23
Consider the following reaction.
2MnO 4 (aq) + 5C 2 O 4 2(aq) + 16H+(aq) 2Mn2+(aq) + 10CO 2 (g) + 8H 2 O(l)
The reaction is carried out inside a test tube. Colorimetric analysis is adopted to
monitor the reaction progress.
(a) Describe what you can observe in the test tube when the reaction is going on.
(b) A student argues that the colour change of the solution during the reaction is
mainly due to formation of water which causes dilution of the solution. Do you
agree with him? Give your reason.
(c) Sketch the graph for Concentration of MnO 4 (aq) against Time.
[6M]
Chemistry: Chapter 39 Factors affecting rate of reaction
Sections 39.139.3
24
A student did the following experiments to investigate the rate of reaction between
magnesium and different acids. Magnesium was the limiting reactant in both
experiments.
(a)
(b)
(c)
(d)
Experiment
Reaction
II
91
Trial
[HCl] (mol dm )
2.00
0.250
36.0
1.00
0.250
48.0
0.500
0.250
57.0
0.250
0.250
68.0
0.125
0.250
121
0.0625
0.250
158
[S 2 O 3
1
for trials 1 to 6.
t
1
against [HCl].
t
1
and [HCl]. Do you think the relationship
t
between the rate of reaction and [HCl] is similar too? Explain your answer.
(e) Briefly explain the effect of [HCl] on the rate of reaction.
[9M]
26
The graph below shows the volume of carbon dioxide gas produced against time
when excess calcium carbonate is added to x cm3 of 2.0 M hydrochloric acid.
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Volume of CO 2
Time
(a) Write an ionic equation for the reaction.
(b) State and explain the change in the rate of reaction with time. Give a method to
determine the rate of the reaction at a particular time from the curve.
(c) Sketch, on the same graph, the curves would be obtained if:
(i) the same volume of 1.0 M HCl is used.
(ii) the volume of 1.0 M HCl used is doubled.
Label the curves and explain your answer in each case.
[10M]
Section 39.4
27
(a) A student claimed that the temperature of water is always equal to 100oC when it
boils, no matter what type of container is used. Comment on his statement.
(b) Explain, using the collision theory, why a pressure cooker can decrease the time
of cooking.
(c) Suggest ONE advantage of using a pressure cooker apart from decreasing the
time of cooking.
[6M]
28
H 2 O 2 (aq) decomposes to water and oxygen in the presence of MnO 2 powder.
(a) Write a balanced equation for the reaction.
(b) State the function of MnO 2 .
(c) Explain why MnO 2 is used in powdered form.
(d) Explain whether the MnO 2 powder can be reused after the reaction.
(e) Draw a set-up to follow the reaction rate of the chemical reaction.
(f) Give two critical requirements for other reactions so that the set-up mentioned in
(e) can be used to follow the reaction rate.
[10M]
29
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In the presence of an acid, potassium iodide reacts with oxygen to give iodine and
water. The reaction rate of this reaction was measured at several temperatures in order
to investigate the effect of temperature on the rate of reaction.
(a) Write a balanced ionic equation for the above reaction.
(b) Outline the procedure of an experiment, which can be used to investigate the
effect of temperature on reaction rate of the reaction by titrimetric analysis.
(c) (i) Sketch a graph showing the relationship between the reaction rate and
temperature. (Label the axes clearly.)
(ii) Explain whether the graph is a straight line or an exponential curve.
[10M]
30
The reaction between ammonium chloride and sodium nitrite in aqueous solution can
be represented by the following equation.
NH 4 Cl(aq) + NaNO 2 (aq) N 2 (g) + 2H 2 O(l) + NaCl(aq)
The graph below shows the change in volume of nitrogen gas with time from a
Volume of N 2 (cm3)
Time (s)
(a) (i)
Describe the change in rate of formation of nitrogen with time. Explain your
answer in terms of collision theory.
(ii) Explain why the volume of nitrogen eventually remains constant.
(iii) What was the maximum volume of nitrogen produced?
(iv) At what time was the reaction half completed?
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(b) (i)
State and explain any change in the rate of formation of nitrogen if the
1
2
3
Reaction conditions
25C
25C
50C
Sketch, on the same graph, the three curves obtained from the experiments.
(c) Explain the differences in the initial rates between
(i) Experiments 1 and 2.
(ii) Experiments 2 and 3.
[11M]
32
Sulphuric acid reacts with zinc powder to form zinc sulphate and hydrogen gas.
(a) Write a balanced ionic equation for the above reaction.
(b) Explain the effect of concentration of reactants on reaction rate.
(c) State and explain the effect of adding the following chemicals on the
concentration of hydrogen ions and the rate of production of hydrogen gas.
(i) Adding solid sodium carbonate
(ii) Adding potassium sulphate solution
(iii) Bubbling hydrogen chloride gas
(d) Explain any difference in the rate of the reaction if the same mass of zinc
granules is used instead of zinc powder at the same temperature and pressure.
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[15M]
33
A student took a lump of limestone (calcium carbonate) weighing exactly 1 g and
dissolved it in an excess amount of hydrochloric acid. The gas given off during this
reaction was collected and its volume was measured at regular time intervals. The
experiment was repeated using small fragments of limestone. The table below gives
the results:
Time (min)
Experiment A
Volume of gas (cm3)
Experiment B
Volume of gas (cm3)
11.0
18.5
22.0
37.5
33.0
54.5
43.5
67.5
53.5
74.5
63.0
78.5
71.0
80.0
77.5
80.0
79.5
80.0
10
80.0
80.0
11
80.0
80.0
12
80.0
80.0
(a) The experiment was designed to show the effect of using solid particles with
different surface areas. Suggest TWO factors that should be kept constant in
these experiments.
(b) Plot, on the same graph, the rate curves obtained from experiments A and B.
State which experiment used a lump of limestone.
(c) With reference to the results of these experiments, explain the following
phenomena briefly.
(i) Aluminium foil can be stored safely but containers of aluminium dust carry
the hazard warning DUST EXPLOSION POSSIBLE.
(ii) Twigs are better for lighting fires than logs.
[9M]
34
When excess lumps of magnesium carbonate are added to dilute hydrochloric acid,
the following reaction takes place.
MgCO 3 (s) + 2HCl(aq) MgCl 2 (aq) + CO 2 (g) + H 2 O(l)
(a) Suggest TWO ways to study the rate of this reaction. In each case sketch a graph
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to show the change in the value of the chosen variable with time.
(b) State and explain TWO ways in which the rate of the reaction can be increased.
(c) State and explain whether the total volume of carbon dioxide gas produced
would increase, decrease or remained unchanged if
(i) more lumps of magnesium carbonate were used.
(ii) the experiments were carried out at a higher temperature.
[12M]
35
30 g of Na 2 S 2 O 3 granules reacted with 250 cm3 of 0.50 M I 2 solution.
(a) Write a balanced ionic equation for this reaction.
(b) Which of the reactants is the limiting reagent?
(c) Suggest TWO methods to increase the rate of the reaction.
(d) What physical property can be measured to monitor the reaction?
[7M]
36
A student carried out five experiments to investigate the factors affecting reaction rate
of the reaction between magnesium and dilute hydrochloric acid. Five rate curves
were obtained from these experiments. Magnesium metal is in excess in the five
experiments. The table below shows the experimental conditions in each experiment.
1
20
75
70
70
50
2.0
2.0
3.0
3.0
3.0
20
35
50
35
35
Size of Mg
ribbons
granules
powder
granules
powder
Experiment
3
Volume of H 2 (g)
(a) Explain why sodium is not used to carry out the experiment.
(b) Assign the following rate curves to their corresponding experiments.
Time
97
Change in
rate, if any
reaction
Reason
Using 5 g of powdered
zinc
Using 3 g of zinc
granules
[Remarks: Assume that
the size of granules
remains unchanged.]
Using 100 cm3 of 2.0 M
ethanoic acid
Changing the temperature
to 40C
Adding a few drops of
aqueous copper(II) nitrate
Simply state in the table whether you would expect the rate to be increased, decreased
or unchanged, and in each case give a reason for your answer.
[10M]
39
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Amount of X (mol)
0.010
0.0066
0.0046
0.0030
0.0024
0.0020
0.0020
(a) Plot a graph to determine the initial rate of the reaction (in mol s1).
(b) Sketch, on the same graph, the rate curve that would be obtained if a catalyst was
used in the reaction. Label the new curve as b and explain any difference
between the two curves.
(c) The catalyst used in (b) is in the form of granules. Suggest and explain a method
to increase the reaction rate.
[8M]
40
Consider the following reaction:
S 2 O 8 2(aq) + 2I(aq) 2SO 4 2(aq) + I 2 (aq)
(a) Suggest ONE method to measure the reaction rate. Explain your answer.
(b) Except adding a catalyst, suggest TWO methods to increase the reaction rate.
(c) (i) The above reaction is very slow at room temperature and pressure. Suggest
a reason for this phenomenon.
(ii) Fe(III) ions can be used as a catalyst to the reaction. Give a balanced
equation for the reaction between Fe(III) ions and iodide ions.
(iii) Explain how peroxodisulphate ions can be reduced to sulphate ions. Write a
balanced equation for the reaction involved.
(iv) Hence state two properties of a catalyst.
(d) Give the names of the catalysts used in the following processes.
(i) Manufacture of cheese
(ii) Contact process
(iii) Decomposition of hydrogen peroxide
[14M]
Section 39.7
41
Consider the following reaction:
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Time
Temperature (C)
37
80
100
(b)
(c)
(d)
(e)
43
Catalysts have characteristic effects in chemical reactions and they are important in
modern chemistry. Answer the following questions about catalysts.
(a) What is a catalyst?
(b) Explain why the iron used in Haber process should be finely divided?
(c) Name the catalyst used in Contact process. Give the oxidation state of the metal
in this catalyst.
(d) A student made the following statement about enzyme:
Browning of some fruits and vegetables is caused by the presence of enzymes
produced by the cells. These enzymes react with ingredients of the fruits and
vegetables to form a brown substance.
Comment on his statement.
(e) Give TWO applications of enzyme in industry.
[11M]
Chemistry: Chapter 40 Molar volume of gases at room temperature and pressure
(r.t.p.)
Sections 40.140.2
44
The following graph represents the results of three experiments involving the reaction
of magnesium and dilute hydrochloric acid.
101
1
3
Time (s)
Answer the following questions, giving a reason for each of your answers.
(a) Which experiment has the highest initial rate?
(b) Which experiment uses the most concentrated acid?
(c) Which experiment produces the largest volume of gas?
(d) Given that magnesium was used in excess, V cm3 of M mol dm3 hydrochloric
acid was used in Experiment 2 at 25C.
(i)
M
mol dm3, in terms of V,
2
needed in Experiment 3.
(ii) Suggest TWO suitable conditions for Experiment 1.
[10M]
45
Consider the following reaction:
2H 2 O 2 (aq) 2H 2 O(l) + O 2 (g)
(a) Oxygen can be prepared by the catalytic decomposition of hydrogen peroxide.
This reaction is catalysed by manganese(IV) oxide.
(i) Explain the term decomposition.
(ii) Given that manganese(IV) oxide increases the rate of reaction, state the
criteria to be fulfilled to show that it is a catalyst for this reaction.
(iii) Draw the set-up that could be used to prepare and collect oxygen produced
by the decomposition of hydrogen peroxide.
(b) At room temperature and pressure, 100 cm3 of 2.0 M hydrogen peroxide
decomposed in the presence of a catalyst.
(i) Calculate the number of moles of hydrogen peroxide in 100 cm3 of 2.0 M
hydrogen peroxide.
(ii) Calculate the number of moles of oxygen (O 2 ) formed.
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103
Time (s)
3
10
15
20
25
30
35
10
15
18
19
20
20
20
104
Volume of O 2 (cm3)
Time (min)
(a) Calculate the initial rate (in cm3 min1) of oxygen gas consumed in the reaction.
(b) Calculate the average rate (in cm3 min1) of oxygen gas consumed in the
reaction.
(c) (i) What was the total volume of gases when the reaction was complete?
(ii) Calculate the overall percentage change of volume of the gases in the
reaction.
[7M]
54
Hydrogen peroxide decomposes at r.t.p. according to the following equation:
2H 2 O 2 (aq) 2H 2 O(l) + O 2 (g)
(a) Describe ONE method to determine the rate of the above reaction.
(b) At the end of the reaction, 100 cm3 of 1.0 M hydrogen peroxide solution gives
oxygen of percentage yield 86.7%. Calculate the volume of oxygen produced in
cm3.
(c) Name a catalyst for this reaction.
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[7M]
Section 40.3
55
Sulphur dioxide is usually found in the exhaust gas produced by combustion of fossil
fuels. It is one of the major sources of acid rain which causes corrosion to objects
containing calcium carbonate.
(a) Write the chemical equation(s) to explain the formation of acid rain by sulphur
dioxide.
(b) Write a chemical equation to explain the corrosion of marble by acid rain.
(c) It is found that 1600 dm3 of sulphur dioxide at r.t.p. is produced by a car every
day. If all the amount of sulphur dioxide produced is involved in the formation of
acid rain, calculate the mass of calcium carbonate corroded by the acid rain
containing such amount of sulphur dioxide.
[7M]
56
Hydrocarbons undergo complete combustion to give carbon dioxide under sufficient
oxygen supply. Toxic carbon monoxide is produced if the oxygen supply is
insufficient. Catalytic converters are usually installed in vehicles to minimize the
emission of carbon monoxide in exhaust gas.
(a) (i) Balance the following equation:
CH 3 CH 2 CH 3 (g) + O 2 (g) CO 2 (g) + CO(g) + H 2 O(l)
(ii) Suppose 4.95 g of propane (CH 3 CH 2 CH 3 ) gas is introduced. What is the
volume of carbon monoxide produced at r.t.p. from the above incomplete
combustion?
(b) Inside the converter, carbon monoxide is converted to carbon dioxide in the
presence of oxygen. Write a chemical equation for the reaction involved.
(c) (i) What is the volume of oxygen required at r.t.p. to remove the amount of
carbon monoxide calculated in part (a)(ii)?
(ii) Express the amount of oxygen required in g.
[8M]
57
The operation of automobile airbags depends on the rapid decomposition of sodium
azide, NaN 3 , to its elements.
(a) Write a balanced equation for this decomposition.
(b) If an airbag has a volume of 5.20 104 cm3, calculate the number of moles of
nitrogen gas required to fill it at room temperature and pressure.
(c) Calculate the mass of sodium azide needed to provide such volume of nitrogen.
(d) If the decomposition is complete in 40 ms, calculate the average rate of
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29
44
53
59
60
60
(a) Draw an experimental set-up which is suitable for carrying out this experiment.
(b) Plot a graph of volume of hydrogen gas against time. Label the curve as X.
(c)
(d)
(e)
(f)
107
108
63
The Castle Peak power station burns about 25 000 tonnes of coal each day. The coal
contains 0.6% by mass of sulphur.
(a) Calculate the mass of sulphur burnt each day.
(b) The sulphur burns in oxygen to give sulphur dioxide. Write an equation for the
reaction.
(c) Calculate the
(i) mass;
(ii) volume of sulphur dioxide produced each day from the power station at
r.t.p..
(1 tonne = 1 106 g; molar volume of any gas at r.t.p. = 24.0 dm3 mol1.)
[6M]
64
In Brazil, the fuels used in cars are blended with alcohol. Assume that a fuel contains
75% by mass of octane (C 8 H 18 ) and 25% by mass of ethanol (C 2 H 5 OH), and water
vapour is formed after combustion.
(a) Write balanced equations for the combustion of octane and ethanol.
(b) Calculate the volume of oxygen required to completely burn 100 g of the fuel at
r.t.p.
[5M]
65
Ammonia is manufactured by Haber Process industrially.
N 2 (g) + 3H 2 (g)
2NH 3 (g)
An excess amount of N 2 (g) and 72.0 cm3 of H 2 (g) were reacted at r.t.p.
(a) Calculate the number of moles of N 2 (g) used for complete production of NH 3 (g).
(b) Calculate the volume of NH 3 (g) produced.
(c) Do you think the value you calculated in (b) can be obtained in a school
laboratory? Give a reason for your answer.
[6M]
66
0.70 g of magnesium ribbon was added to a beaker containing excess 0.50 M H 2 SO 4
at r.t.p.
(a) State ONE observation of the reaction.
(b) Write a balanced equation for the reaction.
(c) A student claimed that there was not enough information to calculate the volume
of gaseous product. State whether he is correct or not. If he is correct, state what
other information is needed. If he is incorrect, calculate the volume of the
gaseous product.
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[5M]
67
The major components of town gas are hydrogen and methane, which are made from
naphtha, C 5 H 12 . Naphtha reacts with steam to form carbon monoxide and hydrogen.
These two gases further react to form methane.
(a) Write balanced equations for the manufacture of hydrogen and methane.
(b) Find the mass and volume (at room temperature and pressure) of methane
formed when 2.8 g of CO and 1.5 g of H 2 are allowed to react.
(c) When town gas is passed over heated iron(III) oxide, iron is formed.
(i) Write a balanced equation to show the reaction involved.
(ii) Calculate the volume of H 2 , measured at room temperature and pressure,
that would be needed in the complete reduction of 100 g of iron(III) oxide.
(iii) Calculate the volume of town gas, measured at room temperature and
pressure, used in the above reduction, assuming that town gas contains 49%
of H 2 by volume.
[11M]
68
100 cm3 of ammonia was reacted with excess copper oxide at room temperature and
pressure. Copper and a gaseous product are formed at the end of the experiment.
(a) Write a balanced equation to show the reaction involved.
(b) Calculate
(i) the number of moles of ammonia used.
(ii) the volume of the gaseous product formed.
(c) Calculate the mass of copper oxide reacted with ammonia.
(d) Calculate the number of copper atoms reacted.
[7M]
69
Dilute nitric acid reacts with copper to produce nitrogen monoxide.
(a) Write a balance equation for the reaction.
(b) Calculate the volume of nitrogen monoxide obtained by the complete reaction of
100 g of copper with excess dilute nitric acid at room temperature and pressure.
(c) Calculate the number of copper atoms reacted.
(d) Nitrogen monoxide is colourless. However, during the reaction, a brown gas was
evolved.
(i) Explain the above phenomenon with a proper chemical equation.
(ii) Calculate the volume of nitrogen monoxide needed to produce 500 cm3 of
the brown gas.
(iii) Calculate the volume of air, measured at room temperature and pressure,
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