Chemistry 5
Chapter-6
Gases Part-2
7 October 2002
Some Cool Chemistry Research
Prof. H. Park & Group
HongkunPark
In many instances, several properties of gas change at once. To analyze, consider following:•initial: P
i
V
i
= n
i
RT
i
•final: P
f
V
f
= n
f
RT
f
Example, calculate the volume of a helium balloon, which is used to carry instruments into the upper atmosphere, if the initial volume is 1x10
6
L, T= 300 K & P=1 atm, and final T=240 K & P=0.1 atm.
General Gas Equation
R = P
i
V
i
/n
i
T
i
P
i
V
i
/n
i
T
i
= P
f
V
f
/n
f
T
f
, general gas eqn.P
i
V
i
/n
i
T
i
= P
f
V
f
/n
f
T
f
n
i
= n
f
, unless there’s a leak!V
f
= (P
i
V
i
/T
i
)(T
f
/P
f
)= (P
i
/P
f
)(T
f
/T
i
)V
i
= (1/0.1)(240/300)1x10
6
L=
8x10
6
L
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