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3.0HRT-3-2013(ACEG)[1]
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Vidyamandir ClassesVMC/JEE-2013 1 3.0HRT - 3/ACEG
Aggarwal Corporate Heights, 3rd Floor, Plot No. A - 7, Netaji Subhash
Place,Pitam Pura, Delhi - 110034 Phone: 011-45221190 - 93. Fax : 25222953
30/11/2011
3.0HRT - 3/IITJEE - 2013
M.M. : 22503:00 P.M. - 06:00 P.M.
TEST CODE : ACEG
TIME : 3.00 Hrs
1. The question paper contains 75 questions and has 3 parts : (Part I: Chemistry, Part - II: Physics,Part - III: Mathematics) of 25 questions
and 3 marks each.2.
Each question has
Only One choice correct
. You will be given
3 marks
corresponding to the correct answer and
minus one (1) marks (NEGATIVE MARKING)

for every wrong answer.


PART - I
CHEMISTRY
1.
Pure ammonia is placed in a vessel at a temperature where its dissociation
constant is appreciable.At equilibrium.
(A)
K
p
does not change significantly with pressure
(B)

does not change with pressure


(C)
Concentration of NH
3
does not change with pressure
(D)
Concentration of H
2
is less than that of N
2
2.
The equilibrium SO
2
Cl
2
(g)

SO
2
(g) + Cl
2
(g) is attained at25C

in a closed container and an inert gas,helium, is introduced. Which of the


following statement is correct ?
(A)
Concentrations of SO
2
, Cl
2
and SO
2

Cl
2
change
(B)
More Cl
2
is formed
(C)
Concentration of SO
2
is reduced
(D)
None of these
SPACE FOR ROUGH WORK

Vidyamandir ClassesVMC/JEE-2013 2 3.0HRT - 3/ACEG


3.
The decomposition of N
2
O
4
into NO
2
is carried out at 280K in chloroform. When equilibrium has beenestablished
0.2 mole of N
2
O
4
and
3

210

mole of NO
2
are present in 2 litres of solution. The equilibriumconstant for the reaction
242
N
O
2
N
O

is :
(A)
2
110

(B)
3
210

(C)
5
110

(D)
5
210

4.
If pressure is applied to the equilibrium system of solid

liquid, the melting point of the solid


(A)
will not change
(B)
may increase or decrease depending upon its nature
(C)
will always increase
(D)
will always decrease
5.
A buffer solution is prepared in which the concentration of NH

3
is 0.30 M and the concentration of
4
NH

is0.20 M. What is the pH of this solution ? (The equilibrium constant K


b
for NH
3
equals
5
1 . 8 1 0

)
(A)
8.73
(B)
9.08
(C)
9.43
(D)
11.72
6.
K
a
for hydrofluoric acid is
4
6 . 9 1 0

. What is K
C
for this reaction ?

2
F
(
a
q
)
H
O
(
)
H
F
a
O
H
(
a
q
)

(A)
11
6 .


(B)
11
1 . 4 1 0

(C)
9
2 . 6 1 0

(D)
6
8 . 3 1 0

7.
The dissociation constant K
a
of a weak monobasic acid is
7
10

. What is the approximate pH of a 0.1 M solutionof the acid ?


(A)
1
(B)
2
(C)
3
(D)
4
8.
For a certain temperature the chemical reaction represented by the following
equation has an equilibriumconstant of 4.
222
C
O
(
g
)
H
O
(
g
)
C
O
(
g
)
H
(
g
)

A mixture initially containing one mole of each of CO and steam is allowed


to reach equilibrium. How manymoles of CO are now present ?
(A)
1/4
(B)
1/3

(C)
1/2
(D)
2/3
9.
One mole of a compound AB reacts with one mole of a compound CD
according to the
equation,A
B
C
D
A
D
C
B

. When equilibrium had been established, it was found that 3/4 mole each of
reactantAB and CD had been converted to AD and CB. There is no change in
volume. The equilibrium constant for thereaction is :
(A)
916
(B)
19
(C)
169
(D)
9
SPACE FOR ROUGH WORK

Vidyamandir ClassesVMC/JEE-2013 3 3.0HRT - 3/ACEG


10.
When 25 g of MCO
3
(s) were enclosed in a 10 litre evacuated flask heated to
7 2 7 C 8 0 %

of MCO
3
gotdecomposed into solid MO (Molecular weight = 56) and CO

2
(g). K
p
for the decomposition of MCO
3
is :
(A)
1.642 atm
(B)
3.91 atm
(C)
0.631 atm
(D)
4.261 atm
11.
Which of the following solution cannot function as a buffer when mixed in
equal volume ?
(A)
0.1 M HCl mixed with 0.2 M NH
4
OH.
(B)
0.2 M CH
3
CO
2
H mixed with 0.1 M NaOH.
(C)
0.1 M NaOH mixed with 0.1 MH
2
CO
3
.
(D)
0.1 M CH
3
CO
2
H mixed with 0.1 MNH
4
OH.
12.
A 0.1 M solution of acetic acid is titrated with a 0.05M solution of NaOH.
What is the pH when60%of theacid has been neutralized ? (pKa of CH
3
COOH = 4.74, log 2 = 0.3, log 3 = 0.48)

(A)
2.38
(B)
4.56
(C)
4.92
(D)
7
13.
Ka for HCN is
10
510

at25C

. For maintaining a constant pH = 9, the volume of 5 M KCN solutionrequired


to be added to 10 ml of 2M HCN solution is :
(A)
4 ml
(B)
7.95 ml
(C)
2 ml
(D)
9.3 ml
14.
The oxidation state(s) of Cl in CaOCl
2
(bleaching powder) is/are :
(A)
+ 1 only
(B)
1

only
(C)
1 a n d

(D)
None of these
15.
3
610


mole K
2
Cr
2
O
7
reacts completely with
3
910

mole X
n+
to give
33
X O a n d C r

. The value of n is :
(A)
1
(B)
2
(C)
3
(D)
None of these
16.
If m
A
gram of a metal A displaces m
B
gram of another metal B from its salt solution and if the equivalentweights
are E
A
and E
B
respectively then equivalent weight of A can be expressed as :
(A)
AABB
mEEm

(B)
ABAB
mmEE

(C)
BABA
mEEm

(D)
AABB
mEEm

17.
In a chemical reaction, K
2
Cr
2
O
7
+ xH
2
SO
4
+ ySO
2

K
2
SO
4
+ Cr
2
(SO
4
)
3
+ zH
2
O ; the value of x, y and zrespectively are :
(A)
x = 1, y = 3, z = 1
(B)
x = 4, y = 1, z = 4
(C)
x = 3, y = 2, z = 1
(D)
x = 2, y = 2, z = 1
SPACE FOR ROUGH WORK

Vidyamandir ClassesVMC/JEE-2013 4 3.0HRT - 3/ACEG


18.
Hydrazine reacts with KIO
3
in presence of HCl as :
2
4
3
2
2
N
H
I
O
2
H
I
C
l
N
3
H

C
O

The equivalent masses of N


2
H
4
and KIO
3
respectively are :
(A)
8 and 53.5
(B)
16 and 53.5
(C)
8 and 35.6
(D)
8 and 87
19.
The ratio of moles of Fe (II) oxidized by equal volumes of equimolar KMnO
4
and K
2
Cr
2
O
7
solutions in acidicmedium will be :
(A)
5:3
(B)
1:1
(C)
1:2
(D)
5:6
20.
Dichromate ion in acidic medium oxidizes stannous ion as :
2
2
4
3
272
x
S
n
y
C
r
O
z
H
a
S
n
b
C
r
c
H
O

The incorrect statement is :


(A)
the value of
x : y i s 1 : 3

(B)
the value of x + y + z is 18
(C)
a : b i s 3 : 2
(D)
the value of
z
c
i
s
7

21.
pK
b
of NH
4
OH is 4.74 and pK
b
o f
A , B , C a n d D

are 3, 4, 5, 6 respectively. An aqueous solution of 0.01M


increasing order :
(A)
4
4
4
N
H
A
N
H
B
N
H
C

(B)
4
4
4
N
H
D
N
H
B
N
H
C

(C)
4
4
4
N
H
D
N
H
C
N
H
B

(D)
None of these
22.
Equilibrium constant of the reaction is

has pH in given
4
N

D
4

A
4

7
3 .

2
O
C
l
(
O
H
(
a

. What is the K
a
for HOCl ?
(A)
8
2 . 8 1 0

(B)
7
3 . 6 1 0

(C)
4
610

(D)
6
2 . 8 1 0

23.
The pH of 0.1M
(A)
4
N a C l

(B)
4
H C l N

(C)
4
N a C N

a
q

q
)

solution of the following salts increases in the order.


N


(D)
4
H C l N a C l N a C N N H C l

24.
Which of the following will not show common ion effect on addition of HCl ?
(A)
CH
3
COOH
(B)
H
2
S
(C)
C
6
H
5
COOH
(D)
H
2
SO
4
25.
10 ml of a strong acid solution of pH = 2.000 are mixed with 990 ml of
another strong acid solution of pH = 4.000 of. The pH of the resulting
solution will be :
(A)
4.002
(B)
4.000
(C)
4.200
(D)
3.72
SPACE FOR ROUGH WORK

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