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3, AFS, BHISIANA
CHEMISTRY -X11
Time allowed 3 hours
Max. marks 70
General Instructions:
(i)
(ii)
Q.no. 1-8 are very short answer question & carry 1 mark each
(iii)
Q.no. 9-18 are short answer question & carry 2 marks each
(iv)
Q.no. 19-27 are short answer question & carry 3 marks each
(v)
Q.no. 28-30 are long answer question & carry 5 marks each
(vi)
14. Write the mechanism of dehydration of ethyl alcohol with the help of conc. H 2SO4 to give
alkene.
15. Complete the following reactions:
Cl
(i)
Conc. H2SO4
+ HNO3( conc.)
(ii)
C2H5Cl + AgCN
OR
The decomposition of Cl2O7 at 400 K in a gas phase to Cl2 and O2 is the first order reaction.
(i)After 50 seconds the pressure of Cl2O7 falls from 0.062 to 0.044 mm.Calculate the rate
constant.
(ii)Calculate the pressure of Cl2O7 after 100 seconds of decomposition at this temperature.
25.(a)Why alkyl halides have high boiling points than corresponding alkanes?
(b)Which has higher boiling point and why ?(i)n-butyl chloride (ii) secondary butyl chloride
(c) Why are aryl halides less reactive than alkyl halide towards nucleophilic substitution
reaction .
26.(a)Arrange the following in increasing order of bond angle.
(i)NH3 ,PH3,AsH3 ,SbH3,BiH3
(b)
OR
(a) Why is V2O3 strongly reducing agent ?
(b) What is the value of spin only magnetic moment for d4 in strong field?
(c) What happens when alkaline KMnO4 reacts with iodide ions in reaction?
(d) What is the general electronic configuration of lanthanoides?